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Magnetochemistry, Volume 9, Issue 3

2023 March - 29 articles

Cover Story: The TMTSF cation constituted the first organic superconductor, reported in 1980. It is interesting to investigate the effect of 4f electrons on the conductivity properties of TMTSF cations. The 4f electrons have large anisotropic magnetic moments due to strong spin-orbital coupling. The use of the polyvalent 4f metal complex as a counter-anion also indicates a different degree of conduction band filling in the radical of TMTSF molecules, compared to that of monovalent anions such as PF6, Cl, I. In this work, a new molecular conductor of (TMTSF)5[Dy(NCS)4(NO3)2]CHCl3 was prepared by the electrochemical oxidation method. The crystal shows anisotropic one-dimensional semiconducting behavior with a room temperature conductivity of 0.2 S·cm−1 and an activation energy of 34 meV at ambient pressure. View this paper
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Articles (29)

  • Article
  • Open Access
1 Citations
2,001 Views
24 Pages

Investigation of the Prospects for the Use of Iron-Containing Nanocomposites Doped with Rare Earth Elements as Catalysts for the Purification of Aqueous Media

  • Kayrat K. Kadyrzhanov,
  • Artem L. Kozlovskiy,
  • Kamila B. Egizbek,
  • Sholpan N. Kubekova,
  • Inesh E. Kenzhina and
  • Maxim V. Zdorovets

The great interest in nanostructured magnetic composites is due to their great prospects for use as a basis for the development of catalysts for the adsorption of manganese in wastewater. Interest in magnetic nanocomposites in this direction is prima...

  • Article
  • Open Access
5 Citations
2,378 Views
20 Pages

The conventional ultrasonic thickness measurement method is ineffective in detecting the measured specimen with a step change in thickness as it is easy to cause multimode acoustic mixing in the ultrasonic detection process. To solve this problem, th...

  • Article
  • Open Access
4 Citations
2,257 Views
13 Pages

Magnetic and Transport Anomalies and Large Magnetocaloric Effect in Cubic R4PtAl (R = Ho and Er)

  • Kartik K. Iyer,
  • Sudhindra Rayaprol,
  • Ram Kumar,
  • Shidaling Matteppanavar,
  • Suneel Dodamani,
  • Kalobaran Maiti and
  • Echur V. Sampathkumaran

We report the electronic properties of R4PtAl (R = Ho, and Er), which contains three sites for R, by the measurements of magnetization (ac and dc), heat-capacity, transport, and magnetoresistance (MR). Dc magnetization data reveal antiferromagnetic o...

  • Article
  • Open Access
4 Citations
2,932 Views
13 Pages

The purpose of this study was to apply functionalized magnetic nanoparticles for the treatment of amyloidosis, a disease characterized by the accumulation of aberrant protein forms with an insoluble amyloid structure. The dissolution and clearance of...

  • Feature Paper
  • Article
  • Open Access
2 Citations
1,880 Views
14 Pages

The relativistic effects of the values of the shielding constants of 1H, 13C, 15N, 57Fe, 59Co, 61Ni, 105Pd, and 195Pt nuclei were studied at the four-component relativistic level and were compared to the results of non-relativistic calculations perfo...

  • Article
  • Open Access
1 Citations
2,044 Views
17 Pages

Magnetic Inversion and Regional Tectonics of the Dabie Orogen

  • Liang Zhang,
  • Guangyin Lu,
  • Ziqiang Zhu,
  • Shujin Cao,
  • Yajing Mao,
  • Xinyue Chen and
  • Lichang Wang

Physical property inversion techniques are the methods to reveal the internal structures of Earth’s lithosphere. In this study, we introduce an Occam-type inversion algorithm into a spherical coordinate system, and invert the magnetization base...

  • Article
  • Open Access
28 Citations
3,388 Views
13 Pages

Preparation of Magnetic Iron Oxide Incorporated Mesoporous Silica Hybrid Composites for pH and Temperature-Sensitive Drug Delivery

  • Madhappan Santhamoorthy,
  • Kokila Thirupathi,
  • Selvakumar Krishnan,
  • Loganathan Guganathan,
  • Sushma Dave,
  • Thi Tuong Vy Phan and
  • Seong-Cheol Kim

In clinical applications for cancer treatment, chemotherapy coupled with thermotherapy is highly considered. The development of multifunctional nanocomposite materials is an appealing strategy for use in various applications including biomedical appl...

  • Feature Paper
  • Review
  • Open Access
3 Citations
6,058 Views
21 Pages

Magnetic Switchability via Thermal-Induced Structural Phase Transitions in Molecular Solids

  • Shan-Nan Du,
  • Chan-Ying Yao,
  • Jun-Liang Liu and
  • Ming-Liang Tong

Magnetically switchable molecular solids with stimuli-responsive ON/OFF characteristics are promising candidates for smart switches and magnetic storage. In addition to conventional spin-crossover/charge-transfer materials whose magnetic responses ar...

  • Article
  • Open Access
7 Citations
3,375 Views
13 Pages

Interventional biopsy needles need to be accurately localized to the target tissue during magnetic resonance imaging (MRI) interventions. In this context, severe susceptibility artifacts affect the visibility of structures in the MR images depending...

  • Article
  • Open Access
2 Citations
2,265 Views
12 Pages

Antiferromagnetism and Structure of Sr1−xBaxFeO2F Oxyfluoride Perovskites

  • Crisanto A. Garcia-Ramos,
  • Kiril Krezhov,
  • María T. Fernández-Díaz and
  • José A. Alonso

Recently, a series of oxyfluorides, Sr1−xBaxFeO2F with x = 0, 0.25, 0.50, and 0.75 obtained through a novel synthesis route, were characterized by X-ray and neutron powder diffraction (NPD), magnetization measurements, and 57Fe Mössbauer s...

  • Communication
  • Open Access
4 Citations
3,316 Views
11 Pages

A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex

  • Qingyun Wan,
  • Masanori Wakizaka,
  • Haitao Zhang,
  • Yongbing Shen,
  • Nobuto Funakoshi,
  • Chi-Ming Che,
  • Shinya Takaishi and
  • Masahiro Yamashita

A new molecular conductor of (TMTSF)5[Dy(NCS)4(NO3)2]CHCl3 was prepared using the electrochemical oxidation method. The complex crystallizes in the Cmc21 (36) space group, where the partially-oxidized TMTSF molecules form a 1D (one-dimensional) colum...

  • Article
  • Open Access
5 Citations
2,836 Views
10 Pages

We have studied the magnetic properties of ion doped MnFe2O4 nanoparticles with the help of a modified Heisenberg model and Green’s function theory taking into account all correlation functions. The magnetization Ms and the Curie temperature TC...

  • Study Protocol
  • Open Access
10 Citations
3,972 Views
23 Pages

Through inductive coupling, AC transmission lines can generate large amounts of voltage to buried oil and gas pipelines in areas with common corridors, posing a threat to the cathodic protection effect of pipelines. Therefore, this paper investigates...

  • Article
  • Open Access
2 Citations
2,445 Views
13 Pages

Zirconia ceramics are prominent engineering materials and are widely used in computers, consumer electronics, and the fifth-generation communication industry. However, zirconia ceramics are a typical hard-to-cut material, and the product structures a...

  • Review
  • Open Access
7 Citations
5,696 Views
28 Pages

Interacting with Futuristic Topological Quantum Materials: A Potential Candidate for Spintronics Devices

  • Prashant Kumar,
  • Ravi Kumar,
  • Sanjeev Kumar,
  • Manoj Kumar Khanna,
  • Ravinder Kumar,
  • Vinod Kumar and
  • Akanksha Gupta

Spintronics, also known as magneto-electronics or spin transport electronics, uses the magnetic moment of the electron due to intrinsic spin along with its electric charge. In the present review, the topological insulators (2D, 3D, and hydride) were...

  • Article
  • Open Access
1,818 Views
10 Pages

Nowadays, modern scientific research has sparked a renewed interest to study the interaction of electromagnetic field (EM) with magnetic nanostructures and in particular in nanophotonics and spintronics. The current work is devoted to an ab initio st...

  • Article
  • Open Access
4 Citations
2,517 Views
13 Pages

μSR Study of Unconventional Pairing Symmetry in the Quasi-1D Na2Cr3As3 Superconductor

  • Amitava Bhattacharyya,
  • Devashibhai Adroja,
  • Yu Feng,
  • Debarchan Das,
  • Pabitra Kumar Biswas,
  • Tanmoy Das and
  • Jun Zhao

We report the finding of a novel pairing state in a newly discovered superconductor Na2Cr3As3. This material has a non-centrosymmetric quasi-one-dimensional crystal structure and is superconducting at TC 8.0 K. We find that the magnetic penetrat...

  • Article
  • Open Access
9 Citations
3,132 Views
13 Pages

Delivery of dCas9 Activator System Using Magnetic Nanoparticles Technology as a Vector Delivery Method for Human Skin Fibroblast

  • Mahdi Mohammadi Ghanbarlou,
  • Shahriyar Abdoli,
  • Hamed Omid,
  • Leila Qazizadeh,
  • Hadi Bamehr,
  • Mozhgan Raigani,
  • Hosein Shahsavarani,
  • Morteza Karimipour and
  • Mohammad Ali Shokrgozar

The overexpression of stem cell-related genes such as octamer-binding transcription factor 4 (OCT4) and (sex determining region Y)-box 2 (SOX2) has been indicated to play several critical roles in stem cell self-renewal; moreover, the elevation of th...

  • Article
  • Open Access
1 Citations
2,324 Views
11 Pages

Polymetallic complexes with covalently bridged metal centers that interact magnetically are important in the molecular magnetism field, with binuclear compounds receiving special attention because they represent the simplest type of multinuclear spec...

  • Article
  • Open Access
6 Citations
3,547 Views
17 Pages

Magnetic Hyperthermia and Antibacterial Response of CuCo2O4 Nanoparticles Synthesized through Laser Ablation of Bulk Alloy

  • Imran Ali,
  • Yasir Jamil,
  • Saeed Ahmed Khan,
  • Yunxiang Pan,
  • Aqeel Ahmed Shah,
  • Ali Dad Chandio,
  • Sadaf Jamal Gilani,
  • May Nasser Bin Jumah,
  • Yusra Fazal and
  • Zhonghua Shen
  • + 1 author

The wide variety of uses for nanoparticles (NPs) is due to their unique combination of features in a single assembly. The arc melted copper-cobalt ingot sample were qualitatively studied using laser induced breakdown spectroscopy (LIBS). Later, using...

  • Article
  • Open Access
5 Citations
2,740 Views
17 Pages

Fluorescent Magnetic Mesoporous Nanoprobes for Biotechnological Enhancement Procedures in Gene Therapy

  • Manuel A. González-Gómez,
  • Román Seco-Gudiña,
  • Pelayo García-Acevedo,
  • Ángela Arnosa-Prieto,
  • Lisandra de Castro-Alves,
  • Yolanda Piñeiro and
  • José Rivas

In recent years, nanotechnology has deployed a new set of theragnostic tools, including magnetic resonance contrast agents, nano-delivery systems and magnetic hyperthermia treatments in cancer therapy, exploiting not only the small size of nanopartic...

  • Feature Paper
  • Article
  • Open Access
7 Citations
3,202 Views
13 Pages

NMR of Paramagnetic Proteins: 13C Derived Paramagnetic Relaxation Enhancements Are an Additional Source of Structural Information in Solution

  • Leonardo Querci,
  • Inês B. Trindade,
  • Michele Invernici,
  • José Malanho Silva,
  • Francesca Cantini,
  • Ricardo O. Louro and
  • Mario Piccioli

In paramagnetic metalloproteins, longitudinal relaxation rates of 13C′ and 13Cα nuclei can be measured using 13C detected experiments and converted into electron spin-nuclear spin distance restraints, also known as Paramagnetic Relaxation...

  • Article
  • Open Access
19 Citations
4,425 Views
13 Pages

A Strong Magnetic Field Alters the Activity and Selectivity of the CO2RR by Restraining C–C Coupling

  • Peichen Wang,
  • Yafei Qu,
  • Xiangfu Meng,
  • Jinwei Tu,
  • Wei Zheng,
  • Lin Hu and
  • Qianwang Chen

As an external field, a magnetic field can change the electrocatalytic activity of catalysts through various effects. Among them, electron spin polarization on the catalyst surface has attracted much attention. Herein, we investigate the sensitive re...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,541 Views
9 Pages

Superconductivity and Fermi Surface Studies of β-(BEDT-TTF)2[(H2O)(NH4)2Cr(C2O4)3]·18-Crown-6

  • Brett Laramee,
  • Raju Ghimire,
  • David Graf,
  • Lee Martin,
  • Toby J. Blundell and
  • Charles C. Agosta

We report rf-penetration depth measurements of the quasi-2D organic superconductor β-(BEDT-TTF)2[(H2O)(NH4)2Cr(C2O4)3]·18-crown-6, which has the largest separation between consecutive conduction layers of any 2D organic metal with...

  • Review
  • Open Access
14 Citations
4,351 Views
15 Pages

Application of Electron Paramagnetic Resonance in an Electrochemical Energy Storage System

  • Xiancheng Sang,
  • Xixiang Xu,
  • Zeyuan Bu,
  • Shuhao Zhai,
  • Yiming Sun,
  • Mingyue Ruan and
  • Qiang Li

The improvement of our living standards puts forward higher requirements for energy storage systems, especially rechargeable batteries. Unfortunately, phenomena such as capacity failure, etc. have been major difficulties in the field of energy storag...

  • Feature Paper
  • Article
  • Open Access
4 Citations
2,174 Views
11 Pages

A DyIII Complex of a Pentadentate Schiff Base with Field-Induced Single-Ion Magnet Behaviour

  • Julio Corredoira-Vázquez,
  • Paula Oreiro-Martínez,
  • Ana M. García-Deibe,
  • Jesús Sanmartín-Matalobos and
  • Matilde Fondo

The influence of the solvent in the reaction of dysprosium(III) chloride hydrate with the N3O2 ligand H2L (2,6-bis(2-hydroxyphenyliminomethyl)pyridine) was studied To this end, the new mononuclear chloride complex [Dy(L)Cl(H2O)2] (1) was isolated in...

  • Article
  • Open Access
3 Citations
2,346 Views
14 Pages

Surface-Bulk 2D Spin-Crossover Nanoparticles within Ising-like Model Solved by Using Entropic Sampling Technique

  • Catherine Cazelles,
  • Mamadou Ndiaye,
  • Pierre Dahoo,
  • Jorge Linares and
  • Kamel Boukheddaden

We model the thermal effects in different 2D spin-crossover (SCO) square lattices within the frame of the Ising-like model using Monte Carlo entropic sampling (MCES) method to enhance the scan of macrostates beyond the most probable thermal ones. In...

  • Article
  • Open Access
6 Citations
2,584 Views
15 Pages

A MoNx coating serves as an effective wear protection layer and is crucial for the investigation of its tribological characteristics at various temperatures. This study examined the tribological characteristics of MoNx coatings that were deposited th...

  • Article
  • Open Access
4 Citations
3,046 Views
15 Pages

Photothermal Hyperthermia Study of Ag/Ni and Ag/Fe Plasmonic Particles Synthesized Using Dual-Pulsed Laser

  • Imran Ali,
  • Jun Chen,
  • Saeed Ahmed Khan,
  • Yasir Jamil,
  • Aqeel Ahmed Shah,
  • Abdul Karim Shah,
  • Sadaf Jamal Gilani,
  • May Nasser Bin Jumah,
  • Yusra Fazal and
  • Zhonghua Shen
  • + 1 author

Magneto-plasmonic Ag/Ni and Ag/Fe nanoparticles (NPs) were synthesized in this work using the environmentally safe and contaminant-free dual-pulsed Q-switched Nd:YAG 1064 nm laser ablation method. The optical and magnetic characteristics of synthesiz...

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Magnetochemistry - ISSN 2312-7481