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Crystals, Volume 9, Issue 4

April 2019 - 44 articles

Cover Story: Lanthanum’s d-electrons are more delicious than gallium’s p-electrons! Zintl phases may be oxidized by reaction with gaseous hydrogen, thereby forming hydrides. LaGa2 in the AlB2 type intercalates hydrogen atoms into La3Ga2 interstitials, which leads to the formation of a superstructure, reduction of La-d contribution at the Fermi level, and the opening of a small bandgap. Hydrogen thus prefers ‘eating up’ lanthanum’s d-electrons instead of reacting with the gallium polyanion like alkaline earth analogues AeGa2 do, which form covalent Ga–H bonds. View this paper
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Articles (44)

  • Review
  • Open Access
144 Citations
12,145 Views
16 Pages

25 April 2019

Vaterite is the least thermodynamically stable anhydrous calcium carbonate polymorph. Its existence is very rare in nature, e.g., in some rock formations or as a component of biominerals produced by some fishes, crustaceans, or birds. Synthetic vater...

  • Article
  • Open Access
18 Citations
4,600 Views
10 Pages

Adenine as a Halogen Bond Acceptor: A Combined Experimental and DFT Study

  • Yannick Roselló,
  • Mónica Benito,
  • Elies Molins,
  • Miquel Barceló-Oliver and
  • Antonio Frontera

25 April 2019

In this work, we report the cocrystallization of N9-ethyladenine with 1,2,4,5-tetrafluoro-3,6-diiodobenzene (TFDIB), a classical XB donor. As far as our knowledge extends, this is the first cocrystal reported to date where an adenine derivative acts...

  • Article
  • Open Access
25 Citations
5,726 Views
9 Pages

24 April 2019

The extensive research on photonic topological insulators has opened up an intriguing way to control electromagnetic (EM) waves. In this work, we numerically demonstrate reconfigurable microwave photon analogues of topological insulator (TIs) in a tr...

  • Article
  • Open Access
3 Citations
5,477 Views
12 Pages

24 April 2019

Two binuclear coordination compounds of Cu(II) chloride with the bitopic ligand 1,1,2,2-tetrakis(pyrazol-1-yl)ethane (Pz4) of the composition [Cu2(µ2-Pz4)(DMSO)2Cl4]·4H2O and [Cu2(µ2-Pz4)(DMSO)2Cl4]∙2DMSO were prepared and characte...

  • Article
  • Open Access
8 Citations
4,683 Views
10 Pages

Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles

  • Ryan J. Paull,
  • Tiffany Ly,
  • Zachary R. Mansley,
  • Kenneth R. Poeppelmeier and
  • Laurence D. Marks

23 April 2019

A general approach to the formation of well-faceted nanoparticles is discussed and successfully applied to the production of several rare-earth scandates. Two steps were used, with higher temperatures first to nucleate the perovskite phase, followed...

  • Article
  • Open Access
12 Citations
4,260 Views
12 Pages

Assembly of Imidazolyl-Substituted Nitronyl Nitroxides into Ferromagnetically Coupled Chains

  • Vasily Romanov,
  • Irina Bagryanskaya,
  • Nina Gritsan,
  • Dmitry Gorbunov,
  • Yulia Vlasenko,
  • Mehman Yusubov,
  • Elena Zaytseva,
  • Dominique Luneau and
  • Evgeny Tretyakov

23 April 2019

New nitronyl nitroxides, namely, 2-(4,5-dimethylimidazol-2-yl)- and 2-(4,5-dichloroimidazol-2-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyl, were prepared in crystalline form. According to single-crystal X-ray data, intra- and interm...

  • Article
  • Open Access
3 Citations
3,311 Views
15 Pages

22 April 2019

A series of three-dimensional numerical simulations were performed to understand the thermal-solutal capillary-buoyancy flow of Ge1-xSix melts during Czochralski crystal growth with a rotating crystal or crucible. The crystal and crucible rotation Re...

  • Article
  • Open Access
6 Citations
4,452 Views
9 Pages

Direct Amplification of High Energy Pulsed Laser in Fiber-Single Crystal Fiber with High Average Power

  • Feng Li,
  • Zhi Yang,
  • Zhiguo Lv,
  • Yang Yang,
  • Yishan Wang,
  • Xiaojun Yang,
  • Wei Zhao,
  • Qianglong Li and
  • Yufeng Wei

21 April 2019

A laser master oscillator power amplifier (MOPA) system consisting of a fiber amplifier and a two-stage Yb:YAG single crystal fiber (SCF) is experimentally studied. The nonlinear stimulated Raman scattering (SRS) is avoided by limiting the output pow...

  • Article
  • Open Access
6 Citations
4,248 Views
13 Pages

20 April 2019

Polymers are poor heat conductors, so the cooling of thick-walled shapes results in temperature gradients. Here, isotactic polypropylene (iPP) is chosen as a model polymer for the study of polymer crystallization in a temperature gradient field. The...

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Crystals - ISSN 2073-4352