A New Fuzzy Preference Relation (FPR) Approach to Prioritizing Drinking Water Hazards: Ranking, Mapping, and Operational Guidance
Abstract
1. Introduction
- -
- Nitrates (NO3−). In Central and Eastern Europe, the problem of nitrate pollution of water associated with intensive agriculture remains significant. Studies in Poland have shown that in some municipalities, concentrations in groundwater exceed 50 mg/L, increasing the risk of methemoglobinemia in infants (blue baby syndrome) [10]. Similar results have been reported in the Czech Republic and Hungary [11].
- -
- Lead (Pb). Lead contamination in drinking water is well documented, for example, in the Flint (USA) incident, where corrosion of old pipes led to neurotoxic exposure of thousands of children [12]. In Europe, the problem mainly concerns internal installations—studies in the United Kingdom have shown that in older buildings, Pb concentrations in water exceeded 10 μg/L [13].
- -
- Arsenic (As). The most well-known incidents of mass exposure concern Bangladesh and India, where tens of millions of people have been using groundwater with As concentrations reaching hundreds of μg/L for decades, resulting in an epidemic of skin and bladder cancer [14]. In Europe, the problem has been noted in southern Italy and Hungary, among other places, where geothermal waters naturally contain arsenic in concentrations above 10 μg/L [15,16].
- -
- Trihalomethanes (THMs). An analysis by Villanueva [17] covering 26 EU countries showed that approximately 6500 cases of bladder cancer per year (about 5% of the total) can be attributed to chronic exposure to THMs in drinking water, even in systems that comply with the 100 μg/L limit.
- -
- Manganese (Mn). Epidemiological studies in Canada and the USA have shown that chronic consumption of water with elevated manganese concentrations (above 100 μg/L) is associated with reduced cognitive ability in children [18].
- -
- Copper (Cu). Exceedances of acceptable values are recorded locally in highly corrosive water supply systems—chronic exposure can lead to hepatotoxicity and gastric problems [19].
- -
- Iron (Fe). In most cases, iron does not pose a health risk, but it is the cause of consumer complaints due to its colour, taste and sediment, and it can also promote the secondary growth of microorganisms in the network [6].
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- Water Quality Index (WQI). Many studies use WQI, a multi-parameter index that aggregates various variables (chemical, physicochemical, biological) into a single index value, which facilitates communication of the overall water status. For example, Luo et al. [20] used WQI together with multidimensional analysis to assess 17 drinking water parameters in the city of Nanning (China), including metals such as arsenic, lead and mercury [20].
- -
- Statistical and probabilistic methods. Other studies use classification and comparison methods, such as ranking or aggregation approaches, as well as probabilistic risk measures. In a study of the Douro River Basin (Portugal), the authors used various risk measures (mean, variance, exceedance probability, value at risk, etc.) and then merged the ranking of monitoring stations on this basis [21].
- -
- WQI with uncertainty analysis. Methods combining the classic WQI with uncertainty analysis are becoming increasingly common. Critical studies of the arbitrariness in the selection of weights indicate that the choice of parameters and their weights can significantly affect the final result and interpretation of water status. An example of this is analyses that have shown that different weighting schemes lead to different quality assessments [22].
2. Materials and Methods
2.1. Basics of the Research Methodology
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- trapezoidal function μ(x; a, b, c, d)
- -
- triangular function μ(x; a, b, c)
2.2. Prioritisation of Water Quality Parameters: Assumptions and Stages of the Method (FPR–FPI)
2.2.1. Stage 1. Selection of Parameters for Analysis
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- health significance (toxicity, carcinogenic potential, impact on sensitive groups),
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- frequency of occurrence in water supply systems,
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- technological/operational consequences (colour, sediments).
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- highest priority (rank 5): parameter with the highest priority due to carcinogenicity and neurotoxicity, with proven health effects even with chronic low exposure (e.g., arsenic, lead).
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- high priority (rank 4): parameter of high health significance, more frequently exceeded in monitoring or with a documented link to negative effects (e.g., nitrates, THM, mercury),
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- medium priority (rank 3): parameter of significant toxicological importance, but less frequently exceeding normative values (e.g., chromium),
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- low priority (rank 1–2): copper, manganese, iron—mainly local exceedances and aesthetic/technological problems, less toxicological and health significance.
2.2.2. Stage 2. Analysis of Decision Rules
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- absolutely more dangerous (absolute preference): aij = 0.9
- -
- definitely more dangerous: aij = 0.80
- -
- significantly more dangerous: aij = 0.70
- -
- slightly more dangerous: aij = 0.55
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- equally dangerous: aij = 0.50
- The sum of preferences ai relative to aj and aj relative to ai is equal to one, i.e., there is so-called additive reciprocity: (aij) + (aji) = 1 for all i ≠ j.
- Diagonal: aii = 0.5 for all i.
- Accepting the relationship (aji) = 1 − (aij) and (aii) = 0.5 creates a fuzzy relation (of preference) with the membership function μA (ai, aj).
2.2.3. Stage 3. Selection of Membership Functions (μ) for the Adopted Priority Categories and Defuzzification Using the Centroid of Singletons Method (A Priori Calibration)
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- Very low (VL)—trapezoidal ⟨a = 0.00, b = 0.00, c = 0.15, d = 0.25⟩, (centre C = 0.10)
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- Low (L)—triangular ⟨a = 0.15, b = 0.30, c = 0.45⟩, (centre C = 0.30)
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- Medium (M)—triangular ⟨a = 0.35, b = 0.50, c = 0.65⟩, (centre C = 0.50)
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- High (H)—triangular ⟨a = 0.55, b = 0.70, c = 0.85⟩, (centre C = 0.70)
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- Very high (VH)—trapezoidal ⟨a = 0.75, b = 0.85, c = 1.00, d = 1.00⟩, (centre C = 0.90).
2.2.4. Stage 4. Construction of the Preference Matrix
- —expert assessment, e = 1, …, m:
- m—number of experts.
2.2.5. Stage 5. Aggregation of Results—Determination of the Fuzzy Priority Index (FPI)
2.2.6. Stage 6. Mapping Actions and Creating a Fuzzy Queue of Water Quality Parameters
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- The nodes (crosses with labels) are water quality parameters arranged in descending order according to FPI (from highest priority to lowest).
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- The edges connect neighbours in the ranking—they show how strong the local advantage of the previous parameter over the next one is.
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- The edge label is in the form a(i → j)—this is a value from the preference matrix: the degree to which parameter i is more important/dangerous than neighbouring parameter j (a ∈ [0, 1]; 0.50 ≈ tie).
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- The thickness of the line is proportional to the strength of the preference a(i → j): the thicker the line, the greater the advantage.
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- The colour of the line is used to visually distinguish between levels of strength (see legend); in the black and white version, line thickness + value label are used.
3. Characteristics of the Study Object
- (1)
- Initial ozonation—oxidation of colour, taste, and odour compounds and initial disinfection (ozone generated from oxygen);
- (2)
- Coagulation (aluminium salts)—removal of colloids and poorly settling suspensions affecting turbidity and colour (e.g., humic substances, silica, organic pollutants);
- (3)
- Sedimentation in horizontal settling tanks—separation of flocs formed during coagulation;
- (4)
- Filtration through sand and anthracite–sand beds—removal of fine particulates;
- (5)
- Intermediate ozonation—further oxidation of residual colour/taste/odour compounds and reinforcement of disinfection;
- (6)
- Granular activated carbon (GAC) filtration—removal of dissolved organics and reduction of selected micro-pollutants;
- (7)
- UV pre-disinfection—enhancement of microbiological stability, improvement of organoleptic qualities, and reduction in chlorination doses;
- (8)
- Final disinfection with chlorine compounds (chlorine dioxide and chlorine gas)—ensuring sanitary quality in the distribution network; chlorine dioxide is produced in situ from sodium chlorite and chlorine gas;
- (9)
- pH correction using sodium carbonate (as needed)—mitigation of corrosivity in the distribution system.
4. Results
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- regulatory significance—all are included in the catalogue of parameters of Directive (EU) 2020/2184 [7], with specified parametric values (Part B—chemical parameters; Fe and Mn as indicator parameters in Part C) or monitoring guidelines.
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- the diversity of risk-creating mechanisms, which allows for reliable testing of the proposed prioritisation methodology:
- carcinogenicity (As, Cr(VI), part of DBP/THM),
- neurotoxicity and developmental effects (Pb, Hg, Mn),
- acute effects in infants (NO3−),
- gastrointestinal effects and metallic taste (Cu),
- nuisances/secondary operational risks (Fe, Mn).
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- operational challenges in European water supply systems: corrosion and metal leaching from installations, water ageing, seasonal variability of NO3− parameters, prevailing hydraulic conditions.
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- availability of data from routine water quality monitoring programmes for water supply systems, which facilitates the use of the method in other cities.
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- aij ∈ [0, 1]—degree of preference of i over j.
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- additive reciprocity: aij + aji = 1 for i ≠ j
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- diagonal in the matrix: aii = 0.5 (no preference for i over i).
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- only ratings for pairs i < j (upper triangle) were collected. Values for j < i were automatically reconstructed based on the rule: aji = 1 − aij.
5. Discussion
6. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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| Parameter | Main Health Effects | Technological Criterion | Priority Level (Rank 1–5) | Justification | Action Map |
|---|---|---|---|---|---|
| Arsenic (As) | Highly carcinogenic (skin, bladder and lung cancer), skin lesions, | None | 5 | One of the most dangerous parameters, documented health effects with chronic exposure. | Immediate corrective action; suspension of supply or switching of source; implementation of advanced technologies (adsorption, membranes); priority monitoring and reporting. |
| Lead (Pb) | Neurotoxicity (children), developmental disorders, hypertension, nephrotoxicity | corrosion of installations | 5 | High toxicological significance, especially in sensitive groups. | Elimination of the source (replacement of lead installations, corrosion control); child health protection programmes; intensive monitoring and consumer information. |
| Mercury (Hg) | Neurotoxicity, kidney damage, foetal effects | None | 4 | Highly toxic, but rarely exceeds standards in water supplies. | Increased monitoring frequency; identification of the source of contamination; implementation of reduction technologies (e.g., ion exchange); notifications in case of exceedances. |
| THM (Trihalomethanes) | Cancer risk (bladder, intestine), inhalation and dermal effects | Disinfection by-product | 4 | Commonly found, risk signals even at concentrations below EU standards. | Optimization of the disinfection process (contact time, chloramination, DBP precursors); implementation of technologies limiting the formation of THM (GAC, ozone, biological filtration); monitoring at network points. |
| Nitrates (NO3−) | Methaemoglobinaemia (infants), possible links to stomach cancer | insignificant | 4 | Very important parameter in agriculture; high risk for infants. | Monitoring in agricultural areas; identification of sources of inflow (sewage, fertilisers); alternative water sources for infants; implementation of desalination/denitrification in treatment. |
| Chromium (Cr) | Carcinogenic (Cr(VI)), toxic to kidneys and liver | Industrial nature | 3 | Significant toxicologically, but exceedances in water supply systems are rare. | Periodic monitoring; testing of industrial sources; contingency plan in case of increased concentrations; implementation of reduction technologies (e.g., reduction of Cr(VI) to Cr(III) + coagulation). |
| Copper (Cu) | Diarrhoea, liver damage with chronic exposure | corrosion of installations | 2 | Significant mainly in the case of long-term exceedances in domestic installations. | Monitoring of internal installations (corrosion of copper pipes); operating recommendations (flushing of the network, pH control); measures to be taken in the event of long-term exceedances. |
| Manganese (Mn) | Neurotoxicity (children), developmental disorders | sediment, secondary contamination | 2 | Moderate health risk, more often an aesthetic and technological problem. | Regular rinsing of nets; use of filtration in treatment plants; measures mainly in the case of aesthetic problems and secondary contamination. |
| Iron (Fe) | No significant health effects (except for haemochromatosis in high doses) | colour, taste, sediment | 1 | Secondary parameter, more of a visual quality issue than a toxicological one. | Measures to reduce sediment and colour (iron removal, network flushing); response to consumer complaints; maintaining the |
| As | Pb | THM | … | |
| As | 0.5 | a12 | a13 | … |
| Pb | 1 − a12 | 0.5 | a23 | … |
| THM | 1 − a13 | 1 − a23 | 0.5 | … |
| … | … | … | … | … |
| FPI Range | Priority Category |
|---|---|
| <0.20 | Very low (VL) |
| 0.20–0.40 | Low (L) |
| 0.40–0.60 | Medium (M) |
| 0.60–0.80 | High (H) |
| ≥0.80 | Very high (VH) |
| FPI Range | Priority Category | Proposed Actions |
|---|---|---|
| <0.20 | Very low (VL) | Routine monitoring; action only in response to complaints/aesthetic nuisances. |
| 0.20–0.40 | Low (L) | Planned monitoring; analysis in case of upward trends; local action. |
| 0.40–0.60 | Medium (M) | Periodic in-depth investigations; source analysis; targeted corrosion/precursor control. |
| 0.60–0.80 | High (H) | Increased monitoring frequency; optimisation/implementation of removal technologies (e.g., GAC, membranes, denitrification); notifications in case of exceedances. |
| ≥0.80 | Very high (VH) | Immediate corrective action; possible suspension of supply/switching of source; advanced technologies; priority reporting and supervision. |
| Parameter | Risk Group | Health/Operational Justification | Regulatory Comments (WHO/DWD) [1,6,7,8] |
|---|---|---|---|
| Nitrates (NO3−) | Inorganic pollutants (agriculture) | Methaemoglobinaemia in infants; possible thyroid disorders; strong | WHO: 50 mg/L; DWD: 50 mg/L |
| Lead (Pb) | Heavy metal (installation materials) | Developmental neurotoxicity, increased cardiovascular RR; release from lead fittings and fixtures | DWD: 5 μg/L from 12 January 2036 (until then 10 μg/L; 5 μg/L when using new materials in internal installations). |
| Arsenic (As) | Metalloids (geogenic) | Carcinogen (skin, bladder, lungs); chronic exposure | WHO: 10 μg/L DWD: 10 μg/L |
| Chromium (Cr; toxicologically mainly Cr(VI)) | Heavy metal | Caution regarding carcinogenicity | DWD: 25 μg/L from 2036 (until then 50 μg/L) |
| Copper (Cu) | Metal (installation materials) | Potential hepatotoxicity with chronic exposure; depends on pH/alkalinity and water stagnation in pipes | DWD: 2 mg/L |
| Manganese (Mn) | Metal (water supply network material) | Neurodevelopmental risk in children, sediment formation, discolouration; promotes biofilm formation | DWD: indicator value 50 μg/L (indicator parameter—operational significance) |
| Iron (Fe) | Metal (water supply network material) | Nuisance (colour, taste), deposits, risk of secondary quality degradation; significant impact on consumer complaints | WHO: parameter Aesthetic DWD: indicator 200 μg/L |
| THM—total | Disinfection by-products (DBPs) | Increased risk of bladder cancer (chronic exposure); dependent on water temperature and age | WHO: individual guidelines DWD: total 100 μg/L (chloroform, bromoform, dibromochloromethane, bromodichloromethane). |
| Comparison Pair Number | Parameter_i | Parameter_j | Expert Assessment 1 | Expert Assessment 2 | Expert Assessment 3 | Median |
|---|---|---|---|---|---|---|
| P01 | As | Pb | 0.57 | 0.56 | 0.53 | 0.56 |
| P02 | As | THM | 0.59 | 0.59 | 0.63 | 0.59 |
| P03 | As | NO3− | 0.70 | 0.66 | 0.68 | 0.68 |
| P04 | As | Hg | 0.77 | 0.76 | 0.76 | 0.76 |
| P05 | As | Cr | 0.74 | 0.82 | 0.79 | 0.79 |
| P06 | As | Mn | 0.82 | 0.88 | 0.86 | 0.86 |
| P07 | As | Cu | 0.90 | 0.90 | 0.90 | 0.90 |
| P08 | As | Fe | 0.90 | 0.90 | 0.90 | 0.90 |
| P09 | Pb | THM | 0.56 | 0.56 | 0.57 | 0.56 |
| P10 | Pb | NO3− | 0.59 | 0.63 | 0.60 | 0.60 |
| P11 | Pb | Hg | 0.71 | 0.71 | 0.67 | 0.71 |
| P12 | Pb | Cr | 0.76 | 0.75 | 0.73 | 0.75 |
| P13 | Pb | Mn | 0.80 | 0.82 | 0.76 | 0.80 |
| P14 | Pb | Cu | 0.89 | 0.86 | 0.87 | 0.87 |
| P15 | Pb | Fe | 0.90 | 0.90 | 0.90 | 0.90 |
| P16 | THM | NO3− | 0.53 | 0.58 | 0.56 | 0.56 |
| P17 | THM | Hg | 0.63 | 0.58 | 0.63 | 0.63 |
| P18 | THM | Cr | 0.65 | 0.67 | 0.69 | 0.67 |
| P19 | THM | Mn | 0.77 | 0.73 | 0.76 | 0.76 |
| P20 | THM | Cu | 0.80 | 0.78 | 0.80 | 0.80 |
| P21 | THM | Fe | 0.85 | 0.85 | 0.85 | 0.85 |
| P22 | NO3− | Hg | 0.54 | 0.60 | 0.56 | 0.56 |
| P23 | NO3− | Cr | 0.66 | 0.59 | 0.57 | 0.59 |
| P24 | NO3− | Mn | 0.68 | 0.71 | 0.64 | 0.68 |
| P25 | NO3− | Cu | 0.73 | 0.69 | 0.70 | 0.70 |
| P26 | NO3− | Fe | 0.79 | 0.79 | 0.77 | 0.79 |
| P27 | Hg | Cr | 0.58 | 0.56 | 0.57 | 0.57 |
| P28 | Hg | Mn | 0.63 | 0.64 | 0.59 | 0.63 |
| P29 | Hg | Cu | 0.69 | 0.70 | 0.67 | 0.69 |
| P30 | Hg | Fe | 0.75 | 0.76 | 0.78 | 0.76 |
| P31 | Cr | Mn | 0.62 | 0.55 | 0.55 | 0.55 |
| P32 | Cr | Cu | 0.61 | 0.61 | 0.64 | 0.61 |
| P33 | Cr | Fe | 0.66 | 0.71 | 0.65 | 0.66 |
| P34 | Mn | Cu | 0.54 | 0.55 | 0.55 | 0.55 |
| P35 | Mn | Fe | 0.64 | 0.58 | 0.59 | 0.59 |
| P36 | Cu | Fe | 0.59 | 0.53 | 0.55 | 0.55 |
| As | Pb | THM | NO3− | Hg | Cr | Mn | Cu | Fe | |
| As | 0.50 | 0.56 | 0.59 | 0.68 | 0.76 | 0.79 | 0.86 | 0.90 | 0.90 |
| Pb | 0.44 | 0.50 | 0.56 | 0.60 | 0.71 | 0.75 | 0.80 | 0.87 | 0.90 |
| THM | 0.41 | 0.44 | 0.50 | 0.56 | 0.63 | 0.67 | 0.76 | 0.8 | 0.85 |
| NO3− | 0.32 | 0.40 | 0.44 | 0.50 | 0.56 | 0.59 | 0.68 | 0.7 | 0.79 |
| Hg | 0.24 | 0.29 | 0.37 | 0.44 | 0.50 | 0.57 | 0.63 | 0.69 | 0.76 |
| Cr | 0.21 | 0.25 | 0.33 | 0.41 | 0.43 | 0.50 | 0.55 | 0.61 | 0.66 |
| Mn | 0.14 | 0.2 | 0.24 | 0.32 | 0.37 | 0.45 | 0.50 | 0.55 | 0.59 |
| Cu | 0.10 | 0.13 | 0.20 | 0.30 | 0.31 | 0.39 | 0.45 | 0.50 | 0.55 |
| Fe | 0.10 | 0.10 | 0.15 | 0.21 | 0.24 | 0.34 | 0.41 | 0.45 | 0.50 |
| Parameter | FPI | μ(VL) | μ(L) | μ(M) | μ(H) | μ(VH) | Score (COGS) |
|---|---|---|---|---|---|---|---|
| As | 0.76 | 0.00 | 0.00 | 0.00 | 0.60 | 0.10 | 0.73 |
| Pb | 0.70 | 0.00 | 0.00 | 0.00 | 1.00 | 0.00 | 0.70 |
| THM | 0.64 | 0.00 | 0.00 | 0.07 | 0.60 | 0.00 | 0.68 |
| NO3− | 0.56 | 0.00 | 0.00 | 0.60 | 0.07 | 0.00 | 0.52 |
| Hg | 0.50 | 0.00 | 0.00 | 1.00 | 0.00 | 0.00 | 0.50 |
| Cr | 0.43 | 0.00 | 0.13 | 0.53 | 0.00 | 0.00 | 0.46 |
| Mn | 0.36 | 0.00 | 0.60 | 0.07 | 0.00 | 0.00 | 0.32 |
| Cu | 0.30 | 0.00 | 1.00 | 0.00 | 0.00 | 0.00 | 0.30 |
| Fe | 0.25 | 0.00 | 0.67 | 0.00 | 0.00 | 0.00 | 0.30 |
| Parameter | FPI | Score | Priority Category | Operational Activities |
|---|---|---|---|---|
| As | 0.76 | 0.72 | High (H) | Immediate corrective action; suspension of supply or switching of source; implementation of advanced technologies (adsorption, membranes); priority monitoring and reporting. |
| Pb | 0.7 | 0.7 | High (H) | Elimination of the source (replacement of lead installations, corrosion control); child health protection programmes; intensive monitoring and consumer information. |
| THM (total) | 0.64 | 0.68 | High (H) | Optimization of the disinfection process (contact time, chloramination, DBP precursors); implementation of technologies limiting the formation of THM (GAC, ozone, biological filtration); monitoring at network points. |
| NO3− | 0.56 | 0.52 | Medium (M) | Monitoring in agricultural areas; identification of sources of inflow (sewage, fertilisers); alternative water sources for infants; implementation of desalination/denitrification in treatment. |
| Hg | 0.5 | 0.50 | Medium (M) | Increased monitoring frequency; identification of pollution sources; implementation of reduction technologies (e.g., ion exchange); notifications in case of exceedances. |
| Cr | 0.43 | 0.46 | Medium (M) | Periodic monitoring; testing of industrial sources; contingency plan in case of increased concentrations; implementation of reduction technologies (e.g., reduction of Cr(VI) to Cr(III) + coagulation). |
| Mn | 0.36 | 0.32 | Low (L) | Regular flushing of the network; use of filtration in treatment plants; measures mainly in the case of aesthetic problems and secondary contamination. |
| Cu | 0.3 | 0.3 | Low (L) | Monitoring of internal installations (corrosion of copper pipes); operational recommendations (flushing the network, pH control); measures in the event of prolonged exceedances. |
| Fe | 0.25 | 0.3 | Low (L) | Measures to reduce deposits and colour (iron removal, network flushing); response to consumer complaints; maintaining the aesthetics and acceptability of water. |
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Piegdoń, I.; Tchórzewska-Cieślak, B.; Raček, J. A New Fuzzy Preference Relation (FPR) Approach to Prioritizing Drinking Water Hazards: Ranking, Mapping, and Operational Guidance. Water 2025, 17, 3410. https://doi.org/10.3390/w17233410
Piegdoń I, Tchórzewska-Cieślak B, Raček J. A New Fuzzy Preference Relation (FPR) Approach to Prioritizing Drinking Water Hazards: Ranking, Mapping, and Operational Guidance. Water. 2025; 17(23):3410. https://doi.org/10.3390/w17233410
Chicago/Turabian StylePiegdoń, Izabela, Barbara Tchórzewska-Cieślak, and Jakub Raček. 2025. "A New Fuzzy Preference Relation (FPR) Approach to Prioritizing Drinking Water Hazards: Ranking, Mapping, and Operational Guidance" Water 17, no. 23: 3410. https://doi.org/10.3390/w17233410
APA StylePiegdoń, I., Tchórzewska-Cieślak, B., & Raček, J. (2025). A New Fuzzy Preference Relation (FPR) Approach to Prioritizing Drinking Water Hazards: Ranking, Mapping, and Operational Guidance. Water, 17(23), 3410. https://doi.org/10.3390/w17233410

