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Minerals, Volume 8, Issue 9

2018 September - 56 articles

Cover Story: Artificial and singular geochemical environments are created around the engineered barrier systems (EBS) that are designed to isolate high-level nuclear wastes in deep geological repositories. A concrete-bentonite interface takes place within the EBS and produces a significant alkaline chemical environment. This paper discusses the formation of authigenic minerals, mostly Mg hydroxides and disordered hydrous Mg-silicates. They evolve to a saponitic composition through aging. This reactive system can be compared to the geochemical evolutionary reaction paths described in the formation of Mg-Clays as a common signature for natural alkaline-saline lacustrine environments found in semi-arid climates. It is also remarkable how the precipitation of these minerals buffers the pH, presumably preventing the progressive increase of pH to > 11 values and then protecting bentonite from further alteration. View this paper
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Articles (56)

  • Article
  • Open Access
11 Citations
4,727 Views
9 Pages

Aurihydrargyrumite, a Natural Au6Hg5 Phase from Japan

  • Daisuke Nishio-Hamane,
  • Takahiro Tanaka and
  • Tetsuo Minakawa

19 September 2018

Aurihydrargyrumite, a natural Au6Hg5 phase, was found in Iyoki, Uchiko, Ehime Prefecture, Shikoku Island, Japan. Aurihydrargyrumite with a metallic silver luster occurs as a submicron- to 2 μm-thick layer on the outermost surface of the placer gol...

  • Article
  • Open Access
61 Citations
8,969 Views
11 Pages

Rare Earth and Phosphorus Leaching from a Flotation Tailings of Florida Phosphate Rock

  • Haijun Liang,
  • Patrick Zhang,
  • Zhen Jin and
  • David W. DePaoli

19 September 2018

Phosphorite, or phosphate rock, is the raw material of phosphoric acid production. It has also been regarded as the most important secondary rare earth element (REE) resource due to low contents of rare earth elements contained in the ore. In Florida...

  • Article
  • Open Access
58 Citations
7,832 Views
19 Pages

Chemical Stability and Leaching Behavior of One-Part Geopolymer from Soil and Coal Fly Ash Mixtures

  • April Anne S. Tigue,
  • Roy Alvin J. Malenab,
  • Jonathan R. Dungca,
  • Derrick Ethelbhert C. Yu and
  • Michael Angelo B. Promentilla

18 September 2018

Aluminosilicate minerals have become an important resource for an emerging sustainable material for construction known as geopolymer. Geopolymer, an alkali-activated material, is becoming an attractive alternative to Portland cement because of its lo...

  • Feature Paper
  • Article
  • Open Access
31 Citations
8,565 Views
18 Pages

Intracrystalline Reaction-Induced Cracking in Olivine Evidenced by Hydration and Carbonation Experiments

  • Romain Lafay,
  • German Montes-Hernandez,
  • François Renard and
  • Pierre Vonlanthen

18 September 2018

In order to better understand the microtextural changes associated with serpentinization reactions, natural millimeter-sized olivine grains were experimentally reacted with alkaline NaOH and NaHCO3 solutions at a temperature of 200 °C and for duratio...

  • Article
  • Open Access
29 Citations
7,757 Views
19 Pages

Infra Red Spectroscopy of the Regulated Asbestos Amphiboles

  • Giancarlo Della Ventura,
  • Ruggero Vigliaturo,
  • Reto Gieré,
  • Simone Pollastri,
  • Alessandro F. Gualtieri and
  • Gianluca Iezzi

18 September 2018

Vibrational spectroscopies (Fourier Transform Infra Red, FTIR, and Raman) are exceptionally valuable tools for the identification and crystal–chemical study of fibrous minerals, and asbestos amphiboles in particular. Raman spectroscopy has been widel...

  • Article
  • Open Access
2 Citations
5,123 Views
22 Pages

Supergene Uranyl Mineralization of the Rabejac Deposit, Lodève, France

  • Fabrice Dal Bo,
  • Frédéric Hatert and
  • Simon Philippo

18 September 2018

The Rabejac uranium deposit that is located in the Lodève region, France, is the type locality for three uranyl minerals species (fontanite, seelite, and rabejacite). In addition, this deposit shows an extraordinary supergene uranyl mineraliza...

  • Article
  • Open Access
4 Citations
5,610 Views
16 Pages

Petrology of Peridotites and Nd-Sr Isotopic Composition of Their Clinopyroxenes from the Middle Andaman Ophiolite, India

  • Tomoaki Morishita,
  • Masako Yoshikawa,
  • Akihiro Tamura,
  • Juan Miguel Guotana and
  • Biswajit Ghosh

17 September 2018

The Andaman Ophiolite, India, is located at the southeastern end of the Tethyan ophiolites. We examine petrology and mineralogy of two lherzolites and a completely serpentinized dunite associated with lherzolite from the middle Andaman Island. Major...

  • Article
  • Open Access
21 Citations
4,615 Views
13 Pages

Comparative Analysis of Attachment to Chalcopyrite of Three Mesophilic Iron and/or Sulfur-Oxidizing Acidophiles

  • Qian Li,
  • Baojun Yang,
  • Jianyu Zhu,
  • Hao Jiang,
  • Jiaokun Li,
  • Ruiyong Zhang and
  • Wolfgang Sand

14 September 2018

Adhesion plays an important role in bacterial dissolution of metal sulfides, since the attached cells initiate the dissolution. In addition, biofilms, forming after bacterial attachment, enhance the dissolution. In this study, interactions between in...

  • Article
  • Open Access
37 Citations
5,710 Views
24 Pages

Particle Size Distribution of Cemented Rockfill Effects on Strata Stability in Filling Mining

  • Jiangyu Wu,
  • Meimei Feng,
  • Jingmin Xu,
  • Peitao Qiu,
  • Yiming Wang and
  • Guansheng Han

14 September 2018

It is of great significance for engineering safety, economic benefits, environmental protection, and sustainable development to investigate the strata stability in filling mining with cemented rockfill. Consequently, this paper is based on a specific...

  • Article
  • Open Access
26 Citations
6,527 Views
17 Pages

Structural Control on Clay Mineral Authigenesis in Faulted Arkosic Sandstone of the Rio do Peixe Basin, Brazil

  • Ingrid B. Maciel,
  • Angela Dettori,
  • Fabrizio Balsamo,
  • Francisco H.R. Bezerra,
  • Marcela M. Vieira,
  • Francisco C.C. Nogueira,
  • Emma Salvioli-Mariani and
  • Jorge André B. Sousa

14 September 2018

Clay minerals in structurally complex settings influence fault zone behavior and characteristics such as permeability and frictional properties. This work aims to understand the role of fault zones on clay authigenesis in arkosic, high-porosity sands...

  • Review
  • Open Access
17 Citations
10,279 Views
17 Pages

14 September 2018

The Lengenbach quarry is a world-famous mineral locality, especially known for its rare and well-crystallized Tl, Pb, Ag, and Cu bearing sulfosalts. As of June 2018, it is the type locality for 44 different mineral species, making it one of the most...

  • Article
  • Open Access
18 Citations
8,949 Views
14 Pages

13 September 2018

Characterization of mine waste rocks and prediction of acid mine drainage (AMD) play an important role in preventing AMD. Although high-tech analytical methods have been highlighted for mineral characterization and quantification, simple testing meth...

  • Article
  • Open Access
41 Citations
4,713 Views
17 Pages

13 September 2018

Seawater has been considered as an alternative to freshwater for flotation. However, many ions in seawater were reported to depress molybdenite (MoS2), with the depressing mechanisms being insufficiently understood. In this study, the influence of di...

  • Article
  • Open Access
24 Citations
10,021 Views
25 Pages

13 September 2018

The Ernest Henry Iron-Oxide-Copper-Gold deposit is the largest known Cu-Au deposit in the Eastern Succession of the Proterozoic Mount Isa Inlier, NW Queensland. Cu-Au mineralization is hosted in a K-feldspar altered breccia, bounded by two major pre-...

  • Review
  • Open Access
33 Citations
5,701 Views
12 Pages

13 September 2018

Research in gold (Au) geomicrobiology has developed extensively over the last ten years, as more Au-bearing materials from around the world point towards a consistent story: That microbes interact with Au. In weathering environments, Au is mobile, ta...

  • Article
  • Open Access
21 Citations
5,683 Views
16 Pages

Effect of H2O2 on the Separation of Mo-Bi-Containing Ore by Flotation

  • Shangyong Lin,
  • Runqing Liu,
  • Wei Sun,
  • Yuehua Hu and
  • Haisheng Han

13 September 2018

Hydrogen peroxide (H2O2) is a strong oxidizer that causes non-selective oxidation of sulfide minerals, and its influence on bismuth sulfide ores is not well-documented. In this study, H2O2 was proposed as an alternative bismuthinite depressant, and i...

  • Article
  • Open Access
53 Citations
6,775 Views
16 Pages

Impact of Clay Minerals on the Dewatering of Coal Slurry: An Experimental and Molecular-Simulation Study

  • Xiaomin Ma,
  • Yuping Fan,
  • Xianshu Dong,
  • Ruxia Chen,
  • Hongliang Li,
  • Dong Sun and
  • Suling Yao

11 September 2018

The cleaning process of coals is challenging due to the existence of clay minerals. The overall objective of this study is to investigate how the dewatering of coal slurry is impacted by the presence of clay minerals, i.e., kaolinite and montmorillon...

  • Article
  • Open Access
25 Citations
8,199 Views
19 Pages

10 September 2018

The Saint-Honoré carbonatite complex hosts a rare earth element (REE) deposit traditionally interpreted as being produced by late-stage hydrothermal fluids that leached REE from apatite or dolomite found in the early units and concentrated the...

  • Feature Paper
  • Article
  • Open Access
43 Citations
7,188 Views
17 Pages

10 September 2018

The newly discovered Tiegelongnan Cu (Au) deposit is a giant porphyry deposit overprinted by a high-sulfidation epithermal deposit in the western part of the Bangong–Nujiang metallogenic belt, Duolong district, central Tibet. It is mainly controlled...

  • Article
  • Open Access
6 Citations
5,019 Views
13 Pages

10 September 2018

Rusinovite, Ca10(Si2O7)3Cl2, was found at two new localities, including Shadil-Khokh volcano, South Ossetia and Bellerberg volcano, Caspar quarry, Germany. At both of these localities, rusinovite occurs in altered carbonate-silicate xenoliths embedde...

  • Article
  • Open Access
75 Citations
14,448 Views
22 Pages

Striving Toward a Circular Economy for Phosphorus: The Role of Phosphate Rock Mining

  • Bernhard Geissler,
  • Ludwig Hermann,
  • Michael C. Mew and
  • Gerald Steiner

8 September 2018

As an element, phosphorus (P) is one of a kind. While it is essential for all life on Earth, phosphorus is neither substitutable nor infinite especially in terms of highly concentrated phosphate rock deposits. Society as a whole—and key stakeho...

  • Article
  • Open Access
7 Citations
7,866 Views
22 Pages

8 September 2018

Economic and subeconomic concentrations of Sn, In, rare earth elements (REE), Ta, and Nb are known in Central Brazil, in the Goias Tin Province. The Sn-P enriched albitites studied in this paper occur in sharp contact with peraluminous granites of th...

  • Article
  • Open Access
11 Citations
9,542 Views
12 Pages

7 September 2018

The SART (sulfidization, acidification, recycling, and thickening) process (SP) has been successfully implemented in gold cyanidation plants to address issues associated with high cyanide-soluble copper content ores. However, this process could produ...

  • Article
  • Open Access
19 Citations
4,191 Views
12 Pages

7 September 2018

In recent works on the determination of graphitization of carbonaceous materials (CM) within the principal slip zone (PSZ) of the Longmenshan fault (China), we demonstrated that the formation of graphite, resulted from strain and frictional heating,...

  • Article
  • Open Access
20 Citations
8,691 Views
22 Pages

Geology and U-Th-Pb Dating of the Gakara REE Deposit, Burundi

  • Seconde Ntiharirizwa,
  • Philippe Boulvais,
  • Marc Poujol,
  • Yannick Branquet,
  • Cesare Morelli,
  • Joël Ntungwanayo and
  • Gilbert Midende

7 September 2018

The Gakara Rare Earth Elements (REE) deposit is one of the world’s highest grade REE deposits, likely linked to a carbonatitic magmatic-hydrothermal activity. It is located near Lake Tanganyika in Burundi, along the western branch of the East A...

  • Article
  • Open Access
31 Citations
11,163 Views
21 Pages

Evaluation of Magnetic Separation Efficiency on a Cassiterite-Bearing Skarn Ore by Means of Integrative SEM-Based Image and XRF–XRD Data Analysis

  • Markus Buchmann,
  • Edgar Schach,
  • Raimon Tolosana-Delgado,
  • Thomas Leißner,
  • Jennifer Astoveza,
  • Marius Kern,
  • Robert Möckel,
  • Doreen Ebert,
  • Martin Rudolph and
  • Urs A. Peuker
  • + 1 author

6 September 2018

Image analysis data obtained from scanning electron microscopy provided data for a detailed evaluation of the separation efficiency for various processes involving the beneficiation of particulate materials. A dry magnetic separation by a drum type m...

  • Article
  • Open Access
11 Citations
4,608 Views
16 Pages

6 September 2018

In this study, a new approach, “dynamic wettability”, and atomic force microscopy (AFM) imaging analysis techniques were successfully used to characterize the hydrophobization mechanism of the collector dodecylamine (DDA) on muscovite and...

  • Article
  • Open Access
38 Citations
5,177 Views
14 Pages

5 September 2018

In this work, halloysite nanotubes (HNTs) without modification were used as an efficient adsorbent to explore its natural adsorption capability, which showed excellent adsorption ability for low-concentration ciprofloxacin (CIP). The physicochemical...

  • Article
  • Open Access
8 Citations
4,436 Views
19 Pages

Ore-Forming Processes at the Xiajinbao Gold Deposit in Eastern Hebei Province: Constraints from EPMA and LA-ICPMS Analysis

  • Cheng Wang,
  • Yongjun Shao,
  • Kuanxin Huang,
  • Haodi Zhou,
  • Jianguo Zhang,
  • Zhongfa Liu and
  • Qingquan Liu

5 September 2018

The Xiajinbao gold deposit is located at the northern margin of the North China Craton. Hydrothermal pyrites belonging to three stages were identified: Py1; Py2; and Py3. Geochemical study of these pyrites was conducted using electron probe microanal...

  • Article
  • Open Access
18 Citations
6,306 Views
18 Pages

Induration Process of MgO Flux Pellet

  • Qiangjian Gao,
  • Xin Jiang,
  • Haiyan Zheng and
  • Fengman Shen

5 September 2018

The induration process of oxidized pellet, containing the oxidation of magnetite phase (Fe3O4) and the sintering of oxidized magnetite phase (hematite–Fe2O3), is significant to obtain sufficient pellet strength. The current study focuses on the...

  • Article
  • Open Access
10 Citations
3,578 Views
13 Pages

4 September 2018

Graphitization of carbonaceous materials (CM) has been experimentally demonstrated as potential evidence of seismic slip within a fault gouge. The southern segment of the Longmenshan fault, a CM-rich-gouge fault, accommodated coseismic slip during th...

  • Article
  • Open Access
39 Citations
6,338 Views
23 Pages

4 September 2018

Measurement while drilling (MWD) data are gathered during drilling operations and can provide information about the strength of the rock penetrated by the boreholes. In this paper MWD data from a marble open-pit operation in northern Norway are studi...

  • Article
  • Open Access
30 Citations
5,951 Views
12 Pages

Water Adsorption on the β-Dicalcium Silicate Surface from DFT Simulations

  • Qianqian Wang,
  • Hegoi Manzano,
  • Iñigo López-Arbeloa and
  • Xiaodong Shen

4 September 2018

β-dicalcium silicate (β-Ca2SiO4 or β-C2S in cement chemistry notation) is one of the most important minerals in cement. An improvement of its hydration rate would be the key point for developing environmentally-friendly cements with lo...

  • Article
  • Open Access
70 Citations
6,281 Views
13 Pages

3 September 2018

The strength and consistency of cemented paste backfill (CPB) are of key concerns in the stope stability and cost control for underground mines. It is common practice to use additives, such as superplasticizer, to improve the performance of CPB. This...

  • Article
  • Open Access
5 Citations
4,132 Views
16 Pages

Synchrotron Radiation Based Study of the Catalytic Mechanism of Ag+ to Chalcopyrite Bioleaching by Mesophilic and Thermophilic Cultures

  • Zhenyuan Nie,
  • Weiwei Zhang,
  • Hongchang Liu,
  • Jinlan Xia,
  • Wei Zhu,
  • Duorui Zhang,
  • Lei Zheng,
  • Chenyan Ma,
  • Yidong Zhao and
  • Wen Wen

3 September 2018

The catalytic mechanism of Ag+ for chalcopyrite bioleaching by mesophilic culture (at 30 °C) and thermophilic culture (at 48 °C) was investigated using synchrotron radiation-based X-ray diffraction (SR-XRD) and S K-edge and Fe L-edge X-ray ab...

  • Article
  • Open Access
22 Citations
6,628 Views
16 Pages

3 September 2018

In many cases, it may be possible to recover value (e.g., metals, land) from legacy mine wastes and tailings when applying leaching-based remediation such as dump/heap leaching or in-vessel soil washing. However, if the lixiviant used has the potenti...

  • Article
  • Open Access
36 Citations
6,680 Views
20 Pages

1 September 2018

The Dongguashan copper (gold) deposit in Anhui Province is one of the largest copper (gold) deposits in the Tongling ore district, which is the most important region in the Middle–Lower Yangtze River Metallogenic Belt, Eastern China. Stratiform...

  • Article
  • Open Access
21 Citations
4,906 Views
14 Pages

Column Leaching of Greek Low-Grade Limonitic Laterites

  • Kostas Komnitsas,
  • Evangelos Petrakis,
  • Olga Pantelaki and
  • Anna Kritikaki

31 August 2018

In this study, column leaching experiments were carried out to investigate the extraction of Ni and Co from low-grade limonitic laterites from Agios Ioannis mines in central Greece. Tests were carried out in laboratory Plexiglas columns using H2SO4 a...

  • Article
  • Open Access
10 Citations
4,651 Views
14 Pages

Metal Removal from Acid Waters by an Endemic Microalga from the Atacama Desert for Water Recovery

  • Marcela Martínez,
  • Yanett Leyton,
  • Luis A. Cisternas and
  • Carlos Riquelme

31 August 2018

The environmental problems generated by waste from the mining industry in the mineral extraction for business purposes are known worldwide. The aim of this work is to evaluate the microalga Muriellopsis sp. as a potential remover of metallic ions suc...

  • Article
  • Open Access
44 Citations
7,683 Views
21 Pages

Origin of Platinum Group Minerals (PGM) Inclusions in Chromite Deposits of the Urals

  • Federica Zaccarini,
  • Giorgio Garuti,
  • Evgeny Pushkarev and
  • Oskar Thalhammer

31 August 2018

This paper reviews a database of about 1500 published and 1000 unpublished microprobe analyses of platinum-group minerals (PGM) from chromite deposits associated with ophiolites and Alaskan-type complexes of the Urals. Composition, texture, and parag...

  • Article
  • Open Access
18 Citations
7,509 Views
16 Pages

Quantitative and Qualitative Research on the Waste from the Mining of Rock Raw Materials in Lower Silesia

  • Urszula Kaźmierczak,
  • Jan Blachowski,
  • Justyna Górniak-Zimroz and
  • Herbert Wirth

30 August 2018

The Lower Silesia area in SW Poland is characterized by a geological structure that is conducive to mining activity. The exploitation of rock raw materials plays an important role in this sector of the economy. By the end of 2017, there were in total...

  • Article
  • Open Access
21 Citations
5,700 Views
24 Pages

Microwave-Assisted Acid Activation of Clays Composed of 2:1 Clay Minerals: A Comparative Study

  • Juan Antonio Cecilia,
  • Laura Pardo,
  • Manuel Pozo,
  • Eva Bellido and
  • Francisco Franco

30 August 2018

The effect of the microwave-assisted acid treatment (MAT) on the structure and texture of dioctahedral (montmorillonite) and trioctahedral (saponite) smectites, kerolitic clays and sepiolites were studied by scanning electron microscopy, nitrogen ads...

  • Feature Paper
  • Article
  • Open Access
14 Citations
5,136 Views
15 Pages

29 August 2018

Ca,Mg-sulfates are subduction-related sources of oxidized S-rich fluid under lithospheric mantle P,T-parameters. Experimental study, aimed at the modeling of scenarios of S-rich fluid generation as a result of desulfation and subsequent sulfide forma...

  • Article
  • Open Access
11 Citations
11,982 Views
15 Pages

Kriging Interpolation for Evaluating the Mineral Resources of Cobalt-Rich Crusts on Magellan Seamounts

  • Dewen Du,
  • Shijuan Yan,
  • Fengli Yang,
  • Zhiwei Zhu,
  • Qinglei Song and
  • Gang Yang

29 August 2018

The evaluation of mineral resources on seamounts by geostatistics faces two key challenges. First, the conventional distance/orientation- and the simple distance-based variogram functions used are ineffective at expressing the spatial self-correlatio...

  • Article
  • Open Access
8 Citations
6,813 Views
16 Pages

28 August 2018

This paper introduces the concept of using a geometallurgical flowsheet as a tool to design, visualize and communicate a geometallurgical program. The development of the concept is carried out using a case study of an industrial mineral mining operat...

  • Article
  • Open Access
10 Citations
4,787 Views
10 Pages

27 August 2018

The flotation behaviors of diatomite and albite using dodecylamine (DDA) as a collector were investigated and compared. The pure mineral flotation results indicate that the flotability difference between albite and diatomite is above 87% at pH 5.5 to...

  • Article
  • Open Access
29 Citations
4,711 Views
16 Pages

25 August 2018

Novel collector lead(II)-benzohydroxamic acid (Pb(II)–BHA) complexes in aqueous solution were characterized by using experimental approaches, including Ultraviolet-visible (UV-Vis) spectroscopy and electrospray ionization-mass spectrometry (ESI...

  • Article
  • Open Access
31 Citations
5,288 Views
14 Pages

Effects of Xanthate on Flotation Kinetics of Chalcopyrite and Talc

  • Limei Bai,
  • Jie Liu,
  • Yuexin Han,
  • Kai Jiang and
  • Wenqing Zhao

25 August 2018

This paper investigated the effects of using or not using potassium butyl xanthate (PBX) as a collector on the flotation kinetics of talc and chalcopyrite. By means of atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR), a c...

  • Article
  • Open Access
15 Citations
4,625 Views
20 Pages

Revisiting the Organic Template Model through the Microstructural Study of Shell Development in Pinctada margaritifera, the Polynesian Pearl Oyster

  • Jean-Pierre Cuif,
  • Yannicke Dauphin,
  • Gilles Luquet,
  • Kadda Medjoubi,
  • Andrea Somogyi and
  • Alberto Perez-Huerta

25 August 2018

A top-down approach to the mineralized structures and developmental steps that can be separated in the shells of Pinctada margaritifera was carried out. Detailed characterizations show that each of the two major layers usually taken into account (the...

  • Feature Paper
  • Article
  • Open Access
20 Citations
6,551 Views
16 Pages

Cr Release from Cr-Substituted Goethite during Aqueous Fe(II)-Induced Recrystallization

  • Jian Hua,
  • Manjia Chen,
  • Chengshuai Liu,
  • Fangbai Li,
  • Jian Long,
  • Ting Gao,
  • Fei Wu,
  • Jing Lei and
  • Minghua Gu

24 August 2018

The interaction between aqueous Fe(II) (Fe(II)aq) and iron minerals is an important reaction of the iron cycle, and it plays a critical role in impacting the environmental behavior of heavy metals in soils. Metal substitution into iron (hydr)oxides h...

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Minerals - ISSN 2075-163X