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Polymers, Volume 4, Issue 2

2012 June - 23 articles

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Articles (23)

  • Review
  • Open Access
45 Citations
14,755 Views
20 Pages

21 June 2012

Polysaccharides are used extensively in various industrial applications, such as food, adhesives, coatings, construction, paper, pharmaceuticals, and personal care. Many polysaccharide structures need to be modified in order to improve their end-use...

  • Review
  • Open Access
58 Citations
20,476 Views
33 Pages

Microfluidics-Nano-Integration for Synthesis and Sensing

  • Simona Badilescu and
  • Muthukumaran Packirisamy

20 June 2012

The recent progress and achievements in the development of preparation of nano and microparticles in a microfluidic environment is reviewed. Microfluidics exploit fluid mechanics to create particles with a narrow range of sizes and offers a finely co...

  • Article
  • Open Access
24 Citations
8,343 Views
19 Pages

19 June 2012

Novel polyester-type thermoplastic elastomers based on poly(alkylene succinate)s were synthesized by the lipase-catalyzed copolymerization of cyclic diol/succinate oligomer and cyclic diol/alkylthiosuccinate oligomer. These copolymers exhibited biode...

  • Article
  • Open Access
7 Citations
9,481 Views
17 Pages

A Nanoparticle Approach towards Morphology Controlled Organic Photovoltaics (OPV)

  • Thomas R. Andersen,
  • Quanxiang Yan,
  • Thue T. Larsen-Olsen,
  • Roar Søndergaard,
  • Qi Li,
  • Birgitta Andreasen,
  • Kion Norrman,
  • Mikkel Jørgensen,
  • Wei Yue and
  • Eva Bundgaard
  • + 3 authors

11 June 2012

Silicon nano-particles grafted with two different organic oligomers were prepared; the oligomers used were a phenylene-vinylene (PV) oligomer and a 3,3'''-didodecylquaterthiophene. The graftings were performed by the use of two different functional g...

  • Article
  • Open Access
8 Citations
7,688 Views
15 Pages

Superparamagnetic Nanocomposites Templated with Pyrazole-Containing Diblock Copolymers

  • Sanchita Biswas,
  • Kevin D. Belfield,
  • Ritesh K. Das,
  • Siddhartha Ghosh and
  • Arthur F. Hebard

31 May 2012

Monodisperse maghemite nanoparticles, templated in novel, well-defined pyrazole-containing norbornene-based block copolymers, provided a superparamagnetic nanocomposite with high saturation magnetization at room temperature under an applied magnetic...

  • Article
  • Open Access
3 Citations
8,057 Views
16 Pages

Synthesis and Optical Study of a New Oligophenylene

  • Sarra Ben Amor,
  • Ayoub Haj Said,
  • Mourad Chemek,
  • Florian Massuyeau,
  • Jany Wéry,
  • Eric Faulques,
  • Kamel Alimi and
  • Sadok Roudesli

31 May 2012

A new substituted oligophenylene was prepared by the Knoevenagel condensation of 4-methoxybezaldehyde with a functionalized oligophenylene (OMPA). The latter was obtained by (4-methoxy phenyl) acetonitrile electrochemical oxidation. The resulting mod...

  • Article
  • Open Access
28 Citations
14,306 Views
16 Pages

Random Poly(Amino Acid)s Synthesized by Ring Opening Polymerization as Additives in the Biomimetic Mineralization of CaCO3

  • Vladimir Dmitrovic,
  • Gijs J.M. Habraken,
  • Marco M.R.M. Hendrix,
  • Wouter J.E.M. Habraken,
  • Andreas Heise,
  • Gijsbertus De With and
  • Nico A.J.M Sommerdijk

23 May 2012

Biominerals such as bones, teeth and seashells, very often have advanced material properties and are a source of inspiration for material chemists. As in biological systems acidic proteins play an important role in regulating the formation of CaCO3 b...

  • Article
  • Open Access
17 Citations
9,873 Views
12 Pages

15 May 2012

Controlled radical polymerization of N-vinylcarbazole (NVK) via microwave-assisted reversible addition-fragmentation chain transfer (RAFT) polymerization is described. As chain transfer agent, 1,3,5-benzyl tri (diethyldithiocarbamate), was used. The...

  • Article
  • Open Access
19 Citations
9,742 Views
13 Pages

14 May 2012

Condensation polymerization of 5-aminoisophthalic acid methyl ester 1 bearing a N-tri(ethylene glycol) methyl ester (TEG) chain as an AB2 monomer was conducted and the properties of the resulting hyperbranched polyamides (HBPA) were investigated. Whe...

  • Article
  • Open Access
77 Citations
10,781 Views
13 Pages

3 May 2012

Novel hybrid magnetic hydrogels have demonstrated their influence in several areas, particularly in biomedical science where these innovative materials are showing interesting applications for controlled drug delivery. A hybrid hydrogel with CoFe2O4...

  • Review
  • Open Access
16 Citations
10,477 Views
32 Pages

2 May 2012

In recent years, controlled photoradical polymerization has been established using 2,2,6,6-tetramethylpiperidine-1-oxyl as a mediator. This review article will describe the molecular weight control, polymerization mechanism, influence of initiator st...

  • Article
  • Open Access
6 Citations
7,642 Views
16 Pages

25 April 2012

Very few studies concern the isotropic phase of Side-Chain Liquid-Crystalline Polymers (SCLCPs). However, the interest for the isotropic phase appears particularly obvious in flow experiments. Unforeseen shear-induced nematic phases are revealed away...

  • Article
  • Open Access
6 Citations
7,425 Views
19 Pages

Calcite Biohybrids as Microenvironment for Stem Cells

  • Liliana Astachov,
  • Zvi Nevo and
  • Razi Vago

23 April 2012

A new type of composite 3D biomaterial that provides extracellular cues that govern the differentiation processes of mesenchymal stem cells (MSCs) has been developed. In the present study, we evaluated the chondrogenecity of a biohybrid composed of a...

  • Review
  • Open Access
135 Citations
20,545 Views
25 Pages

23 April 2012

Encapsulation of cells in hydrogel particles has been demonstrated as an effective approach to deliver therapeutic agents. The properties of hydrogel particles, such as the chemical composition, size, porosity, and number of cells per particle, affec...

  • Article
  • Open Access
7 Citations
9,753 Views
9 Pages

Templated Formation of Hydroxyapatite Nanoparticles from Self-Assembled Nanogels Containing Tricarboxylate Groups

  • Yoshihiro Sasaki,
  • Setsuko Yamane,
  • Kei Kurosu,
  • Shin-Ichi Sawada and
  • Kazunari Akiyoshi

20 April 2012

Nanosized hydroxyapatite (HAp) materials have received much attention in the context of their advanced biomedical applications, including tissue engineering and drug delivery systems. Hybridization of nanosized HAp with organic molecules is a promisi...

  • Article
  • Open Access
21 Citations
12,140 Views
19 Pages

Modification of oligo-Ricinoleic Acid and Its Derivatives with 10-Undecenoic Acid via Lipase-Catalyzed Esterification

  • Douglas G. Hayes,
  • Vinay K. Mannam,
  • Ran Ye,
  • Haizhen Zhao,
  • Salvadora Ortega and
  • M. Claudia Montiel

17 April 2012

Lipases were employed under solvent-free conditions to conjugate oligo-ricinoleic acid derivatives with 10-undecenoic acid, to incorporate a reactive terminal double bond into the resultant product. First, undecenoic acid was covalently attached to o...

  • Article
  • Open Access
78 Citations
11,937 Views
13 Pages

16 April 2012

Cellulose tri-stearate (CTs) was synthesized employing trifluoroacetic anhydride (TFAA), stearic acid (SA), with microcrystal cellulose (MCC) and characterized with FT-IR and 1H-NMR. The degree of substitution of CTs was determined by the traditional...

  • Article
  • Open Access
15 Citations
9,191 Views
12 Pages

16 April 2012

The radical-scavenging activities of two thiols, eight (thio)barbituric acid derivatives and six chain-breaking phenolic antioxidants were investigated using the induction period method for polymerization of methyl methacrylate (MMA) initiated by the...

  • Review
  • Open Access
11 Citations
7,106 Views
11 Pages

13 April 2012

Polymeric surfaces in contact with blood in vivo are foreign bodies and are quickly isolated from blood by the non-specific defense systems. Nanoparticles (NP) used as drug carriers are normally quickly taken up by phagocytes and sequestered in liver...

  • Review
  • Open Access
93 Citations
13,466 Views
15 Pages

13 April 2012

Hybrid hydrogels from biopolymers have been applied for various indications across a wide range of biomedical, pharmaceutical, and functional food industries. In particular, hybrid hydrogels synthesized from two biopolymers have attracted increasing...

  • Article
  • Open Access
12 Citations
7,784 Views
22 Pages

27 March 2012

A series of homopolymeric and copolymeric hydrogels containing the N-isopropylacrylamide and vinyl monomers with α-amino acid (L-valine and L-phenylalanine) residues have been synthesized and their swelling properties were evaluated under different e...

  • Review
  • Open Access
187 Citations
29,834 Views
51 Pages

26 March 2012

The relentless increase in the demand for useable power from energy-hungry economies continues to drive energy-material related research. Fuel cells, as a future potential power source that provide clean-at-the-point-of-use power offer many advantage...

  • Review
  • Open Access
56 Citations
11,860 Views
24 Pages

23 March 2012

Because of their extraordinary properties, such as high thermal stability, flame retardant, high chemical resistance and high mechanical strength, thermotropic liquid crystalline polymers (TLCPs) have recently gained more attention while being useful...

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Polymers - ISSN 2073-4360