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Crystals, Volume 13, Issue 6

2023 June - 129 articles

Cover Story: Surface chemistry and roughness influence surface energy and hence the wettability of the material’s surface. We have analysed the time dependence of the oxide layer growth and possible surface adsorbates on the surface topography of an Al59Cu25Fe13B3 quasicrystalline material in relation to changes in the surface energy. Under ambient conditions, the quasicrystal was naturally covered by an oxide layer; we refer to its surface energy as “surfenergy” to distinguish it from the conventional surface energy of a bare quasicrystal surface. The surfenergy depends on the polar component, which is the most sensitive to the material’s processing and may be tuned over more than an order of magnitude. The results indicate possible routes for the engineering and fine-tuning of quasicrystalline surfaces. View this paper
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Articles (129)

  • Article
  • Open Access
17 Citations
5,441 Views
13 Pages

20 June 2023

The research on rapid and efficient detection of microplastics in water is still in its early stages. Fluorescence feature recognition represents an important and innovative approach to microplastic detection. While carbon quantum dots have been wide...

  • Article
  • Open Access
3 Citations
2,251 Views
19 Pages

Experimental Study of the Evolution of Creep-Resistant Steel’s High-Temperature Oxidation Behavior

  • Gabriela Baranová,
  • Mária Hagarová,
  • Miloš Matvija,
  • Dávid Csík,
  • Vladimír Girman,
  • Jozef Bednarčík and
  • Pavel Bekeč

20 June 2023

This study shows that in an atmosphere containing water vapor, the oxide layer on the surface of the 9CrNB steel MarBN (Martensitic 9Cr steel strengthened by Boron and MX Nitrides) was formed by an outer layer of hematite Fe2O3 and Cr2O3 and an inner...

  • Communication
  • Open Access
5 Citations
2,450 Views
8 Pages

20 June 2023

Two-dimensional materials present abundant novel properties when used in advanced applications, which develops considerable focus. In this investigation, the first-principles calculations are explored to study the structural characteristic of the mon...

  • Article
  • Open Access
2,381 Views
19 Pages

Crystal Structure Analysis and Characterization of NADP-Dependent Glutamate Dehydrogenase with Alcohols Activity from Geotrichum candidum

  • Jing Zhu,
  • Hai Hou,
  • Kun Li,
  • Xiaoguang Xu,
  • Chunmei Jiang,
  • Dongyan Shao,
  • Junling Shi and
  • Dachuan Yin

20 June 2023

To better understand its mechanism of activity towards higher alcohols, we overexpressed and purified new Geotrichum candidum GDH (GcGDH). The purified GcGDH (50.27 kDa) was then crystallized, and the crystal diffracted to a resolution of 2.3 Å...

  • Article
  • Open Access
4 Citations
3,333 Views
17 Pages

Temperature Induced Monoclinic to Orthorhombic Phase Transition in Protonated ZSM-5 Zeolites with Different Si/Al Ratios: An In-Situ Synchrotron X-ray Powder Diffraction Study

  • Nicola Precisvalle,
  • Maura Mancinelli,
  • Matteo Ardit,
  • Giada Beltrami,
  • Lara Gigli,
  • Alfredo Aloise,
  • Enrico Catizzone,
  • Massimo Migliori,
  • Girolamo Giordano and
  • Annalisa Martucci
  • + 1 author

20 June 2023

ZSM-5 zeolite is the synthetic counterpart to mutinaite. After thermal activation of the as-synthesized form, the symmetry of the ZSM-5 zeolite is lowered to the monoclinic P21/n. ZSM-5 then undergoes a polymorphic displacive phase transition from th...

  • Article
  • Open Access
4 Citations
2,174 Views
12 Pages

20 June 2023

The densification of cemented carbides during sintering was studied using an existing constitutive model based on powder particle size and material composition. In the present analysis, we study how well the constitutive model can capture the experim...

  • Article
  • Open Access
2 Citations
2,777 Views
11 Pages

20 June 2023

Agate attracts the attention of gem mineralogists because of its variable colors. The color of agate is closely related to its naming and classification, so it is necessary to study the color and mineral origin of agate. In this paper, the mineralogi...

  • Review
  • Open Access
25 Citations
9,748 Views
9 Pages

Recent Advances in Polydopamine for Surface Modification and Enhancement of Energetic Materials: A Mini-Review

  • Ziquan Qin,
  • Dapeng Li,
  • Yapeng Ou,
  • Sijia Du,
  • Qingjie Jiao,
  • Jiwu Peng and
  • Ping Liu

19 June 2023

Polydopamine (PDA), inspired by the adhesive mussel foot proteins, is widely applied in chemical, biological, medical, and material science due to its unique surface coating capability and abundant active sites. Energetic materials (EMs) play an esse...

  • Article
  • Open Access
11 Citations
2,626 Views
14 Pages

Developing CeO2-CoAl2O4 Semiconductor Ionic Based Heterostructure Composite Electrolyte for Low-Temperature Solid Oxide Fuel Cells (SOFCs)

  • Yiwang Dong,
  • Muhammad Yousaf,
  • Muhammad Ali Kamran Yousaf Shah,
  • Muhammad Akbar,
  • Yuzheng Lu,
  • Lei Zhang,
  • Qadeer Akbar Sial,
  • Peng Cao and
  • Changhong Deng

19 June 2023

Semiconductor ionic electrolytes, especially heterostructure composites, have a significant role in enhancing oxide ion conductivity and peak power density (PPD) because of their interfacial contact. In this work, the fluorite structure CeO2 and spin...

  • Article
  • Open Access
1 Citations
2,271 Views
16 Pages

Two Conformational Polymorphs of a Bioactive Pyrazolo[3,4-d]pyrimidine

  • Sang Loon Tan,
  • Yee Seng Tan,
  • Jia Hui Ng,
  • Anton V. Dolzhenko and
  • Edward R. T. Tiekink

19 June 2023

Two monoclinic (P21/c; Z′ = 1) polymorphs, α (from methanol) and β (from ethanol, n-propanol and iso-propanol), of a bioactive pyrazolo[3,4-d]pyrimidine derivative have been isolated and characterised by X-ray crystallography as well...

  • Review
  • Open Access
10 Citations
3,608 Views
14 Pages

19 June 2023

Transmission electron microscope (TEM) is thought as one powerful tool to imaging the atomic-level structure of organic inorganic hybrid perovskite (OIHP) materials, which provides valuable and essential guidance toward high performance OIHP-related...

  • Article
  • Open Access
7 Citations
2,664 Views
21 Pages

19 June 2023

In this correspondence, a new photonic crystal fiber biosensor structure on the basis of surface plasmon resonance is proposed for the measurement of the refractive index (RI) and TSM temperature simultaneously. In this design, the central and extern...

  • Article
  • Open Access
2 Citations
2,824 Views
8 Pages

19 June 2023

Triangular lattice magnets have attracted extensive research interest because they are potential hosts for geometrically frustrated magnetism and strong quantum fluctuations. Here, utilizing a laser floating zone technique, we report the first-time s...

  • Article
  • Open Access
6 Citations
3,209 Views
10 Pages

Study on Growth Interface of Large Nd:YAG Crystals

  • Jiliang Quan,
  • Guanzhen Ke,
  • Yali Zhang,
  • Jian Liu and
  • Jinqiang Huang

19 June 2023

A study was performed on the growth interface of a large-diameter 1 at% neodymium-doped yttrium aluminum garnet (Nd:YAG) single crystal grown using the Czochralski method. Red parallel light and an orthogonal polarizing system were used to observe th...

  • Article
  • Open Access
4 Citations
2,315 Views
21 Pages

19 June 2023

Under strain control tests and cyclic loading, extruded magnesium alloys exhibit a special mechanism of plastic deformation (“twinning” and “de-twining”). As a result, magnesium alloys exhibit an asymmetric material behavior t...

  • Review
  • Open Access
25 Citations
7,673 Views
16 Pages

19 June 2023

Liquid lead–bismuth eutectic alloy is one of the candidate coolants for fourth-generation nuclear power systems because of its good physical and chemical properties, neutron economic performance, and safety. However, the compatibility between the coo...

  • Article
  • Open Access
8 Citations
3,935 Views
16 Pages

The Multi-Analytical Characterization of Calcium Oxalate Phytolith Crystals from Grapevine after Treatment with Calcination

  • Gwenaëlle Trouvé,
  • Laure Michelin,
  • Damaris Kehrli,
  • Ludovic Josien,
  • Séverinne Rigolet,
  • Bénédicte Lebeau and
  • Reto Gieré

18 June 2023

Calcium oxalate phytoliths are one of the most prominent types of Ca speciation in the plant kingdom, and they store extensive amounts of carbon in crystalline form. Ca phytoliths were investigated in the root, trunk, and bark of Vitis vinifera Chass...

  • Article
  • Open Access
5 Citations
3,444 Views
11 Pages

Enhanced Performances of Quantum Dot Light-Emitting Diodes with an Organic–Inorganic Hybrid Hole Injection Layer

  • Ling Chen,
  • Donghuai Jiang,
  • Wenjing Du,
  • Jifang Shang,
  • Dongdong Li and
  • Shaohui Liu

18 June 2023

PEDOT:PSS (polyethylene dioxythiophene:polystyrenesulfonate) is a commonly used hole injection layer (HIL) in optoelectronic devices due to its high conductive properties and work function. However, the acidic and hygroscopic nature of PEDOT:PSS can...

  • Review
  • Open Access
10 Citations
4,009 Views
13 Pages

Photoaligned Liquid Crystalline Structures for Photonic Applications

  • Aleksey Kudreyko,
  • Vladimir Chigrinov,
  • Gurumurthy Hegde and
  • Denis Chausov

17 June 2023

With the advancement of information display technologies, research on liquid crystals is undergoing a tremendous shift to photonic devices. For example, devices and configurations based on liquid crystal materials are being developed for various appl...

  • Article
  • Open Access
10 Citations
3,543 Views
13 Pages

Effect of Aging Temperature on Precipitates Evolution and Mechanical Properties of GH4169 Superalloy

  • Anqi Liu,
  • Fei Zhao,
  • Wensen Huang,
  • Yuanbiao Tan,
  • Yonghai Ren,
  • Longxiang Wang and
  • Fahong Xu

17 June 2023

GH4169 is primarily strengthened through precipitation, with heat treatment serving as a crucial method for regulating the precipitates of the alloy. However, the impact of aging temperature on the microstructure and properties of GH4169 has not been...

  • Article
  • Open Access
2 Citations
2,247 Views
15 Pages

16 June 2023

Alunogen, Al2(SO4)3·17H2O, occurs as an efflorescent in acid mine drainage, low-temperature fumarolic or pseudofumarolic (such as with coal fires) terrestrial environments. It is considered to be one of the main Al-sulphates of Martian soils,...

  • Article
  • Open Access
2 Citations
2,056 Views
9 Pages

Collective Relaxation Processes in Nonchiral Nematics

  • Neelam Yadav,
  • Yuri P. Panarin,
  • Wanhe Jiang,
  • Georg H. Mehl and
  • Jagdish K. Vij

16 June 2023

Nematic–nematic transitions in a highly polar nematic compound are studied, in thick cells in which the molecules are aligned parallel to the substrates but perpendicular to the applied electric field, using dielectric spectroscopy in the frequ...

  • Article
  • Open Access
11 Citations
3,218 Views
15 Pages

Nitrogen-Doped Graphene Quantum Dot–Tin Dioxide Nanocomposite Ultrathin Films as Efficient Electron Transport Layers for Planar Perovskite Solar Cells

  • Ha Chi Le,
  • Nam Thang Pham,
  • Duc Chinh Vu,
  • Duy Long Pham,
  • Si Hieu Nguyen,
  • Thi Tu Oanh Nguyen and
  • Chung Dong Nguyen

16 June 2023

Tin dioxide (SnO2) has recently been recognized as an excellent electron transport layer (ETL) for perovskite solar cells (PSCs) due to its advantageous properties, such as its high electron mobility, suitable energy band alignment, simple low-temper...

  • Article
  • Open Access
3 Citations
1,859 Views
13 Pages

Structural, Morphological and Dielectric Characterization of BiFeO3 Fibers Grown by the LFZ Technique

  • Marina Vieira Peixoto,
  • Florinda Mendes Costa,
  • Susana Devesa and
  • Manuel Pedro Fernandes Graça

16 June 2023

BiFeO3 fibers were prepared by the Laser Floating Zone (LFZ) technique using different growth speeds. The structural characterization of the samples was undertaken using X-ray diffraction (XRD) and Raman spectroscopy, the morphological characterizati...

  • Article
  • Open Access
4 Citations
3,538 Views
18 Pages

15 June 2023

The classical polarimetric method has been widely used in liquid crystal on silicon (LCoS) phase measurement with a simple optical setup. However, due to interference caused by LCoS cover glass reflections, the method lacks accuracy for phase uniform...

  • Review
  • Open Access
34 Citations
9,657 Views
13 Pages

15 June 2023

Zeolites, as a class of crystalline minerals, find a wide range of applications in various fields, such as catalysis, separation, and adsorption. More recently, these materials have also been developed for advanced applications, such as gas storage,...

  • Article
  • Open Access
2 Citations
1,800 Views
21 Pages

15 June 2023

In this paper, we numerically and experimentally show that the director field orientation degeneracy within the Translationally Invariant Configuration (TIC) of a cholesteric liquid crystal under an electric field can be lifted by imposing a magnetic...

  • Article
  • Open Access
11 Citations
2,323 Views
15 Pages

Novel Porous Organic Polymer for High-Performance Pb(II) Adsorption from Water: Synthesis, Characterization, Kinetic, and Isotherm Studies

  • Saad Melhi,
  • Eid H. Alosaimi,
  • Belal El-Gammal,
  • Wafa A. Alshahrani,
  • Yasser F. El-Aryan,
  • Hamdan A. Al-Shamiri and
  • Habib Elhouichet

15 June 2023

The aim of the current study was to develop a novel triphenylaniline-based porous organic polymer (TPABPOP-1) by the Friedel–Crafts reaction for the efficient elimination of Pb(II) from an aqueous environment. XPS, FTIR, SEM, TGA, and 13C CP/MA...

  • Article
  • Open Access
2 Citations
2,374 Views
14 Pages

Cerium Niobate Hollow Sphere Engineered Graphitic Carbon Nitride for Synergistic Photothermal/Chemodynamic Cancer Therapy

  • Kayalvizhi Samuvel Muthiah,
  • Senthilkumar Thirumurugan,
  • Yu-Chien Lin,
  • Rajalakshmi Sakthivel,
  • Udesh Dhawan,
  • An-Ni Wang,
  • Michael Hsiao and
  • Ren-Jei Chung

15 June 2023

Reactive oxygen species (ROS)-mediated chemodynamic therapy (CDT) and photothermal therapy (PTT) have potential for various cancer treatments. However, they are still bound by the demands of Fenton reaction conditions such as oxygen dependence, inher...

  • Article
  • Open Access
2 Citations
1,962 Views
15 Pages

Phase Structures and Dielectric Properties of (n + 1)SrO − nCeO2 (n = 2) Microwave Ceramic Systems with TiO2 Addition

  • Qi Su,
  • Jingjing Qu,
  • Fei Liu,
  • Changlai Yuan,
  • Xiao Liu,
  • Mingwei Su,
  • Liufang Meng and
  • Guohua Chen

15 June 2023

Ti4+-ion-doped (n + 1)SrO − nCeO2 (n = 2) ceramic systems were prepared with the conventional solid-state reaction method, and the effects of the phase structures and compositions, sintering behaviors, microstructures and microwave dielectric p...

  • Article
  • Open Access
2 Citations
2,433 Views
11 Pages

Structural Disorder of CuO, ZnO, and CuO/ZnO Nanowires and Their Effect on Thermal Conductivity

  • Helver Augusto Giraldo-Daza,
  • José Darío Agudelo-Giraldo,
  • César Leandro Londoño-Calderón and
  • Henry Reyes-Pineda

15 June 2023

In this work, the structural defects and the thermal conductivity of CuO, ZnO, and CuO/ZnO nanowires have been studied, using molecular dynamics simulation with COMB3 potential. The initial parameters and atoms positions were taken from reports of bu...

  • Article
  • Open Access
4 Citations
2,840 Views
15 Pages

Aqueous Chemical Synthesis of Nanosized ZnGa2O4 Using Mild Reaction Conditions: Effect of pH on the Structural, Morphological, Textural, Electronic, and Photocatalytic Properties

  • Dalia Téllez-Flores,
  • Manuel Sánchez-Cantú,
  • María de Lourdes Ruiz-Peralta,
  • Esteban López-Salinas,
  • Armando Pérez-Centeno,
  • Francisco Tzompantzi and
  • Alejandro Escobedo-Morales

14 June 2023

The effect of pH on the structural, textural, morphological, and electronic properties of ZnGa2O4 nanoparticles obtained by coprecipitation using mild reaction conditions (25 °C; 30 min) was studied. The pH ranges in which coprecipitation reactio...

  • Article
  • Open Access
1 Citations
2,236 Views
12 Pages

Properties of Potassium Doped and Tantalum Containing Tungsten after Heavy Ion Irradiation

  • Juan Du,
  • Chuan Wu,
  • Tianyu Zhao,
  • Pan Wen,
  • Pinghuai Wang,
  • Jun Tang,
  • Xiang Liu and
  • Jiming Chen

14 June 2023

Tungsten potassium (WK) alloy has been reported as one of the ideal plasma-facing materials (PFMs). Tantalum alloying is a good method to improve the mechanical properties of tungsten. The effect of tantalum contents on the irradiation resistance of...

  • Editorial
  • Open Access
1 Citations
1,621 Views
2 Pages

Extractive Metallurgy and Chemistry

  • Dmitry Zinoveev,
  • Pavel Grudinsky and
  • Valery Dyubanov

13 June 2023

In recent years, the proper management and recycling of metallurgical waste have become increasingly important due to their significant environmental impact and the potential for the recovery of valuable metals in order to save natural resources [...]

  • Article
  • Open Access
2 Citations
1,827 Views
14 Pages

Consolidation of Zn-Hydroxyapatite and Zn-Bioactive Glass Composites Using High-Pressure Torsion

  • Amanda P. Carvalho,
  • Andressa C. de O. Assunção,
  • Jorgimara de O. Braga,
  • Débora R. Lopes,
  • Diogo M. M. dos Santos,
  • Eduardo Henrique M. Nunes,
  • Fernando Cotting and
  • Roberto B. Figueiredo

13 June 2023

There has been a great interest in developing zinc-based composites for biological applications. Mixing bioactive particles and obtaining a well-dispersed structure is not straight forward though. The present study reports a novel processing route in...

  • Article
  • Open Access
3 Citations
2,176 Views
19 Pages

12 June 2023

Titanium alloys are widely used as construction materials in the aerospace and automotive industries. They have many advantages but also have limitations related to their susceptibility to high-temperature oxidation and hot corrosion. Many efforts to...

  • Article
  • Open Access
2 Citations
2,928 Views
10 Pages

Synthesis and Structure Characterization of Three Pharmaceutical Compounds Based on Tinidazole

  • Na Li,
  • Yuting Chen,
  • Ruixin Chen,
  • Mingjuan Zhang,
  • Tingting Wu and
  • Kang Liu

12 June 2023

Tinidazole (TNZ), a 5-nitroimidazole derivative, has received increasing attention due to its pharmacological activities in treatment for amebic and parasitic infections. In this paper, we synthesized three novel drug supramolecular compounds success...

  • Article
  • Open Access
1 Citations
2,172 Views
11 Pages

12 June 2023

In recent years, unidimensional photonic crystal-based biosensors have attracted significant attention due to their potential for label-free bio-detection of cells, proteins, and other organic molecules. These biosensors are based on alternating mate...

  • Article
  • Open Access
4 Citations
2,688 Views
19 Pages

12 June 2023

Reduction–oxidation (redox) cycling of a solid oxide fuel cell (SOFC) due to leakage of a fuel or standby and shutdown cycling is an issue that has attracted the attention of many research groups for a long time. The researchers mainly note the harmf...

  • Article
  • Open Access
3 Citations
3,844 Views
10 Pages

Energy-Composition Relations in Ni3(Al1−xXx) Phases

  • Nikolai A. Zarkevich,
  • Timothy M. Smith and
  • John W. Lawson

11 June 2023

The secondary phase, such as Ni3Al-based L12 γ′, is crucially important for the precipitation strengthening of superalloys. Composition–structure–property relations provide useful insights for guided alloy design. Here we use...

  • Article
  • Open Access
16 Citations
3,430 Views
16 Pages

11 June 2023

The multicomponent reaction of 4-nitrobenzaldehyde with acetophenone and urea in the presence of HCl was investigated, and, as a result, 4,5-bis(4-nitrophenyl)-8a-phenyl-decahydro-[1,3]diazino[4,5-d]pyrimidine-2,7-dione was synthesized. The structure...

  • Article
  • Open Access
4 Citations
2,031 Views
14 Pages

11 June 2023

The influence of ionic substitution in the Ca1−xCoxHPO4·nH2O compound was studied systematically for the first time. Among the fascinating features of these biomaterials is that they can be easily tailored for specific applications, for...

  • Article
  • Open Access
1 Citations
2,919 Views
13 Pages

11 June 2023

In ferroelectric memory, the repeated application of external electric fields can cause ferroelectric fatigue, limiting its stability and service life, especially as the storage unit size decreases. To address this issue, we conducted first-principle...

  • Article
  • Open Access
2 Citations
2,796 Views
11 Pages

Two-Dimensional Lattices with Lanthanoids, Anilato Ligands and Formamide

  • Samia Benmansour,
  • Antonio Hernández-Paredes,
  • Kilian Defez-Aznar and
  • Carlos J. Gómez-García

11 June 2023

Here, we illustrate the use of formamide (fma) and anilato-type ligands to build two-dimensional lattices with lanthanoids. Thus, we describe the synthesis and crystal structure of four lattices formulated as [Ln2(C6O4X2)3(fma)6]·6fma with Ln/...

  • Article
  • Open Access
3 Citations
2,717 Views
14 Pages

3D Printed Microfluidic Cell for SAXS Time-Resolved Measurements of the Structure of Protein Crystallization Solutions

  • Margarita A. Marchenkova,
  • Sergei V. Chapek,
  • Petr V. Konarev,
  • Ksenia B. Ilina,
  • Georgy S. Peters,
  • Yury V. Pisarevsky,
  • Vladimir A. Shishkov,
  • Alexander V. Soldatov and
  • Mikhail V. Kovalchuk

11 June 2023

A multichannel microfluidic cell (MFC) obtained using 3D printing for studying the structure of complex solutions by small-angle X-ray scattering (SAXS) is described. MFC was tested at the BioMUR beamline of the Kurchatov synchrotron. A comparative a...

  • Article
  • Open Access
3 Citations
2,013 Views
20 Pages

10 June 2023

One-dimensional spin crossover (SCO) solids that convert between the low spin (LS) and the high spin (HS) states are widely studied in the literature due to their diverse thermal and optical characteristics which allow obtaining many original behavio...

  • Article
  • Open Access
9 Citations
2,479 Views
15 Pages

A Novel Design to Eliminate Lüders Band in Medium-Mn Steel and Its Microstructure-Property Relationship

  • Rendong Liu,
  • Zhiping Hu,
  • Chunqing Lin,
  • Dapeng Yang,
  • Xingli Gu,
  • Xin Xu and
  • Jinyu Guo

10 June 2023

In the current work, we design a novel medium Mn steel with a superior mechanical property and no Lüders band. For industrial applications, a “low Mn addition” chemical composition and two kinds of different annealing processes with...

  • Article
  • Open Access
3 Citations
2,748 Views
12 Pages

The Optimizing Effect of Nitrogen Flow Ratio on the Homoepitaxial Growth of 4H-SiC Layers

  • Weilong Yuan,
  • Yicheng Pei,
  • Ning Guo,
  • Yunkai Li,
  • Xiuhai Zhang and
  • Xingfang Liu

10 June 2023

In this study, a 4H-SiC homoepitaxial layer was grown on a 150 mm 4° off-axis substrate using a horizontal hot-wall CVD reactor. The research aimed to investigate the impact of varying the C/Si ratio and temperature while also changing the N2 flo...

  • Article
  • Open Access
2 Citations
3,183 Views
17 Pages

10 June 2023

In this paper, two cathinone derivatives, 4F-3Me-α-PVP and N-ethylheptedrone, seized on the illegal drug market in Poland, were described and characterized by various instrumental analytical methods. The compounds were characterized by electros...

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Crystals - ISSN 2073-4352