Chemistry, Volume 7, Issue 5

The presence of a so-called ‘inert pair effect’ in the chemistry of the 6p elements has been recognised for almost a century. Following a brief historical overview and a summary of the explanations that have been advanced to account for t...

Selenium, an essential metalloid, plays a dual role in biological systems: while crucial for maintaining normal biological processes, excessive levels can be toxic. Organisms mitigate selenium toxicity through a biochemical process known as methylati...

Photocatalytic oxidation technology harnesses solar energy for pollutant mineralization, presenting significant potential for environmental applications. A critical bottleneck remains the development of high-performance photocatalysts. This study cen...

To develop new hybrid anticancer agents, 3,5-bis(benzylidene)-4-piperidone scaffolds (compounds 1–6) were functionalized with (1R)-borneoyl chloroacetate (8) or (1S)-camphorsulfonyl chloride (10). Covalent attachment of the camphorsulfonyl moie...

To address the greenhouse effect and environmental pollution stemming from fossil fuels, the development of new energy sources is widely regarded as a critical pathway toward achieving carbon neutrality. Microalgae, as a feedstock for third-generatio...

Biosensing plays a vital role in medical diagnostics, environmental monitoring, and food safety, enabling highly sensitive and specific detection of diverse biological and chemical targets. However, conventional biosensing platforms still suffer from...

Non-perturbative approaches to linear and nonlinear responses (NLR) of atoms, molecules, and molecular aggregates are reviewed in relation to low and high harmonic generations (HG) by laser fields. These response properties are effective for the gene...

Thiochromen-4-ones are known to possess useful optical properties and rich bioactivities, including antioxidant, antimicrobial, and anticancer properties. They are known to inhibit tumor cell growth, induce apoptosis, and have antiplatelet aggregatio...

Five different 2,4-difluorobenzamide derivatives were synthesized and fully characterized by ¹H/¹³C/¹⁹F/2D NMR spectroscopy using DMSO-d₆ as solvent and MS. All compounds occur as rotation conformers resulting from the partial amide double bond with...

Molecular dynamics simulations were conducted using the attachment energy (AE) model to investigate the growth morphology of lead 2,4,6-trinitrororesorcinate (LTNR, lead styphnate) under vacuum and different solvents. The adsorption energy of LTNR on...

The goal of this study is to estimate the amount of lost data in electron microscopy and to analyze the extent to which experimentally acquired images are utilized in peer-reviewed scientific publications. Analysis of the number of images taken on el...

Gold nanoparticles (AuNPs) are attracting more and more attention in life sciences, especially due to their versatile physicochemical properties whereby their colloidal stability in water and organic solvents is crucial. In this study, a systematic c...

A straightforward synthetic method is advanced to produce hard-to-reach polycyclic compounds belonging to the [1,2,5]oxadiazolo[3,4-b]quinoxaline ring system. This approach draws on a combination of the nucleophilic aromatic substitution of hydrogen...

The reaction of 4,4′-bipyridine (C₁₀H₈N₂) with the alkali metal pentacyanocyclopentadienides [Na{C₅(CN)₅}(MeOH)] and [KC₅(CN)₅] gives the coordination polymers [Na{C₅(CN)₅}(EtOH)(H₂O)(C₁₀H₈N₂)] (1) and [K{C₅(CN)₅}(H₂O)₂] • 2 (C₁₀H₈N₂) (2)...

An increase in the production of cationic dyes is expected over the next decade, which will have an impact on health and the environment. This work reports an adsorbent hydrogel composed of poly(acrylic acid) [poly(AA)] and Fe₃O₄ particles, prepared...

Density functional theory calculations are performed to examine the reactivity of the coordinatively unsaturated (NH₃)₄RhO²⁺, (NH₃)₄CoO²⁺, and (NH₃)₄FeO⁺ species with methane and methanol. The ground low-spin state of rhodium oxide provides ideal ene...

Advancing catalysts for low-temperature NH₃-SCR enhances their viability as a terminal flue gas denitration solution across diverse operating regimes. A high-performance, hydrothermally stable catalyst for low-temperature SCR was synthesized by depos...

With the rapid industrialization, excessive reliance on fossil fuels has resulted in energy crises and environmental pollution, driving the search for sustainable alternatives. Biomass-derived resources have emerged as promising candidates to replace...

The activation of carbon dioxide by transition metal complexes is a fundamental process in catalysis and carbon capture. In this study, density functional theory (DFT) calculations, combined with Quantum Theory of Atoms in Molecules (QTAIM) and Natur...

A series of twenty-five salicylic acid derivatives was synthesized and structurally characterized by ¹H and ¹³C-APT NMR and IR spectroscopic techniques, and HRMS analysis. The derivatives were subjected to biological evaluation against species of the...

Lead-free perovskite variants have emerged as promising candidates due to their self-trapped exciton emission. However, in ASnX₃ systems, facile oxidation of Sn(II) to Sn(IV) yields A₂SnCl₆ vacancy-ordered derivatives. Paradoxically, despite possessi...

The chemical composition of Rosa alba L. aromatic products extracted with liquified 1,1,1,2-tetrafluoroethane (freon R134a) has been evaluated in static and dynamic modes of extraction. The yield varies in the range 0.039–0.048% for the differe...

Cancer is one of the leading causes of illness and death in the world. It is observed that the main reason for the low effectiveness of cancer treatment is limited bioavailability. Another noted cause is the lack of specificity of conventional chemot...

MgF₂ films are prepared using plasma-enhanced atomic layer deposition (PEALD). The influence of substrate temperature on the growth behavior, chemical composition, and optical properties of MgF₂ films is systematically investigated. The experimental...

Applying therapeutic elements to prevent injury from potential infections is a promising avenue in the development of novel bone substitutes; however, achieving controllable delivery of therapeutic ions is crucial to realizing their expected function...

The thioether-functionalized 2-azabutadiene (ⁱPrS)₂C=C(H)-N=CPh₂ L1 ligates to Mn(CO)₅Br to form the five-membered chelate compound fac-MnBr(CO)₃[(ⁱPrS)₂C=C(H)-N=CPh₂] MnPropBr, whose crystal structure has been determined from X-ray diffraction...

Extraction processes of alginates from Sargassum spp. generate a substantial number of solid residues that are commonly discarded. This study explores the sustainable transformation of these residues into nitrogen-doped biocarbon through chemical act...

Turmeric is a spice that has gained significant popularity in global cuisine. Beyond its culinary applications, it possesses significant medicinal properties, including antioxidant, anti-inflammatory, and antibacterial properties, which are attribute...

With the rising importance of nuclear energy in the global energy landscape, the sustainable development of uranium resources has garnered increasing attention. Salt lake brine, as an unconventional uranium source, holds significant potential due to...

Chronic injuries and diseases related to oxidative stress are major global concerns as they impose a great medical burden and lead to serious public health issues. Antioxidant peptides derived from pea protein can serve as potent antioxidants and foo...

The creation of larger prebiotic molecules in astronomical regions may require aminoketene (NH₂CHCO) as an intermediate, and the two conformers of this molecule exhibit infrared vibrational frequencies with intensities larger even than the antisymmet...

Heat shock proteins (HSPs), a family of proteins including HSP27, HSP40, HSP60, HSP70, and HSP90, play critical roles in cellular processes and are often dysregulated in cancer. Heat Shock Factor 1 (HSF1) protein, the master regulator of HSP expressi...

A molten-metal catalyst exhibits strong resistance to carbon encapsulation and deactivation, due to its unique physical and chemical properties, demonstrating excellent catalytic activity and stability. This paper overviews recent developments in mol...

The ion doping of hydroxyapatite (HA) has gained appeal as a chemical method of improving and adding new characteristics to materials used in biomedical engineering. Dimension, morphology, porosity, surface charge, topology, composition, and other ma...

This study employs molecular orbital (MO) analysis, density of states (DOS) analysis, and advanced techniques such as charge density difference (CDD), transition density matrix (TDM), transition electric dipole moment density (TEDM), and transition m...