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Magnetochemistry, Volume 8, Issue 7

2022 July - 9 articles

Cover Story: Micro- and nano-structured metal layers are attractive for numerous applications including microelectronics, microcopies and electrocatalysis. Using pulse-reverse electroplating on a planar but magnetically patterned electrode, tall copper structures of about 2 μm height are obtained. A new numerical approach is presented which allows better agreement with the experimental results. A detailed discussion of the magnetic forces and the buoyancy force involved allows us to clarify the growth mechanism of the micro-structures during the alternating pulses and to give an explanation of why the maximum height of the structures is limited to a few microns. View this paper
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Articles (9)

  • Article
  • Open Access
2,131 Views
11 Pages

ESR Investigations of the Submicron LiFe1−xMnxPO4 Systems

  • Tatiana Gavrilova,
  • Adilya Yagfarova,
  • Sergey Khantimerov,
  • Dinar Abdullin,
  • Nina Kosova and
  • Nail Suleimanov

Magnetic properties of the submicron carbon-coated LiFe1−xMnxPO4 (x = 0, 0.01, 0.1) systems were investigated using the electron spin resonance (ESR) method. The observed ESR signal consisted of two broad resonance lines with a Lorentzian line...

  • Article
  • Open Access
15 Citations
4,682 Views
13 Pages

Terbium (III) Oxide (Tb2O3) Transparent Ceramics by Two-Step Sintering from Precipitated Powder

  • Dianjun Hu,
  • Xiaoying Li,
  • Lixuan Zhang,
  • Ilya Snetkov,
  • Penghui Chen,
  • Zhengfa Dai,
  • Stanislav Balabanov,
  • Oleg Palashov and
  • Jiang Li

As a result of preliminary air calcination and subsequent reduction in a flowing NH3 atmosphere of the precursor from the liquid precipitation method for the first time, pure-phase Tb2O3 powder with an average particle size of 135 nm was prepared. Th...

  • Article
  • Open Access
8 Citations
2,988 Views
16 Pages

Magnetic and Luminescence Properties of 8-Coordinated Pyridyl Adducts of Samarium(III) Complexes Containing 4,4,4-Trifluoro-1-(naphthalen-2-yl)-1,3-butanedionate

  • Franz A. Mautner,
  • Florian Bierbaumer,
  • Ramon Vicente,
  • Saskia Speed,
  • Ánnia Tubau,
  • Roland C. Fischer and
  • Salah S. Massoud

A novel series of polypyridyl adducts, [Sm(ntfa)3(NN)] (24), with ntfa = 4,4,4-trifluoro-1-(naphthalen-2-yl)-1,3-butanedionate, NN = 2,2′-bipyridine (bipy), 4,4′-dimethyl-2,2′-bipyridine (4,4′-Me2bipy), and 5,5′-d...

  • Feature Paper
  • Article
  • Open Access
5 Citations
3,124 Views
66 Pages

Theory of Chiral Electrodeposition by Chiral Micro-Nano-Vortices under a Vertical Magnetic Field -1: 2D Nucleation by Micro-Vortices

  • Ryoichi Morimoto,
  • Miki Miura,
  • Atsushi Sugiyama,
  • Makoto Miura,
  • Yoshinobu Oshikiri,
  • Iwao Mogi,
  • Yusuke Yamauchi,
  • Satoshi Takagi and
  • Ryoichi Aogaki

Remarkable chiral activity is donated to a copper deposit surface by magneto-electrodeposition, whose exact mechanism has been clarified by the three-generation model. In copper deposition under a vertical magnetic field, a macroscopic tornado-like r...

  • Article
  • Open Access
4 Citations
2,661 Views
10 Pages

Influence of a Constant Magnetic Field on the Mechanism of Adrenaline Oxidation

  • Vyacheslav N. Kazin,
  • Evgenii A. Guzov,
  • Valentina A. Moshareva and
  • Evgenii M. Pliss

In order to establish the role of the magnetic effect in the key stages of the autoxidation and initiated oxidation radical-chain reactions, the experimental data and kinetic analysis of the influence of a magnetic field on the oxidative transformati...

  • Feature Paper
  • Article
  • Open Access
1 Citations
2,917 Views
20 Pages

Corrosion Behavior of ZnMn Coatings Magnetoelectrodeposited

  • Lamia Allam,
  • Florica S. Lazar and
  • Jean-Paul Chopart

The zinc–manganese alloy coatings have been obtained without and with superimposition of a 0.3 T magnetic field in a parallel direction to the working surface electrode. The electrodeposition during 30 min, for two applied potentials (E = &minu...

  • Article
  • Open Access
2 Citations
2,586 Views
8 Pages

M-type Sr0.1Ca0.4La0.5Fe12O19 powder specimens doped with different precursors RFe2O4(R = Co, Ni, Cu, Zn, and Mg) were prepared via a traditional solid-state reaction method. The structural and magnetic properties of the specimens were studied. Only...

  • Review
  • Open Access
3 Citations
2,310 Views
14 Pages

Breaking of Odd Chirality in Magnetoelectrodeposition

  • Iwao Mogi,
  • Ryoichi Morimoto,
  • Ryoichi Aogaki and
  • Kohki Takahashi

Electrodeposition under magnetic fields (magnetoelectrodeposition; MED) can induce surface chirality on copper films. The chiral signs of MED films should depend on the magnetic field polarity; namely, the reversal of the magnetic field causes the op...

  • Article
  • Open Access
8 Citations
2,903 Views
12 Pages

Pulse Reverse Plating of Copper Micro-Structures in Magnetic Gradient Fields

  • Mengyuan Huang,
  • Margitta Uhlemann,
  • Kerstin Eckert and
  • Gerd Mutschke

Micro-structured copper layers are obtained from pulse-reverse electrodeposition on a planar gold electrode that is magnetically patterned by magnetized iron wires underneath. 3D numerical simulations of the electrodeposition based on an adapted reac...

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Magnetochemistry - ISSN 2312-7481