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Crystals, Volume 15, Issue 8

2025 August - 79 articles

Cover Story: This work expands the library of copper acetylacetonate adducts to include both volatile and non-volatile ligands. Four pentacoordinate complexes, two coordination polymers and one oligomer were synthesized and are discussed. The use of bidentate ligands yielded one-dimensional coordination polymers, while the use of monodentate ligands produced weaker pentacoordinate adducts. Of particular note is the synthesis and characterization of the pyridine adduct, which, despite its simplicity, has been structurally elucidated for the first time. Furthermore, the new adducts enable correlations to be established between the electronic properties of the ligand substituent and the structural diversity of the complexes. Additionally, Hirshfeld surface analysis was employed to investigate intermolecular interactions in the pyridine derivatives. View this paper
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Articles (79)

  • Article
  • Open Access
1,328 Views
14 Pages

21 August 2025

Beryl is classified as a cyclosilicate mineral, and its color is primarily determined by the type and oxidation state of trace elements. In this study, natural yellow-green beryl was used as the research subject, and heat treatment experiments were p...

  • Article
  • Open Access
1,019 Views
20 Pages

Luminescent Arylalkynyltitanocenes: Effect of Modifying the Electron Density at the Arylalkyne Ligand, or Adding Steric Bulk or Constraint to the Cyclopentadienyl Ligand

  • Matilda Barker,
  • Samantha C. Walter,
  • Elizabeth A. McCallum,
  • River S. Golden,
  • John H. Zimmerman,
  • Jackson S. McCarthy,
  • Colin D. McMillen and
  • Paul S. Wagenknecht

21 August 2025

Photocatalysis using complexes of d0 metals with ligand-to-metal charge-transfer (LMCT) excited states is an active area of research. Because titanium is the second most abundant transition metal in the earth’s crust, d0 complexes of TiIV are a...

  • Article
  • Open Access
1,051 Views
19 Pages

Temperature- and Emission Wavelength-Dependent Time Responses of Strontium Aluminates

  • Virginija Vitola,
  • Tinko Eftimov,
  • Kristian Nikolov,
  • Samia Fouzar and
  • Katrina Krizmane

20 August 2025

In this paper, we study the temperature- and emission wavelength-dependent time responses of previously reported precursor-driven Eu2+- and Dy3+-doped strontium-aluminate phosphors to create unique luminescent anti-counterfeiting tags suitable for de...

  • Article
  • Open Access
2 Citations
1,146 Views
16 Pages

Dispersion of Sintered Mg-Ni-Ce Materials for Efficient Hydrogen Storage

  • Nuriya Mukhamedova,
  • Arman Miniyazov,
  • Aisara Sabyrtayeva,
  • Timur Tulenbergenov and
  • Ospan Oken

20 August 2025

This paper presents the results of the effect of dispersion on the structural-phase state of the material for hydrogen storage of the Mg-Ni-Ce system. X-ray phase analysis and scanning electron microscopy studies have shown that the sequential use of...

  • Article
  • Open Access
1,226 Views
10 Pages

A Novel System for Crystal Polymorph Discovery via Selective-Wavelength Infrared Irradiation Using Metamaterials

  • Yoshio Kondo,
  • Tsuyoshi Totani,
  • Satoru Odashima,
  • Daiki Kato and
  • Norimitsu Tohnai

20 August 2025

The control of crystal polymorphs is central to the design of pharmaceuticals and functional materials. Conventionally, crystal polymorph production has been controlled primarily by adjusting chemical and thermodynamic parameters. In this study, we d...

  • Article
  • Open Access
1 Citations
997 Views
17 Pages

Investigating the Influence of Cerium Doping on the Structural, Optical, and Electrical Properties of ZnCexCo2xO4 Zinc Cobaltite Thin Films

  • Abdellatif El-Habib,
  • Mohamed Oubakalla,
  • Samir Haloui,
  • Youssef Nejmi,
  • Mohamed El Bouji,
  • Amal Yousfi,
  • Fouad El Mansouri,
  • Abdessamad Aouni,
  • Mustapha Diani and
  • Mohammed Addou

20 August 2025

Cerium-doped zinc cobaltite spinel thin films, ZnCexCo2−xO4 (0.00≤x≤0.05), were synthesized via spray pyrolysis, and their structural, morphological, optical, and electrical properties were analyzed. X-ray diffraction (XRD) confirmed...

  • Article
  • Open Access
841 Views
11 Pages

Behaviors of Gas-Rich Crystalline Fluid Inclusions

  • Luis Salgado,
  • François Faure and
  • Gérard Coquerel

20 August 2025

A novel behavior of fluid inclusions (FIs) in crystals is reported in this study. Typically, at “high” temperature, FIs in molecular crystals become faceted, adopting the morphology of a single crystal. Usually, upon cooling, these facete...

  • Article
  • Open Access
871 Views
13 Pages

Structure and Nonlinear Optical Characterization of a New Acentric Crystal of a 4-Hydroxybenzohydrazide Derivative

  • Emanuela Santagata,
  • Yovan de Coene,
  • Stijn Van Cleuvenbergen,
  • Koen Clays,
  • Emmanuele Parisi,
  • Fabio Borbone and
  • Roberto Centore

20 August 2025

We report the crystal structure and nonlinear optical (NLO) characterization of the monohydrate form of N′-[(E)-(2-fluorophenyl)methylidene]-4-hydroxybenzohydrazide (o-FHH), an organic compound showing strong potential for second-order nonlinea...

  • Article
  • Open Access
2,525 Views
17 Pages

20 August 2025

The long-term durability of steel structures in contact with soil remains a critical challenge due to the complex and aggressive nature of many soil environments. This study presents a thorough evaluation of the corrosion resistance and microstructur...

  • Article
  • Open Access
1 Citations
1,011 Views
18 Pages

Continuous Symmetry Breaking and Complexity of Biological Membranes

  • Samo Kralj,
  • Veronika Kralj-Iglič and
  • Aleš Iglič

20 August 2025

We consider domain-type patterns in biological membranes that possess an in-plane membrane order. Domains are inseparably linked to topological defects, and many features related to them can be guessed based on universal topological arguments. Howeve...

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Crystals - ISSN 2073-4352