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Catalysts, Volume 7, Issue 10

October 2017 - 31 articles

Cover Story: Brookite - the once least known TiO2 polymorph - is now recognized as an active phase with peculiar properties and photocatalytic performances. In this review, the most recent advances in brookite TiO2 materials synthesis and applications are summarized, focusing on structure/activity relations studies of phase and morphology-controlled materials. The days in which brookite was considered just an undesirable byproduct are long gone, it is now time to dig deeper and find out even more about this and other less familiar TiO2 polymorphs. View this paper
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Articles (31)

  • Article
  • Open Access
20 Citations
5,281 Views
13 Pages

Activated Carbon-Supported Tetrapropylammonium Perruthenate Catalysts for Acetylene Hydrochlorination

  • Xing Li,
  • Haiyang Zhang,
  • Baochang Man,
  • Lijuan Hou,
  • Chuanming Zhang,
  • Hui Dai,
  • Mingyuan Zhu,
  • Bin Dai,
  • Yanzhao Dong and
  • Jinli Zhang

24 October 2017

The Ru-based catalysts, including Ru/AC (activated carbon), TPAP (tetrapropylammonium perruthenate)/AC, TPAP/AC-HNO3, and TPAP/AC-HCl, were prepared and assessed for the direct synthesis of vinyl chloride monomer. The results indicate that the TPAP/A...

  • Article
  • Open Access
37 Citations
17,303 Views
24 Pages

Water–Gas Shift Reaction over Ni/CeO2 Catalysts

  • Ludmilla Bobrova,
  • Dmitry Andreev,
  • Eugene Ivanov,
  • Natalia Mezentseva,
  • Mikhail Simonov,
  • Lev Makarshin,
  • Alexander Gribovskii and
  • Vladislav Sadykov

20 October 2017

This paper reports the results of a study of a water–gas shift reaction over nickel–ceria catalysts with different metal loading. Within this study, the overall CO conversion and observed kinetic behavior were investigated over the temperature range...

  • Article
  • Open Access
14 Citations
9,459 Views
10 Pages

Concept of Vaporized Urea Dosing in Selective Catalytic Reduction

  • Rafal Sala,
  • Piotr Bielaczyc and
  • Marek Brzezanski

19 October 2017

This work tried to identify the influence of dosing vaporized urea solution in a selective catalytic reduction (SCR) system. In the SCR method, optimising the urea evaporation and mixing properties can significantly improve the NOx conversion efficie...

  • Article
  • Open Access
21 Citations
5,211 Views
14 Pages

Alcohol Dehydrogenation on Kraft Lignin-Derived Chars with Surface Basicity

  • Francisco J. García-Mateos,
  • Imane Moulefera,
  • Juana M. Rosas,
  • Abdelghani Benyoucef,
  • José Rodríguez-Mirasol and
  • Tomás Cordero

19 October 2017

The properties of lignin and its potential as a renewable source make it an ideal precursor for carbon products. Specifically, the high content of Na observed in Kraft lignin makes this industrial by-product an interesting precursor for the preparati...

  • Article
  • Open Access
45 Citations
7,084 Views
11 Pages

Synthesis of Biolubricant Basestocks from Epoxidized Soybean Oil

  • Rosa Turco,
  • Riccardo Tesser,
  • Rosa Vitiello,
  • Vincenzo Russo,
  • Salvatore Andini and
  • Martino Di Serio

19 October 2017

This work deals with the preparation of biolubricant basestocks through the ring-opening reaction of epoxidized soybean oil (ESO) by alcohols in presence of solid acid catalysts (SAC-13 resin). To this end, different experimental runs were carried ou...

  • Feature Paper
  • Review
  • Open Access
199 Citations
22,825 Views
19 Pages

18 October 2017

Machine learning has proven to be a powerful technique during the past decades. Artificial neural network (ANN), as one of the most popular machine learning algorithms, has been widely applied to various areas. However, their applications for catalys...

  • Feature Paper
  • Article
  • Open Access
38 Citations
7,530 Views
14 Pages

Flame-Made Cu/TiO2 and Cu-Pt/TiO2 Photocatalysts for Hydrogen Production

  • Massimo Bernareggi,
  • Maria Vittoria Dozzi,
  • Luca Giacomo Bettini,
  • Anna Maria Ferretti,
  • Gian Luca Chiarello and
  • Elena Selli

16 October 2017

The effect of Cu or Cu-Pt nanoparticles in TiO2 photocatalysts prepared by flame spray pyrolysis in one step was investigated in hydrogen production from methanol photo-steam reforming. Two series of titanium dioxide photocatalysts were prepared, con...

  • Feature Paper
  • Review
  • Open Access
147 Citations
14,332 Views
34 Pages

16 October 2017

Synthetic dyes are widely used in textile, paper, food, cosmetic, and pharmaceutical industries. During industrial processes, some of these dyes are released into the wastewater and their successive release into rivers and lakes produces serious envi...

  • Review
  • Open Access
73 Citations
10,217 Views
16 Pages

13 October 2017

Electrons, photogenerated in conduction bands (CB) and trapped in electron trap defects (Tids) in titanium dioxide (TiO2), play crucial roles in characteristic reductive reactions. This review summarizes the recent progress in the research on electro...

  • Feature Paper
  • Review
  • Open Access
92 Citations
12,185 Views
19 Pages

Brookite: Nothing New under the Sun?

  • Matteo Monai,
  • Tiziano Montini and
  • Paolo Fornasiero

13 October 2017

Advances in the synthesis of pure brookite and brookite-based TiO2 materials have opened the way to fundamental and applicative studies of the once least known TiO2 polymorph. Brookite is now recognized as an active phase, in some cases showing enhan...

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Catalysts - ISSN 2073-4344