Materials, Volume 12, Issue 5
2019 March-1 - 156 articles
Cover Story: A successful optimization of the thermoelectric properties of the Zintl phase, Yb14ZnSb11, is described as an almost electron precise Zintl phase with 13.24Yb2+ + 0.75Yb3+ + ZnSb49- + Sb37- + 4Sb3-. Replacement of Yb3+ with either Y3+, approximately the same size as Yb3+, or La3+, larger than Yb3+, is investigated. These two rare earths can be substitution in Yb14-xRExZnSb11 (RE = Y, La, x~0.5) and drastically improves the thermoelectric efficiency while also improving structural characteristics such as melting temperatures. The effective mass increases with temperature providing a significant increase in the Seebeck coefficient. Ideas for further increasing the efficiencies of the thermoelectric properties are provided. View this paper. - Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
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