Table of Contents
Molecules, Volume 23, Issue 12 (December 2018)
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Cover Story (view full-size image) Novel methinic functionalized and dendritic C-scorpionates is directed to the synthesis of new [...] Read more. Novel methinic functionalized and dendritic C-scorpionates is directed to the synthesis of new derivatives of tripodal C-scorpionate compounds. Tris-2,2,2-(1-pyrazolyl)ethanol, HOCH2C(pz)3, one of the most important derivatives of hydrotris(pyrazolyl)methane, was used as a building block for the synthesis of new functionalized C-scorpionates, with the aim of expanding the scope of this unexplored class of compounds. The first dendritic C-scorpionate was successfully prepared and used in the important industrial catalytic reactions, Sonogashira and Heck C-C cross-couplings. This work revealed that the anchorage of a tris(pyrazolyl)methane derivative on a dendritic surface is feasible and generates an important support for further studies in supramolecular and coordination chemistry, and in catalysis. View Paper here.