29 Results Found

Ionic liquids are an important component for constructing functional materials, and polyxometalate cluster anion is a promising partner for building inorganic–organic hybrid materials comprising ionic liquids. In such hybrid materials, the prec...

A series of commercial silica-supported polyoxometalate ionic liquids ([Cnmim]3PMo12O40) with different substitutes in the imidazole ring were prepared via a facile ball milling method and employed as catalysts in the oxidative desulfurization of org...

With the increasingly strict limitations on emission standards of vehicles, deep desulfurization in fuel is indispensable for social development worldwide. In this study, a series of hybrid materials based on SiO2-supported polyoxometalate ionic liqu...

Polyoxometalate (POM)-based ionic liquids (POM-ILs) are gaining increasing attention due to their diverse structures and functionalities. POMs in POM-ILs not only act as essential structural building blocks but also play a crucial role in their funct...

Solid electrolytes are crucial materials for lithium-ion or fuel-cell battery technology due to their structural stability and easiness for handling. Emergence of high conductivity in solid electrolytes requires precise control of the composition and...

Wettability is an important factor affecting the performance of catalytic oxidative desulfurization. In order to develop an efficient catalyst for the extractive coupled catalytic oxidative desulfurization (ECODS) of fuel oil by H2O2 and acetonitrile...

Polyoxometalate-based ionic liquid hybrid materials with a pyridinium cation, containing Brönsted acid sites, were synthesized and used as catalysts for the oxidation of model and real diesel fuels. Keggin-type polyoxometalates with the formulae...

Moulds inhabiting mineral-based materials may cause their biodeterioration, contributing to inestimable losses, especially in the case of cultural heritage objects and architectures. Fungi in mouldy buildings may also pose a threat to human health an...

The temperature of industrial gas containing harmful H2S can reach hundreds of degrees. However, few processes can be used directly for H2S removal from industrial high-temperature gas. In this work, three polyoxometalates with different central atom...

A novel porous polyoxometalate (POM)-based composite (Co4PW–PDDVAC) was prepared via the solidification of water-soluble polytungstate (Co4PW) on the polymeric ionic liquid dimethyldodecyl-4-polyethylene benzyl ammonium chloride (PDDVAC) via a...

An effective process to remove nitrogen-based compounds from fossil fuels without harming the process of sulfur removal is an actual gap in refineries. A success combination of desulfurization and denitrogenation processes capable of completely remov...

This paper deals with the preparation and the characterization of four new ionic liquids resulting from the pairing of various polyoxotungstates or polyoxomolybdates with the cation trihexyltetradecylphosphonium. The physical properties measured by d...

A correlation between polyoxotungstate structures and their catalytic performance for oxidative desulfurization processes was investigated. Bridged lanthanopolyoxometalates that incorporate identical metallic centers with Keggin- Eu[PW11O39]11−...

Different methodologies were used to increase the oxidative desulfurization efficiency of the Keggin phosphotungstate [PW12O40]3− (PW12). One possibility was to replace the acid proton by three different ionic liquid cations, forming the novel...

Polyoxometalates based ionic liquids (POM-ILs) exhibit a high catalytic activity in oxidative desulfurization. In this paper, four new POM-IL hybrids based on transition metal mono-substituted Keggin-type phosphomolybdates, [Bmim]5[PMo11M(H2O)O39] (B...

Two carboxylic functionalized poly(ionic liquids) and polyoxometalate ionic self-assemblies with tunable amphiphilic and oxidative activity and porous structure were designed and synthesized. They were used as efficient heterogeneous catalysts exhibi...

An effective and sustainable process capable of simultaneously execute desulfurization and denitrogenation of fuels is in fact an actual necessity in the refinery industry. The key to achieve this goal is the parallel oxidation of sulfur and nitrogen...

To address the challenge of ultra-deep desulfurization in fuels, a series of heteropolyacid-based poly(ionic liquid) catalysts (C4-PIL@PW, C8-PIL@PW, and C16-PIL@PW) were synthesized via radical polymerization and anion exchange methods. The prepared...

With the rapid growth in fuel demand, deep desulfurization of fuel oil is vitally necessary for the sake of health and environmental protection. In this work, a kind of magnetic ionic liquid supported silica is prepared by a facile ball milling metho...

In this article, a series of effective catalysts based on betaine and sulfuric or phosphomolybdic acids was obtained. These compositions were characterized by various physicochemical methods and tested in the oxidation of sulfur- and nitrogenous-cont...

Polyoxomolybdate inorganic-organic hybrid crystals were synthesized with 1-decyl-3-methylimidazolium and 1-dodecyl-3-methylimidazolium as ionic-liquid surfactants. Both hybrid crystals possessed alternate stacking of surfactant layers and octamolybd...

A polyoxomolybdate inorganic-organic hybrid crystal was synthesized with deprotonatable ionic-liquid surfactant. 1-dodecylimidazolium cation was employed for its synthesis. The hybrid crystal contained δ-type octamolybdate (Mo8) isomer, and possessed...

A successful encapsulation of Keggin-type polyoxomolybdate (H3[PMo12O40], PMo12) into metal-organic framework (MOF) materials with an identical framework but distinct metal centers (ZIF-8 with Zn2+ and ZIF-67 with Co2+) was accomplished by a straight...

Biomass conversion to 5-hydroxymethylfurfural (HMF) has been widely investigated as a sustainable alternative to petroleum-based feedstock, since it can be efficiently converted to fuel, plastic, polyester, and other industrial chemicals. In this rep...

The production of green fuel oil is of the utmost importance for maintaining a healthy life and environment in the current world. Effective and complete removal of sulfur refractory compounds (such as 4,6-dimethyldibenzothiophene and other alkyl-subs...

This review surveys recent advances and emerging prospects in phase-transfer catalysis (PTC) for fuel desulfurization. In response to increasingly stringent environmental regulations, the removal of sulfur from transportation fuels has become imperat...

Lignocellulose, composed of cellulose, hemicellulose, and lignin, holds immense promise as a renewable resource for the production of sustainable chemicals and fuels. Unlocking the full potential of lignocellulose requires efficient pretreatment stra...

An effective and sustainable oxidative desulfurization process for treating a multicomponent model fuel was successfully developed using as a heterogeneous catalyst a composite material containing as an active center the europium Lindqvist [Eu(W5O18)...

Polyoxometalates (POMs) are clusters of units of oxoanions of transition metals, such as Mo, W, V and Nb, that can be formed upon acidification of neutral solutions. Once formed, some POMs have shown to persist in solution, even in the neutral and ba...