25 Results Found

Ba0.5Sr0.5Co0.8Fe0.2O3-δ perovskite-type compounds are well-known mixed ionic-electronic conductors for oxygen electrocatalytic applications, although their performance is strictly dependent on the selected preparation methodology and processin...

The step from the testing of oxygen transport membranes on a lab scale to long-term operation on a large scale is a challenge. In a previous study, membrane failure was observed at defined positions of one end of the cooled tubular Ba0.5Sr0.5Co0.8Fe0...

High-entropy perovskite materials (HEPMs), characterized by their multi-element composition and highly disordered structure, can incorporate multiple rare earth elements at the A-site, producing perovskites with enhanced CO2 resistance, making them s...

The insufficient oxygen reduction reaction activity of cathode materials is one of the main obstacles to decreasing the operating temperature of solid oxide fuel cells (SOFCs). Here, we report a Zn-doped perovskite oxide Ba0.5Sr0.5(Co0.8Fe0.2)0.96Zn0...

The phenomena taking place in Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) as cathodic material in solid oxide fuel cells are investigated by electrochemical impedance spectroscopy. BSCF powders are prepared by solution combustion synthesis. Measureme...

In the last decades, several works have been carried out on solid oxide fuel cell (SOFC) and solid oxide electrolysis cell (SOEC) technologies, as they are powerful and efficient devices for energy conversion and electrochemical storage. By increasin...

Currently, the trade-off between oxygen permeation flux and structural stability in conventional perovskite oxides restricts the practical application of oxygen permeable membranes. In this study, a high-entropy design was applied to the B-site of BS...

Reactive Air Brazing (RAB) enables the joining of vacuum-sensitive oxide ceramics, such as Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF), to metals in a one-step process. However, damage may form in ceramic or joint during RAB. In this work, experiment...

The perovskite-type oxide Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) is known as a highly active and stable oxygen evolution reaction (OER) electrocatalyst composited out of non-noble metals. The possibility of using the scalable flame spray synthesis (FS...

The electrochemical reduction of molecular oxygen is a fundamental process in Solid Oxide Fuel Cells and requires high efficiency cathode materials. Two La0.25Ba0.25Sr0.5Co0.8Fe0.2O3−δ-based perovskite compounds were prepared by solution...

The widespread application of protonic ceramic fuel cells is limited by the lack of oxygen electrodes with excellent activity and stability. Herein, the strategy of halogen doping in a Ba0.6Sr0.4Co0.7Fe0.2Nb0.1O3-δ (BSCFN) cathode is discussed...

Recently, Fe-based perovskite oxides, such as Ln1-xSrxFeO3-δ (Ln = La, Pr, Nd, Sm, Eu) have been proposed as potential alternative electrode materials for solid oxide fuel cells (SOFCs), due to their good phase stability, electrocatalytic activ...

The separation of oxygen from air by means of inorganic ceramic membranes requires gas-tight ceramic–metal joints that enable reliable permeation operation in the oxygen partial pressure gradient at 850 °C. Reactive air brazing is a promisi...

Hexagonal perovskite-related oxides Ba7Ta3.7Mo1.3O20.15 (BTM) have recently been reported as promising electrolyte materials for intermediate-temperature solid oxide fuel cells (IT-SOFCs). In this work, sintering properties, thermal expansion coeffic...

An A‑ and B‑site substitutional study of SrFeO3−δ perovskites (A’xA1−xB’yB1−yO3−δ, where A = Sr and B = Fe) was performed for a two‑step solar thermochemical air separation cycle. The cycle steps encomp...

The isotopic content (δ13C, δ2H, δ18O) and concentrations of 30 elements (Li, Na, Mg, P, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Rb, Sr, Ag, Cd, Ba, Pb, La, Ce, Pr, Nd, Sm, Eu, Gd, and Tb) were determined in different wild an...

The effects of the electrochemical oxygen reduction reaction (ORR) on the surface of single-phase perovskite cathodes are well understood, but its potential for use in a complex system consisting of different material types is unexplored. Herein, we...

Multi-elemental (Ca, Mg, Na, K, Al, As, Ba, Cd, Co, Cr, Cu, Fe, Li, Mn, Mo, Ni, P, Pb, Sb, Se, Tl, V, and Zn) and stable isotope (i.e., δ2H, δ18O, and δ13CDIC) analyses were performed on 13 (8 Slovenian and 5 imported) bottled miner...

Yttrium-doped barium zirconate is a commonly used electrolyte material for Protonic Ceramic Fuel Cells (PCFC) due to its high protonic conductivity and high chemical stability. However, it is also known for its poor sinterability and poor grain bound...

Multiple siderite beds developed in the first member of the Lower Cretaceous Nantun Formation (K1n1) in the basin. The results show that the siderites in K1n1 of the study area are mostly stratiform or massive, with three micromorphological features...

Cobalt-based perovskite oxides exhibit remarkable catalytic activity owing to abundant oxygen vacancies and mixed ionic–electronic conductivity, but they suffer from structural instability. In contrast, iron-based perovskite oxides are thermoch...

Eighteen water samples collected from eight CO2-rich springs in the northern part of the Gyeongsang sedimentary basin (GSB), South Korea showed distinct hydrochemistry, in particular, pH, total dissolved solids (TDS), and Na contents, and they were c...

Exsolved perovskites can be obtained from lanthanum ferrites, such as La0.6Sr0.4Fe0.8Co0.2O3, as result of Ni doping and thermal treatments. Ni can be simply added to the perovskite by an incipient wetness method. Thermal treatments that favor the ex...

In the Carajás Mineral Province, gossan formation and lateritization have produced numerous supergene orebodies at the expense of IOCG deposits and host rocks. The Alvo 118 deposit comprises massive and disseminated hypogene copper sulfides as...

The integration of mixed ionic electronic conducting (MIEC) membranes for air separation in a small-to-medium scale unit for H2 production (in the range of 650–850 Nm3/h) via auto-thermal reforming of methane has been investigated in the present stu...