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Polymers

Polymers is an international, peer-reviewed, open access journal of polymer science published semimonthly online by MDPI. Belgian Polymer Group (BPG), European Colloid & Interface Society (ECIS), National Interuniversity Consortium of Materials Science and Technology (INSTM) and North American Thermal Analysis Society (NATAS) are affiliated with Polymers and their members receive a discount on the article processing charges.

Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
High Visibility: indexed within Scopus, SCIE (Web of Science), Ei Compendex, PubMed, PMC, FSTA, CAPlus / SciFinder, Inspec, and other databases.
Journal Rank: JCR - Q1 (Polymer Science) / CiteScore - Q1 (General Chemistry )
Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 14 days after submission; acceptance to publication is undertaken in 2.6 days (median values for papers published in this journal in the first half of 2025).
Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in MDPI journals, in appreciation of the work.
Testimonials: See what our authors and editors say about Polymers.
Journal Cluster of Polymer and Macromolecular Science: Polymers, Gels, Polysaccharides, Textiles, Macromol, Microplastics and Adhesives.

Impact Factor: 4.9 (2024); 5-Year Impact Factor: 5.2 (2024)

Imprint Information Journal Flyer Open Access ISSN: 2073-4360

Latest Articles

21 pages, 1944 KiB

Open AccessArticle

Principles and Practical Steps of Simplifying the Construction of the Cushion Curves of Closed-Cell Foam Materials

by Deqiang Sun, Pengcheng Qiu, Hongjuan Chen, Xinyuan Zhang and Siyu Wang

Polymers 2025, 17(17), 2292; https://doi.org/10.3390/polym17172292 (registering DOI) - 24 Aug 2025

The cushion curves of cushioning materials play crucial roles in scientific and reliable cushioning designs and in reducing damage losses for fragile products during distributions. The construction methods of cushion curves of closed-cell foam materials (CFMs) mainly include the Janssen factor, Rusch curve, [...] Read more.

The cushion curves of cushioning materials play crucial roles in scientific and reliable cushioning designs and in reducing damage losses for fragile products during distributions. The construction methods of cushion curves of closed-cell foam materials (CFMs) mainly include the Janssen factor, Rusch curve, cushion factor, and energy absorption diagram. The construction principle of these methods is reviewed in detail, and their disadvantages are mainly discussed. According to relevant ASTM and GB/T experimental standards, the peak acceleration–static stress cushion curve is based on dynamic impacts, which are most consistent with the dropping situation of product packages, so this kind of cushion curve is the standard and most widely applied for product cushioning designs. However, when generating the peak acceleration–static stress cushion curves, the experimental work is extremely huge. Three methods, namely the dynamic factor method, dynamic stress–dynamic energy method, and dynamic cushion factor–dynamic energy method, can significantly reduce the experimental workload and simplify constructing cushion curves. The novel dynamic cushion factor–dynamic stress method is proposed to simplify constructing the cushion curves. The practical generation steps of constructing cushion curves based on the four simplified methods are created and presented in detail. Full article

(This article belongs to the Special Issue Advances in Cellular Polymeric Materials)

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18 pages, 3659 KiB

Open AccessArticle

Preservation Effect of Protein-Based Composite Coating Solution from Highland Barley Distillers’ Grains on Crown Pears

by Qian Lv, Jie Zhao and Yiquan Zhang

Polymers 2025, 17(17), 2291; https://doi.org/10.3390/polym17172291 (registering DOI) - 24 Aug 2025

Crown pears exhibit high susceptibility to rot and rapid deterioration, resulting in quality degradation and fruit softening. Edible coatings serve as an effective preservation technology to extend their shelf life. In this study, a composite coating solution was formulated using vitamin C (Vc), [...] Read more.

Crown pears exhibit high susceptibility to rot and rapid deterioration, resulting in quality degradation and fruit softening. Edible coatings serve as an effective preservation technology to extend their shelf life. In this study, a composite coating solution was formulated using vitamin C (Vc), glycerol, ethanol, and gliadin derived from highland barley distillers’ grains. The coating formulation was optimized via single-factor experiments and Box–Behnken response surface methodology, with crown pears’ weight loss as the evaluation metric. The optimal composition comprised 19.86 mg/mL gliadin, 1.47% (v/v) glycerol, 2.49% (w/v) Vc, and 80.20% (v/v) ethanol, achieving a minimized weight loss of (3.30 ± 0.01)%. Treated pears coated with this optimized formulation were stored for 28 days. Preservation efficacy was evaluated through measurements of weight loss, decay rate, total number of colonies, firmness, titratable acid content, and polyphenol oxidase activity. Compared to the uncoated control group, the composite coating treatment significantly mitigated the decline in firmness, weight loss, and titratable acid content of crown pears. Furthermore, it effectively suppressed the increase in polyphenol oxidase (PPO) activity, decay rate, and total number of colonies, thereby extending the shelf life of the fruit. Full article

(This article belongs to the Section Biobased and Biodegradable Polymers)

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15 pages, 855 KiB

Open AccessArticle

Comonomer Reactivity Trends in Catalytic Ethene/1-Alkene Copolymerizations to Linear Low-Density Polyethylene

by Gianluigi Galasso, Roberta Cipullo, Vincenzo Busico and Antonio Vittoria

Polymers 2025, 17(17), 2290; https://doi.org/10.3390/polym17172290 (registering DOI) - 24 Aug 2025

Linear Low-Density Polyethylene (LLDPE) is a versatile polyolefin made by copolymerizing ethene with minor amounts of a 1-alkene. The short side chain branches in the comonomer units partly hinder the ability of the polyethylene main chain to crystallize, thus providing a way to [...] Read more.

Linear Low-Density Polyethylene (LLDPE) is a versatile polyolefin made by copolymerizing ethene with minor amounts of a 1-alkene. The short side chain branches in the comonomer units partly hinder the ability of the polyethylene main chain to crystallize, thus providing a way to fine-tune material properties between the extremes of a thermoplastic and a moderate elastomer. In this function, higher 1-alkenes such as 1-hexene or 1-octene are more effective than shorter homologs like propene or 1-butene, because their alkyl substituents are fully incompatible with the polyethylene lattice. On the other hand, the former comonomers are also more expensive and, above all, poorly reactive with heterogeneous Ziegler–Natta (ZN) catalysts, the workhorses of the polyolefin industry; as a matter of fact, they can only be used with technologically more demanding molecular catalysts. The molecular kinetic factors governing this important and complicated catalytic reactivity are still poorly understood, and perusal of the literature led us to conclude that data reliability is often questionable due to experimental limitations in reaction equipment and protocols, particularly in academic laboratories. In this study, we made use of a state-of-the-art High-Throughput Experimentation workflow to measure the reactivity ratios with ethene of two representative higher 1-alkenes, namely 1-hexene and 1-decene, in the presence of a variety of well-defined molecular catalysts of metallocene and post-metallocene nature comparatively with a typical MgCl₂/TiCl₄ ZN catalyst for polyethylene application. We found that the two comonomers react almost identically with molecular catalysts, whereas a major decrease in reactivity for 1-decene compared with 1-hexene was observed idiosyncratically for the ZN catalyst. In our opinion, the overall results suggest that in the latter case, surface effects can be dominant over direct comonomer interactions with the coordination sphere of the active metal in dictating the observed molecular kinetic behavior. Full article

(This article belongs to the Section Polymer Chemistry)

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15 pages, 8156 KiB

Open AccessArticle

Comparative Study of Continuous-Flow Reactors for Emulsion Polymerization

by Kai-Yen Chin, Angus Shiue, Pei-Yu Lai, Chien-Chen Chu, Shu-Mei Chang and Graham Leggett

Polymers 2025, 17(17), 2289; https://doi.org/10.3390/polym17172289 (registering DOI) - 24 Aug 2025

Polymer fouling in batch and tubular reactors creates safety hazards from heat buildup and blockages. The continuous Corning Advanced-Flow™ Reactor (AFR) offers enhanced mass and heat transfer, improving safety and efficiency. This study evaluated three reactor systems—a monolithic AFR, an AFR with an [...] Read more.

Polymer fouling in batch and tubular reactors creates safety hazards from heat buildup and blockages. The continuous Corning Advanced-Flow™ Reactor (AFR) offers enhanced mass and heat transfer, improving safety and efficiency. This study evaluated three reactor systems—a monolithic AFR, an AFR with an external pipe, and a conventional tubular reactor—for the mini-emulsion polymerization of styrene and subsequent styrene–acrylic acid copolymerization. The AFR operability under varying monomer concentrations was assessed and investigated, with the residence time’s effects on conversion. For styrene polymerization at 20–35 wt% monomer, the highest conversions achieved were 88.0% in the AFR, 85.8% in the tubular reactor, and 98.9% in the AFR with pipe. Uniform particles were obtained at ≤30 wt%, whereas at 35 wt%, the monolithic AFR experienced clogging and loss of particle uniformity. Similarly, in styrene–acrylic acid copolymerization (15–17.5 wt% monomer), the maximum conversions reached 80.1% in the AFR and 95.4% in the AFR with pipe, while the monolithic AFR again experienced blockage at 17.5 wt%. In conclusion, integrating an external pipe with the AFR, coupled with higher flow rates, significantly improved initiator diffusion, enhanced monomer conversion, and mitigated blockage. This approach enabled the efficient, continuous production of nanoscale, uniformly sized polystyrene and styrene–acrylic acid copolymers even at high monomer concentrations. Full article

(This article belongs to the Section Polymer Chemistry)

12 pages, 5061 KiB

Open AccessArticle

A Programmable Soft Electrothermal Actuator Based on a Functionally Graded Structure for Multiple Deformations

by Fan Bu, Feng Zhu, Zhengyan Zhang and Hanbin Xiao

Polymers 2025, 17(17), 2288; https://doi.org/10.3390/polym17172288 (registering DOI) - 24 Aug 2025

Soft electrothermal actuators have attracted increasing attention in soft robotics and wearable systems due to their simple structure, low driving voltage, and ease of integration. However, traditional designs based on homogeneous or layered composites often suffer from interfacial failure and limited deformation modes, [...] Read more.

Soft electrothermal actuators have attracted increasing attention in soft robotics and wearable systems due to their simple structure, low driving voltage, and ease of integration. However, traditional designs based on homogeneous or layered composites often suffer from interfacial failure and limited deformation modes, restricting their long-term stability and actuation versatility. In this study, we present a programmable soft electrothermal actuator based on a functionally graded structure composed of polydimethylsiloxane (PDMS)/multiwalled carbon nanotube (MWCNTs) composite material and an embedded EGaIn conductive circuit. Rheological and mechanical characterization confirms the enhancement of viscosity, modulus, and tensile strength with increasing MWCNTs content, confirming that the gradient structure improves mechanical performance. The device shows excellent actuation performance (bending angle up to 117°), fast response (8 s), and durability (100 cycles). The actuator achieves L-shaped, U-shaped, and V-shaped bending deformations through circuit pattern design, demonstrating precise programmability and reconfigurability. This work provides a new strategy for realizing programmable, multimodal deformation in soft systems and offers promising applications in adaptive robotics, smart devices, and human–machine interfaces. Full article

(This article belongs to the Special Issue Recent Developments in Polymeric Composites and Hybrid Materials Through Advanced Manufacturing)

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20 pages, 2725 KiB

Open AccessArticle

Sulfonated Poly(ether ether ketone)–Zirconia Organic–Inorganic Hybrid Membranes with Enhanced Ion Selectivity and Hydrophilicity for Vanadium Redox Flow Batteries

by Xiang Li, Tengling Ye, Wenfei Liu, Ge Meng, Wenxin Guo, Sergey A. Grigoriev, Dongqing He and Chuanyu Sun

Polymers 2025, 17(17), 2287; https://doi.org/10.3390/polym17172287 (registering DOI) - 23 Aug 2025

Proton-exchange membranes (PEMs) are the pivotal components of vanadium redox flow batteries (VRFBs) and play a critical role in the comprehensive output performance of VRFB systems. Currently, the most widely commercialized membranes are Nafion series membranes produced by DuPont, Wilmington, DE, USA, but [...] Read more.

Proton-exchange membranes (PEMs) are the pivotal components of vanadium redox flow batteries (VRFBs) and play a critical role in the comprehensive output performance of VRFB systems. Currently, the most widely commercialized membranes are Nafion series membranes produced by DuPont, Wilmington, DE, USA, but the high vanadium permeability and cost hinder their large-scale promotion. Hence, there is an active demand for developing a low-cost, high-performance, and energy-efficient PEM to promote the commercialization of VRFB systems. In this paper, sulfonated poly(ether ether ketone) (SPEEK) as matrix and zirconia nanoparticles as inorganic filler were used for composite modification to prepare a series of SPEEK–ZrO₂ organic–inorganic hybrid membranes for VRFBs. The thickness of these membranes was 50–100 μm. Compared with Nafion 115 (thickness 128 μm), composite membranes demonstrated obvious cost advantages. The results showed that the SP–Z-X series membranes had higher water uptake (53.26–71.1%) and proton conductivity (0.11–0.24 S cm⁻¹). SP–Z-5 displayed the best comprehensive output performance at 200 mA cm⁻² (CE: 99.01%, VE: 81.95%, EE: 81.11%). These hybrid membranes are very cost-effective and exhibit high potential for application in VRFB applications, and are expected to lead to the industrial application of VRFBs on a large scale. Full article

(This article belongs to the Section Polymer Membranes and Films)

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29 pages, 3349 KiB

Open AccessReview

Plant-Based Biofillers for Polymer Composites: Characterization, Surface Modification, and Application Potential

by Mateusz Pęśko and Anna Masek

Polymers 2025, 17(17), 2286; https://doi.org/10.3390/polym17172286 (registering DOI) - 23 Aug 2025

The mounting global concern regarding the accumulation of plastic waste underscores the necessity for the development of innovative solutions, with particular emphasis on the incorporation of plant-based biofillers into polymer composites as a sustainable alternative to conventional materials. This review provides a comprehensive [...] Read more.

The mounting global concern regarding the accumulation of plastic waste underscores the necessity for the development of innovative solutions, with particular emphasis on the incorporation of plant-based biofillers into polymer composites as a sustainable alternative to conventional materials. This review provides a comprehensive and structured overview of the recent progress (2020–2025) in the integration of plant-based biofillers into both thermoplastic and thermosetting polymer matrices, with a focus on surface modification techniques, physicochemical characterization, and emerging industrial applications. Unlike the prior literature, this work highlights the dual environmental and material benefits of using plant-derived fillers, particularly in the context of waste valorization and circular material design. By clearly identifying a current research gap—the limited scalability and processing efficiency of biofillers—this review proposes a strategy in which plant-derived materials function as key enablers for sustainable composite development. Special attention is given to extraction methods of lignocellulosic fillers from renewable agricultural waste streams and their subsequent functionalization to improve matrix compatibility. Additionally, it delineates the principal approaches for biofiller modification, demonstrating how their properties can be tailored to meet specific needs in biocomposite production. This critical synthesis of the state-of-the-art literature not only reinforces the role of biofillers in reducing dependence on non-renewable fillers but also outlines future directions in scaling up their use, improving durability, and expanding performance capabilities of sustainable composites. Overall, the presented analysis contributes novel insights into the material design, processing strategies, and potential of plant biofillers as central elements in next-generation green composites. Full article

(This article belongs to the Special Issue Recycling of Engineering Polymers: Process and Physico-Chemical Changes)

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73 pages, 1156 KiB

Open AccessReview

Lattice Structures in Additive Manufacturing for Biomedical Applications: A Systematic Review

by Samuel Polo, Amabel García-Domínguez, Eva María Rubio and Juan Claver

Polymers 2025, 17(17), 2285; https://doi.org/10.3390/polym17172285 (registering DOI) - 23 Aug 2025

The present study offers a systematic review of the current state of research on lattice structures manufactured by additive technologies for biomedical applications, with the aim of identifying common patterns, such as the use of triply periodic minimal surfaces (TPMS) for bone scaffolds, [...] Read more.

The present study offers a systematic review of the current state of research on lattice structures manufactured by additive technologies for biomedical applications, with the aim of identifying common patterns, such as the use of triply periodic minimal surfaces (TPMS) for bone scaffolds, as well as technological gaps and future research opportunities. Employing the PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) methodology, the review process ensures methodological rigor and replicability across the identification, screening, eligibility, and inclusion phases. Additionally, PRISMA was tailored by prioritizing technical databases and engineering-specific inclusion criteria, thereby aligning the methodology with the scope of this field. In recent years, a substantial surge in interdisciplinary research has underscored the promise of architected porous structures in enhancing mechanical compatibility, fostering osseointegration, and facilitating personalized medicine. A growing body of literature has emerged that explores the optimization of geometric features to replicate the behavior of biological tissues, particularly bone. Additive manufacturing (AM) has played a pivotal role in enabling the fabrication of complex geometries that are otherwise unachievable by conventional methods. The applications of lattice structures range from permanent load-bearing implants, commonly manufactured through selective laser melting (SLM), to temporary scaffolds for tissue regeneration, often produced with extrusion-based processes such as fused filament fabrication (FFF) or direct ink writing (DIW). Notwithstanding these advances, challenges persist in areas such as long-term in vivo validation, standardization of mechanical and biological testing, such as ISO standards for fatigue testing, and integration into clinical workflows. Full article

(This article belongs to the Special Issue Engineering and Medical Polymer Additive Manufacturing: Current and Future Trends)

22 pages, 4283 KiB

Open AccessArticle

Characterization of Envira Fibers Endemic to the Amazon Rainforest and Their Potential for Reinforcement in Polymer Composites

by Miriane Alexandrino Pinheiro, Leoncio Soares Galvao Neto, Alisson Clay Rios da Silva, Sérgio Neves Monteiro, Felipe Perisse Duarte Lopes, Marcos Allan Leite dos Reis and Verônica Scarpini Candido

Polymers 2025, 17(17), 2284; https://doi.org/10.3390/polym17172284 (registering DOI) - 23 Aug 2025

Natural lignocellulosic fibers (NLFs) replacing synthetic fibers have been used as reinforcement in polymer matrix composites. In this work, a lesser-known NLF endemic to the Amazon region, the envira fiber (Bocageopsis multiflora), was analyzed for its basic physical, thermochemical, morphological, and [...] Read more.

Natural lignocellulosic fibers (NLFs) replacing synthetic fibers have been used as reinforcement in polymer matrix composites. In this work, a lesser-known NLF endemic to the Amazon region, the envira fiber (Bocageopsis multiflora), was analyzed for its basic physical, thermochemical, morphological, and mechanical characteristics. In addition, epoxy matrix composites with 10, 20, 30, and 40 vol% of continuous and aligned envira fibers were evaluated by Fourier transform infrared spectroscopy (FTIR) and tensile tests. The results were statistically compared by ANOVA and Tukey’s test. The density found for the envira fiber was 0.23 g/cm³. The crystallinity index and microfibrilar angle obtained were 69.5% and 7.07°, respectively. Fiber thermal stability was found up to around 210 °C. FTIR confirmed the presence of functional groups characteristic of NLFs. Morphological analysis by SEM revealed that the envira fiber displayed fine bundles of fibrils and a rough surface along its length. The average strength value of the envira fiber was found to be 62 MPa. FTIR analysis of the composites confirmed the presence of the main constituents of the epoxy resin and NLFs. The tensile strength results indicated that the envira fiber addition increased the strength of the composites up to 40 vol%. The analysis of the fracture region revealed brittle aspects. These results indicate that envira fibers present potential reinforcement for polymer matrix composites and can be used in engineering applications, favored by their lightness and cost-effectiveness. Full article

(This article belongs to the Section Polymer Composites and Nanocomposites)

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44 pages, 2911 KiB

Open AccessReview

Molecularly Imprinted Polymer Nanoparticles for Pharmaceutical Applications: Sample Preparation, Sensor-Based Detection, and Controlled Drug Release

by Sibel Büyüktiryaki

Polymers 2025, 17(17), 2283; https://doi.org/10.3390/polym17172283 (registering DOI) - 23 Aug 2025

Molecularly imprinted polymer nanoparticles (MIP NPs) are synthetic receptors with selective recognition sites for target molecules. They are employed instead of biorecognition elements in many applications due to their high affinity and selectivity, stability, easy preparation, and low cost. Their nanoscale size provides [...] Read more.

Molecularly imprinted polymer nanoparticles (MIP NPs) are synthetic receptors with selective recognition sites for target molecules. They are employed instead of biorecognition elements in many applications due to their high affinity and selectivity, stability, easy preparation, and low cost. Their nanoscale size provides enhanced surface interactions, faster response times, improved biocompatibility, and effective cellular penetration, particularly in complex biological environments. MIP NPs provide high selectivity and structural versatility in the sample preparation, sensor-based detection, and controlled drug delivery, serving as promising alternatives to conventional methods. This review highlights the recent advancements in the synthesis and application of MIP NPs in three critical areas: sample preparation, sensor-based detection, and controlled drug release. Additionally, recent developments in green synthesis approaches, biocompatible materials, and surface functionalization strategies that are effective in the performance of MIP NPs are mentioned. Full article

(This article belongs to the Special Issue Applications of Polymer Nanomaterials in Biomedicine)

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14 pages, 1232 KiB

Open AccessArticle

Influence of Bioactive Glass Incorporation in Resin Adhesives of Orthodontic Brackets on Adhesion Properties and Calcium Release

by Ana Paula Valente Pinho Mafetano, Fernanda Alves Feitosa, Gabriela da Silva Chagas, Nathália Moreira Gomes, Marcella Batista Rocha, Mariane Cintra Mailart, Karen Cristina Kazue Yui and Cesar Rogério Pucci

Polymers 2025, 17(17), 2282; https://doi.org/10.3390/polym17172282 (registering DOI) - 23 Aug 2025

This study evaluated a light-cure orthodontic adhesive with the incorporation of bioactive glass particles and its effects on shear bond strength (SBS), adhesive remnant index (ARI), degree of conversion (DC), calcium release, and particle size distribution. Bioactive glass was added to the Transbond [...] Read more.

This study evaluated a light-cure orthodontic adhesive with the incorporation of bioactive glass particles and its effects on shear bond strength (SBS), adhesive remnant index (ARI), degree of conversion (DC), calcium release, and particle size distribution. Bioactive glass was added to the Transbond XT Adhesive (3M ESPE), resulting in five groups: TXT (0% wt of bioactive glass-incorporated—negative control); TXT20 (20% wt of bioactive glass-incorporated); TXT30 (30% wt of bioactive glass-incorporated), TXT50 (50% wt of bioactive glass-incorporated), and FLB (positive control—FL BOND II adhesive system with S-PRG particles, SHOFU Inc.). Data were analyzed with one-way ANOVA followed by Tukey’s test (α = 0.05). Quantitative SEM analysis confirmed submicron particle agglomerates (median equivalent circular diameter 0.020–0.108 µm). The TXT20 exhibited the highest values of degree of conversion (p < 0.05) (73.02 ± 3.33A). For SBS (in MPa): Control Group TXT—19.50 ± 1.40A, Group TXT20 18.22 ± 1.04AB, Group FLB 17.62 ± 1.45B, Group TXT30 14.48 ± 1.46C and Group TXT50 14.13 ± 1.02C (p < 0.05). For calcium release the group TXT50 2.23 ± 0.11D showed higher values (p < 0.05). The incorporation of distinct bioactive glass particle concentrations influenced the shear bond strength, degree of conversion, and calcium release. While the 50 wt% bioactive glass group exhibited the highest calcium release, both 20 wt% of bioactive glass group and the positive control group exhibited the highest degree of conversion without compromising the bonding strength. Full article

(This article belongs to the Special Issue Designing Polymers for Emerging Applications)

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19 pages, 6194 KiB

Open AccessArticle

Effect of Polylactic Acid (PLA) Blends on Cellulose Degradable Plastics from the Lotus Stem (Nelumbo nucifera)

by Rozanna Dewi, Novi Sylvia, Muhammad Subhan, Budhi Santri Kusuma, Aldila Ananda, Medyan Riza, Januar Parlaungan Siregar, Choon Kit Chan, Tezara Cionita and Elsherif Emad Ahmed Abdelrahman

Polymers 2025, 17(17), 2281; https://doi.org/10.3390/polym17172281 (registering DOI) - 23 Aug 2025

Lotus stems contain cellulose, which can be utilized as a base material for producing green products, specifically degradable plastics. This research investigates the effect of polylactic acid (PLA) blends on cellulose degradable plastics from the lotus stem (Nelumbo nucifera). The mechanical [...] Read more.

Lotus stems contain cellulose, which can be utilized as a base material for producing green products, specifically degradable plastics. This research investigates the effect of polylactic acid (PLA) blends on cellulose degradable plastics from the lotus stem (Nelumbo nucifera). The mechanical characteristics are as follows: tensile strength of 0.7703–3.3212 MPa, elongation of 0.58–1.16%, Young’s modulus of 78.7894–364.6118 MPa. Compound analysis showed the presence of O-H, C-C, and C=O groups, and the presence of microbial activity in the soil can also lead to the degradation of these groups due to their hydrophilic nature, which allows them to bind water. Thermal analysis within a temperature range of 413.24 °C to 519.80 °C, shows that significant weight loss begins with the formation of crystalline structures. The degradable plastic exhibiting the lowest degree of swelling consists of 1 g of cellulose and 8 g of PLA, resulting in a swelling value of 6.25%. The degradable plastic is anticipated to decompose most rapidly after 52 days, utilizing 2 g of PLA and 7 g of cellulose. This complies with standard requirement, which sets a maximum degradation period of 180 days for polymers. Full article

(This article belongs to the Special Issue Advanced Cellulose Polymers and Derivatives)

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23 pages, 3962 KiB

Open AccessArticle

PLA/PBS Biocomposites for 3D FDM Manufacturing: Effect of Hemp Shive Content and Process Parameters on Printing Quality and Performances

by Emilia Garofalo, Luciano Di Maio and Loredana Incarnato

Polymers 2025, 17(17), 2280; https://doi.org/10.3390/polym17172280 (registering DOI) - 23 Aug 2025

This study investigates the processability—via Fused Deposition Modeling (FDM) 3D printing—and mechanical performance of biocomposites based on polylactic acid (PLA), polybutylene succinate (PBS), and their 50/50 wt% blend, each reinforced with hemp shive at 3 and 5 wt%. Blending PLA with PBS represents [...] Read more.

This study investigates the processability—via Fused Deposition Modeling (FDM) 3D printing—and mechanical performance of biocomposites based on polylactic acid (PLA), polybutylene succinate (PBS), and their 50/50 wt% blend, each reinforced with hemp shive at 3 and 5 wt%. Blending PLA with PBS represents a straightforward and encouraging strategy to enhance both the printability and mechanical properties of the individual resins, expanding the range of their potential applications. The addition of hemp shive—a by-product of hemp processing—not only enhances the biodegradability of the composites but also improves their thermo-mechanical performance, as well as aligning with circular economy principles. The rheological characterization, performed on all the systems, evidenced that the PLA/PBS blend possesses viscoelastic properties well suited for FDM, enabling smooth extrusion through the nozzle, good shape stability after deposition, and effective interlayer adhesion. Moreover, the constrain effect of hemp shives within the polymer matrix reduced the extrudate swell, a key factor affecting the dimensional accuracy of the printed parts. Optimal processing conditions were identified at a nozzle temperature of 190 °C and a printing speed of 70 mm/s, providing a favorable compromise between print quality, final performances and production efficiency. From a mechanical perspective, the PLA/PBS blend exhibited an 8.6-fold increase in elongation at break compared to neat PLA, and its corresponding composite showed a ductility nearly three times higher than the PLA-based counterpart’s. In conclusion, the findings of this study provide new insights into the interplay between material formulation, rheological behavior and printing conditions, supporting the development of sustainable, hemp-reinforced biocomposites for additive manufacturing applications. Full article

(This article belongs to the Special Issue New Progress of Polymeric Materials in Advanced Manufacturing, 2nd Edition)

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33 pages, 2450 KiB

Open AccessReview

Research Progress on Polymer-Based Nanocarriers for Tumor-Targeted Delivery of Survivin siRNA

by Luya Ren, Shaoxia Wang, Bin-Chun Li and Guo-Bin Ding

Polymers 2025, 17(17), 2279; https://doi.org/10.3390/polym17172279 (registering DOI) - 23 Aug 2025

Survivin, a pivotal member of the inhibitor of apoptosis proteins (IAP) family, plays critical roles in cell cycle regulation and division. Survivin is overexpressed in most malignancies, making it an attractive therapeutic target. Due to its high specificity and potency, siRNA-based RNA interference [...] Read more.

Survivin, a pivotal member of the inhibitor of apoptosis proteins (IAP) family, plays critical roles in cell cycle regulation and division. Survivin is overexpressed in most malignancies, making it an attractive therapeutic target. Due to its high specificity and potency, siRNA-based RNA interference (RNAi) has emerged as a powerful therapeutic strategy for effectively downregulating disease-related genes such as survivin in cancer therapy. However, naked siRNA suffers from rapid enzymatic degradation, poor cellular uptake, and off-target effects, severely limiting its therapeutic efficacy in vivo. Development of polymer-based nanocarriers for tumor-targeted delivery of survivin siRNA (siSurvivin) holds great potential to address these challenges. In this review, we first described the structure and function of survivin and summarized the survivin-targeted therapeutic strategy. Then, the siRNA delivery systems, particularly the polymeric nanocarriers, were introduced. Furthermore, a plethora of polymer-based nanocarriers for tumor-targeted siSurvivin delivery, including synthetic polymers (branched polymers, dendritic polymers, polymeric micelles), natural polymers (polysaccharides, proteins, and others), lipid-polymer hybrid nanoparticles, and polymer composite nanoparticles, were elaborated. Promising results underscore the potential of polymer-based nanocarriers for survivin siRNA delivery to enhance cancer therapy, providing a roadmap for future clinical translation. Full article

(This article belongs to the Special Issue Polymers for Drug/Gene Delivery and Controlled Release)

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33 pages, 6102 KiB

Open AccessArticle

Molded Part Warpage Optimization Using Inverse Contouring Method

by Damir Godec, Filip Panđa, Mislav Tujmer and Katarina Monkova

Polymers 2025, 17(17), 2278; https://doi.org/10.3390/polym17172278 - 22 Aug 2025

Warpage is among the most prevalent defects affecting injection molded parts. In this study, we aimed to develop methods to minimize warpage through mold design. Common strategies include matching the cavity geometry to the intended shape of the part, adjusting cavity dimensions to [...] Read more.

Warpage is among the most prevalent defects affecting injection molded parts. In this study, we aimed to develop methods to minimize warpage through mold design. Common strategies include matching the cavity geometry to the intended shape of the part, adjusting cavity dimensions to offset material shrinkage, and optimizing the cooling system and critical injection molding parameters. These optimization methods can offer significant improvements, but recently introduced methods that optimize the molded part and mold cavity shape result in higher levels of warpage reduction. In these methods, optimization of the shape of the molded part is achieved by shaping it in the opposite direction of warpage—a method known as inverse contouring. Inverse contouring of molded parts is a design technique in which mold cavities are intentionally modified to incorporate compensatory geometric deviations in regions anticipated to exhibit significant warpage. The final result after molded part ejection and warpage is a significant reduction in deviations between the warped and reference molded part geometries. In this study, a two-step approach for minimizing warpage was used: the first step was optimizing the most significant injection molding parameters, and the second was inverse contouring. In the first step, Response Surface Methodology (RSM) and Autodesk Moldflow Insight 2023 simulations were used to optimize molded part warpage based on three processing parameters: melt temperature, target mold temperature, and coolant temperature. For improved accuracy, a Computer-Aided Design (CAD) model of the warped molded part was exported into ZEISS Inspect 2023 software and aligned with the reference CAD geometry of the molded part. The maximal warpage value after the initial simulation was 1.85 mm based on Autodesk Moldflow Insight simulations and 1.67 mm based on ZEISS Inspect alignment. After RSM optimization, the maximal warpage was 0.73 mm. In the second step, inverse contouring was performed on the molded part, utilizing the initial injection molding simulation results to further reduce warpage. In this step, the CAD model of the redesigned, inverse-contoured molded part was imported into Moldflow Insight to conduct a second iteration of the injection molding simulation. The simulation results were exported into ZEISS Inspect software for a final analysis and comparison with the reference CAD model. The warpage values after inverse contouring were reduced within the range of ±0.30 mm, which represents a significant decrease in warpage of approximately 82%. Both steps are presented in a case study on an injection molded part made of polybutylene terephthalate (PBT) with 30% glass fiber (GF). Full article

(This article belongs to the Section Polymer Processing and Engineering)

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11 pages, 1632 KiB

Open AccessArticle

A Tb (Ⅲ) Coordination Polymer Based on 5-(2-(Pyrazole-1-yl) Pyridine-5-yl) Terephthalic Acid and Its Visual Detection of Quinolone Antibiotics

by Ai Wang, Yichong Li, Wei Zhao and Jia Liu

Polymers 2025, 17(17), 2277; https://doi.org/10.3390/polym17172277 - 22 Aug 2025

The abuse of quinolone antibiotics in the medical and livestock industries potentially causes environmental accumulation that may impair ecological stability. Based on the organic ligand 5-(pyrazole-1-yl) pyridine-5-yl) terephthalic acid (H₂PPIPA), a terbium(III) complex, [Tb(HPPIPA)(PPIPA)(H₂O)]ₙ (complex 1), was synthesized [...] Read more.

The abuse of quinolone antibiotics in the medical and livestock industries potentially causes environmental accumulation that may impair ecological stability. Based on the organic ligand 5-(pyrazole-1-yl) pyridine-5-yl) terephthalic acid (H₂PPIPA), a terbium(III) complex, [Tb(HPPIPA)(PPIPA)(H₂O)]ₙ (complex 1), was synthesized via solvothermal reaction with Tb(NO₃)₃·6H₂O. Luminescence studies revealed that complex 1 functions as a turn-on fluorescent probe for the selective detection of ofloxacin (OFX), levofloxacin (LFX), and norfloxacin (NFX), with detection limits of 27.9, 17.1, and 8.0 nM, respectively. Owing to its high selectivity and anti-interference capability, the complex was successfully applied for the determination of OFX and LFX in milk samples. Furthermore, a test strip impregnated with complex 1 enabled naked-eye fluorescence detection of OFX, LFX, and NFX under 254 nm UV light. Additionally, a fluorescence sensing film fabricated from complex 1 exhibited excellent recyclability, allowing for at least seven consecutive detection cycles without significant signal loss. This study innovatively designed and synthesized a novel Tb(III)-based coordination polymer fluorescent probe utilizing an original ligand scaffold, achieving the first reported visual detection of quinolone antibiotics with fluorescence test strips and agar films. Full article

(This article belongs to the Special Issue Coordination Polymers: Design, Preparation, and Application)

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22 pages, 1417 KiB

Open AccessArticle

Free Vibration Behavior of CFRP Composite Sandwich Open Circular Cylindrical Shells with 3D Reentrant Negative Poisson’s Ratio Core

by Shi-Chen Liu and Yun-Long Chen

Polymers 2025, 17(17), 2276; https://doi.org/10.3390/polym17172276 - 22 Aug 2025

This study explores the free vibration behavior of carbon fiber-reinforced sandwich open circular cylindrical shells featuring 3D reentrant auxetic cores (3D RSOCCSs). For theoretical predictions, a model integrating the Rayleigh–Ritz method (RRM) and Reddy’s third-order shear deformation theory (TOSDT) is adopted, whereas the [...] Read more.

This study explores the free vibration behavior of carbon fiber-reinforced sandwich open circular cylindrical shells featuring 3D reentrant auxetic cores (3D RSOCCSs). For theoretical predictions, a model integrating the Rayleigh–Ritz method (RRM) and Reddy’s third-order shear deformation theory (TOSDT) is adopted, whereas the finite element analysis approach is used for simulation predictions. All-composite 3D RSOCCSs specimens are produced via hot-press molding and interlocking assembly, and the modal characteristics of 3D RSOCCSs are obtained through hammer excitation modal tests. The predicted modal properties are in good agreement with the experimental results. In addition, the influences of fiber ply angles and geometric parameters on the natural frequency in the free vibration are thoroughly analyzed, which can offer insights for the vibration analysis of lightweight auxetic metamaterial cylindrical shells and promote their practical use in engineering scenarios focused on vibration mitigation. Full article

(This article belongs to the Special Issue Polymeric Sandwich Composite Materials)

24 pages, 4305 KiB

Open AccessArticle

Driving the Green Transition: Innovative Tyre Formulation Using Agricultural and Pyrolysed Tyres Waste

by Carlo Di Bernardo, Francesca Demichelis, Mehran Dadkhah, Debora Fino, Massimo Messori and Camilla Noè

Polymers 2025, 17(17), 2275; https://doi.org/10.3390/polym17172275 - 22 Aug 2025

The rubber industry is facing increasing pressure to adopt sustainable practices due to environmental concerns associated with the use of non-renewable resources and the growing accumulation of waste tyres and agricultural byproducts. This study explores the potential of partially replacing conventional carbon black [...] Read more.

The rubber industry is facing increasing pressure to adopt sustainable practices due to environmental concerns associated with the use of non-renewable resources and the growing accumulation of waste tyres and agricultural byproducts. This study explores the potential of partially replacing conventional carbon black (CB) with sustainable alternatives derived from agricultural waste (wine by-products) and pyrolysed waste tyres in natural rubber/styrene-butadiene rubber (NR/SBR) composites for tyre applications. A series of NR/SBR composites were formulated with varying ratios of CB to agricultural waste and pyrolysed tyre waste, while maintaining consistent levels of other additives. The resulting composites were then subjected to a comprehensive suite of analyses, including scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) surface area measurements, Fourier transform infrared spectroscopy (FTIR), bound rubber content determination, Payne effect analysis, thermogravimetric analysis (TGA), dynamic mechanical thermal analysis (DMTA), and mechanical property testing. Furthermore, a Life Cycle Assessment (LCA) and Life Cycle Costing (LCC) analysis were conducted to evaluate the environmental and economic viability of the proposed CB replacements. The results reveal that the incorporation of agricultural waste and pyrolysed tyre waste can significantly impact the curing behaviour, mechanical properties, and thermal stability of rubber composites. Importantly, some of the formulations demonstrate comparable tensile strength, elongation at break, and hardness compared to traditional CB-filled composites. The LCA and LCC analyses further highlight the potential for substantial reductions in greenhouse gas emissions, fossil resource depletion, and overall production costs, thereby supporting the transition toward more sustainable tyre manufacturing practices. Full article

(This article belongs to the Special Issue Sustainable Bio-Based and Circular Polymers and Composites)

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23 pages, 5608 KiB

Open AccessFeature PaperReview

Development of Self-Healing Polyurethane and Applications in Flexible Electronic Devices: A Review

by Jie Du, Xinlan Zhao, Yang Li, Wanqing Lei and Xing Zhou

Polymers 2025, 17(17), 2274; https://doi.org/10.3390/polym17172274 - 22 Aug 2025

Traditional polyurethanes have gained widespread application due to their excellent mechanical properties, wear resistance, and processability. However, these materials are susceptible to cracking or fracture under environmental stresses. In recent years, self-healing polyurethanes have garnered significant attention as a critical research field owing [...] Read more.

Traditional polyurethanes have gained widespread application due to their excellent mechanical properties, wear resistance, and processability. However, these materials are susceptible to cracking or fracture under environmental stresses. In recent years, self-healing polyurethanes have garnered significant attention as a critical research field owing to their key capabilities, such as repairing physical damage, restoring mechanical strength, structural adaptability, and cost-effective manufacturing. This review systematically examines the healing mechanisms, structural characteristics, and performance metrics of self-healing polyurethanes, with in-depth analysis of their repair efficacy across various applications—particularly in flexible electronic devices. It demonstrates that self-healing polyurethanes overcome traditional failure modes in flexible electronics through self-repair-function integration mechanisms. Their stimuli-responsive healing behavior is driving the evolution of this field toward an intelligent regenerative electronics paradigm. Full article

(This article belongs to the Special Issue Polymer Modification for Soft Matter and Flexible Devices)

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19 pages, 3530 KiB

Open AccessReview

Direct Analysis of Solid-Phase Carbohydrate Polymers by Infrared Multiphoton Dissociation Reaction Combined with Synchrotron Radiation Infrared Microscopy and Electrospray Ionization Mass Spectrometry

by Takayasu Kawasaki, Heishun Zen, Kyoko Nogami, Ken Hayakawa, Takeshi Sakai and Yasushi Hayakawa

Polymers 2025, 17(17), 2273; https://doi.org/10.3390/polym17172273 - 22 Aug 2025

To determine the structure of carbohydrate polymers using conventional analytical technology, several complicated steps are required. We instead adopted a direct approach without the need for pretreatments, using an intense infrared (IR) laser for carbohydrate analysis. IR free-electron lasers (FELs) driven by a [...] Read more.

To determine the structure of carbohydrate polymers using conventional analytical technology, several complicated steps are required. We instead adopted a direct approach without the need for pretreatments, using an intense infrared (IR) laser for carbohydrate analysis. IR free-electron lasers (FELs) driven by a linear accelerator possess unique spectroscopic features, including extensive wavelength tunability and high laser energy in the IR region from 1000 cm⁻¹ (10 μm) to 4000 cm⁻¹ (2.5 μm). FELs can induce IR multiphoton dissociation reactions against various molecules by supplying vibrational excitation energy to the corresponding chemical bonds. Chitin from crayfish and cellulose fiber were irradiated by FELs tuned to νC–O (9.1–9.8 μm), νC–H (3.5 μm), and δH–C–O (7.2 μm) in glycosidic bonds, and their low-molecular-weight sugars were separated, which were revealed by combining synchrotron radiation IR spectroscopy and electrospray ionization mass spectrometry. An intense IR laser can be viewed as a “molecular scalpel” for dissecting and directly analyzing the internal components in rigid biopolymers. This method is simple and rapid compared with general analytical techniques. Full article

(This article belongs to the Special Issue Advanced Spectroscopy for Polymers: Design and Characterization)

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