Ammonia (NH
3) is a promising zero-carbon fuel to eliminate carbon footprint while the high autoignition temperature and low combustion rate of NH
3 remain challenging for practical implementation. Using dimethyl ether (DME) as pilot ignition fuel can substantially promote the reactivity of NH
3, thus paving the way for a widespread application of NH
3. In this study, the ignition process and nitrogen oxides (NO
x) emissions of the NH
3 liquid spray ignited by liquid DME spray were numerically investigated using Converge software. The ambient temperatures (T
amb) ranging from 900 K to 1100 K were used to mimic the in-cylinder temperature typically encountered in turbocharger engines. The effect of ammonia energy ratio (AER) and fuel injection timing was examined as well. It is found that only half of NH
3 is consumed at T
amb = 900 K while 97.4% of NH
3 is burned at T
amb = 1100 K. Nitric oxide (NO) and nitrogen dioxide (NO
2) formation also have strong correlation with T
amb and NO
2 is usually formed around the periphery of NO through these two channels HO
2 + NO = NO
2 + OH and NO + O(+M) = NO
2(+M). Extremely high nitrous oxide (N
2O, formed by NH + NO = H + N
2O) and carbon monoxide (CO) are produced with the presence of abundant unburned NH
3 at T
amb = 900 K. Additionally, increasing AER from 60% to 90% results in slightly declined combustion efficiency of NH
3 from 98.7% to 94%. NO emission has a non-monotonical relationship with AER owing to the ‘trade-off’ relationship between HNO concentration and radical pool at varying AERs. A higher AER of 95% leads to failed ignition of NH
3. Advancing DME injection not only increases combustion efficiency, but also reduces NO
x and CO emissions.
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