Recycling

29 pages, 1873 KiB

Open AccessArticle

Robust Statistical Approaches for Stratified Data of Municipal Solid Waste Composition: A Case Study of the Czech Republic

by Radovan Šomplák, Veronika Smejkalová, Vlastimír Nevrlý and Jaroslav Pluskal

Recycling 2025, 10(4), 162; https://doi.org/10.3390/recycling10040162 - 12 Aug 2025

Abstract

Accurate information on waste composition is essential for strategic planning in waste management and developing environmental technologies. However, detailed analyses of individual waste containers are both time- and cost-intensive, resulting in a limited number of available samples. Therefore, it is crucial to apply [...] Read more.

Accurate information on waste composition is essential for strategic planning in waste management and developing environmental technologies. However, detailed analyses of individual waste containers are both time- and cost-intensive, resulting in a limited number of available samples. Therefore, it is crucial to apply statistical methods that enable reliable estimation of average waste composition and its variability, while accounting for territorial differences. This study presents a statistical approach based on territorial stratification, aggregating data from individual waste container analyses to higher geographic units. The methodology was applied in a case study conducted in the Czech Republic, where 19.4 tons of mixed municipal waste (MMW) were manually analyzed in selected representative municipalities. The method considers regional heterogeneity, monitors the precision of partial estimates, and supports reliable aggregation across stratified regions. Three alternative approaches for constructing interval estimates of individual waste components are presented. Each interval estimate addresses variability from the random selection of waste containers and the selection of strata representatives at multiple levels. The proposed statistical framework is particularly suited to situations where the number of samples is small, a common scenario in waste composition analysis. The approach provides a practical tool for generating statistically sound insights under limited data conditions. The main fractions of MMW identified in the Czech Republic were as follows: paper 6.7%, plastic 7.3%, glass 3.6%, bio-waste 28.4%, metal 2.1%, and textile 3.0%. The methodology is transferable to other regions with similar waste management systems. Full article

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22 pages, 895 KiB

Open AccessArticle

Platform-Driven Sustainability in E-Commerce: Consumer Behavior Toward Recycled Fashion

by Eleni Sardianou and Maria Briana

Recycling 2025, 10(4), 161; https://doi.org/10.3390/recycling10040161 - 11 Aug 2025

Abstract

Digital platforms in fashion e-commerce are progressively shaping sustainable consumption practices. This research explores the interplay between consumer behaviors toward recycled and second-hand fashion, and the adoption of digital platform-driven innovations. The analysis is based on a structured questionnaire and an online survey [...] Read more.

Digital platforms in fashion e-commerce are progressively shaping sustainable consumption practices. This research explores the interplay between consumer behaviors toward recycled and second-hand fashion, and the adoption of digital platform-driven innovations. The analysis is based on a structured questionnaire and an online survey of 1000 consumers conducted in 2025, employing a combination of descriptive and inferential statistical techniques, including both cluster and factor analysis. The findings suggests that demographic factors—particularly age, education, and gender—significantly shape consumer attitudes toward digital innovations in fashion e-commerce apps. The analysis also confirms that the perceived effectiveness of AI and AR tools is significantly correlated with an increased interest in circular fashion options, including second-hand marketplaces and recycled clothing. The study emphasizes the strategic importance of platform features in fostering conscious fashion choices, thereby offering practical insights for retailers aiming to harmonize technological innovation with sustainability goals. Full article

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20 pages, 2007 KiB

Open AccessArticle

Value-Added Recycling of Pre-Consumer Textile Waste: Performance Evaluation of Cotton Blend Knitted T-Shirts

by Muhammad Babar Ramzan, Sajida Ikram, Sheheryar Mohsin Qureshi, Muhammad Waqas Iqbal and Muhammad Qamar Khan

Recycling 2025, 10(4), 160; https://doi.org/10.3390/recycling10040160 - 8 Aug 2025

Viewed by 182

Abstract

This study investigates the effects of waste for value addition in form of use of textile waste to comfortable and durable garments based on blending recycled cotton fibers extracted from spinning, weaving, and cutting waste with virgin cotton in different ratios of 70:30, [...] Read more.

This study investigates the effects of waste for value addition in form of use of textile waste to comfortable and durable garments based on blending recycled cotton fibers extracted from spinning, weaving, and cutting waste with virgin cotton in different ratios of 70:30, 80:20, and 90:10 to produce yarns of 22/1 count, which are used to develop single jersey knitted T-Shirt, examining key properties such as mechanical and thermos-physiological properties. Grey fabric (unprocessed fabric) with a higher virgin cotton content and from spinning waste exhibited superior bursting strength, overall moisture management capacity, and thermal conductivity. In contrast, air permeability and water vapor permeability were highest in fabric made with weaving waste. After scouring and bleaching, the finished fabric (processed fabric) was compared with the grey fabrics. The results demonstrate that the finished fabric has slightly reduced bursting strength, water vapor permeability, and moisture management capacity while significantly enhancing air permeability and maintaining thermal conductivity. T-shirt properties were evaluated across various blend ratios and waste types over multiple washing cycles. Overall, the study demonstrates that recycled cotton fibers, particularly those from spinning waste, can be successfully produced into high-performance knitted t-shirts, offering a sustainable alternative to fully virgin cotton products without compromising performance significantly. Full article

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25 pages, 339 KiB

Open AccessArticle

Pro-Environmental Behavior and Attitudes Towards Recycling in Slovak Republic

by Silvia Lorincová and Mária Osvaldová

Recycling 2025, 10(4), 159; https://doi.org/10.3390/recycling10040159 - 7 Aug 2025

Viewed by 148

Abstract

Climate changes have increased interest in the circular economy, an alternative model that seeks to minimize environmental impact and maximize resource reuse. A key element of this model is individuals’ behaviors and attitudes, which determine the overall efficiency of recycling processes. The study [...] Read more.

Climate changes have increased interest in the circular economy, an alternative model that seeks to minimize environmental impact and maximize resource reuse. A key element of this model is individuals’ behaviors and attitudes, which determine the overall efficiency of recycling processes. The study fills the gap by investigating how selected socio-demographic factors affect attitudes and intentions toward recycling and material reuse in the Slovak Republic, by using the Perceived Characteristics of Innovating (PCI) framework. Through a two-way ANOVA, we tested the hypotheses that higher education correlates with stronger recycling attitudes and that women are more willing than men to engage in circular practices. The results show that gender differences in consumer attitudes towards the circular economy do occur, but their magnitude is often conditioned by education level. Education proved to be the strongest predictor of ecological behavior: respondents with higher education reported stronger beliefs in the importance of recycling and a greater willingness to act sustainably. The interaction between gender and education revealed that university-educated women hold the most pronounced pro-environmental attitudes, underscoring the importance of gender-sensitive educational strategies. It is recommended that environmental education and outreach focus on less-educated groups, particularly women, who have high potential to influence their communities. Full article

16 pages, 1369 KiB

Open AccessArticle

Recycling Waste Cottonseed Hulls to Biomaterials for Ammonia Adsorption

by Thomas Klasson, Bretlyn Pancio and Allen Torbert

Recycling 2025, 10(4), 158; https://doi.org/10.3390/recycling10040158 - 6 Aug 2025

Viewed by 260

Abstract

Ammonia emissions in poultry houses are common and pose health concerns for animals and workers. However, effective control of these emissions with sustainable products is lacking. Therefore, we investigated if an agricultural byproduct, cottonseed hulls, could be recycled through pyrolysis and used to [...] Read more.

Ammonia emissions in poultry houses are common and pose health concerns for animals and workers. However, effective control of these emissions with sustainable products is lacking. Therefore, we investigated if an agricultural byproduct, cottonseed hulls, could be recycled through pyrolysis and used to remove ammonia from air. In this study, the efficacy of ammonia removal was observed using cottonseed hull biomaterials pyrolyzed at seven different temperatures: 250, 300, 350, 400, 500, 600, and 700 °C. In this study, ammonia was passed through a column filled with pyrolyzed material, and ammonia in the filtered air was monitored. The results showed that materials pyrolyzed at intermediate temperatures of 350 and 400 °C were the most efficient at ammonia removal and were able to adsorb approximately 3.7 mg NH₃/g of material. Despite extensive characterization, ammonia adsorption could not be linked to intrinsic material properties. Evaluation of the materials showed that the carbon in the pyrolyzed materials would be stable over time should the spent material be used as a soil amendment. Full article

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21 pages, 19752 KiB

Open AccessArticle

Phase Characterisation for Recycling of Shredded Waste Printed Circuit Boards

by Laurance Donnelly, Duncan Pirrie, Matthew Power and Andrew Menzies

Recycling 2025, 10(4), 157; https://doi.org/10.3390/recycling10040157 - 6 Aug 2025

Viewed by 204

Abstract

In this study, we adopt a geometallurgical analytical approach common in mineral processing in the characterization of samples of shredded waste printed circuit board (PCB) E-waste, originating from Europe. Conventionally, bulk chemical analysis provides a value for E-waste; however, chemical analysis alone does [...] Read more.

In this study, we adopt a geometallurgical analytical approach common in mineral processing in the characterization of samples of shredded waste printed circuit board (PCB) E-waste, originating from Europe. Conventionally, bulk chemical analysis provides a value for E-waste; however, chemical analysis alone does not provide information on the textural variability, phase complexity, grain size, particle morphology, phase liberation and associations. To address this, we have integrated analysis using binocular microscopy, manual scanning electron microscopy, phase, textural and compositional analyses by automated (SEM-EDS), phase analysis based on (Automated Material Identification and Classification System (AMICS) software, and elemental analysis using micro-XRF. All methods used have strengths and limitations, but an integration of these analytical tools allows the detailed characterization of the texture and composition of the E-waste feeds, ahead of waste reprocessing. These data can then be used to aid the design of optimized processing circuits for the recovery of the key payable components, and assist in the commercial trading of e-scrap. Full article

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18 pages, 7363 KiB

Open AccessArticle

Agronomic Evaluation of Compost Formulations Based on Mining Tailings and Microbial Mats from Geothermal Sources

by María Jesús Puy-Alquiza, Miren Yosune Miranda Puy, Raúl Miranda-Avilés, Pooja Vinod Kshirsagar and Cristina Daniela Moncada Sanchez

Recycling 2025, 10(4), 156; https://doi.org/10.3390/recycling10040156 - 5 Aug 2025

Viewed by 229

Abstract

This study, conducted in Mexico, evaluates the agricultural potential of three compost formulations BFS1, BFS2, and BFS3 produced from mining tailings and thermophilic microbial mats and collected from geothermal environments. The physicochemical characterization included pH, electrical conductivity (EC), macronutrients (N, P, K, Ca, [...] Read more.

This study, conducted in Mexico, evaluates the agricultural potential of three compost formulations BFS1, BFS2, and BFS3 produced from mining tailings and thermophilic microbial mats and collected from geothermal environments. The physicochemical characterization included pH, electrical conductivity (EC), macronutrients (N, P, K, Ca, Mg, and S), micronutrients (Fe, Zn, B, Cu, Mn, Mo, and Ni), organic matter (OM), and the carbon-to-nitrogen (C/N) ratio. All composts exhibited neutral pH values (7.38–7.52), high OM content (38.5–48.4%), and optimal C/N ratios (10.5–13.9), indicating maturity and chemical stability. Nitrogen ranged from 19 to 21 kg·t⁻¹, while potassium and calcium were present in concentrations beneficial for crop development. However, EC values (3.43–3.66 dS/m) and boron levels (>160 ppm) were moderately high, requiring caution in saline soils or with boron-sensitive crops. A semi-quantitative Compost Quality Index (CQI) ranked BFS3 highest due to elevated OM and potassium content, followed by BFS1. BFS2, while rich in nitrogen, scored lower due to excessive boron. One-way ANOVA revealed no significant difference in nitrogen (p > 0.05), but it did reveal significant differences in potassium (p < 0.01) and boron (p < 0.001) among formulations. These results confirm the potential of mining tailings—microbial mat composts are low-cost, nutrient-rich biofertilizers. They are suitable for field crops or as components in nursery substrates, particularly when EC and boron are managed through dilution. This study promotes the circular reuse of geothermal and industrial residues and contributes to sustainable soil restoration practices in mining-affected regions through innovative composting strategies. Full article

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31 pages, 1741 KiB

Open AccessReview

Recycled Concrete Aggregate in Asphalt Mixtures: A Review

by Juan Gabriel Bastidas-Martínez, Hugo Alexander Rondón-Quintana and Luis Ángel Moreno-Anselmi

Recycling 2025, 10(4), 155; https://doi.org/10.3390/recycling10040155 - 2 Aug 2025

Viewed by 201

Abstract

Effective management and handling of construction and demolition waste (CDW) can yield significant technical and environmental benefits for road pavement construction. This article aims to provide a comprehensive and up-to-date chronological review of studies on the mechanical performance of asphalt mixtures—primarily hot mix [...] Read more.

Effective management and handling of construction and demolition waste (CDW) can yield significant technical and environmental benefits for road pavement construction. This article aims to provide a comprehensive and up-to-date chronological review of studies on the mechanical performance of asphalt mixtures—primarily hot mix asphalt (HMA)—incorporating recycled concrete aggregate (RCA). Since the main limitation of RCA is the presence of residual adhered mortar, the review also includes studies that applied various surface treatments (mechanical, chemical, and thermal, among others) to enhance mixture performance. The article summarizes the experimental procedures used and highlights the key findings and conclusions of the reviewed research. Although the results are varied and sometimes contradictory—mainly due to the source variability and heterogeneity of RCA—the use of these materials is technically viable. Moreover, their application can provide environmental, social, and economic advantages, particularly in the construction of low-traffic roadways. Finally, the article identifies research gaps and offers recommendations for future researches. Full article

(This article belongs to the Special Issue Recycled Materials in Sustainable Pavement Innovation)

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30 pages, 2603 KiB

Open AccessReview

Sugarcane Industry By-Products: A Decade of Research Using Biotechnological Approaches

by Serafín Pérez-Contreras, Francisco Hernández-Rosas, Manuel A. Lizardi-Jiménez, José A. Herrera-Corredor, Obdulia Baltazar-Bernal, Dora A. Avalos-de la Cruz and Ricardo Hernández-Martínez

Recycling 2025, 10(4), 154; https://doi.org/10.3390/recycling10040154 - 2 Aug 2025

Viewed by 401

Abstract

The sugarcane industry plays a crucial economic role worldwide, with sucrose and ethanol as its main products. However, its processing generates large volumes of by-products—such as bagasse, molasses, vinasse, and straw—that contain valuable components for biotechnological valorization. This review integrates approximately 100 original [...] Read more.

The sugarcane industry plays a crucial economic role worldwide, with sucrose and ethanol as its main products. However, its processing generates large volumes of by-products—such as bagasse, molasses, vinasse, and straw—that contain valuable components for biotechnological valorization. This review integrates approximately 100 original research articles published in JCR-indexed journals between 2015 and 2025, of which over 50% focus specifically on sugarcane-derived agroindustrial residues. The biotechnological approaches discussed include submerged fermentation, solid-state fermentation, enzymatic biocatalysis, and anaerobic digestion, highlighting their potential for the production of biofuels, enzymes, and high-value bioproducts. In addition to identifying current advances, this review addresses key technical challenges such as (i) the need for efficient pretreatment to release fermentable sugars from lignocellulosic biomass; (ii) the compositional variability of by-products like vinasse and molasses; (iii) the generation of metabolic inhibitors—such as furfural and hydroxymethylfurfural—during thermochemical processes; and (iv) the high costs related to inputs like hydrolytic enzymes. Special attention is given to detoxification strategies for inhibitory compounds and to the integration of multifunctional processes to improve overall system efficiency. The final section outlines emerging trends (2024–2025) such as the use of CRISPR-engineered microbial consortia, advanced pretreatments, and immobilization systems to enhance the productivity and sustainability of bioprocesses. In conclusion, the valorization of sugarcane by-products through biotechnology not only contributes to waste reduction but also supports circular economy principles and the development of sustainable production models. Full article

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Graphical abstract

19 pages, 4487 KiB

Open AccessArticle

Recycling Volcanic Lapillus as a Supplementary Cementitious Material in Sustainable Mortars

by Fabiana Altimari, Luisa Barbieri, Andrea Saccani and Isabella Lancellotti

Recycling 2025, 10(4), 153; https://doi.org/10.3390/recycling10040153 - 1 Aug 2025

Viewed by 291

Abstract

This study investigates the feasibility of using volcanic lapillus as a supplementary cementitious material (SCM) in mortar production to improve the sustainability of the cement industry. Cement production is one of the main sources of CO₂ emissions, mainly due to clinker production. [...] Read more.

This study investigates the feasibility of using volcanic lapillus as a supplementary cementitious material (SCM) in mortar production to improve the sustainability of the cement industry. Cement production is one of the main sources of CO₂ emissions, mainly due to clinker production. Replacing clinker with SCMs, such as volcanic lapillus, can reduce the environmental impact while maintaining adequate mechanical properties. Experiments were conducted to replace up to 20 wt% of limestone Portland cement with volcanic lapillus. Workability, compressive strength, microstructure, resistance to alkali-silica reaction (ASR), sulfate, and chloride penetration were analyzed. The results showed that up to 10% replacement had a minimal effect on mechanical properties, while higher percentages resulted in reduced strength but still improved some durability features. The control sample cured 28 days showed a compressive strength of 43.05 MPa compared with 36.89 MPa for the sample containing 10% lapillus. After 90 days the respective values for the above samples were 44.76 MPa and 44.57 MPa. Scanning electron microscopy (SEM) revealed good gel–aggregate adhesion, and thermogravimetric analysis (TGA) confirmed reduced calcium hydroxide content, indicating pozzolanic activity. Overall, volcanic lapillus shows promise as a sustainable SCM, offering CO₂ reduction and durability benefits, although higher replacement rates require further optimization. Full article

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23 pages, 4356 KiB

Open AccessArticle

Quantifying Cotton Content in Post-Consumer Polyester/Cotton Blend Textiles via NIR Spectroscopy: Current Attainable Outcomes and Challenges in Practice

by Hana Stipanovic, Gerald Koinig, Thomas Fink, Christian B. Schimper, David Lilek, Jeannie Egan and Alexia Tischberger-Aldrian

Recycling 2025, 10(4), 152; https://doi.org/10.3390/recycling10040152 - 1 Aug 2025

Viewed by 239

Abstract

Rising volumes of textile waste necessitate the development of more efficient recycling systems, with a primary focus on the optimization of sorting technologies. Near-infrared (NIR) spectroscopy is a state-of-the-art method for fiber identification; however, its accuracy in quantifying textile blends, particularly common polyester/cotton [...] Read more.

Rising volumes of textile waste necessitate the development of more efficient recycling systems, with a primary focus on the optimization of sorting technologies. Near-infrared (NIR) spectroscopy is a state-of-the-art method for fiber identification; however, its accuracy in quantifying textile blends, particularly common polyester/cotton blend textiles, still requires refinement. This study explores the potential and limitations of NIR spectroscopy for quantifying cotton content in post-consumer textiles. A lab-scale NIR sorter and a handheld NIR spectrometer in complementary wavelength ranges were applied to a diverse range of post-consumer textile samples to test model accuracies. Results show that the commonly assumed 10% accuracy threshold in industrial sorting can be exceeded, especially when excluding textiles with <35% cotton content. Identifying and excluding the range of non-linearity significantly improved the model’s performance. The final models achieved an RMSEP of 6.6% and bias of −0.9% for the NIR sorter and an RMSEP of 3.1% and bias of −0.6% for the handheld NIR spectrometer. This study also assessed how textile characteristics—such as color, structure, product type, and alkaline treatment—affect spectral behavior and model accuracy, highlighting their importance for refining quantification when high-purity inputs are needed. By identifying current limitations and potential sources of errors, this study provides a foundation for improving NIR-based models. Full article

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20 pages, 1701 KiB

Open AccessArticle

Life Cycle Assessment of Biomass Waste and Coal Co-Firing: Advancing Circular Economy in Energy Production

by Stiven J. Sofán-Germán, Miguel E. Doria-Oviedo, Jesus D. Rhenals-Julio and Jorge M. Mendoza-Fandiño

Recycling 2025, 10(4), 151; https://doi.org/10.3390/recycling10040151 - 1 Aug 2025

Viewed by 268

Abstract

This study uses life cycle analysis (LCA) to evaluate the environmental impacts of co-firing bituminous coal with agricultural biomass waste, such as coconut and rice husks, emphasising circular economy principles. Seven experimental scenarios with different coal-to-biomass ratios were designed, ranging from pure coal [...] Read more.

This study uses life cycle analysis (LCA) to evaluate the environmental impacts of co-firing bituminous coal with agricultural biomass waste, such as coconut and rice husks, emphasising circular economy principles. Seven experimental scenarios with different coal-to-biomass ratios were designed, ranging from pure coal to pure biomass. The results show that Scenario B (100% rice husk) achieved the best overall environmental performance, with the lowest global warming potential (300 kg CO₂ equivalent), eutrophication potential (4.742 kg PO₄ equivalent), and smog formation potential (0.012 kg C₂H₄ equivalent). Additionally, Scenario F (15% biomass mix) recorded the lowest acidification potential (57.39 kg SO₂ eq), indicating that even partial substitution can yield significant environmental benefits. In contrast, Scenario C (100% coal) exhibited the highest acidification (164.08 kg SO₂ eq) and eutrophication (8.82 kg PO₄ eq) potential. Overall, the results demonstrate that co-firing biomass waste significantly reduces pollutant emissions compared to burning coal alone. This study highlights the effectiveness of biomass waste co-firing in mitigating environmental impacts, promoting resource recovery, and supporting a sustainable energy transition within a circular economy framework. Full article

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17 pages, 9519 KiB

Open AccessArticle

Lead Recovery from Flue Dust by Using Ultrasonic-Enhanced Hydrogen Peroxide Water Washing

by Tian Wang, Yuxi Xie, Phan Duc Lenh, Thiquynhxuan Le and Libo Zhang

Recycling 2025, 10(4), 150; https://doi.org/10.3390/recycling10040150 - 1 Aug 2025

Viewed by 247

Abstract

An ultrasonic-enhanced hydrogen peroxide water-washing process was developed to recover lead from raw flue dust (RFD) under neutral conditions. At optimal parameters (40 °C, 30 min, 4 mL H₂O₂, liquid-to-solid ratio 2:1, 240 W ultrasound), the Pb mass fraction [...] Read more.

An ultrasonic-enhanced hydrogen peroxide water-washing process was developed to recover lead from raw flue dust (RFD) under neutral conditions. At optimal parameters (40 °C, 30 min, 4 mL H₂O₂, liquid-to-solid ratio 2:1, 240 W ultrasound), the Pb mass fraction in the solid residue increased from 41.68% in the RFD to 68.11%, accompanied by a Pb recovery rate of 97.1%. These values are significantly higher than those obtained under identical conditions without ultrasound (64.07% and 95.93%, respectively). Ultrasound promotes de-agglomeration and generates •OH radicals that accelerate the oxidation of PbSO₃ to insoluble PbSO₄ while concurrently removing impurity cadmium. This research offers a green and efficient alternative to traditional lead recovery methods, fostering sustainable development in the metallurgical industry. Full article

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21 pages, 2332 KiB

Open AccessArticle

Evaluation of Spent Catalyst from Fluid Catalytic Cracking in Fly Ash and Blast Furnace Slag Based Alkali Activated Materials

by Yolanda Luna-Galiano, Domigo Cabrera-Gallardo, Mónica Rodríguez-Galán, Rui M. Novais, João A. Labrincha and Carlos Leiva Fernández

Recycling 2025, 10(4), 149; https://doi.org/10.3390/recycling10040149 - 1 Aug 2025

Viewed by 267

Abstract

The objective of this work is to evaluate how spent catalyst from fluid catalytic cracking (SCFCC) affects the physical, mechanical and durability properties of fly ash (FA) and blast furnace slag (BFS)-based alkali-activated materials (AAMs). Recycling of SCFCC by integrating it in a [...] Read more.

The objective of this work is to evaluate how spent catalyst from fluid catalytic cracking (SCFCC) affects the physical, mechanical and durability properties of fly ash (FA) and blast furnace slag (BFS)-based alkali-activated materials (AAMs). Recycling of SCFCC by integrating it in a AAM matrix offers several advantages: valorization of the material, reducing its disposal in landfills and the landfill cost, and minimizing the environmental impact. Mineralogical, physical and mechanical characterization were carried out. The durability of the specimens was studied by performing acid attack and thermal stability tests. Mass variation, compressive strength and porosity parameters were determined to assess the durability. BFS- and FA-based AAMs have a different chemical composition, which contribute to variations in microstructure and physical and mechanical properties. Acid neutralization capacity was also determined to analyse the acid attack results. Porosity, including the pore size distribution, and the acid neutralization capacity are crucial in explaining the resistance of the AAMs to sulfuric acid attack and thermal degradation. Herein, a novel route was explored, the use of SCFCC to enhance the durability of AAMs under harsh operating conditions since results show that the compositions containing SCFCC showed lower strength decay due to the lower macroporosity proportions in these compositions. Full article

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33 pages, 3709 KiB

Open AccessReview

A Review of Methods and Data on the Recycling of Plastics from the European Waste Stream of Electric and Electronic Equipment

by Nicolas Nève, Xavier Mackré-Delannoy, Bruno Fayolle, Matthieu Gervais, Stéphane Pompidou, Carole Charbuillet, Cyrille Sollogoub and Nicolas Perry

Recycling 2025, 10(4), 148; https://doi.org/10.3390/recycling10040148 - 28 Jul 2025

Viewed by 367

Abstract

Plastics make up a significant proportion of the stream of the European Waste of Electric and Electronic Equipment (WEEE), yet the use of recycled plastic materials is very low in new manufactured products. A description of the WEEE waste stream in Europe is [...] Read more.

Plastics make up a significant proportion of the stream of the European Waste of Electric and Electronic Equipment (WEEE), yet the use of recycled plastic materials is very low in new manufactured products. A description of the WEEE waste stream in Europe is given, with a focus on the plastic materials commonly found in WEEE that include four principal polymers: polypropylene (PP), polycarbonate (PC), acrylonitrile-butadiene-styrene (ABS) and polystyrene (PS). Furthermore, the legislative aspects related to WEEE and plastics recycling in Europe are complex, and numerous norms have been dictated by the European Commission. These norms are crucial to the sector of polymer recycling and production in Europe. Moreover, an overview of the entire treatment chain is presented. More specifically, each step of a typical recycling chain is introduced, with a focus on the sorting of plastics and the separation of polymers. Lastly, the influence of contaminants in the plastic fraction is discussed, both in terms of polymer particles and unwanted additives. By showing the impact of the purity rate on the mechanical properties of recycled plastics, the consequences of inadequate end-of-life treatment for WEEE-plastics is highlighted, hence linking the quality of recycled plastics to the separation step and the re-compounding of recycled granulates. Full article

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22 pages, 3056 KiB

Open AccessArticle

Recycled Glass and Plastic Waste in Sustainable Geopolymer Systems for Affordable Housing Solutions

by Zhao Qing Tang, Yat Choy Wong, Yali Li and Eryadi Kordi Masli

Recycling 2025, 10(4), 147; https://doi.org/10.3390/recycling10040147 - 27 Jul 2025

Viewed by 404

Abstract

The increasing demand for sustainable construction materials has driven research into low-carbon geopolymers that mitigate both cement-related emissions and plastic and glass waste accumulation. This study explores the development of geopolymer concrete incorporating fly ash (FA), slag (S), and FA + S blends, [...] Read more.

The increasing demand for sustainable construction materials has driven research into low-carbon geopolymers that mitigate both cement-related emissions and plastic and glass waste accumulation. This study explores the development of geopolymer concrete incorporating fly ash (FA), slag (S), and FA + S blends, with 10% recycled crushed glass (RCG) and recycled plastic waste (RPW) as partial coarse aggregate replacements. Compressive strength testing revealed that FA + S-based geopolymers (25FA + S) with 100% ordinary Portland cement (OPC) replacement achieved a 7-day strength of 24.6 MPa, representing a 98% improvement over control specimens. Slag-based geopolymers demonstrated water absorption properties comparable to OPC, indicating enhanced durability. Microstructural analyses using SEM, XRD, and EDS confirmed the formation of a dense aluminosilicate matrix, with slag promoting FA reactivity and reinforcing interfacial transition zone (ITZ). These effects contributed to superior mechanical performance and water resistance. Despite minor shrinkage-induced cracking, full OPC replacement with S or FA + S geopolymers outperformed control specimens, consistently exceeding the target strength of 15 MPa required for low-impact, single-story housing applications within seven days. These findings underscore the potential of geopolymer systems for rapid and sustainable construction, offering an effective solution for reducing carbon footprints and repurposing industrial waste. Full article

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26 pages, 796 KiB

Open AccessArticle

Developing an Integrated Circular Economy Framework for Nanomaterial-Enhanced Recycled PET (nrPET): Advancing Sustainable and Resilient Road Construction Practices

by Demiss A. Belachew and Walied A. Elsaigh

Recycling 2025, 10(4), 146; https://doi.org/10.3390/recycling10040146 - 22 Jul 2025

Viewed by 299

Abstract

The rapid growth in plastic consumption, particularly polyethylene terephthalate (PET), has led to a significant increase in plastic waste, posing a major environmental challenge. Developing an integrated circular economy framework for nanomaterial-enhanced recycled PET (nrPET) can be a promising approach to address this [...] Read more.

The rapid growth in plastic consumption, particularly polyethylene terephthalate (PET), has led to a significant increase in plastic waste, posing a major environmental challenge. Developing an integrated circular economy framework for nanomaterial-enhanced recycled PET (nrPET) can be a promising approach to address this issue and advance sustainable and resilient road construction practices. This comprehensive review examines the current use of rPET in road construction, its existing limitations, and the role of nanomaterials in enhancing the performance of these materials. The review explores the mechanisms by which nanomaterials, such as carbon nanotubes, graphene, nanosilica, and clay nanoplatelets, can improve the properties of rPET, leading to more durable, weather-resistant, and cost-effective road materials. Furthermore, the review analyzes the environmental and sustainability benefits of using nrPET in road construction, focusing on carbon footprint reduction, conservation of natural resources, and alignment with circular economy principles. The potential for job creation, social benefits, and support for circular economy initiatives are also discussed. The review then delves into the challenges associated with the implementation of this framework, including technical barriers, economic and market barriers, regulatory and policy challenges, and environmental and safety considerations. Strategies to address these challenges, such as advancements in nanotechnology, scaling up circular economy models, and fostering collaborative research, are presented. Finally, the article proposes a framework and outlines future directions and research opportunities, emphasizing the exploration of emerging nanomaterials, scaling up circular economy models, and encouraging collaborations between researchers, industry stakeholders, policymakers, and communities. Full article

(This article belongs to the Special Issue Recycled Materials in Sustainable Pavement Innovation)

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21 pages, 3984 KiB

Open AccessArticle

Organic Acid Leaching of Black Mass with an LFP and NMC Mixed Chemistry

by Marc Simon Henderson, Chau Chun Beh, Elsayed Oraby and Jacques Eksteen

Recycling 2025, 10(4), 145; https://doi.org/10.3390/recycling10040145 - 21 Jul 2025

Viewed by 458

Abstract

There is an increasing demand for the development of efficient and sustainable battery recycling processes. Currently, many recycling processes rely on toxic inorganic acids to recover materials from high-value battery chemistries such as lithium nickel manganese cobalt oxides (NMCs) and lithium cobalt oxide [...] Read more.

There is an increasing demand for the development of efficient and sustainable battery recycling processes. Currently, many recycling processes rely on toxic inorganic acids to recover materials from high-value battery chemistries such as lithium nickel manganese cobalt oxides (NMCs) and lithium cobalt oxide (LCOs). However, as cell manufacturers seek more cost-effective battery chemistries, the value of the spent battery value chain is increasingly diluted by chemistries such as lithium iron phosphate (LFPs). These cheaper alternatives present a difficulty when recycling, as current recycling processes are geared towards dealing with high-value chemistries; thus, the current processes become less economical. To date, much research is focused on treating a single battery chemistry; however, often, the feed material entering a battery recycling facility is contaminated with other battery chemistries, e.g., LFP feed contaminated with NMC, LCO, or LMOs. This research aims to selectively leach various battery chemistries out of a mixed feed material with the aid of a green organic acid, namely oxalic acid. When operating at the optimal conditions (2% solids, 0.25 M oxalic acid, natural pH around 1.15, 25 °C, 60 min), this research has proven that oxalic acid can be used to selectively dissolve 95.58% and 93.57% of Li and P, respectively, from a mixed LFP-NMC mixed feed, all while only extracting 12.83% of Fe and 8.43% of Mn, with no Co and Ni being detected in solution. Along with the high degree of selectivity, this research has also demonstrated, through varying the pH, that the selectivity of the leaching system can be altered. It was determined that at pH 0.5 the system dissolved both the NMC and LFP chemistries; at a pH of 1.15, the LFP chemistry (Li and P) was selectively targeted. Finally, at a pH of 4, the NMC chemistry (Ni, Co and Mn) was selectively dissolved. Full article

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15 pages, 677 KiB

Open AccessArticle

Zero-Shot Learning for Sustainable Municipal Waste Classification

by Dishant Mewada, Eoin Martino Grua, Ciaran Eising, Patrick Denny, Pepijn Van de Ven and Anthony Scanlan

Recycling 2025, 10(4), 144; https://doi.org/10.3390/recycling10040144 - 21 Jul 2025

Viewed by 343

Abstract

Automated waste classification is an essential step toward efficient recycling and waste management. Traditional deep learning models, such as convolutional neural networks, rely on extensive labeled datasets to achieve high accuracy. However, the annotation process is labor-intensive and time-consuming, limiting the scalability of [...] Read more.

Automated waste classification is an essential step toward efficient recycling and waste management. Traditional deep learning models, such as convolutional neural networks, rely on extensive labeled datasets to achieve high accuracy. However, the annotation process is labor-intensive and time-consuming, limiting the scalability of these approaches in real-world applications. Zero-shot learning is a machine learning paradigm that enables a model to recognize and classify objects it has never seen during training by leveraging semantic relationships and external knowledge sources. In this study, we investigate the potential of zero-shot learning for waste classification using two vision-language models: OWL-ViT and OpenCLIP. These models can classify waste without direct exposure to labeled examples by leveraging textual prompts. We apply this approach to the TrashNet dataset, which consists of images of municipal solid waste organized into six distinct categories: cardboard, glass, metal, paper, plastic, and trash. Our experimental results yield an average classification accuracy of 76.30% with Open Clip ViT-L/14-336 model, demonstrating the feasibility of zero-shot learning for waste classification while highlighting challenges in prompt sensitivity and class imbalance. Despite lower accuracy than CNN- and ViT-based classification models, zero-shot learning offers scalability and adaptability by enabling the classification of novel waste categories without retraining. This study underscores the potential of zero-shot learning in automated recycling systems, paving the way for more efficient, scalable, and annotation-free waste classification methodologies. Full article

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16 pages, 2206 KiB

Open AccessArticle

Turning Waste into Wealth: Sustainable Amorphous Silica from Moroccan Oil Shale Ash

by Anas Krime, Sanaâ Saoiabi, Mouhaydine Tlemcani, Ahmed Saoiabi, Elisabete P. Carreiro and Manuela Ribeiro Carrott

Recycling 2025, 10(4), 143; https://doi.org/10.3390/recycling10040143 - 20 Jul 2025

Viewed by 323

Abstract

Moroccan oil shale ash (MOSA) represents an underutilized industrial by-product, particularly in the Rif region, where its high mineral content has often led to its neglect in value-added applications. This study highlights the successful conversion of MOSA into amorphous mesoporous silica (AS-Si) using [...] Read more.

Moroccan oil shale ash (MOSA) represents an underutilized industrial by-product, particularly in the Rif region, where its high mineral content has often led to its neglect in value-added applications. This study highlights the successful conversion of MOSA into amorphous mesoporous silica (AS-Si) using a sol–gel process assisted by polyethylene glycol (PEG-6000) as a soft template. The resulting AS-Si material was extensively characterized to confirm its potential for environmental remediation. FTIR analysis revealed characteristic vibrational bands corresponding to Si–OH and Si–O–Si bonds, while XRD confirmed its amorphous nature with a broad diffraction peak at 2θ ≈ 22.5°. SEM imaging revealed a highly porous, sponge-like morphology composed of aggregated nanoscale particles, consistent with the nitrogen adsorption–desorption isotherm. The material exhibited a specific surface area of 68 m²/g, a maximum in the pore size distribution at a pore diameter of 2.4 nm, and a cumulative pore volume of 0.11 cm³/g for pores up to 78 nm. DLS analysis indicated an average hydrodynamic diameter of 779 nm with moderate polydispersity (PDI = 0.48), while a zeta potential of –34.10 mV confirmed good colloidal stability. Furthermore, thermogravimetric analysis (TGA) and DSC suggested the thermal stability of our amorphous silica. The adsorption performance of AS-Si was evaluated using methylene blue (MB) and ciprofloxacin (Cipro) as model pollutants. Kinetic data were best fitted by the pseudo-second-order model, while isotherm studies favored the Langmuir model, suggesting monolayer adsorption. AS-Si could be used four times for the removal of MB and Cipro. These results collectively demonstrate that AS-Si is a promising, low-cost, and sustainable adsorbent derived from Moroccan oil shale ash for the effective removal of organic contaminants from aqueous media. Full article

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26 pages, 2472 KiB

Open AccessArticle

Incorporating Recyclates Derived from Household Waste into Flexible Food Packaging Applications: An Environmental Sustainability Assessment

by Trang T. Nhu, Anna-Sophie Haslinger, Sophie Huysveld and Jo Dewulf

Recycling 2025, 10(4), 142; https://doi.org/10.3390/recycling10040142 - 17 Jul 2025

Viewed by 376

Abstract

Integrating recyclates into food packaging is key towards circularity while meeting functionality and safety requirements; however, associated environmental impacts remain underexplored. This gap was addressed through a cradle-to-gate life cycle assessment, using the Environmental Footprint method, along with substitution and cut-off approaches for [...] Read more.

Integrating recyclates into food packaging is key towards circularity while meeting functionality and safety requirements; however, associated environmental impacts remain underexplored. This gap was addressed through a cradle-to-gate life cycle assessment, using the Environmental Footprint method, along with substitution and cut-off approaches for handling the multifunctionality of recycling. Recyclates were derived from polyethylene (PE)-rich household food packaging waste, purified via delamination-deinking. Firstly, results show that shifting from virgin multi-material to mono-material multilayer structures with or without recyclates, while maintaining functionality, offers environmental benefits. Secondly, recyclates should sufficiently substitute virgin materials in quantity and quality, decreasing the need for primary plastics and avoiding recyclate incorporation without functionality. Otherwise, thicker laminates are obtained, increasing processability challenges and environmental impacts, e.g., 12% for particulate matter, and 14% for mineral-metal resource use when the recycle content rises from 34 to 50%. Thirdly, a fully closed loop for flexible food packaging is not yet feasible. Key improvements lie in reducing residues generated during recycling, especially in delamination-deinking, lowering energy use in recompounding, and using more efficient transport modes for waste collection. Further research is essential to optimise the innovative technologies studied for flexible food packaging and refine them for broader applications. Full article

(This article belongs to the Special Issue Challenges and Opportunities in Plastic Waste Management)

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19 pages, 1165 KiB

Open AccessArticle

Expansion of Mechanical Biological Residual Treatment Plant with Fermentation Stage for Press Water from Organic Fractions Involving a Screw Press

by Rzgar Bewani, Abdallah Nassour, Thomas Böning, Jan Sprafke and Michael Nelles

Recycling 2025, 10(4), 141; https://doi.org/10.3390/recycling10040141 - 16 Jul 2025

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Abstract

A three-year optimization study was conducted at a mechanical biological treatment plant with the aim of enhancing organic fractions recovery from mechanically separated fine fractions (MSFF) of residual waste using a screw press. The study aimed to optimize key operating parameters for the [...] Read more.

A three-year optimization study was conducted at a mechanical biological treatment plant with the aim of enhancing organic fractions recovery from mechanically separated fine fractions (MSFF) of residual waste using a screw press. The study aimed to optimize key operating parameters for the employed screw press, such as pressure, liquid-to-MSFF, feeding quantity per hour, and press basket mesh size, to enhance volatile solids and biogas recovery in the generated press water for anaerobic digestion. Experiments were performed at the full-scale facility to evaluate the efficiency of screw press extraction with other pretreatment methods, like press extrusion, wet pulping, and hydrothermal treatment. The results indicated that hydrolysis of the organic fractions in MSFF was the most important factor for improving organic extraction from the MSFF to press water for fermentation. Optimal hydrolysis efficiency was achieved with a digestate and process water-to-MSFF of approximately 1000 L/ton, with a feeding rate between 8.8 and 14 tons per hour. Increasing pressure from 2.5 to 4.0 bar had minimal impact on press water properties or biogas production, regardless of the press basket size. The highest volatile solids (29%) and biogas (50%) recovery occurred at 4.0 bar pressure with a 1000 L/ton liquid-to-MSFF. Further improvements could be achieved with longer mixing times before pressing. These findings demonstrate the technical feasibility of the pressing system for preparing an appropriate substrate for the fermentation process, underscoring the potential for optimizing the system. However, further research is required to assess the cost–benefit balance. Full article

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39 pages, 3281 KiB

Open AccessReview

Sustainable Alkali-Activated and Geopolymer Materials: What Is the Future for Italy?

by Laura Ricciotti, Daniele Lucariello, Valeria Perrotta, Antonio Apicella and Raffaella Aversa

Recycling 2025, 10(4), 140; https://doi.org/10.3390/recycling10040140 - 15 Jul 2025

Viewed by 622

Abstract

Using innovative and sustainable materials has become crucial for developed countries. Reusing waste as a secondary raw material in industrial processes central to the circular economy could enhance environmental sustainability and support local economies. Building materials such as Portland cement have a significant [...] Read more.

Using innovative and sustainable materials has become crucial for developed countries. Reusing waste as a secondary raw material in industrial processes central to the circular economy could enhance environmental sustainability and support local economies. Building materials such as Portland cement have a significant environmental impact due to greenhouse gas emissions and construction and demolition waste (CDW), which is challenging to recycle. Research into sustainable alternatives is, therefore, essential. The European Union has set ambitious targets to reduce greenhouse gas emissions by 55% by 2030 and achieve climate neutrality by 2050. The National Recovery and Resilience Plan (PNRR) supports the green transition in Italy by promoting sustainable materials like geopolymers. These ceramic-like materials are based on aluminosilicates obtained through the chemical activation of waste rich in silica and aluminosilicate compounds. Though promising, these materials require further research to address challenges like long-term durability and chemical variability. Collaboration between scientific research and industry is essential to develop specific protocols and suitable infrastructures. This article provides a critical review of the advancements and challenges in using alkali-activated waste as construction binders, focusing on Italy, and encourages the exploration of alternative sustainable materials beyond conventional Portland cement. Full article

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18 pages, 3737 KiB

Open AccessArticle

Simulation-Based RF-ICP Torch Optimization for Efficient and Environmentally Sustainable Radioactive Waste Management

by Roman Stetsiuk, Mustafa A. Aldeeb and Hossam A. Gabbar

Recycling 2025, 10(4), 139; https://doi.org/10.3390/recycling10040139 - 15 Jul 2025

Viewed by 308

Abstract

This study examines methods to improve the energy efficiency of radiofrequency inductively coupled plasma (RF-ICP) torches for radioactive waste treatment, with a focus on surpassing the typical energy efficiency limit of approximately 70%. To improve energy efficiency and plasma performance, this research investigates [...] Read more.

This study examines methods to improve the energy efficiency of radiofrequency inductively coupled plasma (RF-ICP) torches for radioactive waste treatment, with a focus on surpassing the typical energy efficiency limit of approximately 70%. To improve energy efficiency and plasma performance, this research investigates the transition from axial gas flow to vortex gas flow patterns using COMSOL Multiphysics software v6.2. Key plasma parameters, including energy efficiency, number of gas vortices, heat transfer, and temperature distribution, were analyzed to evaluate the improvements. The results indicate that adopting a vortex flow pattern increases energy conversion efficiency, increases heat flux, and reduces charge losses. Furthermore, optimizing the torch body design, particularly the nozzle, chamber volume, and gas entry angle, significantly improves plasma properties and energy efficiency by up to 90%. Improvements to RF-ICP torches positively impact waste decomposition by creating better thermal conditions that support resource recovery and potential material recycling. In addition, these improvements contribute to reducing secondary waste, mitigating environmental risks, and fostering long-term public support for nuclear technology, thereby promoting a more sustainable approach to waste management. Simulation results demonstrate the potential of RF-ICP flares as a cost-effective and sustainable solution for the thermal treatment of low- to intermediate-level radioactive waste. Full article

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21 pages, 7071 KiB

Open AccessArticle

An Experimental Investigation into the Performance of Concrete and Mortar with Partial Replacement of Fine Aggregate by Printed Circuit Board (PCB) E-Waste

by Srinivasan Krishnan, Sai Gopal Krishna Bhagavatula, Jayanarayanan Karingamanna and Mini K. Madhavan

Recycling 2025, 10(4), 138; https://doi.org/10.3390/recycling10040138 - 12 Jul 2025

Viewed by 288

Abstract

The increasing accumulation of E-waste presents significant environmental challenges, particularly its disposal and resource management. The present study investigates the potential of printed circuit boards (PCBs) as a partial replacement for fine aggregates in cement mortar and concrete. The replacement levels of PCBs [...] Read more.

The increasing accumulation of E-waste presents significant environmental challenges, particularly its disposal and resource management. The present study investigates the potential of printed circuit boards (PCBs) as a partial replacement for fine aggregates in cement mortar and concrete. The replacement levels of PCBs ranged from 0 to 35 wt% in cement mortar and from 0 to 30 wt% in concrete, aiming to improve the qualities of both mixes. The specimens were cured for 7 and 28 days, respectively, followed by tests to evaluate the flowability and static mechanical properties. The performance of the developed mortar/concrete was analyzed under aggressive environmental conditions by conducting various durability tests. Properties such as acoustic and thermal conductivity were also evaluated to check the suitability of the developed material for its multifunctionality. Test results revealed that the optimal replacement percentages of fine aggregate by PCBs in mortar and concrete mixes were 25 wt% and 20 wt%, respectively. A decline in mechanical properties was observed after a further increase in replacement level. The results demonstrate the feasibility of E-waste integration in cement and mortar as a sustainable waste management solution. Full article

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22 pages, 3937 KiB

Open AccessArticle

Selective Ammonium Recovery from Livestock and Organic Solid Waste Digestates Using Zeolite Tuff: Efficiency and Farm-Scale Prospects

by Matteo Alberghini, Giacomo Ferretti, Giulio Galamini, Cristina Botezatu and Barbara Faccini

Recycling 2025, 10(4), 137; https://doi.org/10.3390/recycling10040137 - 8 Jul 2025

Viewed by 338

Abstract

Implementing efficient strategies for the circular recovery and reuse of nutrients from wastewaters is mandatory to meet the Green Deal objectives and Sustainable Development Goals. In this context we investigated the use of zeolitic tuff (containing chabazite and phillipsite) in the selective recovery [...] Read more.

Implementing efficient strategies for the circular recovery and reuse of nutrients from wastewaters is mandatory to meet the Green Deal objectives and Sustainable Development Goals. In this context we investigated the use of zeolitic tuff (containing chabazite and phillipsite) in the selective recovery and reuse of N from various anaerobic liquid digestates in view of their implementation in farm-scale treatment plants. We tested the method on three livestock digestates and two municipal organic solid waste digestates. Adsorption isotherms and kinetics were assessed on each digestate, and a large set of parameters, including (i) contact time, (ii) initial NH₄⁺ concentration, (iii) presence of competing ions, (iv) total solids content, and (vi) separation methods (microfiltration and clarification), were considered in the experimental design. Our results showed that the adsorption mechanism can be explained by the Freundlich model (R² up to 0.97), indicating a multilayer and heterogeneous adsorption, while the kinetic of adsorption can be explained by the pseudo-second-order model, indicating chemical adsorption and ion exchange. The efficiency in the removal of NH₄⁺ was indirectly related to the K⁺ and total solids content of the digestate. Maximum NH₄⁺ removal exceeded 90% in MSW-derived digestates and 80% within 60 min in livestock-derived digestates at a 5% solid/liquid ratio. Thermodynamic parameters confirmed favorable and spontaneous adsorption (ΔG up to −7 kJ⋅mol⁻¹). Farm-scale projections estimate a nitrogen recovery potential of 1.2 to 16 kg N⋅day⁻¹, depending on digestate type and process conditions. These findings support the application of natural zeolitic tuffs as a low-cost, chemical-free solution for ammonium recovery, contributing to sustainable agriculture and circular economy objectives. Full article

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18 pages, 2433 KiB

Open AccessArticle

Thermodynamic Assessment of the Pyrometallurgical Recovery of a Pb-Ag Alloy from a Mixture of Ammonium Jarosite–Lead Paste Wastes

by Jose Enrique Sanchez Vite, Alejandro Cruz Ramírez, Manuel Eduardo Flores Favela, Ricardo Gerardo Sánchez Alvarado, José Antonio Romero Serrano, Margarita García Hernández, Teresita del Refugio Jiménez Romero and Juan Cancio Jiménez Lugos

Recycling 2025, 10(4), 136; https://doi.org/10.3390/recycling10040136 - 8 Jul 2025

Viewed by 671

Abstract

A previously pyrometallurgical process, developed to obtain a Pb-Ag alloy and a slag rich in sulfur from the recycling of a mixture of industrial wastes of jarosite and lead paste, was thermodynamically assessed at 1200 °C. The industrial jarosite sourced from a Mexican [...] Read more.

A previously pyrometallurgical process, developed to obtain a Pb-Ag alloy and a slag rich in sulfur from the recycling of a mixture of industrial wastes of jarosite and lead paste, was thermodynamically assessed at 1200 °C. The industrial jarosite sourced from a Mexican zinc hydrometallurgical plant corresponded to an ammonium jarosite with a measurable silver content. The specific heat capacity (Cp) of the ammonium jarosite was obtained from TGA and DSC measurements, as well as the thermodynamic functions of enthalpy, entropy, and Gibbs free energy. The Cp was successfully modeled using polynomial regression, with a second-degree polynomial employed to describe the low-temperature behavior. The thermodynamic data generated were input into the thermodynamic software FactSage 8.2 for modeling of the lead paste–ammonium jarosite-Na₂CO₃-SiC system and represented by stability phase diagrams. The thermodynamic assessment of the pyrometallurgical process predicted compounds formed at high temperatures, showing that a Pb-Ag alloy and a slag rich in Na, S, and Fe (NaFeS₂ and NaFeO₂) were obtained. The compounds formed evidence of the effective sulfur retention in the slag, which is crucial for mitigating SO₂ emissions during high-temperature treatments. The experimental compounds, after solidification, were determined by X-ray diffraction measurements to be Na₂Fe(SO₄)₂ and Na₂(SO₄), which reasonably match the thermodynamic assessment. The heat capacity of the ammonium jarosite provides essential thermodynamic insights into the compositional complexities of industrial waste, which are particularly relevant for thermodynamic modeling and process optimization in pyrometallurgical systems aimed at metal recovery and residue valorization. Full article

(This article belongs to the Topic Sustainable Recycling and Reuse of Industrial By-Products or Waste from Geo-Resource Exploitation)

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18 pages, 4826 KiB

Open AccessArticle

Mass Distribution of Organic Carbon, S-Containing Compounds and Heavy Metals During Flotation of Municipal Solid Waste Incineration Fly Ash

by Weifang Chen, Peng Li, Shuyue Zhang and Yifan Chen

Recycling 2025, 10(4), 135; https://doi.org/10.3390/recycling10040135 - 8 Jul 2025

Viewed by 278

Abstract

Flotation was investigated to treat incineration fly ash with diesel, kerosene, TX-100, or SDS as a collector and methyl isobutyl carbinol (MIBC) or 2-Octyl alcohol as a frother. Fly ash was separated into light and residual materials. Comparison of yield, carbon and sulfur [...] Read more.

Flotation was investigated to treat incineration fly ash with diesel, kerosene, TX-100, or SDS as a collector and methyl isobutyl carbinol (MIBC) or 2-Octyl alcohol as a frother. Fly ash was separated into light and residual materials. Comparison of yield, carbon and sulfur removal showed that kerosene and MIBC showed the best performance. The results revealed that flotation was a method that could simultaneously achieve the removal of organics and S-containing compounds. Specifically, approximately 7.63–9.45% of the total mass was collected as light material, which was enriched with organic carbon. Contents of organic carbon reached 14.35 wt%–14.56 wt% in the light materials from those of 2.74 wt%–3.52 wt% in the original fly ash. Elemental analysis further proved that sulfur was also accumulated in light material. Approximately 78.84–81.69% of the organic carbon and 80.47–82.66% of the sulfur were removed. Decarbonization was primarily achieved through the flotation of organic materials, while desulfurization resulted from both flotation and the dissolution of soluble salts. Furthermore, the contents of the chloride and heavy metals in the residual fly ash also decreased. Particle size analysis showed that flotation was effective in the removal of smaller particles, and those particles were also rich in heavy metals. Overall, by selecting the right collector and frother, flotation was also able to reduce the leaching toxicity of heavy metals. The residual fly ash was safe for further disposal. Organic carbon, sulfur and heavy metals were accumulated in the light materials, which accounted for less than 10% of the original mass. The portion of fly ash needing further treatment was therefore greatly reduced. Full article

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15 pages, 3600 KiB

Open AccessArticle

Evaluation of Plastic Waste Degradation Using Terahertz Spectroscopy for Material Recycling

by Hitomi Sonohata, Gaku Manago, Shun Seike, Hidetoshi Kitawaki and Tadao Tanabe

Recycling 2025, 10(4), 134; https://doi.org/10.3390/recycling10040134 - 5 Jul 2025

Cited by 1 | Viewed by 494

Abstract

In Japan, the majority of waste plastics are classified into three categories: approximately 22% are used for material recycling, 3% are used for chemical recycling, and 62% are used for thermal recycling. Thermal recycling is not considered true recycling in the EU, however. [...] Read more.

In Japan, the majority of waste plastics are classified into three categories: approximately 22% are used for material recycling, 3% are used for chemical recycling, and 62% are used for thermal recycling. Thermal recycling is not considered true recycling in the EU, however. To achieve a decarbonized society, Japan must increase the share of material recycling. The accurate identification of plastic materials is essential in this regard, and while near-infrared (NIR) spectroscopy is commonly employed in analyses, it cannot be used to assess degradation levels. Plastics characterized by different degrees of degradation can reduce the quality of recycled products and require additional treatment. In this study, we irradiated artificially degraded polyethylene and polypropylene samples using Fourier transform infrared (FTIR) spectroscopy and terahertz (THz) waves and subsequently compared them with undegraded samples. Our results provide experimental confirmation that THz waves can be used to determine the degree of plastic degradation. When combined with NIR-based material identification, this method could enhance the precision and efficiency of plastic recycling, contributing to a more sustainable recycling system. Full article

(This article belongs to the Special Issue Challenges and Opportunities in Plastic Waste Management)

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24 pages, 5049 KiB

Open AccessArticle

Sustainable Mortar with Waste Glass and Fly Ash: Impact of Glass Aggregate Size and Life-Cycle Assessment

by Vimukthi Fernando, Weena Lokuge, Hannah Seligmann, Hao Wang and Chamila Gunasekara

Recycling 2025, 10(4), 133; https://doi.org/10.3390/recycling10040133 - 4 Jul 2025

Cited by 1 | Viewed by 398

Abstract

This study investigates the use of Glass Fine Aggregate (GFA) and Fly Ash (FA) in mortar for Alkali–Silica Reaction (ASR) mitigation through a multidimensional evaluation. GFA was used to replace river sand in 20% increments up to 100%, while FA replaced cement at [...] Read more.

This study investigates the use of Glass Fine Aggregate (GFA) and Fly Ash (FA) in mortar for Alkali–Silica Reaction (ASR) mitigation through a multidimensional evaluation. GFA was used to replace river sand in 20% increments up to 100%, while FA replaced cement at 10%, 20%, and 30%. Three GFA size ranges were considered: <1.18 mm, 1.18–4.75 mm, and a combined fraction of <4.75 mm. At 100% replacement, <1.18 mm GFA reduced ASR expansion to 0.07%, compared to 0.2% for <4.75 mm and 0.46% for 1.18–4.75 mm GFA. It also improved long-term strength by 25% from 28 days to 6 months due to pozzolanic activity. However, refining GFA to below 1.18 mm increased environmental impacts and resulted in a 4.2% increase in energy demand due to the additional drying process. Incorporating 10% FA reduced ASR expansion to 0.044%, had no significant effect on strength, and decreased key environmental burdens such as toxicity by up to 18.2%. These findings indicate that FA utilisation offers greater benefits for ASR mitigation and environmental sustainability than further refining GFA size. Therefore, combining <4.75 mm GFA with 10% FA is identified as the optimal strategy for producing durable and sustainable mortar with recycled waste glass. Full article

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