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Magnetochemistry, Volume 9, Issue 1

2023 January - 33 articles

Cover Story: Iron substitution within nickel hydroxide nanosheets substantially affects structure and magnetization. As the Fe substitution ratio increases, both the nanocrystallite shape anisotropy and the magnetic coercivity increase in unison. More importantly, at a low Fe substitution ratio of 5 atomic %, the material is ferromagnetic but 10% and 20% Fe-substituted samples exhibit ferrimagnetic ordering. Additionally, for the higher Fe %, we observe magnetization reversal which is likely due to the larger magnetocrystalline anisotropy. This work furthers understanding of the unique interconnections between structure and magnetization of nanomaterials and can lead to improved materials for batteries, catalysts, electronics, gas sensing, and spintronics. View this paper
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Articles (33)

  • Article
  • Open Access
4 Citations
2,605 Views
21 Pages

Tongchuan City, located in Shaanxi Province, northwest China, has limited groundwater resources. Rational planning and exploitation of groundwater are crucial to the sustainable development of the city, for which investigating the distribution of gro...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,620 Views
15 Pages

Slow Methyl Axes Motions in Perdeuterated Villin Headpiece Subdomain Probed by Cross-Correlated NMR Relaxation Measurements

  • Liliya Vugmeyster,
  • Parker J. Nichols,
  • Dmitry Ostrovsky,
  • C. James McKnight and
  • Beat Vögeli

Protein methyl groups can participate in multiple motional modes on different time scales. Sub-nanosecond to nano-second time scale motions of methyl axes are particularly challenging to detect for small proteins in solutions. In this work we employ...

  • Article
  • Open Access
5 Citations
2,540 Views
19 Pages

This study is aimed at the manufacture and the magnetic properties of polycrystalline M-type hexaferrites BaFe12O19 (barium ferrite, or BaM) materials of different magnetic texturing grades, going from a random distribution of the BaM crystallites to...

  • Article
  • Open Access
7 Citations
3,274 Views
14 Pages

Something You Need Might Be under Your Feet: Molecular Magnetism of Heavy Kramers Lanthanide Hydrated Chlorides and Their Complexes with Polydentate Terpy Ligand

  • Svetlana P. Petrosyants,
  • Konstantin A. Babeshkin,
  • Andrey B. Ilyukhin,
  • Pavel S. Koroteev and
  • Nikolay N. Efimov

A study of the molecular magnetism of the hydrated salts [Ln(H2O)6Cl2]Cl (Ln = Gd (1Gd), Dy (1Dy), Er (1Er), Yb (1Yb)) and lanthanide chloride complexes with 2,2′;6′,2″-terpyridine (terpy) synthesized on their basis, [Ln(H2O)4(terpy...

  • Review
  • Open Access
2,799 Views
14 Pages

The ring current region in the Earth’s magnetosphere contains energetic charged particles, which are injected from the magnetotail, get trapped in the inner magnetosphere, and finally drift around the Earth. The current, essentially carried by...

  • Article
  • Open Access
2 Citations
2,058 Views
8 Pages

The phenomenology of the iron pnictide superconductor can be described by the three-band s± Eliashberg theory in which the mechanism of superconducting coupling is mediated by antiferromagnetic spin fluctuations and whose characteristic energy...

  • Article
  • Open Access
1 Citations
2,398 Views
15 Pages

We have detected a large Nernst effect in the charge density wave state of the multiband organic metal α-(BEDT-TTF)2KHg(SCN)4. We find that apart from the phonon drag effect, the energy relaxation processes that govern the electron–phonon...

  • Article
  • Open Access
12 Citations
3,341 Views
16 Pages

Magnetism and EPR Spectroscopy of Nanocrystalline and Amorphous TiO2: Fe upon Al Doping

  • Anatoly Yermakov,
  • Mikhail Uimin,
  • Kirill Borodin,
  • Artem Minin,
  • Danil Boukhvalov,
  • Denis Starichenko,
  • Alexey Volegov,
  • Rushana Eremina,
  • Ivan Yatsyk and
  • Vasiliy Gaviko
  • + 1 author

This work is devoted to the study of the magnetic properties and Electron Paramagnetic Resonance (EPR) spectroscopy of TiO2:Fe nanoparticles doped with Al in different structural states. The sol-gel methods have been used to obtain the particles in b...

  • Feature Paper
  • Article
  • Open Access
4 Citations
5,544 Views
22 Pages

Structure and Magnetism of Iron-Substituted Nickel Hydroxide Nanosheets

  • Samuel W. Kimmel,
  • Barry D. Koehne,
  • Ben Gibson,
  • Wilhelmus J. Geerts,
  • Nikoleta Theodoropoulou and
  • Christopher P. Rhodes

Nanosheets composed of stacked atomic layers exhibit unique magnetic, electrical, and electrochemical properties. Here, we report the effect of iron substitution on the structure and magnetism of nickel hydroxide, Ni(OH)2, nanosheets. Ni(OH)2 and iro...

  • Feature Paper
  • Review
  • Open Access
21 Citations
5,196 Views
55 Pages

This review represents a compendium of computational studies of relativistic effects on the NMR chemical shifts of light nuclei caused by the presence of heavy main group p-block elements in molecules. The narration starts from a brief discussion of...

  • Review
  • Open Access
40 Citations
5,997 Views
25 Pages

Recent Approaches in Magnetic Nanoparticle-Based Biosensors of miRNA Detection

  • Simge Balaban Hanoglu,
  • Duygu Harmanci,
  • Nursima Ucar,
  • Serap Evran and
  • Suna Timur

In recent years, magnetic nanoparticles (MNPs) have been widely used in many fields due to their advantageous properties, such as biocompatibility, easy modifiability, and high chemical stability. One of these areas is the detection of cancer. It is...

  • Feature Paper
  • Article
  • Open Access
1 Citations
2,338 Views
11 Pages

Time-domain structures (TDS), manifested as ≥ 1 ms pulses with significant parallel electric fields, play an important role in accelerating electrons in the field-aligned direction. These precipitated electrons contribute to the formation of auror...

  • Article
  • Open Access
16 Citations
2,956 Views
11 Pages

Surface Plasmon Resonance Biosensor Chip for Human Blood Groups Identification Assisted with Silver-Chromium-Hafnium Oxide

  • Purnendu Shekhar Pandey,
  • Sanjeev Kumar Raghuwanshi,
  • Rajesh Singh and
  • Santosh Kumar

Chromium (Cr), silver (Ag) and hafnium oxide (HfO2) are used in a surface plasmon resonance (SPR)-based biosensor with an optimized design for measuring blood groups at a wavelength of 633 nm. A buffer layer was placed on the SPR active metal in this...

  • Article
  • Open Access
39 Citations
4,651 Views
15 Pages

Study of Defect-Induced Chemical Modifications in Spinel Zinc-Ferrites Nanostructures by In-Depth XPS Investigation

  • Promod Kumar,
  • Mohan Chandra Mathpal,
  • Gajendra Kumar Inwati,
  • Sanjay Kumar,
  • Mart-Mari Duvenhage,
  • Wiets Daniel Roos and
  • Hendrik C. Swart

Spinel zinc ferrite nanomaterials with exceptional physiochemical properties are potential candidates for various applications in the energy and environmental fields. Their properties can be tailored using several methods to widen their applications....

  • Article
  • Open Access
4 Citations
2,352 Views
15 Pages

In this work, we present the manufacturing process of magnetizable membranes based on cotton microfibers, honey, carbonyl iron, and three different concentrations of silver microparticles. Each membrane is used as a dielectric material for the fabric...

  • Article
  • Open Access
12 Citations
3,491 Views
15 Pages

Impact of Silica-Modification and Oxidation on the Crystal Structure of Magnetite Nanoparticles

  • Artur Dzeranov,
  • Lyubov Bondarenko,
  • Denis Pankratov,
  • Gulzhian Dzhardimalieva,
  • Sharipa Jorobekova,
  • Daniel Saman and
  • Kamila Kydralieva

At present, the widespread use of iron oxide nanoparticles, including for commercial purposes, requires strict preservation of their phase composition during their application. The choice of nanoparticle modifier and modification conditions is decisi...

  • Article
  • Open Access
1 Citations
2,754 Views
11 Pages

Two new cobalt(II) complexes with an unsymmetrical bidentate ligand, 2-(1,4,5,6-tetrahydropyrimidin-2-yl)-6-methoxyphenol (H2mthp), were synthesized and crystallographically characterized. Tetra- and hexa-coordinate mononuclear complexes were selecti...

  • Feature Paper
  • Article
  • Open Access
3 Citations
2,166 Views
9 Pages

In this work, we show magnetic-moment-induced metal–insulator transitions in ThMnXN (X = As, P) and elucidate some of the experimentally observed results obtained by Zhang et al. through a first principles density functional study. Our calculat...

  • Article
  • Open Access
2 Citations
2,662 Views
13 Pages

The Study of Structural Features of N- and O-Derivatives of 4,5-Dihydroxyimidazolidine-2-Thione by NMR Spectroscopy and Quantum Chemical Calculations

  • Liudmila E. Kalichkina,
  • Alexander V. Fateev,
  • Polina K. Krivolapenko,
  • Kristina A. Isakova,
  • Alexey S. Knyazev,
  • Victor S. Malkov,
  • Abdigali A. Bakibaev and
  • Vera P. Tuguldurova

In the present work, the new N-methylol and O-alkyl derivatives of 4,5-dihydroxyimidazolidine-2-thione (DHIT) are synthesized. The effects of N-alkyl, N-phenyl, N-methylol, and O-alkyl substituents of DHIT on the 13C and 1H signals in NMR spectra of...

  • Article
  • Open Access
2 Citations
2,437 Views
12 Pages

Metal complexes with pyridine ligands (py) have not been crystallographically characterized in large numbers, while a large number of 2,2′-bipyridine (bpy) complexes have been structurally characterized. Against this background of scarcity of p...

  • Article
  • Open Access
13 Citations
3,719 Views
11 Pages

Interrelation between the Solid-State Synthesis Conditions and Magnetic Properties of the NiCr2O4 Spinel

  • Mikhail Cherosov,
  • Ruslan Batulin,
  • Airat Kiiamov,
  • Alexey Rogov,
  • Iskander Vakhitov,
  • Damir Gabadullin,
  • Dmitrii Tayurskii and
  • Roman Yusupov

The synthesis of the NiCr2O4 compound with the spinel structure via the high-temperature solid-state reaction leads to different deviations of the cationic composition from the nominal depending on the atmosphere in the furnace chamber. The samples p...

  • Review
  • Open Access
32 Citations
6,177 Views
26 Pages

Magnetic nanocomposites (MNCs) combine the features of magnetic nanoparticles and a second material, which provide distinct physical, chemical, and biological properties. The magnetic core for nanocomposite synthesis is extensively used due to its hi...

  • Article
  • Open Access
4 Citations
2,953 Views
11 Pages

Glassy nanocomposites containing Yb3+/Er3+-doped GdF3 and LiGdF4 nanocrystals have been prepared by controlled crystallization of the xerogel and the structural, up-conversion luminescence, and magnetic properties were analyzed and discussed. Structu...

  • Article
  • Open Access
7 Citations
4,343 Views
14 Pages

Influence of the Preparation Technique on the Magnetic Characteristics of ε-Fe2O3-Based Composites

  • Dmitriy O. Testov,
  • Kamil G. Gareev,
  • Ivan K. Khmelnitskiy,
  • Andrei Kosterov,
  • Leonid Surovitskii and
  • Victor V. Luchinin

ε-Fe2O3 is an iron(III) oxide polymorph attracting an increasing interest due to its unique magnetic properties combining extremely high coercivity and relatively large saturation magnetization. We review existing methods for the ε-Fe...

  • Article
  • Open Access
43 Citations
4,118 Views
15 Pages

Levofloxacin Adsorption onto MWCNTs/CoFe2O4 Nanocomposites: Mechanism, and Modeling Using Non-Linear Kinetics and Isotherm Equations

  • Tariq J. Al-Musawi,
  • Yasir Qasim Almajidi,
  • Ethar M. Al-Essa,
  • Rosario Mireya Romero-Parra,
  • Enas R. Alwaily,
  • Nezamaddin Mengelizadeh,
  • Fatemeh Ganji and
  • Davoud Balarak

In the present work, the adsorption mechanism and capacity of MWCNTs/CoFe2O4 nanocomposite as an adsorbent were investigated. Levofloxacin (LFX), a widely used antibiotic, was selected as a hazardous model contaminant in aqueous solutions. The surfac...

  • Article
  • Open Access
13 Citations
3,698 Views
14 Pages

Evidence of Hysteresis Free Ferromagnetic Nature and Significant Magnetocaloric Parameters in FeNi Binary Alloy

  • Mohit K. Sharma,
  • Akshay Kumar,
  • Kavita Kumari,
  • Su-Jeong Park,
  • Naveen Yadav,
  • Seok-Hwan Huh and
  • Bon-Heun Koo

In this study, our aim is to investigate the structural, magnetic, and magnetocaloric properties of the FeNi binary alloy. The FeNi alloy with Fe65Ni35 composition was prepared by ball milling followed by the annealing and quenching processes. A Riet...

  • Opinion
  • Open Access
4 Citations
4,406 Views
9 Pages

Old Discovery Leading to New Era: Metabolic Imaging of Cancer with Deuterium MRI

  • Hao Ding,
  • Athar Haroon,
  • Simon Wan,
  • Thoralf Niendorf and
  • Sola Adeleke

The understanding of metabolic compartments involved in the survival, growth and invasion of tumours is important for modern cancer research. Deuterium metabolic spectroscopy (DMS) and metabolic imaging (DMI) have been demonstrated as robust, straigh...

  • Article
  • Open Access
5 Citations
2,487 Views
14 Pages

In our work, the kinetics of martensitic transformations and the influence of thermal treatments on martensitic transformations, as well as the related magnetic properties of the Ni49Mn32Ga19 ferromagnetic shape memory melt-spun ribbons, have been in...

  • Article
  • Open Access
3 Citations
2,410 Views
10 Pages

Single-crystalline magnetite (Fe3O4) particles having a size beyond the nanometric range (1 µm to 50 µm) and showing high (close to the bulk value) saturation-specific magnetization (σs = 92 emu/g), were obtained by the hydrothermal...

  • Article
  • Open Access
2 Citations
2,760 Views
11 Pages

The Assembly of Grid-type Lanthanide Cluster

  • Jinsong Li,
  • Fan Zhang,
  • Xuefeng Guo,
  • Dan Liu and
  • Jianfeng Wu

A dicompartmental Schiff base ligand was synthesized and used for the assembly of a lanthanide grid-like complex. Dinuclear Dy2 and tetranuclear Dy4 complexes were isolated from the reaction of the ligand with different dysprosium salt. Single crysta...

  • Article
  • Open Access
7 Citations
2,565 Views
14 Pages

Iron Oxides Nanoparticles as Components of Ferroptosis-Inducing Systems: Screening of Potential Candidates

  • Artur Dzeranov,
  • Lyubov Bondarenko,
  • Denis Pankratov,
  • Mikhail Prokof‘ev,
  • Gulzhian Dzhardimalieva,
  • Sharipa Jorobekova,
  • Nataliya Tropskaya,
  • Ludmila Telegina and
  • Kamila Kydralieva

This study presents an analysis of a set of iron oxides nanoparticles (NPs) (γ-Fe2O3, α-FeOOH, δ-FeOOH, 5Fe2O3·9H2O, and Fe3O4) as potential candidates for ferroptosis therapy in terms of a phase state, magnetic characteristi...

  • Article
  • Open Access
3 Citations
2,375 Views
12 Pages

Effect of Infill Density of the Printed PET-G Structures Containing Iron Oxides on Magnetic Properties

  • Lucie Zárybnická,
  • Martin Marek,
  • Radek Ševčík,
  • Radek Stolín,
  • Jaroslav Pokorný and
  • Jiří Šál

This work aims to characterize printing structures with various infill densities composed of a thermoplastic material containing magnetic particles composed of mainly Iron(III) oxides with regard to their possible processing with the additive technol...

  • Article
  • Open Access
19 Citations
4,681 Views
13 Pages

Research on Modification of Fe3O4 Magnetic Nanoparticles with Two Silane Coupling Agents

  • Hongchao Cui,
  • Jiajia Zhang,
  • Jingjing Lu,
  • Zhenkun Li and
  • Decai Li

As a novel functional nanomaterial, Fe3O4 magnetic nanoparticles (MNPs) modified by different surfactants have attracted and are attracting worldwide interest. In this research, we introduced two different silane coupling agents to modify Fe3O4 MNPs...

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Magnetochemistry - ISSN 2312-7481