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Magnetochemistry, Volume 8, Issue 12

2022 December - 29 articles

Cover Story: [Fe(X-salEen)2]BPh4·DMF complexes, with X = Br (1), Cl (2), and F (3), co-crystallized with N-N-dimethylformamide, 1 in the orthorhombic space group P212121, and the isostructurals 2 and 3 in the monoclinic space group P21/n. The low-spin forms were always predominant, although 2 exhibited a larger proportion of high-spin species according to both the magnetization measurements and the Mössbauer spectra. Density functional theory calculations of molecular models and periodic solids reproduced the structures of the crystal very well. However, only some of them could explain the experimental magnetization curves with easier spin crossover of 2. The role of the solvent seemed to be to glue the cation and the anion, and interactions between neighboring cells were negligible. View this paper
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Articles (29)

  • Article
  • Open Access
3 Citations
1,840 Views
15 Pages

In this study, impacts of using a sinusoidal shape encapsulated phase change material (PCM) packed bed (PB) system on the phase change and thermal performance are analyzed in multi-port vented cavity under a partially active magnetic field during hyb...

  • Article
  • Open Access
22 Citations
3,183 Views
28 Pages

Stability Analysis of Buoyancy Magneto Flow of Hybrid Nanofluid through a Stretchable/Shrinkable Vertical Sheet Induced by a Micropolar Fluid Subject to Nonlinear Heat Sink/Source

  • Umair Khan,
  • Aurang Zaib,
  • Anuar Ishak,
  • Abeer M. Alotaibi,
  • Sayed M. Eldin,
  • Nevzat Akkurt,
  • Iskandar Waini and
  • Javali Kotresh Madhukesh

The utilization of hybrid nanofluids (HNs) to boost heat transfer is a promising area of study, and thus, numerous scientists, researchers, and academics have voiced their admiration and interest in this area. One of the main functions of nanofluids...

  • Feature Paper
  • Review
  • Open Access
2 Citations
2,266 Views
30 Pages

This review is devoted to an analysis of currently known heterometallic molecular magnets based on an orbitally degenerate 5d metalloligand, [ReIV(CN)7]3−. Heptacyanidometallates with a pentagonal bipyramidal structure of the coordination site...

  • Article
  • Open Access
3 Citations
2,375 Views
17 Pages

The complexity of Earth’s structure poses a challenge to the multiscale detection capability of geophysics. In this paper, we present a new wavelet-based three-dimensional inversion method for geomagnetic depth sounding. This method is based on...

  • Article
  • Open Access
80 Citations
3,707 Views
16 Pages

Synthesis and Characterization of Composites with Y-Hexaferrites for Electromagnetic Interference Shielding Applications

  • Sajjad Ahmad Khan,
  • Irshad Ali,
  • Abid Hussain,
  • Hafiz Muhammad Asif Javed,
  • Vitalii A. Turchenko,
  • Alex V. Trukhanov and
  • Sergei V. Trukhanov

The current research is focused on the chemical process and characterization of Co-based Y-type hexaferrite, electrochemically active polypyrrole doped with dodecylbenzene sulphonicacid (PPy-DBSA) and their composites. The microemulsion technique was...

  • Feature Paper
  • Article
  • Open Access
11 Citations
3,566 Views
18 Pages

Bifunctional Magnetite–Gold Nanoparticles for Magneto-Mechanical Actuation and Cancer Cell Destruction

  • Anastasiia S. Garanina,
  • Maria V. Efremova,
  • Alexey E. Machulkin,
  • Evgeny V. Lyubin,
  • Natalia S. Vorobyeva,
  • Oxana A. Zhironkina,
  • Olga S. Strelkova,
  • Igor I. Kireev,
  • Irina B. Alieva and
  • Maxim A. Abakumov
  • + 8 authors

Magnetite–gold dumbbell nanoparticles are essential for biomedical applications due to the presence of two surfaces with different chemical natures and the potential combination of magnetic and plasmonic properties. Here, the remote actuation o...

  • Article
  • Open Access
12 Citations
6,441 Views
17 Pages

Magnetorheological Finishing of Chemically Treated Electroless Nickel Plating

  • Mayank Kumar,
  • Tharra Bhavani,
  • Sunil Rawal and
  • Ajay Sidpara

Electroless nickel plating with a nanofinished surface is used in space mirrors, automobile parts, aircraft components, optical instruments, and electronic equipment. Finishing of these components using conventional finishing techniques is limited du...

  • Article
  • Open Access
7 Citations
2,825 Views
16 Pages

A Sustainable Amine Magnetic Biocomposite Based on Rice Husk–Sugarcane Bagasse Fiber for Lead and Contaminant Adsorption in Aqueous Solution

  • Iryanti Fatyasari Nata,
  • Chairul Irawan,
  • Meilana Dharma Putra,
  • Hesti Wijayanti,
  • Yuniza Shentya Dewi and
  • Yenny Meliana

Biomass is a material that can be potentially used as a natural fiber resource. Rice husk (RH) and sugarcane bagasse (SB), respectively containing 36.6% and 60% cellulose, are fibers that have the potential for biocomposite formation. In this study,...

  • Article
  • Open Access
1 Citations
1,937 Views
12 Pages

An innovative magnetostatic force sensor consisting of a laser source, a tiny cantilever beam, and a small permanent magnet was developed and used for defect inspection in ferromagnetic samples in the present article. The penetrating zone within a fe...

  • Article
  • Open Access
3 Citations
3,009 Views
15 Pages

New tools for cancer diagnosis are being studied since early diagnosis can be crucial for a successful treatment. In this context, the use of NMR probes constitutes an efficient method of diagnosis. In this study, we investigated the use of ciproflox...

  • Article
  • Open Access
6 Citations
2,716 Views
10 Pages

Magnetic Domain Structure of Lu2.1Bi0.9Fe5O12 Epitaxial Films Studied by Magnetic Force Microscopy and Optical Second Harmonic Generation

  • Marina Temiryazeva,
  • Evgeny Mamonov,
  • Anton Maydykovskiy,
  • Alexei Temiryazev and
  • Tatiana Murzina

Magnetic structure of functional magnetic dielectrics is traditionally of high interest. Here, we use the magnetic force microscopy (MFM) and nonlinear-optical probe of second harmonic generation for studies of surface domain structure of monocrystal...

  • Article
  • Open Access
3 Citations
2,246 Views
16 Pages

Microstructure, Critical Behavior and Magnetocaloric Properties of Melt-Spun Ni51.82Mn32.37In15.81

  • Karima Dadda,
  • Safia Alleg,
  • Saida Souilah,
  • Jason Daza,
  • Joan Saurina,
  • Joan-Josep Suñol,
  • Lotfi Bessais and
  • El-Kebir Hlil

Heusler alloy with an atomic composition of Ni51.82Mn32.37In15.81 was prepared by melt spinning from arc-melted ingots. X-ray diffraction, scanning electron microscopy and magnetic measurements were used to study the structural, microstructural and m...

  • Article
  • Open Access
4 Citations
2,760 Views
17 Pages

Biodiesel Production from Macroalgae Oil from Fucus vesiculosus Using Magnetic Catalyst in Unconventional Reactor Assisted by Magnetic Field

  • Euripedes Garcia Silveira Junior,
  • Lilian Fiori Boechat de Souza,
  • Victor Haber Perez,
  • Oselys Rodriguez Justo,
  • Euclésio Simionatto and
  • Lincoln Carlos Silva de Oliveira

A novel magnetic catalyst with hollow cylinder shape based on K2CO3/γ-Al2O3/Sepiolite/CoFe2O4 was prepared to convert macroalgae oil (Fucus vesiculosus) into biodiesel in an unconventional reactor assisted by magnetic field. Catalysts were form...

  • Article
  • Open Access
2 Citations
2,736 Views
11 Pages

The sparking discharge process utilises high voltage to melt and evaporate tips of electrodes to create particles that can be deposited on substrate. In our research, we examine the influence of a magnetic field and nitrogen flow on gold thin-film fo...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,917 Views
12 Pages

Effect of the Preparation Conditions on the Magnetic Coercivity of CoPt Alloy Nanowires

  • Mihai Tibu,
  • Nicoleta Lupu and
  • Oana-Georgiana Dragos-Pinzaru

In this paper, 3 µm length and 200 nm diameter CoPt nanowire arrays (NWs) with different Co contents were prepared by electrodeposition at a controlled potential from an aqueous hexachloroplatinate solution. The synthesis occurred at two differ...

  • Article
  • Open Access
9 Citations
2,567 Views
9 Pages

In this paper, (Tb0.7Lu0.3)2O3 magneto-optical transparent ceramics with different ZrO2 doping levels (0~5 at%) were prepared by hydrogen sintering and sequential HIP technique using ZrO2 as a sintering aid. The effect of ZrO2 doping content on the m...

  • Article
  • Open Access
12 Citations
3,038 Views
15 Pages

Green Synthesis of Unsaturated Fatty Acid Mediated Magnetite Nanoparticles and Their Structural and Magnetic Studies

  • Amlan Kumar Das,
  • Apoorva Fanan,
  • Daoud Ali,
  • Vijendra Singh Solanki,
  • Brijesh Pare,
  • Bader O. Almutairi,
  • Neha Agrawal,
  • Neera Yadav,
  • Vikram Pareek and
  • Virendra Kumar Yadav

The green, cost-effective and sustainable synthesis of nanomaterials has been a key concern of scientists and researchers. In this view, MNPs were prepared using a sapota plant leaf extract and the surface of the magnetite nanoparticles was engineere...

  • Review
  • Open Access
42 Citations
8,366 Views
26 Pages

Magnetic Semiconductors as Materials for Spintronics

  • Andrei Telegin and
  • Yurii Sukhorukov

From the various aspects of spintronics the review highlights the area devoted to the creation of new functional materials based on magnetic semiconductors and demonstrates both the main physical phenomena involved and the technical possibilities of...

  • Review
  • Open Access
21 Citations
7,090 Views
20 Pages

Two-Dimensional Doped Materials

  • Junchi Liu,
  • Bo Li and
  • Qiuqiu Li

The recently intensified research in atomically thick two-dimensional (2D) materials has been motivated by their unique properties and the possibility of updating the future electronic and optoelectronic technologies. Doping can change the band struc...

  • Article
  • Open Access
11 Citations
3,868 Views
19 Pages

Amorphous Carbon Films with Embedded Well-Dispersed Nanodiamonds: Plasmon-Enhanced Analysis and Possible Antimicrobial Applications

  • Oleg Streletskiy,
  • Elena Perevedentseva,
  • Ilya Zavidovskiy,
  • Artashes Karmenyan,
  • Vladimir Sychev,
  • Vera Sadykova,
  • Anastasia Kuvarina and
  • Chia-Liang Cheng

An amorphous carbon film with embedded detonation nanodiamond (DND) particles (a-C:ND) was produced by magnetron sputtering of nanodiamond powder. An Ag film was deposited on the carbon structure by radiofrequency magnetron sputtering. The silver fil...

  • Article
  • Open Access
7 Citations
3,073 Views
8 Pages

With their outstanding mechanical and magnetic characteristics, two-dimensional magnetic materials have attracted wide attentions in the field of nanoelectromechanics and spintronics. By tuning the mechanical resonance with external knobs, such as st...

  • Article
  • Open Access
3 Citations
2,310 Views
11 Pages

Size and Ion-Doping Effects on Magnetic, Optical, and Phonon Properties of CuAlO2 Nanoparticles

  • Iliana Naumova Apostolova,
  • Angel Todorov Apostolov and
  • Julia Mihailova Wesselinowa

The magnetic, optical, and phonon properties of ion-doped CuAlO2 nanoparticles on the Cu or Al site are theoretically investigated. The room temperature ferromagnetism in CuAlO2 nanoparticles can be due to the surface, size, and doping effects. The m...

  • Review
  • Open Access
19 Citations
4,150 Views
14 Pages

Faraday isolators are the inherent components of complex laser systems. The isolation degree is essentially determined by the effects that occur in its magneto-optical element, so the choice of material from which it is made is very important. The pr...

  • Article
  • Open Access
2 Citations
2,589 Views
19 Pages

Mesostructure and Magnetic Properties of SiO2-Co Granular Film on Silicon Substrate

  • Natalia A. Grigoryeva,
  • Victor Ukleev,
  • Alexey A. Vorobiev,
  • Alexander I. Stognij,
  • Nikolay N. Novitskii,
  • Leonid V. Lutsev and
  • Sergey V. Grigoriev

Granular films SiO2(Co) exhibit unusual magnetic and magnetotransport properties which are strongly dependent on the composition of the film and material of a substrate. For example, the injection magnetoresistance (IMR) coefficient reaches a giant (...

  • Article
  • Open Access
6 Citations
2,922 Views
9 Pages

Chiral Dy(III) Fluorescent Single-Molecule Magnet Based on an Achiral Flexible Ligand

  • Min Zeng,
  • Lin Miao,
  • Xue-Ru Wu,
  • Cai-Ming Liu and
  • Hui-Zhong Kou

A novel multi-channel barcode module was developed by using chiral co-crystals which contain field-induced SMM behavior and different emission bands. The chiral co-crystals [Zn(H2L)Dy(DBM)2]4(ClO4)4⋅9CH3OH⋅H2O (1a) and [Zn(H2L)Dy(DBM)2]4(Cl...

  • Article
  • Open Access
8 Citations
2,939 Views
12 Pages

Coercivity and Exchange Bias in Ti-Doped Maghemite Nanoparticles

  • Venkatesha Narayanaswamy,
  • Imaddin A. Al-Omari,
  • Aleksandr S. Kamzin,
  • Hafsa Khurshid,
  • Abbas Khaleel,
  • Bashar Issa and
  • Ihab M. Obaidat

Ti-doped maghemite nanoparticles of average crystallite size 12.9 nm were synthesized using the sol–gel method. The XRD profile mainly showed the presence of maghemite phase with very small phases of TiO2 (rutile and anatase). Magnetization hys...

  • Article
  • Open Access
18 Citations
3,502 Views
10 Pages

Nanoparticles of Co-doped copper ferrite, Cu0.75Co0.25Fe2O4, were successfully synthesized by hydrothermal method. The preparation conditions were optimized to produce small nanoparticles with crystallite size of 20 nm that fall into the single-domai...

  • Article
  • Open Access
3 Citations
3,388 Views
19 Pages

Effect of Metal-Oxide Phase on the Magnetic and Magnetocaloric Properties of La0.7Ca0.3MnO3-MO (MO=CuO, CoO, and NiO) Composite

  • Surendra Dhungana,
  • Jacob Casey,
  • Dipesh Neupane,
  • Arjun K. Pathak,
  • Sunil Karna and
  • Sanjay R. Mishra

The study reports the synthesis and characterization of the magnetic and magnetocaloric effects of metal-oxide (MO) modified La0.7Ca0.3MnO3 perovskites manganite. The powder composite samples, with a nominal composition of (1 − x)La0.7Ca0.3MnO3...

  • Article
  • Open Access
4 Citations
3,263 Views
15 Pages

The Halogen Effect on the Magnetic Behaviour of Dimethylformamide Solvates in [Fe(halide-salEen)2]BPh4

  • Rafaela T. Marques,
  • Frederico F. Martins,
  • Deniz F. Bekiş,
  • Ana I. Vicente,
  • Liliana P. Ferreira,
  • Clara S. B. Gomes,
  • Sónia Barroso,
  • Varun Kumar,
  • Yann Garcia and
  • Paulo N. Martinho
  • + 2 authors

Complexes [Fe(X-salEen)2]BPh4·DMF, with X = Br (1), Cl (2), and F (3), were crystallised from N,N′-dimethylformamide with the aim of understanding the role of a high boiling point N,N′-dimethylformamide solvate in the spin crossove...

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Magnetochemistry - ISSN 2312-7481