Chiral Dy(III) Fluorescent Single-Molecule Magnet Based on an Achiral Flexible Ligand
Abstract
:1. Introduction
2. Results
2.1. Crystal Structures
2.2. Magnetic Properties
2.3. Luminescent Properties
3. Materials and Methods
3.1. Materials
3.2. The Preparation of Complex 1
3.3. Physical Measurements
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Informed Consent Statement
Conflicts of Interest
References
- White, K.A.; Chengelis, D.A.; Gogick, K.A.; Stehman, J.; Rosi, N.L.; Petoud, S. Near-Infrared Luminescent Lanthanide MOF Barcodes. J. Am. Chem. Soc. 2009, 131, 18069–18071. [Google Scholar] [CrossRef]
- Zhang, Y.; Zhang, L.; Deng, R.; Tian, J.; Zong, Y.; Jin, D.; Liu, X. Multicolor barcoding in a single upconversion crystal. J. Am. Chem. Soc. 2014, 136, 4893–4896. [Google Scholar] [CrossRef] [PubMed]
- Lu, Y.; Yan, B. Luminescent lanthanide barcodes based on postsynthetic modified nanoscale metal–organic frameworks. J. Mater. Chem. C 2014, 2, 7411–7416. [Google Scholar] [CrossRef]
- Zhao, Y.; Shum, H.C.; Chen, H.; Adams, L.L.; Gu, Z.; Weitz, D.A. Microfluidic generation of multifunctional quantum dot barcode particles. J. Am. Chem. Soc. 2011, 133, 8790–8793. [Google Scholar] [CrossRef] [PubMed]
- Zhang, F.; Haushalter, R.C.; Haushalter, R.W.; Shi, Y.; Zhang, Y.; Ding, K.; Zhao, D.; Stucky, G.D. Rare-earth upconverting nanobarcodes for multiplexed biological detection. Small 2011, 7, 1972–1976. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Pan, M.; Zhu, Y.X.; Wu, K.; Chen, L.; Hou, Y.J.; Yin, S.Y.; Wang, H.P.; Fan, Y.N.; Su, C.Y. Epitaxial Growth of Hetero-Ln-MOF Hierarchical Single Crystals for Domain- and Orientation-Controlled Multicolor Luminescence 3D Coding Capability. Angew. Chem. Int. Ed. Engl. 2017, 56, 14582–14586. [Google Scholar] [CrossRef] [PubMed]
- Chen, C.; Zhang, P.; Gao, G.; Gao, D.; Yang, Y.; Liu, H.; Wang, Y.; Gong, P.; Cai, L. Near-infrared-emitting two-dimensional codes based on lattice-strained core/(doped) shell quantum dots with long fluorescence lifetime. Adv. Mater. 2014, 26, 6313–6317. [Google Scholar] [CrossRef]
- Shikha, S.; Salafi, T.; Cheng, J.; Zhang, Y. Versatile design and synthesis of nano-barcodes. Chem. Soc. Rev. 2017, 46, 7054–7093. [Google Scholar] [CrossRef] [Green Version]
- Ishii, A.; Miyasaka, T. Direct detection of circular polarized light in helical 1D perovskite-based photodiode. Sci. Adv. 2020, 6, eabd3274. [Google Scholar] [CrossRef]
- Zeng, M.; Ren, A.; Wu, W.; Zhao, Y.; Zhan, C.; Yao, J. Lanthanide MOFs for inducing molecular chirality of achiral stilbazolium with strong circularly polarized luminescence and efficient energy transfer for color tuning. Chem. Sci. 2020, 11, 9154–9161. [Google Scholar] [CrossRef]
- Lu, J.; Guo, M.; Tang, J. Recent Developments in Lanthanide Single-Molecule Magnets. Chem.-Asian J. 2017, 12, 2772–2779. [Google Scholar] [CrossRef] [PubMed]
- Marin, R.; Brunet, G.; Murugesu, M. Shining New Light on Multifunctional Lanthanide Single-Molecule Magnets. Angew. Chem.-Int. Ed. 2020, 60, 1728–1746. [Google Scholar] [CrossRef]
- Meng, Y.-S.; Jiang, S.-D.; Wang, B.-W.; Gao, S. Understanding the Magnetic Anisotropy toward Single-Ion Magnets. Acc. Chem. Res. 2016, 49, 2381–2389. [Google Scholar] [CrossRef] [PubMed]
- Zhu, Z.; Zhao, C.; Feng, T.; Liu, X.; Ying, X.; Li, X.-L.; Zhang, Y.-Q.; Tang, J. Air-Stable Chiral Single-Molecule Magnets with Record Anisotropy Barrier Exceeding 1800 K. J. Am. Chem. Soc. 2021, 143, 10077–10082. [Google Scholar] [CrossRef] [PubMed]
- Chen, Y.-C.; Liu, J.-L.; Ungur, L.; Liu, J.; Li, Q.-W.; Wang, L.-F.; Ni, Z.-P.; Chibotaru, L.F.; Chen, X.-M.; Tong, M.-L. Symmetry-Supported Magnetic Blocking at 20 K in Pentagonal Bipyramidal Dy(III) Single-Ion Magnets. J. Am. Chem. Soc. 2016, 138, 2829–2837. [Google Scholar] [CrossRef] [PubMed]
- Li, Z.-H.; Zhai, Y.-Q.; Chen, W.-P.; Ding, Y.-S.; Zheng, Y.-Z. Air-Stable Hexagonal Bipyramidal Dysprosium(III) Single-Ion Magnets with Nearly Perfect D-6h Local Symmetry. Chem.-A Eur. J. 2019, 25, 16219–16224. [Google Scholar] [CrossRef]
- Yang, Q.Y.; Pan, M.; Wei, S.C.; Li, K.; Du, B.B.; Su, C.Y. Linear Dependence of Photoluminescence in Mixed Ln-MOFs for Color Tunability and Barcode Application. Inorg. Chem. 2015, 54, 5707–5716. [Google Scholar] [CrossRef]
- Zhou, Y.; Yan, B. Ratiometric multiplexed barcodes based on luminescent metal–organic framework films. J. Mater. Chem. C 2015, 3, 8413–8418. [Google Scholar] [CrossRef]
- Gao, M.L.; Wang, W.J.; Liu, L.; Han, Z.B.; Wei, N.; Cao, X.M.; Yuan, D.Q. Microporous Hexanuclear Ln(III) Cluster-Based Metal-Organic Frameworks: Color Tunability for Barcode Application and Selective Removal of Methylene Blue. Inorg. Chem. 2017, 56, 511–517. [Google Scholar] [CrossRef]
- Yao, Y.; Gao, Z.; Lv, Y.; Lin, X.; Liu, Y.; Du, Y.; Hu, F.; Zhao, Y.S. Heteroepitaxial Growth of Multiblock Ln-MOF Microrods for Photonic Barcodes. Angew. Chem.-Int. Ed. 2019, 58, 13803–13807. [Google Scholar] [CrossRef]
- Du, B.B.; Zhu, Y.X.; Pan, M.; Yue, M.Q.; Hou, Y.J.; Wu, K.; Zhang, L.Y.; Chen, L.; Yin, S.Y.; Fan, Y.N.; et al. Direct white-light and a dual-channel barcode module from Pr(III)-MOF crystals. Chem. Commun. (Camb.) 2015, 51, 12533–12536. [Google Scholar] [CrossRef] [PubMed]
- Nguyen, H.Q.; Baxter, B.C.; Brower, K.; Diaz-Botia, C.A.; DeRisi, J.L.; Fordyce, P.M.; Thorn, K.S. Programmable Microfluidic Synthesis of Over One Thousand Uniquely Identifiable Spectral Codes. Adv. Opt. Mater. 2017, 5, 1600548. [Google Scholar] [CrossRef] [Green Version]
- Liu, M.-J.; Yuan, J.; Wang, B.-L.; Wu, S.-T.; Zhang, Y.-Q.; Liu, C.-M.; Kou, H.-Z. Spontaneous Resolution of Chiral Co(III)Dy(III) Single-Molecule Magnet Based on an Achiral Flexible Ligand. Cryst. Growth Des. 2018, 18, 7611–7617. [Google Scholar] [CrossRef]
- Sunatsuki, Y.; Fujita, K.; Maruyama, H.; Suzuki, T.; Ishida, H.; Kojima, M.; Glaser, R. Chiral Crystal Structure of a P212121 Kryptoracemate Iron(II) Complex with an Unsymmetric Azine Ligand and the Observation of Chiral Single Crystal Circular Dichroism. Cryst. Growth Des. 2014, 14, 3692–3695. [Google Scholar] [CrossRef]
- Tshuva, E.Y.; Gendeziuk, N.; Kol, M. Single-step synthesis of salans and substituted salans by Mannich condensation. Tetrahedron Lett. 2001, 42, 6405–6407. [Google Scholar] [CrossRef]
- Zeng, M.; Zhou, Z.-Y.; Wu, X.-R.; Liu, C.-M.; Kou, H.-Z. Assembly of a Heterotrimetallic Zn2Dy2Ir Pentanuclear Complex toward Multifunctional Molecular Materials. Inorg. Chem. 2022, 61, 14275–14281. [Google Scholar] [CrossRef]
- Zeng, M.; Ji, S.-Y.; Wu, X.-R.; Zhang, Y.-Q.; Liu, C.-M.; Kou, H.-Z. Magnetooptical Properties of Lanthanide(III) Metal-Organic Frameworks Based on an Iridium(III) Metalloligand. Inorg. Chem. 2022, 61, 3097–3102. [Google Scholar] [CrossRef]
- Liu, C.-M.; Sun, R.; Hao, X.; Wang, B. Chiral Co-Crystals of (S)- or (R)-1,1′-Binaphthalene-2,2′-diol and Zn2Dy2 Tetranuclear Complexes Behaving as Single-Molecule Magnets. Cryst. Growth Des. 2021, 21, 4346–4353. [Google Scholar] [CrossRef]
- Guo, Y.-N.; Xu, G.-F.; Gamez, P.; Zhao, L.; Lin, S.-Y.; Deng, R.; Tang, J.; Zhang, H.-J. Two-Step Relaxation in a Linear Tetranuclear Dysprosium(III) Aggregate Showing Single-Molecule Magnet Behavior. J. Am. Chem. Soc. 2010, 132, 8538. [Google Scholar] [CrossRef]
- Li, L.; Qin, F.; Zhou, Y.; Zheng, Y.; Miao, J.; Zhang, Z. Photoluminescence and time -resolved -luminescence of CaWO 4: Dy 3+phosphors. J. Lumin. 2020, 224, 117308. [Google Scholar] [CrossRef]
- Zeng, M.; Zhan, C.; Yao, J. Novel bimetallic lanthanide metal-organic frameworks (Ln-MOFs) for colour-tuning through energy-transfer between visible and near-infrared emitting Ln3+ ions. J. Mater. Chem. C 2019, 7, 2751–2757. [Google Scholar] [CrossRef]
- Cui, Y.; Yue, Y.; Qian, G.; Chen, B. Luminescent Functional Metal-Organic Frameworks. Chem. Rev. 2012, 112, 1126–1162. [Google Scholar] [CrossRef] [PubMed]
Complexes | 1a | 1b |
---|---|---|
formula | C225H262Cl4Dy4N8O66Zn4 | C224H257Cl4Dy4N8O64.5Zn4 |
formula weight | 5187.95 | 5146.90 |
T/K | 173(2) | 173(2) |
crystal system | tetragonal | tetragonal |
space group | P43 | P41 |
a, b/Å | 29.7479(2) | 29.7491(2) |
c/Å | 25.3023(3) | 25.3017(2) |
α, β, γ/° | 90 | 90 |
V/Å3 | 22,391.0(4) | 22,392.2(3) |
Z | 4 | 4 |
ρcalc/g⋅cm−3 | 1.539 | 1.527 |
μ/mm−1 | 8.583 | 8.562 |
F(000) | 10,192 | 10,500 |
data/restraints/parameters | 29,484/102/2724 | 34,446/103/2666 |
GOF on F2 | 1.019 | 1.013 |
Rint | 0.0253 | 0.0253 |
R1, wR2 [I ≥ 2σ (I)] | 0.0338, 0.0860 | 0.0420, 0.1092 |
R1, wR2 (all data) | 0.0357, 0.0872 | 0.0442, 0.1111 |
Flack parameter | −0.0025(14) | 0.0012(16) |
CCDC | 2,209,058 | 2,209,059 |
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. |
© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Zeng, M.; Miao, L.; Wu, X.-R.; Liu, C.-M.; Kou, H.-Z. Chiral Dy(III) Fluorescent Single-Molecule Magnet Based on an Achiral Flexible Ligand. Magnetochemistry 2022, 8, 166. https://doi.org/10.3390/magnetochemistry8120166
Zeng M, Miao L, Wu X-R, Liu C-M, Kou H-Z. Chiral Dy(III) Fluorescent Single-Molecule Magnet Based on an Achiral Flexible Ligand. Magnetochemistry. 2022; 8(12):166. https://doi.org/10.3390/magnetochemistry8120166
Chicago/Turabian StyleZeng, Min, Lin Miao, Xue-Ru Wu, Cai-Ming Liu, and Hui-Zhong Kou. 2022. "Chiral Dy(III) Fluorescent Single-Molecule Magnet Based on an Achiral Flexible Ligand" Magnetochemistry 8, no. 12: 166. https://doi.org/10.3390/magnetochemistry8120166