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Separations, Volume 8, Issue 7

2021 July - 17 articles

Cover Story: The development of simple and sensitive methods for the determination of metals is challenging. Herein, we report the development of an on-line sorbent extraction platform coupled with FAAS for trace metal determination. The system utilized a novel sol–gel thiocyanatopropyl functionalized silica sorbent. The thiocyanate functional group has been known to form complexes with d-block metals. The main factors affecting the performance of the on-line system were investigated and optimized. Under optimum conditions, high enhancement factors, as well as good sensitivity, precision and accuracy, were observed. Finally, the proposed method was utilized for the analysis of environmental and biological samples. View This Paper
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Articles (17)

  • Article
  • Open Access
9 Citations
4,155 Views
11 Pages

Separation of Lanthanide Isotopes from Mixed Fission Product Samples

  • Leah M. Arrigo,
  • Jun Jiang,
  • Zachary S. Finch,
  • James M. Bowen,
  • Staci M. Herman,
  • Larry R. Greenwood,
  • Judah I. Friese and
  • Brienne N. Seiner

The measurement of radioactive fission products from nuclear events has important implications for nuclear data production, environmental monitoring, and nuclear forensics. In a previous paper, the authors reported the optimization of an intra-group...

  • Article
  • Open Access
4 Citations
2,986 Views
15 Pages

Experimental Study on Flocculation Effect of Tangential Velocity in a Cone-Plate Clarifier

  • Yulong Zhang,
  • Peikun Liu,
  • Linjing Xiao,
  • Yuekan Zhang,
  • Xinghua Yang and
  • Lanyue Jiang

A large number of particles with small size and light density in mine water are difficult to remove by traditional separation equipment. In order to improve the efficiency of mine water treatment, a cone-plate clarifier is proposed in this paper. The...

  • Article
  • Open Access
47 Citations
8,779 Views
18 Pages

Plastic-waste pyrolysis oils contain large amounts of linear, branched, and di-olefinic compounds. This makes it not obvious to determine the detailed group-type composition in particular to the presence of substantial amounts of N-, S-, and O-contai...

  • Article
  • Open Access
9 Citations
3,495 Views
11 Pages

The geometrical parameters of annular centrifugal contactors (ACCs) have an important influence on the extraction efficiency. The present work used a home-made 25 mm ACC constructed by 3D printing to investigate the effect of five geometrical paramet...

  • Feature Paper
  • Article
  • Open Access
20 Citations
4,389 Views
13 Pages

In this study a simple and sensitive on-line sorbent extraction platform coupled with flame atomic absorption spectrometry for trace metals determination was developed. The system utilized for the first time a novel sol-gel thiocyanatopropyl function...

  • Article
  • Open Access
15 Citations
3,321 Views
11 Pages

This study systematically investigated the oxidative treatment of five selected pesticides, alachlor (ALA), carbendazim (CAR), diuron (DIU), pyrimethanil (PYR), and tebuconazole (TEB), by comparing their relative reactivities as a function of three d...

  • Review
  • Open Access
36 Citations
7,357 Views
32 Pages

Molecularly Imprinted Polymers for Dispersive (Micro)Solid Phase Extraction: A Review

  • G. D. Thilini Madurangika Jayasinghe and
  • Antonio Moreda-Piñeiro

The review describes the development of batch solid phase extraction procedures based on dispersive (micro)solid phase extraction with molecularly imprinted polymers (MIPs) and magnetic MIPs (MMIPs). Advantages and disadvantages of the various MIPs f...

  • Article
  • Open Access
10 Citations
3,876 Views
11 Pages

Chromatographic Analysis of Aflatoxigenic Aspergillus flavus Isolated from Malaysian Sweet Corn

  • Rahim Khan,
  • Farinazleen Mohamad Ghazali,
  • Nor Ainy Mahyudin and
  • Nik Iskandar Putra Samsudin

High-performance liquid chromatography (HPLC) provides a quick and efficient tool for accurately characterizing aflatoxigenic and non-aflatoxigenic isolates of Aspergillus flavus. This method also provides a quantitative analysis of AFs in Aspergillu...

  • Article
  • Open Access
1 Citations
3,324 Views
15 Pages

Targeted Expression of TGFBIp Peptides in Mouse and Human Tissue by MALDI-Mass Spectrometry Imaging

  • Venkatraman Anandalakshmi,
  • Guillaume Hochart,
  • David Bonnel,
  • Jonathan Stauber,
  • Shigeto Shimmura,
  • Rajamani Lakshminarayanan,
  • Konstantin Pervushin and
  • Jodhbir S. Mehta

Stromal corneal dystrophies are a group of hereditary disorders caused by mutations in the TGFBI gene. The mutant TGFBIp is prone to protein aggregation and the mutant protein gets deposited in the cornea, leading to severe visual impairment. The mut...

  • Feature Paper
  • Article
  • Open Access
12 Citations
4,223 Views
13 Pages

Formation of Humic-Like Substances during the Technological Process of Lignohumate® Synthesis as a Function of Time

  • Olga Yakimenko,
  • Andrey Stepanov,
  • Svetlana Patsaeva,
  • Daria Khundzhua,
  • Olesya Osipova and
  • Oleg Gladkov

The composition, structure, and biological activity of humic-like substances (HLS) synthesized in the process of lignosulfonate conversion for the production of the humic product Lignohumate® (LH) were examined. It is shown that during the hydrolytic...

  • Review
  • Open Access
16 Citations
5,271 Views
25 Pages

Emerging Contaminants in Seafront Zones. Environmental Impact and Analytical Approaches

  • José S. Câmara,
  • Sarah Montesdeoca-Esponda,
  • Jorge Freitas,
  • Rayco Guedes-Alonso,
  • Zoraida Sosa-Ferrera and
  • Rosa Perestrelo

Some chemical substances have the potential to enter the coastal and marine environment and cause adverse effects on ecosystems, biodiversity and human health. For a large majority of them, their fate and effects are poorly understood as well as thei...

  • Article
  • Open Access
52 Citations
7,001 Views
18 Pages

Effect of Ultrasound-Assisted Extraction Parameters on Total Polyphenols and Its Antioxidant Activity from Mango Residues (Mangifera indica L. var. Manililla)

  • Anahí J. Borrás-Enríquez,
  • Elizabeth Reyes-Ventura,
  • Socorro J. Villanueva-Rodríguez and
  • Lorena Moreno-Vilet

Manililla is a mango variety whose residues contain bioactive compounds such as polyphenols and flavonoids, with high added value. The use of environmentally friendly extraction technology would be of great relevance; hence, this study aimed to evalu...

  • Article
  • Open Access
3 Citations
4,058 Views
14 Pages

The roots of Salvia miltiorrhiza (Danshen) is a precious herbal medicine used to treat cardiovascular diseases. This study establishes a high-performance liquid chromatography-tandem mass spectrometric (HPLC-MS/MS) method to quantify seven bioactive...

  • Article
  • Open Access
25 Citations
4,876 Views
14 Pages

Rhamnolipid Biosurfactants—Possible Natural Anticancer Agents and Autophagy Inhibitors

  • Severina Semkova,
  • Georgi Antov,
  • Ivan Iliev,
  • Iana Tsoneva,
  • Pavel Lefterov,
  • Nelly Christova,
  • Lilyana Nacheva,
  • Ivanka Stoineva,
  • Lyudmila Kabaivanova and
  • Biliana Nikolova
  • + 1 author

Background/Aim: A number of biologically active substances were proved as an alternative to conventional anticancer medicines. The aim of the study is in vitro investigation of the anticancer activity of mono- and di-Rhamnolipids (RL-1 and RL-2) agai...

  • Feature Paper
  • Review
  • Open Access
53 Citations
10,301 Views
26 Pages

Analytical Methods for Extraction and Identification of Primary and Secondary Metabolites of Apple (Malus domestica) Fruits: A Review

  • Maria Assunta Acquavia,
  • Raffaella Pascale,
  • Luca Foti,
  • Giuseppe Carlucci,
  • Laura Scrano,
  • Giuseppe Martelli,
  • Monica Brienza,
  • Donatella Coviello,
  • Giuliana Bianco and
  • Filomena Lelario

Apples represent a greater proportion of the worldwide fruit supply, due to their availability on the market and to the high number of existing cultivar varieties and apple-based products (fresh fruit, fruit juice, cider and crushed apples). Several...

  • Article
  • Open Access
23 Citations
4,865 Views
12 Pages

Characterization of Quercetin Derivatives in Crossing Combination of Habanero White and Capsicum annuum Peppers and of Anti-Inflammatory and Cytotoxic Activity

  • Maria Assunta Acquavia,
  • Raffaella Pascale,
  • Ilaria Pappalardo,
  • Anna Santarsiero,
  • Giuseppe Martelli and
  • Giuliana Bianco

The overproduction of reactive oxygen species and the exposure of the human body to free radicals contribute to the aetiology of many chronic health problems, such as cardiovascular disease and cancer. Supplementation with natural antioxidants could...

  • Article
  • Open Access
3 Citations
2,948 Views
15 Pages

Characterization of Moravian Wines by Selected Chemical Parameters

  • Jan Javorský,
  • Martin Král,
  • Marek Šnirc,
  • Július Árvay,
  • Bohuslava Tremlová and
  • Dani Dordević

Knowledge of analytical values in wines is essential to ensure product safety and compliance with legislation, and it is also essential to understand the various technologies in wine production. The aim of this work was to evaluate the analytical par...

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Separations - ISSN 2297-8739