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Processes, Volume 13, Issue 9 (September 2025) – 360 articles

Cover Story (view full-size image): Continuous crystallizations hold strong potential for manipulating the solid-state properties of active pharmaceutical ingredients (APIs) in the pharmaceutical industry. In this study, a continuous antisolvent sonocrystallization process was developed to generate microparticles of a poorly water-soluble API, mefenamic acid. This technique provides efficient sonication, enhanced heat removal, and scalability. Key parameters, including sonication intensity, crystallization temperature, and solvent/antisolvent flow rates, were investigated. The mean size of the mefenamic acid particles is in the range of 3 μm with a narrower distribution than the unprocessed sample. SEM analysis showed improved crystal shape, while PXRD, FTIR, and DSC confirmed that crystal structure, spectroscopic features, and thermal behavior were unchanged. View this paper
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49 pages, 7031 KB  
Article
Recent Advances in Green and Low-Carbon Energy Resources: Navigating the Climate-Friendly Microgrids for Decarbonized Power Generation
by Daniel Akinyele and Olakunle Olabode
Processes 2025, 13(9), 3028; https://doi.org/10.3390/pr13093028 - 22 Sep 2025
Viewed by 343
Abstract
The role of green and low-carbon energy (gLE) resources in realizing the envisaged future decarbonized energy generation and supply cannot be overemphasized. The world has witnessed growing attention to the application of green energy (gE) sources such as solar, wind, hydro, geothermal, and [...] Read more.
The role of green and low-carbon energy (gLE) resources in realizing the envisaged future decarbonized energy generation and supply cannot be overemphasized. The world has witnessed growing attention to the application of green energy (gE) sources such as solar, wind, hydro, geothermal, and biomass (energy crops, biogas, biodiesel, etc.). There is also the existence of low-carbon energy (LE) resources such as power-to-X, power-to-fuel, power-to-gas, e-fuel, waste-to-energy, etc., which possess huge potential for delivering sustainable energy, thus facilitating a pathway for achieving the desired environmental sustainability. In addition, the evolution of the cyber-physical power systems and the need for strengthening capacity in advanced energy materials are among the key factors that drive the deployment of gLE technologies around the world. This paper, therefore, presents the recent global developments in gLE resources, including the trends in their deployments for different applications in commercial premises. The study introduces different conceptual technical models and configurations of energy systems; the potential of multi-energy generation in a microgrid (m-grd) based on the gLE resources is also explored using the System Advisor Model (SAM) software. The m-grd is being fueled by solar, wind, and fuel cell resources for supplying a commercial load. The quantity of carbon emissions avoided by the m-grd is evaluated compared to a purely conventional m-grd system. The paper presents the cost of energy and the net present cost of the proposed m-grid; it also discusses the relevance of carbon capture and storage and carbon sequestration technologies. The paper provides deeper insights into the understanding of clean and unconventional energy resources. Full article
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24 pages, 2782 KB  
Article
Optimization of Electricity–Carbon Coordinated Scheduling Process for Virtual Power Plants Based on an Improved Snow Ablation Optimizer Algorithm
by Haiji Wang, Ming Zeng, Xueying Lu, Zhijian Chen and Jiankun Hu
Processes 2025, 13(9), 3027; https://doi.org/10.3390/pr13093027 - 22 Sep 2025
Viewed by 149
Abstract
Given the strong coupling between electricity flow and carbon flow, promoting the low-carbon transformation of the energy sector is a crucial measure to actively responding to climate challenges. As a pivotal hub linking the electricity market with the carbon market, promoting electricity–carbon coordinated [...] Read more.
Given the strong coupling between electricity flow and carbon flow, promoting the low-carbon transformation of the energy sector is a crucial measure to actively responding to climate challenges. As a pivotal hub linking the electricity market with the carbon market, promoting electricity–carbon coordinated scheduling of Virtual Power Plants (VPPs) is of great significance in expediting the energy transition process. Based on the introduction of carbon potential, this manuscript constructs a VPP electricity–carbon coordinated scheduling model that incorporates various typical elements, including renewable energy units and demand response. Furthermore, this paper utilizes Brain Storm Optimization (BSO) to improve the Snow Ablation Optimizer (SAO) algorithm and applies the improved algorithm to solve the model developed in this manuscript. Finally, an analysis was conducted using a small-scale VPP project in eastern China, and the results are the following: Firstly, the SAO improved by BSO demonstrates a significant enhancement in solution efficiency. In particular, for the cases presented in this manuscript, the algorithm’s convergence speed increased by 42.85%. Secondly, under the multi-market conditions and with real-time carbon potential, VPPs will possess greater flexibility in scheduling optimization and stronger incentives to fully explore their emission reduction potential through collaborative electricity–carbon scheduling, thereby improving both economic and environmental performance. However, constrained by factors such as the currently low carbon price level, the extent of improvement in VPPs’ performance under real-time carbon potential, compared to fixed carbon potential, remains relatively limited, with a 1.07% increase in economic benefits and a 2.63% reduction in carbon emissions. Thirdly, an increase in carbon prices can incentivize VPPs to continuously tap into their emission reduction potential, but beyond a certain threshold (120 CNY/t in this case study), the marginal contribution of further carbon price increases to emission reductions will progressively decline. Specifically, for every 20-yuan increase in the carbon price, the carbon emission reduction rate of VPPs drops below 1%. Full article
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21 pages, 7087 KB  
Article
Research on the Characteristics and Patterns of Roof Movement in Large-Height Mining Extraction of Shallow Coal Seams
by Yuping Fu, Zhen Zhao and Kai Ma
Processes 2025, 13(9), 3026; https://doi.org/10.3390/pr13093026 - 22 Sep 2025
Viewed by 112
Abstract
This paper focuses on the issues of roof movement and ground pressure behavior in large-height mining extraction of shallow coal seams. By adopting a combined method of theoretical analysis and physical simulation experiments, it establishes a mechanical model for the rotational subsidence of [...] Read more.
This paper focuses on the issues of roof movement and ground pressure behavior in large-height mining extraction of shallow coal seams. By adopting a combined method of theoretical analysis and physical simulation experiments, it establishes a mechanical model for the rotational subsidence of key blocks and a physical simulation test model to conduct stability analysis on the rotational subsidence of key blocks, thereby revealing the characteristics and laws of roof movement. The findings indicate that the horizontal thrust during the rotational subsidence of key blocks increases non-linearly with the rotation angle, exhibiting a higher growth rate when the block size coefficient is less than 0.5. Two modes of instability—sliding and deformation—are observed for key blocks. To prevent sliding instability, the block size coefficient should be maintained below 0.75; however, sliding instability is likely to occur when the rotation angle exceeds 10°. Conversely, smaller rotation angles and larger block size coefficients reduce the likelihood of deformation instability. The reasonable working resistance of the support decreases with the increase in the rotation angle (it decreases sharply when the rotation angle exceeds 10°) and increases with the increase in the block size coefficient. Physical simulation indicates that roof movement is divided into three stages: immediate roof collapse, stratified fracturing and instability of the basic roof, and periodic fracturing of the basic roof. An increase in mining height accelerates the instability of the immediate roof, enlarges the opening of through-layer fissures, shortens the step distance of mining pressure, and heightens the risk of sudden pressure. The research results provide theoretical guidance for the safe and efficient mining with large mining height in shallow coal seams. Full article
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24 pages, 2965 KB  
Article
Research and Application of Dynamic Monitoring Technology for Fracture Stimulation Optimization in Unconventional Reservoirs of the Sichuan Basin Using the Wide-Field Electromagnetic Method
by Changheng Yu, Wenliang Zhang, Zongquan Liu, Heng Ye and Zhiwen Gu
Processes 2025, 13(9), 3025; https://doi.org/10.3390/pr13093025 - 22 Sep 2025
Viewed by 135
Abstract
This study addresses the key technical challenges in monitoring hydraulic fracturing within unconventional reservoirs through an innovative wide-field electromagnetic (WEM) monitoring technique. The method employs a 5A AC-excited wellbore-fracturing fluid system to establish a conductor antenna effect, coupled with a surface electrode array [...] Read more.
This study addresses the key technical challenges in monitoring hydraulic fracturing within unconventional reservoirs through an innovative wide-field electromagnetic (WEM) monitoring technique. The method employs a 5A AC-excited wellbore-fracturing fluid system to establish a conductor antenna effect, coupled with a surface electrode array (100–250 m offset) to detect millivolt-level time-lapse potential anomalies, enabling real-time dynamic monitoring of 142 fracturing stages. A line current source integral model was developed to achieve quantitative fracture network inversion with less than 12% error, attaining 10 m spatial resolution and dynamic updates every 10 min (80% faster than conventional methods). Optimal engineering parameters were identified, including fluid intensity ranges of 25–30 m3/m for tight sandstone and 30–35 m3/m for shale, with particulate diverters achieving 93.1% diversion efficiency (significantly outperforming chemical diverters at 35%). Application in deep reservoirs maintained signal attenuation rates below 5% per kilometer. Theoretically, a nonlinear relationship model between fluid intensity and stimulated area was established, while practical implementation through real-time adjustments in 142 stages enhanced single-well production by 15–20% and reduced diverter costs, advancing the paradigm shift from empirical to scientific fracturing in unconventional reservoir development. Full article
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32 pages, 2931 KB  
Article
A Study on Combustion Parameters and Exhaust Characteristics in a Diesel Engine Using Alternative Fuels at Different SOI and GPP
by Mustafa Vargün, Ilker Turgut Yılmaz, Ahmet Necati Özsezen and Cenk Sayın
Processes 2025, 13(9), 3024; https://doi.org/10.3390/pr13093024 - 22 Sep 2025
Viewed by 140
Abstract
To encourage the use of alternative fuels while limiting the use of fossil fuels, researchers have focused on using more environmentally friendly fuels. Furthermore, the goal is to improve engine performance to increase energy efficiency. A four-stroke, single-cylinder, diesel engine with a common [...] Read more.
To encourage the use of alternative fuels while limiting the use of fossil fuels, researchers have focused on using more environmentally friendly fuels. Furthermore, the goal is to improve engine performance to increase energy efficiency. A four-stroke, single-cylinder, diesel engine with a common rail fuel injection system runs with diesel, biodiesel, and biodiesel–alcohol fuel blends. The tests were performed using a constant engine speed of 2000 rpm and three different gas pedal positions (20%, 50% and 80%). It was found that maximum cylinder gas pressure increased in all test fuels with increased gas pedal position (GPP) and advanced injection start time. In general, the maximum heat release rate increased in blended fuels compared to diesel fuel. In addition, it was seen that advanced injection timings caused an increase in ignition delay in all fuel types. In the same test conditions, it was observed that biodiesel–alcohol fuel blends caused an increase in ignition delay by more than 10% compared to diesel fuel (D100), while shortening combustion duration (CD) by more than 10%. A decreasing trend in CO and HC emissions was observed in the use of biodiesel fuel compared to diesel fuel. With the use of biodiesel–alcohol fuel blends, CO2 emissions tend to decrease. Advanced injection timings caused high NO emissions. Full article
(This article belongs to the Section Energy Systems)
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17 pages, 2628 KB  
Article
Impact of Frying and Storage on Sensory, Cognitive, and Consumer Perception of Chayote Chips Using Static and Dynamic Sensometric Techniques
by Adán Cabal-Prieto, Ana Laura Piña-Martínez, Lucía Sánchez-Arellano, Lorena Guadalupe Ramón-Canul, Víctor Manuel Herrera-Morales, Rosa Isela Castillo-Zamudio, Galdy Hernández-Zárate, Erika María Gasperín-García, Susana Isabel Castillo-Martinez, Alejandro Llaguno-Aguiñaga, José Manuel Sánchez-Orea and Oliver Salas-Valdez
Processes 2025, 13(9), 3023; https://doi.org/10.3390/pr13093023 - 22 Sep 2025
Viewed by 243
Abstract
The objective of this research was to apply static and dynamic sensometric techniques to determine the impact of processing factors (dehydration time, frying exposure time) and storage duration on the sensory and cognitive characteristics, as well as consumer preference, of chayote chips. A [...] Read more.
The objective of this research was to apply static and dynamic sensometric techniques to determine the impact of processing factors (dehydration time, frying exposure time) and storage duration on the sensory and cognitive characteristics, as well as consumer preference, of chayote chips. A total of 18 types of chips were prepared (using a combination of three frying temperatures [140, 150, 160 °C], two exposure times [5 and 10 s], and three periods of storage [0, 30, and 60 days]). A panel of 100 consumers was formed to evaluate sensory and cognitive attributes (emotions and memories) as well as overall liking, using static techniques such as Rate-All-That-Apply (RATA), Check-All-That-Apply (CATA), and a hedonic scale. Finally, the temporal dominance of sensations (TDS) dynamic technique was used to study the behavior of chips with higher levels of preference. The results of the sensory techniques indicated that the storage day factor influenced the sensory results. The samples prepared on the same day were perceived with high intensities of typical attributes of this type of food (bitter-BT, Fried-A, Sweet-A, Potato-A, Toasted-A, Chayote-A, Potato-F, Crunchy, Chayote-F, and Sweet-BT) while evoking positive emotions and memories in consumers (active, enthusiastic, free, good, good nature, happy, interested, satisfied, traditional food, family, summer, party, and mild weather). In terms of preference, consumers selected the chip samples with 0 days of storage. The TDS curves determined that the dominant attributes of the chayote chips with 0 days of storage were chayote flavor, sweet, and fried (with a dominance t = 5–20 s). Regarding the cognitive aspect, these chayote chips evoke positive dominant emotions (good, satisfied, and happy from t = 8–20 s) as well as dominant positive memories of childhood (t = 9–20 s), traditional food (t = 11–20 s), and friendship (t = 11–20 s). Full article
(This article belongs to the Special Issue Applications of Ultrasound and Other Technologies in Food Processing)
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19 pages, 3367 KB  
Article
Assessment of Karacadağ Basalt as a Sustainable Material for Eco-Friendly Road Infrastructure
by Muhammed Enes Türk and Mehmet Hayrullah Akyıldız
Processes 2025, 13(9), 3022; https://doi.org/10.3390/pr13093022 - 22 Sep 2025
Viewed by 192
Abstract
Road construction has historically played a pivotal role in infrastructure development, addressing society’s growing mobility needs. Selecting sub-base and base layer aggregates requires materials that are mechanically durable, compliant with engineering standards, cost-effective, and sustainable. Locally sourcing aggregates enhances economic efficiency while reducing [...] Read more.
Road construction has historically played a pivotal role in infrastructure development, addressing society’s growing mobility needs. Selecting sub-base and base layer aggregates requires materials that are mechanically durable, compliant with engineering standards, cost-effective, and sustainable. Locally sourcing aggregates enhances economic efficiency while reducing the environmental impact. In Southeastern Anatolia, particularly in Diyarbakır, extensive investments in roads, highways, and high-speed rail have increased the demand for high-quality aggregates. Karacadağ basalt, a locally abundant volcanic rock, offers a promising alternative. Its use not only reduces raw material costs but also aids in rehabilitating surface agricultural lands, supporting sustainable urban development and resource conservation. This study assesses the suitability of Karacadağ basalt as a sub-base and base material for highway construction. Two mixtures, namely PMT (Primary Mixture Type) and PMAT (Primary Mixture Alternative Type), were prepared and tested by the Ninth Regional Directorate of Highways using standardized methods including sieve analysis, methylene blue index, Los Angeles abrasion, Weather Resistance, and California Bearing Ratio (CBR) tests. Results indicate that Karacadağ basalt meets all relevant Turkish Highways Technical Specifications. These findings highlight the material’s potential as a sustainable, locally sourced aggregate for infrastructure applications, while suggesting that further testing across diverse quarry sites could enhance reliability and promote wider adoption. Full article
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23 pages, 10074 KB  
Article
Research on Drillability Prediction of Shale Horizontal Wells Based on Nonlinear Regression and Intelligent Optimization Algorithm
by Yanbin Zang, Qiang Wang, Wei Wang, Hongning Zhang, Kanhua Su, Heng Wang, Mingzhong Li, Wenyu Song and Meng Li
Processes 2025, 13(9), 3021; https://doi.org/10.3390/pr13093021 - 22 Sep 2025
Viewed by 213
Abstract
Shale oil and gas reservoirs are characterized by low porosity and low permeability. The development of ultra-long horizontal wells can significantly increase reservoir contact area and enhance single-well production. Shale formations exhibit distinct bedding structures, high formation pressure, high rock hardness, and strong [...] Read more.
Shale oil and gas reservoirs are characterized by low porosity and low permeability. The development of ultra-long horizontal wells can significantly increase reservoir contact area and enhance single-well production. Shale formations exhibit distinct bedding structures, high formation pressure, high rock hardness, and strong anisotropy. These characteristics result in poor drillability, slow drilling rates, and high costs when drilling horizontally, severely restricting efficient development. Therefore, accurately predicting the drillability of shale gas wells has become a major challenge. Currently, most scholars rely on a single parameter to predict drillability, which overlooks the coupled effects of multiple factors and reduces prediction accuracy. To address this issue, this study employs drillability experiments, mineral composition analysis, positional analysis, and acoustic transit-time tests to evaluate the effects of mineral composition, acoustic transit time, bottom-hole confining pressure, and formation drilling angle on the drillability of horizontal well reservoirs, innovatively integrating multiple parameters to construct a nonlinear model and introducing three intelligent optimization algorithms (PSO, AOA-GA, and EBPSO) for the first time to improve prediction accuracy, thus breaking through the limitations of traditional single-parameter prediction. Based on these findings, a nonlinear regression prediction model integrating multiple parameters is developed and validated using field data. To further enhance prediction accuracy, the model is optimized using three intelligent optimization algorithms: PSO, AOA-GA, and EBPSO. The results indicate that the EBPSO algorithm performs the best, followed by AOA-GA, while the PSO algorithm shows the lowest performance. Furthermore, the model is applied to predict the drillability of Well D4, and the results exhibit a high degree of agreement with actual measurements, confirming the model’s effectiveness. The findings support optimization of drilling parameters and bit selection in shale oil and gas reservoirs, thereby improving drilling efficiency and mechanical penetration rates. Full article
(This article belongs to the Section Process Control and Monitoring)
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16 pages, 4246 KB  
Article
Powdered Kombucha Flavored with Fruit By-Products: A Sustainable Functional Innovation
by Maria de Fátima Dantas Linhares, Thatyane Vidal Fonteles, Lorena Silva de Oliveira, Samira Barros de Souza, Emilio de Castro Miguel, Fabiano André Narciso Fernandes and Sueli Rodrigues
Processes 2025, 13(9), 3020; https://doi.org/10.3390/pr13093020 - 22 Sep 2025
Viewed by 246
Abstract
Kombucha is a fermented beverage usually commercialized in liquid form. This study developed a powdered kombucha, flavored with grape (GKP) and mango (MKP) peel extracts—derived from fruit processing by-products—through spray drying with 20% (w/v) maltodextrin as a carrier. The [...] Read more.
Kombucha is a fermented beverage usually commercialized in liquid form. This study developed a powdered kombucha, flavored with grape (GKP) and mango (MKP) peel extracts—derived from fruit processing by-products—through spray drying with 20% (w/v) maltodextrin as a carrier. The spray drying conditions were set to 160 °C inlet temperature and 0.5 L/h feed flow, yielding a maximum powder recovery of 34% for GKP. All powders presented moisture contents below 5%, with values of 4.2% for KP and GKP and 4.02% for MKP, ensuring microbiological safety and long-term stability. Water activity (aw) was also significantly lower in MKP (0.283) compared to KP and GKP (both 0.317). After spray drying, GKP retained up to 93% of TPC, while MKP retained 87%, and KP 82%. Morphological analysis by Scanning Electronic Microscopy (SEM) showed that flavored powders, especially GKP, presented spherical particles with fewer surface defects. Powder flow test showed that MKP presented the best flowability (flow index If = 2.55) compared to GKP (If = 1.71) and KP (If = 1.64 ± 0.02). The results demonstrate that incorporating fruit residues into kombucha and applying spray drying improves the functional and technological properties of this product, with potential applications in functional food formulations and dietary supplements. Full article
(This article belongs to the Section Food Process Engineering)
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2 pages, 132 KB  
Retraction
RETRACTED: Shareef et al. Gastroprophylactic Effects of p-Cymene in Ethanol-Induced Gastric Ulcer in Rats. Processes 2022, 10, 1314
by Suhayla H. Shareef, Morteta H. Al-Medhtiy, Ibrahim Abdel Aziz Ibrahim, Abdullah R. Alzahrani, Ahmed Aj. Jabbar, Yaseen Galali, Nabaz Fisal Shakir Agha, Peshawa Y. Aziz, Muthanna A. Thabit, Derin N. F. Agha, Nur Ain Salehen, Zeena M. Ameen and Mahmood A. Abdulla
Processes 2025, 13(9), 3019; https://doi.org/10.3390/pr13093019 - 22 Sep 2025
Viewed by 138
Abstract
The journal Processes retracts the article “Gastroprophylactic Effects of p-Cymene in Ethanol-Induced Gastric Ulcer in Rats” [...] Full article
(This article belongs to the Special Issue Bioactive Compounds from Natural Plants)
20 pages, 2185 KB  
Article
Fermentation Kinetics Beyond Viability: A Fitness-Based Framework for Microbial Modeling
by Pablo Javier Ruarte, María Carla Groff, María Nadia Pantano, Silvia Cristina Vergara, María José Leiva Alaniz, María Victoria Mestre, Yolanda Paola Maturano and Gustavo Juan Eduardo Scaglia
Processes 2025, 13(9), 3018; https://doi.org/10.3390/pr13093018 - 21 Sep 2025
Viewed by 248
Abstract
Traditional fermentation models often oversimplify kinetics by treating microbial populations as physiologically homogeneous. To address this, we introduce a novel framework that explicitly incorporates cellular fitness by distinguishing the metabolically active subpopulation (“productive cells”) responsible for biosynthesis. This approach integrates established growth models [...] Read more.
Traditional fermentation models often oversimplify kinetics by treating microbial populations as physiologically homogeneous. To address this, we introduce a novel framework that explicitly incorporates cellular fitness by distinguishing the metabolically active subpopulation (“productive cells”) responsible for biosynthesis. This approach integrates established growth models (First Order Plus Dead Time and Logistic) with a modified Luedeking–Piret model (MALP), which introduces a new differential equation to dynamically quantify productive cells. This modeling study relies exclusively on experimental data available in the literature; no new experimental work was conducted. Validated against four diverse fermentation systems from published datasets, the MALP model demonstrated superior predictive accuracy, achieving coefficients of determination (R2 > 0.97) for metabolite kinetics. Sensitivity analysis identified time-delay and maintenance-associated parameters as dominant factors governing system behavior. The key contribution of this work is a mechanistic equation that universally captures the real-world dynamics of metabolite production, providing a more realistic and robust framework for modeling heterogeneous bioprocesses. Full article
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22 pages, 5246 KB  
Article
Improving Health and Safety in Welding Through Remote Human–Robot Collaboration
by Shahram Sheikhi, Sharath P. Subadra, Robert Langer, Lucas Christoph Ebel, Eduard Mayer, Patrick Zuther and Jochen Maaß
Processes 2025, 13(9), 3017; https://doi.org/10.3390/pr13093017 - 21 Sep 2025
Viewed by 317
Abstract
Welding is an essential process across various industries; however, it exposes workers to dangerous fumes, extreme heat and physical stress, which pose considerable health and safety hazards. To tackle these issues, this article introduces the creation of a remote-controlled human–robot welding system aimed [...] Read more.
Welding is an essential process across various industries; however, it exposes workers to dangerous fumes, extreme heat and physical stress, which pose considerable health and safety hazards. To tackle these issues, this article introduces the creation of a remote-controlled human–robot welding system aimed at safeguarding workers while ensuring the quality of the welds. The system monitors a welder’s torch movements through a stereoscopic sensor and accurately reproduces them with a robotic arm, facilitating real-time remote welding. Operated by a student, it effectively welded standardized sheet metals in overhead positions while adhering to critical quality standards. The weld geometry met ISO 5817 requirements, tensile strength surpassed the base material specifications, and bending and hardness assessments verified the durability and integrity of the welds. When utilized in hazardous settings, the system showcases its capability to produce high-quality welds while significantly enhancing worker safety, underscoring its potential for real-world industrial applications. Full article
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11 pages, 2010 KB  
Article
Technical Analysis of Ironmaking in Benxi Region During the Ming Dynasty
by Dongying Zhao and Maofa Jiang
Processes 2025, 13(9), 3016; https://doi.org/10.3390/pr13093016 - 21 Sep 2025
Viewed by 228
Abstract
During the development of metallurgical technology in the feudal period, the main ironmaking technology in the Benxi region was the crucible, reaching its peak period in the Ming Dynasty. By studying the Wangguan ironmaking site in Benxi, the historical details of the Ming [...] Read more.
During the development of metallurgical technology in the feudal period, the main ironmaking technology in the Benxi region was the crucible, reaching its peak period in the Ming Dynasty. By studying the Wangguan ironmaking site in Benxi, the historical details of the Ming Dynasty ironmaking process in the region were investigated, and a technical analysis was carried out. The results show that this historical site was the location of the Hundred-Household Iron Yard in the northeastern region during the Ming Dynasty. The unearthed slag, iron, and crucible samples indicate that a relatively complete ironmaking process chain had been formed at this time. The raw material used for the crucibles was high-alumina clay, which has been widely distributed in Benxi, Liaoning, China, since ancient times. The refractoriness of the crucibles exceeded 1700 °C, and the molar ratio of SiO2 to Al2O3 was close to the upper limit for the optimal formation of mullite and thermal shock resistance. Slag was produced from a typical high-silica, high-alumina aluminosilicate system, and no fluxes, such as limestone and dolomite, were added during the smelting process. Moreover, coal resources have been widely used in ironmaking activities in the Benxi region at least since the Ming Dynasty, and craftsmen at that time had already mastered the technology of using coke as fuel and reductant to control the sulfur content in pig iron. Full article
(This article belongs to the Section Chemical Processes and Systems)
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14 pages, 2652 KB  
Article
Design and Study of a New Rotary Jet Wellbore Washing Device
by Shupei Li, Zhongrui Ji, Qi Feng, Shuangchun Yang and Xiuli Sun
Processes 2025, 13(9), 3015; https://doi.org/10.3390/pr13093015 - 21 Sep 2025
Viewed by 151
Abstract
Wellbore washing technology is a basic operation in wellbore maintenance. Problems such as low automation levels, long processing times, the fact that it is easy to cause downhole falling, and cleaning blind areas greatly affect the use and maintenance of traditional cleaning equipment. [...] Read more.
Wellbore washing technology is a basic operation in wellbore maintenance. Problems such as low automation levels, long processing times, the fact that it is easy to cause downhole falling, and cleaning blind areas greatly affect the use and maintenance of traditional cleaning equipment. These problems usually come from design defects such as a complicated installation process, a lack of an anti-impact structure, and a fixed jet direction. To address the aforementioned issues, this paper proposes an efficient and integrated rapid-disassembly and -assembly automatic filtration rotary jet cleaning device. The device is divided into two main units and further subdivided into four modules. The quick-assembly unit comprises an elastic connection module and a downstroke quick-assembly module, which can automatically compensate for deviations in equipment position during the installation process, ensuring the reliability of the installation process and the sealing of the equipment and facilitating the rapid connection and separation of the tool string. The wellbore cleaning unit includes a hydraulic rotary washing module and a rotary filtration storage module. The wellbore is jet-flushed by hydraulic drive, and the solid particles are separated and filtered during the cleaning fluid circulation process to realize the purification and reuse of the cleaning fluid. The device reduces the installation operation time and labor cost, improves the reliability of equipment in the well, improves the flushing coverage area and the cleaning efficiency, realizes the reuse of the cleaning liquid in the wellbore, reduces the energy consumption of the flowback treatment, and comprehensively improves the cleaning efficiency and the energy utilization efficiency. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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16 pages, 10507 KB  
Article
Displacement Mechanism of Sequential Droplets on a Wetting Confinement
by Wenbin Li, Jie Hu and Renxin Liu
Processes 2025, 13(9), 3014; https://doi.org/10.3390/pr13093014 - 21 Sep 2025
Viewed by 113
Abstract
The stability and uniformity of a liquid line formed by the sequential deposition of droplets are essential to the quality of products in many industry applications. In this work, a numerical model based on the front tracking method (FTM) is developed to investigate [...] Read more.
The stability and uniformity of a liquid line formed by the sequential deposition of droplets are essential to the quality of products in many industry applications. In this work, a numerical model based on the front tracking method (FTM) is developed to investigate the displacement dynamics of sequential droplets on wetting confinement. We systematically examine the impact of wetting conditions and confinement width on the spreading length, morphology, and confined angle for a droplet. In addition, an analytical model is derived to predict the droplet displacement spacing for a uniform line. The analytical results align well with the numerical results, and the sequential droplets displaced with the predicted space achieve the minimum cross-section error and exhibit enhanced uniformity. Our numerical and analytical studies of droplet displacement within wetting confinement provide fundamental insights and a predictive framework for enhancing the uniformity and stability of liquid lines in precision manufacturing processes. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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17 pages, 3940 KB  
Article
Research on the Prediction of Liquid Injection Volume and Leaching Rate for In Situ Leaching Uranium Mining Using the CNN–LSTM–LightGBM Model
by Zhifeng Liu, Zirong Jin, Yipeng Zhou, Zhenhua Wei and Huanyu Zhang
Processes 2025, 13(9), 3013; https://doi.org/10.3390/pr13093013 - 21 Sep 2025
Viewed by 177
Abstract
In traditional in situ leaching (ISL) uranium mining, the injection volume depends on technicians’ on-site experience. Therefore, applying artificial intelligence technologies such as machine learning to analyze the relationship between injection volume and leaching rate in ISL uranium mining, thereby reducing human factor [...] Read more.
In traditional in situ leaching (ISL) uranium mining, the injection volume depends on technicians’ on-site experience. Therefore, applying artificial intelligence technologies such as machine learning to analyze the relationship between injection volume and leaching rate in ISL uranium mining, thereby reducing human factor interference, holds significant guiding importance for production process control. This study proposes a novel uranium leaching rate prediction method based on a CNN–LSTM–LightGBM fusion model integrated with an attention mechanism. Ablation experiments demonstrate that the proposed fusion model outperforms its component models across three key metrics: Mean Absolute Error (MAE), Mean Absolute Percentage Error (MAPE), and Root Mean Square Error (RMSE). Furthermore, comparative experiments reveal that this fusion model achieves superior performance on MAE, MAPE, and RMSE metrics compared to six extensively utilized machine learning methods, including Multi-Layer Perceptron, Support Vector Regression, and K-Nearest Neighbors. Specifically, the model achieves an MAE of 0.085%, an MAPE of 0.833%, and an RMSE of 0.201%. This attention-enhanced fusion model provides technical support for production control in ISL uranium mining and offers valuable references for informatization and intelligentization research in uranium mining operations. Full article
(This article belongs to the Section AI-Enabled Process Engineering)
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17 pages, 3914 KB  
Article
Adaptive Structured Latent Space Learning via Component-Aware Triplet Convolutional Autoencoder for Fault Diagnosis in Ship Oil Purifiers
by Sun Geu Chae, Gwang Ho Yun, Jae Cheul Park and Hwa Sup Jang
Processes 2025, 13(9), 3012; https://doi.org/10.3390/pr13093012 - 21 Sep 2025
Viewed by 210
Abstract
Timely and accurate fault diagnosis of ship oil purifiers is essential for maintaining the operational reliability of a degree-4 maritime autonomous surface ship (MASS). Conventional approaches rely on manual feature engineering or simple machine learning classifiers, limiting their robustness in dynamic maritime environments. [...] Read more.
Timely and accurate fault diagnosis of ship oil purifiers is essential for maintaining the operational reliability of a degree-4 maritime autonomous surface ship (MASS). Conventional approaches rely on manual feature engineering or simple machine learning classifiers, limiting their robustness in dynamic maritime environments. This study proposes an adaptive latent space learning framework that couples a two-dimensional convolutional autoencoder (2D-CAE) with a component-aware triplet-loss regularizer. The loss term structures the latent space to reflect both the fault severity progression and component-specific distinctions, enabling severity-proportional distances among a latent vector learned directly from vibration signals even in a limited data environment. Using data collected on a dedicated ship oil purifier test bed, the method yields a latent vector that encodes the fault severity and physical provenance, enhancing the interpretability and diagnostic accuracy. Experiments demonstrate enhanced performance over state-of-the-art deep models, while offering clear insight into fault evolution and inter-component dependencies. The framework thus advances intelligent, condition-based maintenance for autonomous maritime systems. Full article
(This article belongs to the Section Automation Control Systems)
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27 pages, 6552 KB  
Article
Multi-Objective Path Planning for Warehouse Inspection of Mobile Robots Considering Power Limitations and Multiple Charging Points
by Jinming Zhang, Shuli Jin, Wenshuo Li, Shanghe Li, Jiaming Guo and Xiaoyong Gao
Processes 2025, 13(9), 3011; https://doi.org/10.3390/pr13093011 - 21 Sep 2025
Viewed by 224
Abstract
In large-scale warehouses, mobile robots often face energy shortages during inspection tasks, necessitating multiple charging points. Considering battery limits and multiple charging points makes path planning challenging. This paper presents a two-level solution: (i) local path planning via improved B-RRT* (adaptive Gaussian sampling [...] Read more.
In large-scale warehouses, mobile robots often face energy shortages during inspection tasks, necessitating multiple charging points. Considering battery limits and multiple charging points makes path planning challenging. This paper presents a two-level solution: (i) local path planning via improved B-RRT* (adaptive Gaussian sampling + dynamic goal bias) to build a path-cost matrix, and (ii) global inspection and charging scheduling under multi-charging-point constraints. We evaluate planning time, total path length (as an energy proxy), and the number of sampling points. Experimental results demonstrate that the improved B-RRT* algorithm achieves an average reduction of 10–15% in path length, 20–30% in computation time, and 15–40% in the number of sampling points compared to the initial B-RRT* and RRT* algorithms across various warehouse environments. For global planning with up to 60 inspection targets and 3–5 charging points, a feasible charging schedule is obtained within 150–360 s on a standard desktop (Ryzen 7 5800H, 16 GB RAM), demonstrating strong practicality and scalability. Full article
(This article belongs to the Section Process Control and Monitoring)
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17 pages, 2065 KB  
Article
Enhancing Injection Molding Process by Implementing Cavity Pressure Sensors and an Iterative Learning Control (ILC) Methodology
by Diana Angélica García-Sánchez, Jan Mayén Chaires, Hugo Arcos-Gutiérrez, Isaías E. Garduño, Maria Guadalupe Navarro-Rojero, Adriana Gallegos-Melgar, José Antonio Betancourt-Cantera, Maricruz Hernández-Hernández and Victor Hugo Mercado-Lemus
Processes 2025, 13(9), 3010; https://doi.org/10.3390/pr13093010 - 21 Sep 2025
Viewed by 231
Abstract
Plastic injection molding is a widely used manufacturing process for producing plastic components. However, achieving optimal process stability and part quality remains a persistent challenge due to limited real-time feedback during production. The main objective of this study is to present a method [...] Read more.
Plastic injection molding is a widely used manufacturing process for producing plastic components. However, achieving optimal process stability and part quality remains a persistent challenge due to limited real-time feedback during production. The main objective of this study is to present a method to overcome this limitation by integrating in-mold cavity pressure sensors with an Iterative Learning Control (ILC) strategy to optimize key processing parameters autonomously. The ILC methodology established a closed-loop system; over successive production cycles, cavity pressure profiles were analyzed to automatically adjust the holding pressure, holding time, and switchover point. Each iteration refined the parameters based on sensor data, creating a learning-based optimization loop that accelerated the convergence to optimal settings. The methodology was validated by producing an automotive plastic component. The results demonstrate a 100% success rate in correcting ten critical dimensional errors, fulfilling all part tolerances. Additionally, the overall cycle time decreased by 8%, from 55.0 to 50.6 s. Other findings included updates to key process molding parameters, such as reducing holding pressure from 250 to 230 bar and holding time from 18 to 12 s, as well as increasing the switchover point from 41 to 72 mm. This research confirms that combining real-time cavity pressure monitoring with ILC offers a strong, data-driven framework for significantly improving quality, efficiency, and process stability in injection molding. Full article
(This article belongs to the Section Process Control and Monitoring)
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15 pages, 1401 KB  
Article
Kinetics of Luteolin Extraction from Peanut Shells and Reseda luteola for Potential Applications as a Biofunctional Ingredient
by Efstratios Episkopou, Dimitrios Tsimogiannis, Maria Giannakourou and Petros Taoukis
Processes 2025, 13(9), 3009; https://doi.org/10.3390/pr13093009 - 21 Sep 2025
Viewed by 217
Abstract
This study investigates the extraction kinetics of luteolin, a bioactive flavonoid with recognized antioxidant and health-promoting properties, from the aerial parts of Reseda luteola (dyer’s weld), with emphasis on its industrial potential. A comparative analysis with peanut shells (Arachis hypogea) identified [...] Read more.
This study investigates the extraction kinetics of luteolin, a bioactive flavonoid with recognized antioxidant and health-promoting properties, from the aerial parts of Reseda luteola (dyer’s weld), with emphasis on its industrial potential. A comparative analysis with peanut shells (Arachis hypogea) identified R. luteola as a superior source, containing 14 ± 3 mg of LUT/g of material, approximately eight times higher than the amount in peanut shells. Luteolin occurred predominantly as luteolin-7-O-glycoside (57%) and the aglycone (35%). Methanolic semi-batch extraction at 25 °C yielded 9.6 mg LUT/g (70%) within 60 min at a solid-to-liquid ratio of 1:9, demonstrating significantly greater solvent efficiency than conventional Soxhlet or maceration techniques. Kinetic modeling, based on Fick’s second law, revealed a biphasic process with a low rate constant ratio (3:1) between the two stages, indicating the need for process optimization. These results establish R. luteola as a cost-effective and sustainable source of luteolin for dietary supplements and functional foods, while indicating the need to explore alternative solvents and advanced extraction methods to further optimize yield and efficiency. Full article
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16 pages, 2715 KB  
Article
Hydrate Formation and Mitigation Methods Under Multiple Operational Conditions in Deepwater Drilling
by Yanjun Li, Deli Gao, Shujie Liu, Ying Zhao, Lei Li and Shuzhan Li
Processes 2025, 13(9), 3008; https://doi.org/10.3390/pr13093008 - 21 Sep 2025
Viewed by 188
Abstract
During deepwater drilling operations, when influx gas invades the wellbore, gas hydrates may form through the combination of the gas with free water in the drilling fluid under favorable temperature and pressure conditions. This process can alter the physical properties and flow behavior [...] Read more.
During deepwater drilling operations, when influx gas invades the wellbore, gas hydrates may form through the combination of the gas with free water in the drilling fluid under favorable temperature and pressure conditions. This process can alter the physical properties and flow behavior of the wellbore fluid, potentially leading to safety incidents. To prevent natural gas hydrate formation, mitigate wellbore blockages caused by hydrates, and address the associated safety hazards, this study conducted laboratory experiments to investigate hydrate formation and remediation under multiple deepwater drilling conditions. The hydrate formation boundaries for four different drilling fluid systems—seawater-based bentonite mud, seawater polymer mud, Plus/KCl mud, and HEM mud—were determined for varying well depths and pressure–temperature conditions, and corresponding trend lines were fitted. Key results reveal that a higher carbon content promotes hydrate formation, and the phase equilibrium curves also reveal significant differences among the four drilling fluids. The hydrate aggregation states and blockage processes were clarified for three typical drilling scenarios: drilling, well killing, and drilling suspension. Hydrate formation risk is negligible during normal circulation but increases dramatically during well-killing operations, significantly shrinking the safe operational window. A comparative analysis identified that adding 1% P(M-VCL), a kinetic hydrate inhibitor, to the drilling fluid was the most effective solution, demonstrating superior performance in delaying hydrate nucleation and preventing agglomeration. The study established a complete formation–inhibition–remediation approach for hydrate management in deepwater drilling, thereby enhancing operational safety and efficiency. Full article
(This article belongs to the Section Chemical Processes and Systems)
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20 pages, 635 KB  
Article
Cross-Institution Reweighting of National Green Data Center Indicators: An AHP-Based Multi-Criteria Decision Analysis with Consensus–Divergence Diagnostics
by Chuanzi Deng, Anxiang Li, Chao Fu, Tong Wu and Qiulin Wu
Processes 2025, 13(9), 3007; https://doi.org/10.3390/pr13093007 - 20 Sep 2025
Viewed by 196
Abstract
Evaluating green data centers is a multi-attribute decision problem. To enhance the rigor and precision of green data center assessment, this study verifies the weighting of the national green data center evaluation index system using the Analytic Hierarchy Process (AHP) with the participation [...] Read more.
Evaluating green data centers is a multi-attribute decision problem. To enhance the rigor and precision of green data center assessment, this study verifies the weighting of the national green data center evaluation index system using the Analytic Hierarchy Process (AHP) with the participation of 19 domain experts from various data center sectors. The aim is to gain an in-depth understanding of the perspectives and priorities of different types of institutions regarding evaluation indicators and to investigate the underlying reasons for these perspectives and priorities. Through an analysis of expert sample distribution, this paper reveals the preferences of financial, internet, research, and design, as well as technical consulting service institutions, regarding indicators such as energy-efficient utilization, computational resource utilization, green low-carbon development, scientific layout, and intensive construction. Specifically, financial institutions tend to place a relatively lower emphasis on energy efficiency due to their focus on transaction speed and security. In contrast, internet companies prioritize efficient utilization of computational resources. Research and design institutions consider scientific layout and intensive construction more crucial, while technical consulting service institutions emphasize green and low-carbon development. Meanwhile, we identified substantial discrepancies among experts in determining the weights of specific indicators, suggesting a lack of consensus within the industry about the correlation between these indicators and green data centers. To propel the sustainable development of green data centers, future assessments should refine evaluation dimensions, consider disparities such as data center types and embrace regional differences, actively adopt novel technologies and innovative practices, and establish mechanisms for long-term monitoring and evaluation. Full article
(This article belongs to the Section Process Control and Monitoring)
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20 pages, 35510 KB  
Article
Effect of Glycerol Concentration on the Properties of Semolina- and Farina-Based Biodegradable Films
by Tomasz Tadeusz Murawski, Mikołaj Olczak, Szymon Mateusz Laskowski, Zuzanna Żołek-Tryznowska and Jerzy Szałapak
Processes 2025, 13(9), 3006; https://doi.org/10.3390/pr13093006 - 20 Sep 2025
Viewed by 252
Abstract
This study investigates the properties of biopolymer films derived from semolina and farina, focusing on the effect of varying concentrations of glycerol as a plasticizer. The research fills a gap in the study of grains such as semolina and farina, which have the [...] Read more.
This study investigates the properties of biopolymer films derived from semolina and farina, focusing on the effect of varying concentrations of glycerol as a plasticizer. The research fills a gap in the study of grains such as semolina and farina, which have the potential to expand the range of biodegradable materials. Mechanical tests revealed significant differences between the two film types. Farina-based films were notably more ductile, exhibiting an elongation at break of up to two times their original length, but with a low tensile strength of only 1–2 MPa. In contrast, semolina-based films were significantly stiffer, with a maximum elongation at break of 10%. A notable exception was the semolina film with a 25% glycerol concentration, which displayed an exceptionally high tensile strength of 17 MPa. This is a significant improvement over the typical potato starch-based film tested, which breaks at 5 MPa under static tearing. Furthermore, the study examined the films’ morphology, color, SFE, and surface roughness. Free surface energy ranged from 40 to 60 mJ/m2 in the tests, where the influence of the plasticizer was significant. Color tests clearly show yellow discoloration. Full article
(This article belongs to the Section Materials Processes)
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56 pages, 1658 KB  
Review
The Potential of CFD in Sustainable Microbial Fermenter Design: A Review
by Fatima Imran, Markus Bösenhofer, Christian Jordan and Michael Harasek
Processes 2025, 13(9), 3005; https://doi.org/10.3390/pr13093005 - 20 Sep 2025
Viewed by 206
Abstract
Due to the regulated nature and purity standards of the bioprocess and biotechnology industries, the sector has seen comparatively less sustainable practices than other chemical industries have. The achievement of sustainability in microbial fermenter design requires that quantitative tools with links between process [...] Read more.
Due to the regulated nature and purity standards of the bioprocess and biotechnology industries, the sector has seen comparatively less sustainable practices than other chemical industries have. The achievement of sustainability in microbial fermenter design requires that quantitative tools with links between process parameters and end-environmental outcomes are employed. This review begins with environmentally friendly metrics such as process mass intensity, water and energy intensity, and related indicators that act as a template for resource usage and waste generation assessment. The objective of this paper is to highlight the primary focus on computational fluid dynamics (CFD) applied to bioprocesses in aerated stirred bioreactors using Escherichia coli (E. coli). Second, the objective of this paper is to explore state-of-the-art CFD models and methods documented in the existing literature, providing a fundamental foundation for researchers to incorporate CFD modelling into biotechnological process development, while making these concepts accessible to non-specialists and addressing the research gap of linking CFD outputs with sustainability metrics and life cycle assessment techniques. Impeller rotational models such as sliding mesh are an accurate and commonly used method of modelling the rotation of stirring. Multiple different turbulence models are applied for the purpose of stirred bioreactors, with the family of k-ε models being the most used. Multiphase models such as Euler-Euler models in combination with population balance models and gas dispersion models to model bubble size distribution and bubble characteristics are typically used. Full article
(This article belongs to the Special Issue Bioreactor Design and Optimization Process)
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11 pages, 2881 KB  
Article
Experimental Investigation of Very High Cycle Fatigue and Fatigue Crack Growth Behaviors of X17CrNi15-2 Stainless Steel
by Ran Li, Fengcai Liu, Mengyu Wu, Wenshu Wei, Yuehua Lai, Hao Liu, Jian Ye, Tianze Cao, Jianfeng Li and Wenbo Li
Processes 2025, 13(9), 3004; https://doi.org/10.3390/pr13093004 - 20 Sep 2025
Viewed by 206
Abstract
Understanding the fatigue behavior of materials is essential for designing components capable of enduring prolonged use under varying stress conditions. This study investigates the high-cycle fatigue and fatigue crack growth characteristics of X17CrNi15-2 stainless steel. Very high-cycle fatigue (VHCF) and fatigue crack growth [...] Read more.
Understanding the fatigue behavior of materials is essential for designing components capable of enduring prolonged use under varying stress conditions. This study investigates the high-cycle fatigue and fatigue crack growth characteristics of X17CrNi15-2 stainless steel. Very high-cycle fatigue (VHCF) and fatigue crack growth tests were conducted on conventional fatigue and compact tension (CT) specimens fabricated from X17CrNi15-2 stainless steel. The fatigue crack growth behavior of the CT specimens was analyzed using Paris’ law. A revised version of Paris’ law was suggested based on the fatigue crack growth rate plotted against the stress intensity factor range, expanding on prior research utilizing three-point single-edge notch bend specimens. Scanning electron microscopy (SEM) was employed to examine the fracture mechanisms of both fatigue specimen types. The results indicated that the fatigue specimens failed in the VHCF regime under stress amplitudes ranging from 100 to 450 MPa. A power law correlation between stress amplitude and fatigue life was established, with material constants of 7670.3954 and −0.1663. These findings offer valuable insights into the material’s performance and are crucial for enhancing its suitability in engineering applications where high-cycle fatigue is a critical factor. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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16 pages, 3344 KB  
Article
Evaluation of the Potential of Atmospheric Water Generators to Mitigate Water Scarcity in Northern Chile
by Cristian Cuevas, Aitor Cendoya, Daniel Sacasas and Matias Pezo
Processes 2025, 13(9), 3003; https://doi.org/10.3390/pr13093003 - 20 Sep 2025
Viewed by 171
Abstract
Water scarcity is a problem affecting millions of people in the world, including northern Chile, with several cities declared under water scarcity by the Chilean government. This paper numerically evaluates an atmospheric water generator based on a single vapor compression refrigeration system using [...] Read more.
Water scarcity is a problem affecting millions of people in the world, including northern Chile, with several cities declared under water scarcity by the Chilean government. This paper numerically evaluates an atmospheric water generator based on a single vapor compression refrigeration system using R410A. The monthly water harvesting rate and specific energy consumption are calculated for nine cities distributed throughout northern Chile. Every component is modeled in a modular way, using semi-empirical models, and integrated into an overall model. For the nine cities considered in this study, the monthly water harvesting varies between a maximum of 5518 L, obtained for Huasco during January, and a minimum of 0 L, in Combarbalá and Vicuña in some months during winter. In the case of the specific energy consumption, it varies between 0.355 and 1.146 kWh/L. By taking the period between December and April, the system can collect an average of 3868 L/month, with an average specific energy consumption of 0.533 kWh/L. The working domain of the system is strongly limited by the Chilean climate conditions, which is mainly influenced by the Humboldt Current. This restricts the operational efficiency of the AWGs, especially during the colder and drier months. Nonetheless, the modular modeling approach allows for flexible adaptation and optimization of the system across different geographic locations. Full article
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13 pages, 1717 KB  
Article
Kinetic Study of 1,3-Butadiene Polymerization via CCTP Using the Ziegler–Natta Ternary NdV3/DIBAH/Me2SiCl2 Catalyst System
by Teresa Córdova, José Luis González Zapata, Martha Roa Luna, Ilse Magaña, José Alejandro Díaz Elizondo, Luis Valencia, Ramón Díaz de León and Héctor Ricardo López González
Processes 2025, 13(9), 3002; https://doi.org/10.3390/pr13093002 - 20 Sep 2025
Viewed by 148
Abstract
This study reports the synthesis of high cis-1,4 polybutadiene with a narrow molecular weight distribution (Đ < 2.0) by coordinative chain transfer polymerization (CCTP) using a homogeneous ternary NdV3/diisobutyl aluminum hydride (DIBAH)/dimethyldichlorosilane (Me2SiCl2) Ziegler–Natta catalyst system. [...] Read more.
This study reports the synthesis of high cis-1,4 polybutadiene with a narrow molecular weight distribution (Đ < 2.0) by coordinative chain transfer polymerization (CCTP) using a homogeneous ternary NdV3/diisobutyl aluminum hydride (DIBAH)/dimethyldichlorosilane (Me2SiCl2) Ziegler–Natta catalyst system. The polymerization parameters, notably the monomer-to-initiator ratio ([M]/[Nd]) and the halogen-to-initiator ratio ([Cl]/[Nd]), were systematically varied to define the CCTP operational window. It was found that CCTP conditions are achieved only at low [M]/[Nd] ratios (<2500) and intermediate [Cl]/[Nd] ratios between 1.0 and 2.0, facilitating the production of polymers with molecular weights below 32 kDa and narrow dispersity. Increasing these ratios beyond these thresholds potentially induces the formation of insoluble, hyper-halogenated catalytic species and increases medium viscosity, which significantly broadens the molecular weight distribution (Đ > 4.0) and impairs CCTP control. These findings challenge previous assumptions that higher halogen concentrations are necessary for CCTP, thereby providing important mechanistic insights for tuning active species and achieving improved polymer architecture. The work demonstrates a viable pathway to control polymer microstructure and molecular weight in neodymium-based CCTP, which is critical for design of high-performance elastomeric materials. Full article
(This article belongs to the Section Chemical Processes and Systems)
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22 pages, 2891 KB  
Article
Distribution and Temporal Variations in Negative Pressure Along the Length of the Borehole During Directional Long Drilling
by Jun Liu, Qinghua Zhang and Jianwei Wang
Processes 2025, 13(9), 3001; https://doi.org/10.3390/pr13093001 - 20 Sep 2025
Viewed by 229
Abstract
Pre-extraction gas technology is commonly used in coal mines to extract gas from single coal seams, initial protective layers, and both unprotected and protected coal seams. With the development of drilling equipment, directional long drilling, pre-extraction, coal seam gas technology has been widely [...] Read more.
Pre-extraction gas technology is commonly used in coal mines to extract gas from single coal seams, initial protective layers, and both unprotected and protected coal seams. With the development of drilling equipment, directional long drilling, pre-extraction, coal seam gas technology has been widely applied, and negative pressure extraction is one of the key factors affecting the effectiveness of directional long drilling gas extraction. In order to determine the reasonable length of directional long boreholes, studying the negative pressure distribution and time-varying rules within such boreholes is of great significance for guiding later borehole layout and gas extraction. The COMSOL Multiphysics software v.5.3. was used to couple and solve the dynamic model of temperature, stress, and seepage in coal-containing gas, as well as the mathematical model of negative pressure attenuation in directional long boreholes. The gas pressure distribution in the coal surrounding the directional long borehole and the distribution and time-varying law of negative pressure in the borehole were studied. Then, the distribution and time-varying law of negative pressure in directional long borehole extraction were tested on site. Research has shown that the negative pressure attenuation during directional long drilling has a relatively small impact on the effectiveness of coal gas extraction, while the negative pressure at the hole opening is the key factor affecting the effectiveness of gas extraction. In the early stage of extraction, as the drilling depth increases, the pressure loss inside the hole increases and the negative pressure inside the hole decreases. As the extraction time becomes longer, the pressure loss inside the borehole decreases and the negative pressure inside the borehole gradually returns to the negative pressure value at the orifice. The gas flow velocity inside the extraction borehole gradually increases from the bottom of the hole to the hole opening, and the flow velocity at the bottom of the hole remains basically constant. The gas flow velocity inside the hole gradually decreases with the extension of extraction time, and the smaller the distance from the extraction hole opening, the greater the flow attenuation. The collapse of drilling holes during extraction affects the attenuation of negative pressure inside the hole in the short term. As the extraction time increases, the impact of the collapse on the negative pressure inside the hole is limited. The temperature of coal can significantly affect the negative pressure and gas flow distribution inside the pores. Considering the temperature effect, the gas flow velocity inside the pores is higher and the pressure loss is lower in the short term. On-site tests have determined that the depth of ultra-long directional drilling holes is shallower than 327 m, and the negative pressure changes inside the borehole are not significantly different from the negative pressure at the hole opening. The negative pressure stabilization speed near the hole opening and bottom is fast, usually reaching its peak within 3–10 min. The negative pressure stabilization process from the borehole opening to the hole bottom shows a “fast slow fast” trend. When using double-sided extraction, the time for negative pressure to reach stability is significantly shortened compared to single-sided extraction, and double-sided extraction is beneficial for improving the effectiveness of coalbed methane extraction. Full article
(This article belongs to the Special Issue Circular Economy on Production Processes and Systems Engineering)
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15 pages, 3038 KB  
Article
Removal of Diatrizoic Acid from Water via Liquid Surfactant Membrane with Aliquat 336 as Extractant: Operational Insights and Natural Water Matrices
by Manel Lecheheb and Oualid Hamdaoui
Processes 2025, 13(9), 3000; https://doi.org/10.3390/pr13093000 - 19 Sep 2025
Viewed by 205
Abstract
Hospitals often use diatrizioic acid (DTZA), an iodinated radiocontrast agent, which is poorly biodegradable and persistent in aqueous media. Therefore, the objective of this work is to remove DTZA from water using an advanced separation process, namely liquid surfactant membrane (LSM) or emulsion [...] Read more.
Hospitals often use diatrizioic acid (DTZA), an iodinated radiocontrast agent, which is poorly biodegradable and persistent in aqueous media. Therefore, the objective of this work is to remove DTZA from water using an advanced separation process, namely liquid surfactant membrane (LSM) or emulsion liquid membrane. The LSM system is composed of Aliquat 336 as extractant, Span 80 as emulsifier, kerosene as diluent, and KCl as internal stripping phase. The impacts of experimental parameters impacting the extraction of DTZA from water by LSM, namely surfactant concentration, initial pH of the contaminated solution, extractant dosage, nature of base in the contaminated solution, concentration of the internal stripping phase, nature of stripping solution, emulsion/external solution volume ratio, internal solution/organic phase volume ratio, mixing rate, nature of diluent, emulsification time, emulsification rate, and initial DTZA concentration, were investigated. A highly stable emulsion with a good degree of removal of 90.8% of DTZA in water was obtained for an emulsifier dosage of 3% (w/w), an extractant dosage of 1.0% (w/w), a pH of the contaminated solution of 10 using NH4OH, a concentration of the inner phase of 0.3 N KCl, an internal solution/organic phase volume ratio of 1/1, an emulsion/external solution volume ratio of 20/250, a mixing speed of 250 rpm, an emulsification time of 4 min, and an emulsification speed of 20,000 rpm. Additionally, the extraction of DTZA from various natural water matrices (natural mineral water, tap water and seawater) was examined. The developed LSM method offers a fascinating enhanced separation method for the elimination of DTZA in waters with low chloride ion concentrations. Full article
(This article belongs to the Section Separation Processes)
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24 pages, 4279 KB  
Article
Automated Detection of Shading Faults in Photovoltaic Modules Using Convolutional Neural Networks and I–V Curves
by Jesus A. Arenas-Prado, Angel H. Rangel-Rodriguez, Juan P. Amezquita-Sanchez, David Granados-Lieberman, Guillermo Tapia-Tinoco and Martin Valtierra-Rodriguez
Processes 2025, 13(9), 2999; https://doi.org/10.3390/pr13092999 - 19 Sep 2025
Viewed by 317
Abstract
Renewable energy technologies play a key role in mitigating climate change and advancing sustainable development. Among these, photovoltaic (PV) systems have experienced significant growth in recent years. However, shading, one of the most common faults in PV modules, can drastically degrade their performance. [...] Read more.
Renewable energy technologies play a key role in mitigating climate change and advancing sustainable development. Among these, photovoltaic (PV) systems have experienced significant growth in recent years. However, shading, one of the most common faults in PV modules, can drastically degrade their performance. This study investigates the application of convolutional neural networks (CNNs) for the automated detection and classification of shading faults, including multiple severity levels, using current–voltage (I–V) curves. Four scenarios were simulated in Simulink: a healthy module and three levels of shading severity (light, moderate, and severe). The resulting I–V curves were transformed into grayscale images and used to train and evaluate several custom-designed CNN architectures. The goal is to assess the capability of CNN-based models to accurately identify shading faults and discriminate between severity levels. Multiple network configurations were tested, varying image resolution, network depth, and filter parameters, to explore their impact on classification accuracy. Furthermore, robustness was evaluated by introducing Gaussian noise at different levels. The best-performing models achieved classification accuracies of 99.5% under noiseless conditions and 90.1% under a 10 dB noise condition, demonstrating that CNN-based approaches can be both effective and computationally lightweight. These results underscore the potential of this methodology for integration into automated diagnostic tools for PV systems, particularly in applications requiring fast and reliable fault detection. Full article
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