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Polymers, Volume 9, Issue 1

2017 January - 30 articles

Cover Story: This cover image schematically illustrates the thermoresponsive copolymers investigated in the present study. Dissolution of these terpolymers in aqueous solutions promotes the self-assembling of the block-based terpolymers into spherical micelles of different sizes. On the other hand, the statistical copolymer does not form any micellar structures; this reveals the importance of the block architecture. The self-assembly behaviour, i.e. the formation of micelles or random coil, as well as the size of the micelles, affects the gelation of the aqueous terpolymer solutions. This is critical for biological applications in which gelation is required at body temperature. The temperatures and the concentrations at which a stable gel is formed were visually determined. This study reveals an architectural effect according to which the gelation is strongly affected by the architecture of the terpolymers. By Theoni K. Georgiou. View this paper.
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Articles (30)

  • Article
  • Open Access
34 Citations
9,356 Views
12 Pages

Electrospinning Pullulan Fibers from Salt Solutions

  • Ran Li,
  • Peggy Tomasula,
  • Ana Margarida Moreira De Sousa,
  • Shih-Chuan Liu,
  • Michael Tunick,
  • Kevin Liu and
  • Linshu Liu

22 January 2017

There is an increasing interest in applying the technology of electrospinning for making ultrafine fibers from biopolymers for food-grade applications, and using pullulan (PUL) as a carrier to improve the electrospinnability of proteins and other nat...

  • Article
  • Open Access
29 Citations
10,060 Views
17 Pages

A Comprehensive Systematic Study on Thermoresponsive Gels: Beyond the Common Architectures of Linear Terpolymers

  • Anna P. Constantinou,
  • Hanyi Zhao,
  • Catriona M. McGilvery,
  • Alexandra E. Porter and
  • Theoni K. Georgiou

20 January 2017

In this study, seven thermoresponsive methacrylate terpolymers with the same molar mass (MM) and composition but various architectures were successfully synthesized using group transfer polymerization (GTP). These terpolymers were based on tri(ethyle...

  • Article
  • Open Access
23 Citations
7,095 Views
15 Pages

Structural Features and the Anti-Inflammatory Effect of Green Tea Extract-Loaded Liquid Crystalline Systems Intended for Skin Delivery

  • Patricia Bento da Silva,
  • Giovana Maria Fioramonti Calixto,
  • João Augusto Oshiro Júnior,
  • Raisa Lana Ávila Bombardelli,
  • Bruno Fonseca-Santos,
  • Camila Fernanda Rodero and
  • Marlus Chorilli

18 January 2017

Camellia sinensis, which is obtained from green tea extract (GTE), has been widely used in therapy owing to the antioxidant, chemoprotective, and anti-inflammatory activities of its chemical components. However, GTE is an unstable compound, and may u...

  • Article
  • Open Access
32 Citations
8,583 Views
15 Pages

Multi-Objective Optimizations of Biodegradable Polymer Stent Structure and Stent Microinjection Molding Process

  • Hongxia Li,
  • Xinyu Wang,
  • Yunbo Wei,
  • Tao Liu,
  • Junfeng Gu,
  • Zheng Li,
  • Minjie Wang,
  • Danyang Zhao,
  • Aike Qiao and
  • Yahua Liu

17 January 2017

Biodegradable stents made of poly-l-lactic acid (PLLA) have a promising prospect thanks to high biocompatibility and a favorable biodegradation period. However, due to the low stiffness of PLLA, polymeric stents have a lower radial stiffness and larg...

  • Article
  • Open Access
13 Citations
6,921 Views
10 Pages

17 January 2017

60Co γ-ray irradiation-initiated reversible addition–fragmentation chain transfer (RAFT) polymerization at room temperature with 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN) as the chain transfer agent was first applied to acrylonitrile (AN) polymeriz...

  • Article
  • Open Access
19 Citations
8,500 Views
18 Pages

14 January 2017

The influence of short-term water absorption on the mechanical properties of halloysite nanotubes-multi layer graphene reinforced polyester hybrid nanocomposites has been investigated. The addition of nano-fillers significantly increased the flexural...

  • Review
  • Open Access
139 Citations
14,628 Views
28 Pages

Recent Advances in Conjugated Polymer-Based Microwave Absorbing Materials

  • Ying Wang,
  • Yunchen Du,
  • Ping Xu,
  • Rong Qiang and
  • Xijiang Han

14 January 2017

Microwave absorbing materials (MAMs) are paving the way for exciting applications in electromagnetic (EM) pollution precaution and national defense security, as they offer an advanced alternative to conventional reflection principles to fundamentally...

  • Article
  • Open Access
10 Citations
8,275 Views
12 Pages

13 January 2017

We employ H2/Ar low-damage plasma treatment (H2/Ar-LDPT) to reduce graphene oxide (GO) coating on a polymer substrate—polyethylene terephthalate (PET)—with the assistance of atomic hydrogen (Hα) at low temperature of 70 °C. Four-point probing and ult...

  • Article
  • Open Access
33 Citations
9,598 Views
16 Pages

Nitrogen Doped Macroporous Carbon as Electrode Materials for High Capacity of Supercapacitor

  • Yudong Li,
  • Xianzhu Xu,
  • Yanzhen He,
  • Yanqiu Jiang and
  • Kaifeng Lin

13 January 2017

Nitrogen doped carbon materials as electrodes of supercapacitors have attracted abundant attention. Herein, we demonstrated a method to synthesize N-doped macroporous carbon materials (NMC) with continuous channels and large size pores carbonized fro...

  • Article
  • Open Access
28 Citations
8,975 Views
12 Pages

Molecular Dynamics Simulations for Resolving Scaling Laws of Polyethylene Melts

  • Kazuaki Z. Takahashi,
  • Ryuto Nishimura,
  • Kenji Yasuoka and
  • Yuichi Masubuchi

12 January 2017

Long-timescale molecular dynamics simulations were performed to estimate the actual physical nature of a united-atom model of polyethylene (PE). Several scaling laws for representative polymer properties are compared to theoretical predictions. Inter...

  • Review
  • Open Access
39 Citations
12,190 Views
16 Pages

Development of Conjugated Polymers for Memory Device Applications

  • Hung-Ju Yen,
  • Changsheng Shan,
  • Leeyih Wang,
  • Ping Xu,
  • Ming Zhou and
  • Hsing-Lin Wang

12 January 2017

This review summarizes the most widely used mechanisms in memory devices based on conjugated polymers, such as charge transfer, space charge traps, and filament conduction. In addition, recent studies of conjugated polymers for memory device applicat...

  • Review
  • Open Access
248 Citations
22,179 Views
24 Pages

9 January 2017

Chitosan is a natural polymer that has been widely utilized for many purposes in the food, textile, agriculture, water treatment, cosmetic and pharmaceutical industries. Based on its characteristics, including biodegradability, non-toxicity and antim...

  • Review
  • Open Access
191 Citations
21,361 Views
80 Pages

A Review of Multiscale Computational Methods in Polymeric Materials

  • Ali Gooneie,
  • Stephan Schuschnigg and
  • Clemens Holzer

9 January 2017

Polymeric materials display distinguished characteristics which stem from the interplay of phenomena at various length and time scales. Further development of polymer systems critically relies on a comprehensive understanding of the fundamentals of t...

  • Article
  • Open Access
50 Citations
12,012 Views
18 Pages

Investigation of Thermal and Thermomechanical Properties of Biodegradable PLA/PBSA Composites Processed via Supercritical Fluid-Assisted Foam Injection Molding

  • Sai Aditya Pradeep,
  • Hrishikesh Kharbas,
  • Lih-Sheng Turng,
  • Abraham Avalos,
  • Joseph G. Lawrence and
  • Srikanth Pilla

9 January 2017

Bio-based polymer foams have been gaining immense attention in recent years due to their positive contribution towards reducing the global carbon footprint, lightweighting, and enhancing sustainability. Currently, polylactic acid (PLA) remains the mo...

  • Article
  • Open Access
14 Citations
9,678 Views
11 Pages

Preparation and Properties of Branched Polystyrene through Radical Suspension Polymerization

  • Wenyan Huang,
  • Weikai Gu,
  • Hongjun Yang,
  • Xiaoqiang Xue,
  • Bibiao Jiang,
  • Dongliang Zhang,
  • Jianbo Fang,
  • Jianhai Chen,
  • Yang Yang and
  • Jinlong Guo

6 January 2017

Radical solvent-free suspension polymerization of styrene with 3-mercapto hexyl-methacrylate (MHM) as the branching monomer has been carried out using 2,2′-azobisisobutyronitrile (AIBN) as the initiator to prepare branched polymer beads of high purit...

  • Article
  • Open Access
86 Citations
11,306 Views
13 Pages

6 January 2017

In this paper, the influence of the molecular structure of polylactide (PLA)—characterised by its molar mass and content of d-lactide isomer—on the molecular ordering and α’–α form transition during fibre manufacturing by the wet spinning method is d...

  • Article
  • Open Access
21 Citations
7,585 Views
22 Pages

6 January 2017

Understanding the lateral variations in the elemental and chemical state of constituents induced by electrochemical reactions at nanoscales is crucial for the advancement of electrochemical materials science. This requires in situ studies to provide...

  • Article
  • Open Access
21 Citations
8,152 Views
9 Pages

6 January 2017

The synthesis and photoluminescence properties of crystal crosslinked gels (CCGs) with an aggregation-induced emission (AIE) active crosslinker derived from tetraphenylethene (TPE) is discussed in this article. The CCG was prepared from a metal organ...

  • Article
  • Open Access
46 Citations
7,364 Views
19 Pages

5 January 2017

We investigate the conformational properties of polymers in ionic microgels in the presence of salt ions by molecular dynamics simulations and analytical theory. A microgel particle consists of coarse-grained linear polymers, which are tetra-function...

  • Article
  • Open Access
109 Citations
14,081 Views
12 Pages

4 January 2017

Composites of LDPE filled with different amounts of graphene nanoplatelets (GnP) were prepared in form of films by means of precoating technique and single screw melt-extrusion using two types of screws, compression and mixing. This manufacturing pro...

  • Communication
  • Open Access
13 Citations
10,533 Views
11 Pages

4 January 2017

A new hybrid material for the removal of polycyclic aromatic hydrocarbons (PAH) from water was prepared by the polymerization of pentynyl beta-cyclodextrin (PyβCD) and silica micro-particles (SMP). Phenanthrene, being one of the important members of...

  • Review
  • Open Access
78 Citations
12,842 Views
26 Pages

4 January 2017

Carbon nanotubes (CNTs) are attractive nanostructures that serve as multifunctional transporters in biomedical applications, especially in the field of cancer therapy and diagnosis. Owing to their easily tunable nature and remarkable properties, nume...

  • Article
  • Open Access
170 Citations
10,522 Views
13 Pages

3 January 2017

In the electrospinning process, a modified parallel electrode method (MPEM), conducted by placing a positively charged ring between the needle and the parallel electrode collector, was used to fabricate highly aligned carbon nanotubes/polyacrylonitri...

  • Article
  • Open Access
8 Citations
5,889 Views
15 Pages

The Influence of Biochemical Modification on the Properties of Adhesive Compounds

  • Anna Rudawska,
  • Izabela Haniecka,
  • Magdalena Jaszek and
  • Monika Osińska-Jaroszuk

31 December 2016

The main objective of this study was to determine the effect of biochemical modification of epoxy adhesive compounds on the mechanical properties of a cured adhesive exposed to various climatic factors. The epoxy adhesive was modified by lyophilized...

  • Article
  • Open Access
39 Citations
15,015 Views
17 Pages

Characterization of Thermoplastic Polyurethane (TPU) and Ag-Carbon Black TPU Nanocomposite for Potential Application in Additive Manufacturing

  • Steven T. Patton,
  • Chenggang Chen,
  • Jianjun Hu,
  • Lawrence Grazulis,
  • Amanda M. Schrand and
  • Ajit K. Roy

29 December 2016

Electromechanical, adhesion, and viscoelastic properties of polymers and polymer nanocomposites (PNCs) are of interest for additive manufacturing (AM) and flexible electronics. Development/optimization of inks for AM is complex, expensive, and substr...

  • Review
  • Open Access
93 Citations
19,809 Views
19 Pages

Light-Responsive Polymer Micro- and Nano-Capsules

  • Valentina Marturano,
  • Pierfrancesco Cerruti,
  • Marta Giamberini,
  • Bartosz Tylkowski and
  • Veronica Ambrogi

29 December 2016

A significant amount of academic and industrial research efforts are devoted to the encapsulation of active substances within micro- or nanocarriers. The ultimate goal of core–shell systems is the protection of the encapsulated substance from the env...

  • Article
  • Open Access
5 Citations
6,163 Views
14 Pages

28 December 2016

In this paper, we investigate the effects of gamma (γ) radiation on the spectral and mplified spontaneous emission (ASE) properties of two conjugated polymers (CPs) viz., poly [2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH–PPV) (CPM) and...

  • Article
  • Open Access
28 Citations
7,586 Views
14 Pages

Rapid and Effective Removal of Cu2+ from Aqueous Solution Using Novel Chitosan and Laponite-Based Nanocomposite as Adsorbent

  • Jie Cao,
  • Han Cao,
  • Yuejun Zhu,
  • Shanshan Wang,
  • Dingwei Qian,
  • Guodong Chen,
  • Mingbo Sun and
  • Weian Huang

27 December 2016

In this paper, a novel method for preparing nanoparticle-polymer hybrid adsorbent was established. Laponite was dispersed in distilled water to form Laponite nanoparticles. These nanoparticles were pre-adsorbed by 2-acrylamido-2-methylpropane-sulfoni...

  • Article
  • Open Access
20 Citations
7,139 Views
8 Pages

26 December 2016

Compared to unhealthy UV or γ-ray and high-energy-consumption thermal external stimuli, the promising light emitting diode (LED) external stimulus has some outstanding technological merits such as narrow wavelength distribution, low heat generation a...

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Polymers - ISSN 2073-4360