Materials, Volume 15, Issue 6 (March-2 2022) – 357 articles

In order to apply the rigid biodegradable PLA material for flexible toothbrush bristle products, in this paper, Poly(lactic acid) (PLA) and thermoplastic polyurethane elastomer (TPU) blends (TPU/PLA composites), with a mass ratio of 80:20, were prepared by the melt-blending method to achieve toughening modification. Infrared spectroscopy, scanning electron microscopy, differential scanning calorimetry and low-field nuclear magnetic resonance were used to investigate the effect of the compatibilizer, Maleic anhydride grafted polypropylene (PP-g-MAH), on the compatibility of the blends, and the effect of melamine on the flame retardant properties of the blends was further investigated. The results demonstrated that 3% PP-g-MAH had the best compatibility effect on PLA and TPU; the TPU/PLA composites have a better macromolecular motility and higher crystallization capacity in the amorphous regions through the physical and chemical action by using PP-g-MAH as a compatibilizer. By adding melamine as a flame retardant, the scorch wire ignition temperature of TPU/PLA composites can reach 830 °C, which was elevated by 80 °C compared with pure PLA; however, the flame retardant effect of melamine in a single system was not significant. Melamine acts as a flame retardant by absorbing heat through decomposition and diluting the combustible material by producing an inert gas. Full article

In this paper, the 12k T-700^TM Multiaxial-Warp-Knitting–Needle (MWK–N) C/SiC composite and pin were designed and fabricated using the isothermal chemical vapor infiltration (ICVI) method. The composite’s microstructure and mechanical properties were examined by subjection to tensile and interlaminar shear tests. Three types of double-shear tests were conducted for C/SiC pins, including shear loading perpendicularly, along, and at 45° off-axial to the lamination. The fracture surface of the tensile and shear failure specimens was observed under scanning electronic microscope (SEM). The relationships between the composite’s microstructure, mechanical properties, and damage mechanisms were established. The composite’s average tensile strength was σ_uts = 68.3 MPa and the average interlaminar shear strength was τ_u = 38.7 MPa. For MWK–N–C/SiC pins, the double-shear strength was τ_u = 76.5 MPa, 99.7 MPa, and 79.6 MPa for test types I, II, and III, respectively. Compared with MWK–C/SiC pins, the double-shear strength of MWK–N–C/SiC pins all decreased, i.e., 26.7%, 50.8%, and 8% for test types I, II, and III, respectively. The MWK–N–C/SiC composite and pins possessed high interlaminar shear strength and double-shear strength, due to the needled fiber in the thickness direction, low porosity (10–15%), and high composite density (2.0 g/cm³). Full article

New insights into the chemistry of alumino-phosphate solutions are provided in this contribution. In a first part, a solution with a P/Al molar ratio of 3.2 was prepared for the first time. The binders obtained at 500 and 700 °C were compared to those obtained with the 3 and 3.5 P/Al molar ratio solutions in order to determine the impact of moderate P₂O₅ excess on the final phosphate ceramic nature. In a second part, the widely used P/Al = 3 solution was heat-treated at 500 °C using different heating rates (0.2, 1, and 10 °C/min) to determine how this parameter modifies the final phosphate ceramic composition. Our data show that moderate P₂O₅ excess is sufficient to obtain binders with a high amount of stable cubic aluminium metaphosphate compound at 700 °C but not at 500 °C, where significant P₂O₅ excess is mandatory. We also show that slow heating favors the formation of cubic aluminium metaphosphate compound at 500 °C. Full article

Marine noise pollution generated by propellers is of wide concern. Traditional propeller materials (nickel–aluminum bronze (NAB) alloys) can no longer meet the requirements for reducing shaft vibration. However, the Mn–Cu alloy developed to solve the problem of propeller vibration is affected by seawater corrosion, which greatly limits the application of the alloy in the field of marine materials. In this study, the M2052–NAB gradient alloy was developed for the first time using LENS technology to improve the corrosion resistance while retaining the damping properties of the M2052 alloy. We hope this alloy can provide a material research basis for the development of low-noise propellers. This study shows that, after solution-aging of M2052 alloy as the matrix, the martensitic transformation temperature increased to approach the antiferromagnetic transformation temperature, which promoted twinning and martensitic transformation. The aging process also eliminated dendrite segregation, promoted the equiaxed γ-MnCu phase, and increased the crystal size to reduce the number of dislocations, resulting in obvious modulus softening of the alloy. NAB after deposition had higher hardness and good corrosion resistance than the as-cast alloy, which offers good corrosion protection for the M2052 alloy. This research provides new material options for the field of shipbuilding. Full article

A study of immobilization of hexavalent chromium in the form of Na₂CrO₄ salt by self-compacting soils (SCS) is presented. Carbofill E additive was used as SCS binder. The efficiency of immobilization of Cr (VI) was evaluated by washing out chromium compounds from SCS samples. The influence of the nature of the soil and the content of Carbofill E and Na₂CrO₄ in the SCS samples on the efficiency of Cr (VI) immobilization was studied. It was found that the nature of the soil and the content of Carbofill E in the SCS samples affect the immobilization of Cr (VI). Moreover, increasing the Carbofill E content in SCS samples further increases Cr (VI) immobilization. X-ray diffraction studies of the samples with immobilized hexavalent chromium showed that part of the sample transforms from a readily soluble form of salt into oxide forms of chromium and calcium-chromium, which are practically insoluble in water. Full article

An important element in the correct operation of the rolling mill is appropriate planning of the condition of the rolls because this factor constitutes a limiting element in the production process. In this work, with the aim of indicating the method of proper use of production tools–metallurgical rollers during their operation in a Polish rolling mill, the wear and tear of particular kinds of rollers built in the whole rolling set was determined. For this purpose, data were collected at the strip mill from grinding processes, production reports and roll files, while our statistical analysis, laboratory calculations and measurements were used. These data were used to perform computer calculations on the service life of metallurgical rollers installed in the rolling line. Wear mechanisms were identified in industrial practice. The characteristic features of roller wear were investigated using non-destructive tests, including eddy currents. The laboratory tests reproduced the wear mechanisms in very hot rolling rolls. The statistical method for determining the service life of working rolls indicated that their reconstruction is determined both by natural physical phenomena and inappropriate use in about 30% of cases, mainly in the F5 and F6 cages of the finishing unit. Calculations indicated the possibility of replacing the working rolls made of high chromium cast iron Hi-Cr with those made of HSS in the F5 and F6 cages, which will contribute to an increase in the durability of the rolls, a reduction in production costs and a decrease in the number of roll rebuildings. The service life of HSS rolls is 14,000–20,000 Mg of rolled material per 1 mm of wear on its surface in the radial direction, compared to 2000 Mg for rolls made of high chromium cast iron Hi-Cr. The constructed model may be a source of information for further analyses and decision-making processes supporting the management of metallurgical enterprises. On the basis of the constructed model, it was shown that the analyzed projects, depending on their type and technical specification, will bring measurable economic benefits in the form of reduced annual energy consumption and environmental benefits in the form of reduced carbon dioxide emissions into the atmosphere. The constructed model of the roll consumption, verified in the real conditions of the rolling mills, will contribute to the fulfillment of energy and emission obligations with the EU. Full article

The growing use of composite honeycomb structures in several industries including aircraft has demonstrated the need to develop effective and efficient non-destructive evaluation methods. In recent years, active thermography has attracted great interest as a reliable technology for non-destructive testing and evaluation of composite materials due to its advantages of non-contact, non-destructive, full-area coverage, high speed, qualitative, and quantitative testing. However, non-uniform heating, low spatial resolution, and ambient environmental noise make the detection and characterization of defects challenging. Therefore, in this study, lock-in thermography (LIT) was used to detect water ingress into an aircraft composite honeycomb sandwich structure, and the phase signals were binarized through the Otsu algorithm. A square composite honeycomb with dimensions of 210 mm × 210 mm along with 16 different defective areas of various sizes in groups filled with water by 25%, 50%, 75%, and 100% of the cell volume was considered. The sample was excited at multiple modulation frequencies (i.e., 1 Hz to 0.01 Hz). The results were compared in terms of phase contrast and CNR according to the modulation frequency. In addition, the detectability was analyzed by comparing the number of pixels of water ingress in the binarized image and the theoretical calculation. Full article

Despite technological advances in the production processes of the materials for ceramic façade coatings, the problems of detachments are still frequent. Therefore, this work aims to investigate, through a literature review, the existing gaps related to the adhesion ability of adhesive mortars, identifying new research needs that can better explain the behavior of the material. In addition, an experimental procedure was developed to evaluate the mechanical capacity of adhesive mortars when subjected to cyclic stresses. Dynamic stress measurements are presented for several blocks of mortar and on similar blocks but with a slot drilled prior to measurements (intended to represent failure). From these data we calculated values of stress energy, elastic energy, and dissipated energy. The experimental results showed that the energy involved in the test process accompanied the load values and current stress values. The mortar samples with the previous failure absorbed and dissipated less energy than mortars without failure, showing that materials that have less energy to dissipate, are materials that have developed less capacity to adhere, that is, to keep their parts together. Full article

The article presents the results of experimental research together with the development of a response function presenting the thermal functioning of a new composite of a phase change material with carbon recyclate. The empirical research proved the improvement of the thermal functioning of the phase change material as a result of modifying its structure with carbon-based recycling material. The conducted experimental tests and statistical analysis proved that the obtained innovative composite is characterized by a more effective distribution of stored heat than the pure phase change material, which resulted in reduction of the heating and cooling time of the package by 10 min. The obtained innovative composite can improve the thermal efficiency of short-term heat storage systems, both in building components and in elements of heating and cooling systems, and translates into their increase in thermal efficiency. Full article

Strong nonlinear absorption (NLA), reduced optical limiting (OL) thresholds, and high radiation shielding parameters are required for the effective use of glasses in the laser radiation and nuclear radiation protecting materials. In view of this, the efficacy of Sm₂O₃ on the nonlinear optical (NLO) and OL properties were ascertained (at 532 nm) along with radiation shielding characteristics. The open and closed aperture Z-scan profiles revealed the presence of positive NLA and nonlinear refraction (NLR) phenomena respectively. OL measurements showed the existence of limiting behavior in the studied glasses. The NLA and NLR coefficients were improved while the OL thresholds were decreased as the doping of Sm₂O₃ elevated to a higher doping level. These improvements in NLA, NLR coefficients and OL efficiencies were attributed to the non-bridging oxygens and high polarizable Sm³⁺ ions. The NLA and OL results clearly suggest the high (5 mol %) Sm₂O₃ doped glass (Sm5CNLB) glass is beneficial to protect the delicate devices and human eye by suppressing the high energy laser light. The theoretical linear attenuation coefficients (LAC) values of the presented SmxCNLB glasses were obtained with the help of Phy-X software between 0.284 and 1.333 MeV. At 0.284 MeV, the maximum values occur and take values between 0.302 (for Sm0CNLB) and 0.409 cm⁻¹ (for Sm5CNLB). We found that the LAC for the presented SmxCNLB glasses is a function of Sm₂O₃ content, where the LAC tends to increase, corresponding to the high probabilities of interaction, as the content of Sm₂O₃ changes from 0 to 5 mol %. The effective atomic number (Z_eff) for the presented SmxCNLB glasses was examined between 0.284 and 1.333 MeV. As the amount of Sm₂O₃ is added, the Z_eff increases, and this was observed at any energy. Full article

In this paper, the spatial and temporal damage evolution was described during crevice corrosion through developing a two-dimensional (2-D) model. COMSOL code was used to simulate the crevice corrosion regulated by the I∙R voltage of nickel (Ni) metal in sulfuric acidic. The electrode deformation, potential and current curves, and other typical characteristics were predicted during crevice corrosion, where results were consistent with published experimental results. Then, based on the Ni model, the damage evolution of X100 crevice corrosion in CO₂ solution was simulated, assuming uniform distribution of solution inside and outside the crevice. The results showed that over time, the surface damage of Ni electrode increased under a constant applied potential. As the gap increased, the critical point of corrosion (CPC) inside the crevice moved into a deeper location, and the corrosion damage area (CDA) gradually expanded, but the threshold value of corrosion damage remained almost unchanged. The CDA inside the crevice extended toward the opening and the tip of crevice. Since the potential drop in this region increases with increasing current, the passivation potential point moved towards the opening. As the gap increased and the electrolyte resistance decreased, the critical potential for reaching the maximum corrosion rate moved into a deeper location. It is significant for predicting the initial damage location and the occurrence time of surface damage of crevice corrosion through the 2-D model that is not available through the one-dimensional simplified model. Full article

Renovation, restoration, remodeling, refurbishment, and the retrofitting of buildings often imply applying forces (i.e., concentrated loads) to beams that before were subjected to distributed loads only. In the case of reinforced concrete structures, the new condition causes a beam to bear a concentrated load with the crack pattern that resulted from the distributed loads which had acted before. If the concentrated load is applied at or near the beam’s midspan, the new shear demand reaches the maximum where cracks are vertical or quasi-vertical, and where inclined bars are not common according to any standards. So, the actual shear capacity can be substantially lower than new shear demand due to the concentrated load. This paper focuses on reinforced concrete beams whose load distribution has to be changed from distributed to concentrated and presents a design method to bring the beam’s shear capacity up to the new demand. The method consists of applying fiber composites (fiber-reinforced polymers or fiber-reinforced cementitious material) with fibers at an angle of 45° bonded to the beam’s web. This kind of external reinforcement arrangement has to comply with some practical measures, which are presented as well. The paper also provides the analytical model that predicts the concentrated load-carrying capacity of a beam in the strengthened state. The model accounts for the crack’s verticality, which nullifies the contributions of steel stirrups, aggregate interlock, and dowel action, and for the effective bond length of each fiber, which depends on the distance between the ends of the fiber and the crack it crosses. Full article

The composite films comprising pea starch (St) and ε-polylysine (PL) as the matrix and glycerol and sodium alginate as the plasticizers were investigated. The rheological properties, mechanical properties, Fourier transformed infrared spectroscopy, water vapor permeability (WVP), oil permeability, microstructure, thermogravimetry (TGA), and antimicrobial properties of the composite films were analyzed. The properties of the composite films with different mass ratios of St/PL varied significantly. First, the five film solutions were different pseudoplastic fluids. Additionally, as the mass ratio of PL increased, the tensile strength of the blends decreased from 9.49 to 0.14 MPa, the fracture elongation increased from 38.41 to 174.03%, the WVP increased, and the oil resistance decreased substantially. The films with a broad range of St/PL ratios were highly soluble; however, the solubility of the film with a St/PL ratio of 2:8 was reduced. Lastly, the inhibition of E. coli, B.subtilis, and yeast by the films increased with increasing mass ratios of PL, and the inhibition of B.subtilis was the strongest. Full article

Three ionic liquids (ILs)—1-butyl-1-methyl-pyrrolidinium Imidazolate (BMPyrIM), 1-butyl-3-methyl-imidazolium Imidazolate (BMImIM), and bis(1-butyl-3-methyl-imidazolium Imidazolate) (BBMImIM)—were synthesized and examined experimentally and theoretically as potential inhibitors for mild steel corrosion in HCl (1.0 M) solution. To our knowledge, two of the ILs successfully synthesized in our laboratory named BMPyrIM and BBMImIM are novel. Different electrochemical (potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS)), surface and structural (scanning electron microscopy (SEM), Energy-dispersive X-ray spectroscopy (EDS), Atomic force microscopy (AFM) and Fourier Transform Infrared Spectroscopy (FTIR)) and theoretical (Density functional theory (DFT)) techniques were utilized to confirm their use as efficient environmentally safe inhibitors. These ionic liquids were designed to study the cation effect (imidazolium and pyrrolidinium) and the dimeric effect of the imidazolium-based IL. A pronounced inhibiting effect was recorded using the optimum concentration (5 × 10⁻³ M) of BBMImIM with protection efficiency of 98.6% compared to 94.3% and 92.4% for BMImIM and BMPyrIM, respectively. The investigated ILs act as a mixed-type corrosion inhibitors and their protection obeys Langmuir adsorption isotherm. The results obtained by SEM, EDS and AFM confirmed the mild steel protection by the formation of protective film of the ILs on the steel surface resulted in less damaged surfaces compared with the blank solution. Furthermore, quantum chemical calculations illustrated the electronic structure of the investigated ILs and their optimized adsorptiοn configurations on mild steel surface. The findings from the different techniques helped to provide a supported interpretation of the inhibition mechanism. Full article

As a typical third-generation semiconductor material, silicon carbide (SiC) has been increasingly used in recent years. However, the outstanding performance of SiC component can only be obtained when it has a high-quality surface and low-damage subsurface. Due to the hard–brittle property of SiC, it remains a challenge to investigate the ductile machining mechanism, especially at the nano scale. In this study, a three-dimensional molecular dynamics (MD) simulation model of nanometric cutting on monocrystalline 3C-SiC was established based on the ABOP Tersoff potential. Multi-group MD simulations were performed to study the removal mechanism of SiC at the nano scale. The effects of both cutting speed and undeformed cutting thickness on the material removal mechanism were considered. The ductile machining mechanism, cutting force, hydrostatic pressure, and tool wear was analyzed in depth. It was determined that the chip formation was dominated by the extrusion action rather than the shear theory during the nanocutting process. The performance and service life of the diamond tool can be effectively improved by properly increasing the cutting speed and reducing the undeformed cutting thickness. Additionally, the nanometric cutting at a higher cutting speed was able to improve the material removal rate but reduced the quality of machined surface and enlarged the subsurface damage of SiC. It is believed that the results can promote the level of ultraprecision machining technology. Full article

Submicron hydroxyapatite has been reported to have beneficial effects in bone tissue engineering. This study aimed to fabricate submicron-scale bovine hydroxyapatite (BHA) using the high-energy dry ball milling method. Bovine cortical bone was pretreated and calcined to produce BHA powder scaled in microns. BHA was used to fabricate submicron BHA with milling treatment for 3, 6, and 9 h and was characterized by using dynamic light scattering, scanning electron microscope connected with energy dispersive X-Ray spectroscopy, Fourier-transform infrared spectroscopy, and X-ray diffractometry to obtain its particle size, calcium-to-phosphorus (Ca/P) ratio, functional chemical group, and XRD peaks and crystallinity. Results showed that the particle size of BHA had a wide distribution range, with peaks from ~5 to ~10 µm. Milling treatment for 3, 6, and 9 h successfully gradually reduced the particle size of BHA to a submicron scale. The milled BHA’s hydrodynamic size was significantly smaller compared to unmilled BHA. Milling treatment reduced the crystallinity of BHA. However, the treatment did not affect other characteristics; unmilled and milled BHA was shaped hexagonally, had carbonate and phosphate substitution groups, and the Ca/P ratio ranged from 1.48 to 1.68. In conclusion, the fabrication of submicron-scale BHA was successfully conducted using a high-energy dry ball milling method. The milling treatment did not affect the natural characteristics of BHA. Thus, the submicron-scale BHA may be potentially useful as a biomaterial for bone grafts. Full article

The use of fibres as structural reinforcement in concrete is included in standards, providing guidelines to reproduce their behaviour, which have been proven adequate when steel fibres are used. Nevertheless, in recent years new materials, such as polyolefin fibres, have undergone significant development as concrete reinforcement. This work gives insight on how suitable the constitutive models proposed by the Model Code 2010 (MC2010) are in the case of such polymer fibres. A set of numerical models has been carried out to reproduce the material behaviour proposed by the MC2010 and the approach based on the softening function proposed by the authors. The results show remarkable differences between the experimental results and the numerical simulations when the constitutive models described in the MC2010 are employed for different polyolefin fibre reinforced concrete mixes, while the material behaviour can be reproduced with greater accuracy if the softening function proposed by the authors is employed when this type of macro-polymer fibres is used. Moreover, the relatively complex behaviour of polyolefin fibre reinforced concrete may be reproduced by using such constitutive model. Full article

To improve the safety of nuclear power plants, a Cr protective layer is deposited on zirconium alloys to enhance oxidation resistance of the nuclear fuel cladding during both in-service and hypothetical accidental transients at High Temperature (HT) in Light Water Reactors. The formation of the Cr₂O₃ film on the coating surface considerably helps in reducing the oxidation kinetics of the zirconium alloy, especially during hypothetic Loss of Coolant Accident (LOCA). However, if the Cr coating is successful to increase the oxidation resistance at HT of the zirconium substrate, for in-service conditions, under neutron irradiation, Cr desquamation has to be avoided to guarantee a safe use of the Cr-coated zirconium alloys. Therefore, the adhesion properties have to be maintained despite the structural defects created by sustained neutron irradiation in the reactor environment. This paper proposes to study the behavior of the Zircaloy-Cr interface of a first generation Cr-coated material during a specific in situ ion irradiation. As deposited, the Cr-coated sample presents a f.c.c. C15 Laves-type intermetallic phase at the interface with off-stoichiometric composition. After irradiation and for the specific conditions applied, this interfacial phase has significantly dissolved. Energy Dispersion Spectroscopy revealed that the dissolution was accompanied by a counterintuitive “sharpening” effect. Full article

In the group of vanadium-free titanium alloys used for applications for long-term implants, the Ti-13Zr-13Nb alloy has recently been proposed. The production of a porous layer of oxide nanotubes (ONTs) with a wide range of geometries and lengths on the Ti-13Zr-13Nb alloy surface can increase its osteoinductive properties and enable intelligent drug delivery. This work concerns developing a method of electrochemical modification of the Ti-13Zr-13Nb alloy surface to obtain third-generation ONTs. The effect of the anodizing voltage on the microstructure and thickness of the obtained oxide layers was conducted in 1 M C₂H₆O₂ + 4 wt% NH₄F electrolyte in the voltage range 5–35 V for 120 min at room temperature. The obtained third-generation ONTs were characterized using SEM, EDS, SKP, and 2D roughness profiles methods. The preliminary assessment of corrosion resistance carried out in accelerated corrosion tests in the artificial atmosphere showed the high quality of the newly developed ONTs and the slight influence of neutral salt spray on their micromechanical properties. Full article

This research was performed to investigate the optimum conditions for developing pozzolanic ashes from organic wastes to be used as cement replacement materials. The organic wastes explored in the research are rice husk ash (RHA), wheat straw ash (WSA), and cow dung (CDA). When the organic waste is turned into ash, it develops a pozzolanic character due to the presence of silica. However, the presence of reactive silica and its pozzolanic reactivity depends on the calcination temperature, duration, and grinding. In this research, the organic wastes were calcined at three different calcination temperatures (300 °C, 400 °C, and 800 °C) for 2, 4, 6, and 8 h duration. The obtained ashes were ground for 30 min and replaced by 20% with cement. The samples containing ashes were tested for compressive strength, X-ray diffractometry (XRD), weight loss, and strength activity index (SAI). It was observed that the RHA calcinated at 600 °C for 2 h showed better strength. However, in the case of WSA and CDA, the most favorable calcination condition in terms of strength development was obtained at 600 °C for 6 h duration. The highest SAI was achieved for the mortar samples containing CDA calcinated at 600 °C for 6 h duration (CDA600-6H). The other two ashes (RHA and WSA) did not qualify as pozzolan according to the ASTM C618 classification. This was due to the presence of silica in crystalline form and lower surface area of the ash material. In this research, the ash was ground only for 30 min after calcination which did not contribute to an increase in the specific surface area and thus the pozzolanic activity. The materials ground for the higher duration are recommended for higher SAI. Full article

A combinatorial Co-Cr-Fe-Ni compositional complex alloy (CCA) thin film disk with a thickness of 1 µm and a diameter of 10 cm was processed by multiple-beam-sputtering physical vapor deposition (PVD) using four pure metal sources. The chemical composition of the four constituent elements varied between 4 and 64 at.% in the film, depending on the distance from the four PVD sources. The crystal structure, the crystallite size, the density of lattice defects (e.g., dislocations and twin faults) and the crystallographic texture were studied as a function of the chemical composition. It was found that in a wide range of elemental concentrations a face-centered cubic (fcc) structure with {111} crystallographic texture formed during PVD. Considering the equilibrium phase diagrams, it can be concluded that mostly the phase composition of the PVD layer is far from the equilibrium. Body-centered cubic (bcc) and hexagonal-close packed (hcp) structures formed only in the parts of the film close to Co-Fe and Co-Cr sources, respectively. A nanocrystalline microstructure with the grain size of 10–20 nm was developed in the whole layer, irrespective of the chemical composition. Transmission electron microscopy indicated a columnar growth of the film during PVD. The density of as-grown dislocations and twin faults was very high, as obtained by synchrotron X-ray diffraction peak profile analysis. The nanohardness and the elastic modulus were determined by indentation for the different chemical compositions on the combinatorial PVD film. This study is the continuation of a former research published recently in Nagy et al., Materials 14 (2021) 3357. In the previous work, only the fcc part of the sample was investigated. In the present paper, the study was extended to the bcc, hcp and multiphase regions. Full article

To further explore the potential of Zr-based alloys as a biomaterial that will not interfere with magnetic resonance imaging (MRI), the microstructural characteristics of Zr-xat.% Nb alloys (10 ≤ x ≤ 18), particularly the athermal ω phase and lattice modulation, were investigated by conducting electrical resistivity and magnetic susceptibility measurements and transmission electron microscopy observations. The 10 Nb alloy and 12 Nb alloys had a positive temperature coefficient of electrical resistivity. The athermal ω phase existed in 10 Nb and 12 Nb alloys at room temperature. Alternatively, the 14 Nb and 18 Nb alloys had an anomalous negative temperature coefficient of the resistivity. The selected area diffraction pattern of the 14 Nb alloy revealed the co-occurrence of ω phase diffraction and diffuse satellites. These diffuse satellites were represented by g_β + q when the zone axis was [001] or [113], but not [110]. These results imply that these diffuse satellites appeared because the transverse waves consistent with the propagation and displacement vectors were q = <ζ $\overline{\zeta }$ 0>* for the ζ~1/2 and <110> directions. It is possible that the resistivity anomaly was caused by the formation of the athermal ω phase and transverse wave. Moreover, control of the athermal ω-phase transformation and occurrence of lattice modulation led to reduced magnetic susceptibility, superior deformation properties, and a low Young’s modulus in the Zr-Nb alloys. Thus, Zr-Nb alloys are promising MRI-compatible metallic biomaterials. Full article

DM has a high prevalence worldwide and exerts a negative influence on bone repair around dental implants. Modifications of the microgeometry of implants have been related to positive results in bone repair. This study assessed, for the first time, the influence of an implant with modified macrodesign based on the presence of a healing chamber in the pattern of peri-implant repair under diabetic conditions. Thirty Wistar rats were assigned to receive one titanium implant in each tibia (Control Implant (conventional macrogeometry) or Test Implant (modified macrogeometry)) according to the following groups: Non-DM + Control Implant; Non-DM + Test Implant; DM + Control Implant; DM + Test Implant. One month from the surgeries, the implants were removed for counter-torque, and the bone tissue surrounding the implants was stored for the mRNA quantification of bone-related markers. Implants located on DM animals presented lower counter-torque values in comparison with Non-DM ones, independently of macrodesign (p < 0.05). Besides, higher biomechanical retention levels were observed in implants with modified macrogeometry than in the controls in both Non-DM and DM groups (p < 0.05). Moreover, the modified macrogeometry upregulated OPN mRNA in comparison with the control group in Non-DM and DM rats (p < 0.05). Peri-implant bone repair may profit from the use of implants with modified macrogeometry in the presence of diabetes mellitus, as they offer higher biomechanical retention and positive modulation of important bone markers in peri-implant bone tissue. Full article

The optimal three-dimensional (3D) printing parameters of removable partial denture (RPD) frameworks should be studied to achieve the best accuracy, printing time, and least materials consumed. This study aimed to find the best build angle and support structures’ diameter of the 3D printed (RPD) framework. Sixty (RPD) frameworks (10 in each group) were manufactured by digital light processing (DLP) 3D printing technology at three build angles (110-D, 135-D, and 150-D) and two support structures diameters (thick, L, and thin, S). Six groups were named according to their printing setting as (110-DS, 135-DS, 150-DS, 110-DL, 135-DL, and 150-DL). Frameworks were 3D scanned and compared to the original cast surface using 3D metrology software (Geomagic Control X; 3D Systems, Rock Hill, SC). Both printing time and material consumption were also recorded. Data were tested for the significant difference by one-way analysis of variance (ANOVA) test at (α = 0.05). The correlations between outcome parameters were also calculated. The 110-DL group showed the least accuracy. Significantly, the printing time of the 150-D groups had the lowest time. Material consumption of group 110-DS presented the lowest significantly statistical value. Printing time had a linear correlation with both accuracy and material consumption. Within the study limitations, the 150-degree build angle and thin diameter support structures showed optimal accuracy and time-saving regardless of material consumption. Full article

A high protection level without an excessive weight is a basic assumption in the design of modern armors and protection systems. Optimizing armors is a task of development of the utmost importance, and is the subject of the work contained within this article. Optimization of ballistic inserts was carried out using multicriterial analysis (MCA), which enables the selection of the optimal composition, taking into account properties such as ballistic resistance, physicomechanical, and/or functional properties. For this purpose, various types of composite systems were produced and tested in terms of their fragment-resistant properties according to STANAG 2920 and the composite areal density of different ballistic inserts: Soft inserts made of Twaron^® para-aramid sheets, hard ballistic inserts made of multilayer hot-pressed preimpregnated sheets, and hybrid hard ballistic inserts prepared on the basis of multilayer hot-pressed preimpregnated sheets and ceramics. The application of MCA and performance of experimental fragment resistance tests for a wide spectrum of para-aramid inserts are part of the novelty of this work. The obtained test results showed that depending on the composition of the composite system, we could obtain a wide range of fragmentation resistance in the range of 300 to >1800 m/s, which depended on the areal density and type of composite system used. The results also confirmed that MCA is a good computational tool to select the optimal design of para-aramid ballistic inserts. Full article

Polydimethylsiloxane (PDMS), a silicone elastomer, is increasingly being used in health and biomedical fields due to its excellent optical and mechanical properties. Its biocompatibility and resistance to biodegradation led to various applications (e.g., lung on a chip replicating blood flow, medical interventions, and diagnostics). The many advantages of PDMS are, however, partially offset by its inherent hydrophobicity, which makes it unsuitable for applications needing wetting, thus requiring the hydrophilization of its surface by exposure to UV or O₂ plasma. Yet, the elastomeric state of PDMS translates in a slow, hours to days, process of reducing its surface hydrophilicity—a process denominated as hydrophobic recovery. Using Fourier transform infrared spectroscopy (FTIR) and atomic force microscopy (AFM), the present study details the dynamics of hydrophobic recovery of PDMS, on flat bare surfaces and on surfaces embedded with hydrophilic beads. It was found that a thin, stiff, hydrophilic, silica film formed on top of the PDMS material, following its hydrophilization by UV radiation. The hydrophobic recovery of bare PDMS material is the result of an overlap of various nano-mechanical, and diffusional processes, each with its own dynamics rate, which were analyzed in parallel. The hydrophobic recovery presents a hysteresis, with surface hydrophobicity recovering only partially due to a thin, but resilient top silica layer. The monitoring of hydrophobic recovery of PDMS embedded with hydrophilic beads revealed that this is delayed, and then totally stalled in the few-micrometer vicinity of the embedded hydrophilic beads. This region where the hydrophobic recovery stalls can be used as a good approximation of the depth of the resilient, moderately hydrophilic top layer on the PDMS material. The complex processes of hydrophilization and subsequent hydrophobic recovery impact the design, fabrication, and operation of PDMS materials and devices used for diagnostics and medical procedures. Consequently, especially considering the emergence of new surgical procedures using elastomers, the impact of hydrophobic recovery on the surface of PDMS warrants more comprehensive studies. Full article

New three-ring ester/azomethine homologues series, (E)-4-((4-hydroxybenzylidene)amino)phenyl 4-(alkoxy)benzoate In, were prepared and their properties were investigated experimentally and theoretically. FT-IR, NMR, and elemental analyses were used to confirm the chemical structures of the synthesized compounds. The mesomorphic activities of the planned homologues were evaluated using differential scanning calorimetry (DSC) and polarized optical microscopy. All of the homologous examined were found to have non-mesomorphic properties. Theoretical calculations using the density functional theory (DFT) were used to validate the experimental data and determine the most stable conformation of the synthesized compounds. All calculated conformers’ thermal properties, dipole moments, and polarizability were discussed. The results show that the terminal alkoxy chain length affects the thermal parameters of the conformers. The correlations between these parameters’ values and the conformer type were demonstrated. The base component was expected to be in two conformers according to the orientation of the N atom of imine-linkage. DFT calculations revealed the more probable of the two possible conformers, and the incorporation of the alkoxy terminal chain in one position affect its geometrical and mesomerphic characteristics. Full article

This study presents an experimental investigation on the low-velocity impact response of three-dimensional integrated woven spacer sandwich composites made of high-performance glass fiber reinforced fabric and epoxy resin. 3D integrated woven spacer sandwich composites with five different specifications were produced using a hand lay-up process and tested under low-velocity impact with energies of 5 J, 10 J, and 15 J. The results revealed that the core pile’s heights and diverse impact energies significantly affect the stiffness and energy absorption capacity. There is no significant influence of face sheet thickness on impact response. Moreover, the damage morphologies of 3D integrated woven spacer sandwich composites under different impact energies were analyzed by simple visualization of the specimen. Different damage and failure mechanisms were observed, including barely visible damage, visible damage, and clearly visible damage. Moreover, it was noticed that the damage of 3D integrated woven spacer sandwich composites samples only constraints to the impacted area and does not affect the integrity of the samples. Full article

The morphology and intermolecular interaction are two of the most important factors in the design of highly efficient dye adsorbent in the industry. Millimeter-sized, bead-type, bio-based lignin/chitosan (Lig/CS) adsorbent was designed for the removal of Congo red (CR), based on the electrostatic attraction, π-π stacking, and hydrogen bonding, which were synthesized through the emulsification of the chitosan/lignin mixture followed by chemical cross-linking. The effects of the lignin/chitosan mass ratio, initial pH, temperature, concentration, and contact time on the adsorption were thoroughly investigated. The highest adsorption capacity (173 mg/g) was obtained for the 20 wt% Lig/CS beads, with a removal rate of 86.5%. To investigate the adsorption mechanism and recyclability, an evaluation of the kinetic model and an adsorption/desorption experiment were conducted. The adsorption of CR on Lig/CS beads followed the type 1 pseudo-second-order model, and the removal rate for CR was still above 90% at five cycles. Full article