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24 Results Found

  • Article
  • Open Access
5 Citations
4,652 Views
13 Pages

Low-Temperature Hydrogenation of Toluene Using an Iron-Promoted Molybdenum Carbide Catalyst

  • Song Zhou,
  • Xi Liu,
  • Jian Xu,
  • Hui Zhang,
  • Xiaosong Liu,
  • Pengcheng Li,
  • Xiaodong Wen,
  • Yong Yang and
  • Yongwang Li

8 September 2021

As an alternative to noble metal hydrogenation catalysts, pure molybdenum carbide displays unsatisfactory catalytic activity for arene hydrogenation. Precious metals such as palladium, platinum, and gold are widely used as additives to enhance the ca...

  • Feature Paper
  • Article
  • Open Access
58 Citations
8,722 Views
21 Pages

31 October 2019

The most promising and utilized chemical sensing materials, WO3 and SnO2 were characterized by means advanced synchrotron based XPS, UPS, NAP-XPS techniques. The complementary electrical resistance and sensor testing experiments were also completed....

  • Review
  • Open Access
1,109 Views
25 Pages

The spontaneous formation and stability of a protective passive film on a metal surface are crucial for the metal material’s corrosion resistance during its service life. Passive films have been extensively studied, and our understanding of pas...

  • Communication
  • Open Access
2,713 Views
10 Pages

Electrocatalytic Enhancement of CO Methanation at the Metal–Electrolyte Interface Studied Using In Situ X-ray Photoelectron Spectroscopy

  • Christoph W. Thurner,
  • Leander Haug,
  • Daniel Winkler,
  • Christoph Griesser,
  • Matthias Leitner,
  • Toni Moser,
  • Daniel Werner,
  • Marco Thaler,
  • Lucas A. Scheibel and
  • Thomas Götsch
  • + 5 authors

8 November 2023

For the direct reduction of CO2 and H2O in solid oxide electrolysis cells (SOECs) with cermet electrodes toward methane, a fundamental understanding of the role of elemental carbon as a key intermediate within the reaction pathway is of eminent inter...

  • Article
  • Open Access
3 Citations
2,803 Views
21 Pages

Surface Chemical Effects on Fischer–Tropsch Iron Oxide Catalysts Caused by Alkali Ion (Li, Na, K, Cs) Doping

  • Mirtha Z. Leguizamón León Ribeiro,
  • Joice C. Souza,
  • Igor Ferreira Gomes,
  • Muthu Kumaran Gnanamani,
  • Michela Martinelli,
  • Gary Jacobs and
  • Mauro Celso Ribeiro

2 October 2024

Among the alkali metals, potassium is known to significantly shift selectivity toward value-added, heavier alkanes and olefins in iron-based Fischer–Tropsch synthesis catalysts. The aim of the present contribution is to shed light on the mechan...

  • Article
  • Open Access
6 Citations
4,764 Views
15 Pages

Neptunium(V) and Uranium(VI) Reactions at the Magnetite (111) Surface

  • Pieter Bots,
  • Arjen van Veelen,
  • J. Frederick W. Mosselmans,
  • Christopher Muryn,
  • Roy A. Wogelius and
  • Katherine Morris

Neptunium and uranium are important radionuclides in many aspects of the nuclear fuel cycle and are often present in radioactive wastes which require long term management. Understanding the environmental behaviour and mobility of these actinides is e...

  • Article
  • Open Access
19 Citations
6,049 Views
29 Pages

Carbide-Modified Pd on ZrO2 as Active Phase for CO2-Reforming of Methane—A Model Phase Boundary Approach

  • Norbert Köpfle,
  • Kevin Ploner,
  • Peter Lackner,
  • Thomas Götsch,
  • Christoph Thurner,
  • Emilia Carbonio,
  • Michael Hävecker,
  • Axel Knop-Gericke,
  • Lukas Schlicker and
  • Andrew Doran
  • + 6 authors

2 September 2020

Starting from subsurface Zr0-doped “inverse” Pd and bulk-intermetallic Pd0Zr0 model catalyst precursors, we investigated the dry reforming reaction of methane (DRM) using synchrotron-based near ambient pressure in-situ X-ray photoelectron...

  • Article
  • Open Access
10 Citations
3,167 Views
15 Pages

28 February 2020

The increasing use of polymers is related to a growing disposal problem. Switching to biodegradable polymers such as polybutylene adipate terephthalate (PBAT) is a feasible possibility, but after industrial production of commercially available materi...

  • Article
  • Open Access
58 Citations
8,853 Views
19 Pages

The Identification of Cu–O–C Bond in Cu/MWCNTs Hybrid Nanocomposite by XPS and NEXAFS Spectroscopy

  • Danil V. Sivkov,
  • Olga V. Petrova,
  • Sergey V. Nekipelov,
  • Alexander S. Vinogradov,
  • Roman N. Skandakov,
  • Sergey I. Isaenko,
  • Anatoly M. Ob’edkov,
  • Boris S. Kaverin,
  • Ilya V. Vilkov and
  • Roman I. Korolev
  • + 1 author

7 November 2021

The results of the research of a composite based on multi-walled carbon nanotubes (MWCNTs) decorated with CuO/Cu2O/Cu nanoparticles deposited by the cupric formate pyrolysis are discussed. The study used a complementary set of methods, including scan...

  • Article
  • Open Access
1 Citations
1,788 Views
21 Pages

Structural Analysis of Erbium-Doped Silica-Based Glass-Ceramics Using Anomalous and Small-Angle X-Ray Scattering

  • Helena Cristina Vasconcelos,
  • Maria Meirelles,
  • Reşit Özmenteş and
  • Luís Santos

This study employs advanced structural characterization techniques, including anomalous small-angle X-ray scattering (ASAXS), small-angle X-ray scattering (SAXS), and X-ray photoelectron spectroscopy (XPS), to investigate erbium (Er3+)-doped silica-b...

  • Review
  • Open Access
40 Citations
11,058 Views
49 Pages

14 February 2017

The catalytic oxidation of CO by O2 to form CO2 over Pt surfaces and supported catalysts is one of the most studied catalytic reactions from both fundamental and applied points of view. This review aims to show how the application of a range of time...

  • Feature Paper
  • Article
  • Open Access
6 Citations
6,002 Views
10 Pages

Direct-ARPES and STM Investigation of FeSe Thin Film Growth by Nd:YAG Laser

  • Sandeep Kumar Chaluvadi,
  • Debashis Mondal,
  • Chiara Bigi,
  • Jun Fujii,
  • Rajdeep Adhikari,
  • Regina Ciancio,
  • Alberta Bonanni,
  • Giancarlo Panaccione,
  • Giorgio Rossi and
  • Ivana Vobornik
  • + 1 author

26 February 2021

Research on ultrathin quantum materials requires full control of the growth and surface quality of the specimens in order to perform experiments on their atomic structure and electron states leading to ultimate analysis of their intrinsic properties....

  • Article
  • Open Access
2 Citations
3,873 Views
14 Pages

The Growth Behavior of Amorphous Hydrogenated Carbon a-C:H Layers on Industrial Polycarbonates—A Weak Interlayer and a Distinct Dehydrogenation Zone

  • Torben Schlebrowski,
  • Melanie Fritz,
  • Lucas Beucher,
  • Yongxin Wang,
  • Stefan Wehner and
  • Christian B. Fischer

29 July 2021

Polycarbonate (PC) is a material that is used in many areas: automotive, aerospace engineering and data storage industries. Its hardness is of particular importance, but some applications are affected by its low wettability or scratch susceptibility....

  • Article
  • Open Access
11 Citations
5,026 Views
17 Pages

Fibrillar Self-Assembly of a Chimeric Elastin-Resilin Inspired Engineered Polypeptide

  • Angelo Bracalello,
  • Valeria Secchi,
  • Roberta Mastrantonio,
  • Antonietta Pepe,
  • Tiziana Persichini,
  • Giovanna Iucci,
  • Brigida Bochicchio and
  • Chiara Battocchio

14 November 2019

In the field of tissue engineering, recombinant protein-based biomaterials made up of block polypeptides with tunable properties arising from the functionalities of the individual domains are appealing candidates for the construction of medical devic...

  • Article
  • Open Access
2 Citations
2,720 Views
9 Pages

Fabrication and Characterization of Pre-Defined Few-Layer Graphene

  • Tingting Wang,
  • Liangguang Jia,
  • Quanzhen Zhang,
  • Ziqiang Xu,
  • Zeping Huang,
  • Peiwen Yuan,
  • Baofei Hou,
  • Xuan Song,
  • Kaiqi Nie and
  • Chen Liu
  • + 5 authors

21 December 2022

Graphene is one of the most well-known two-dimensional (2D) materials that has attracted significant interest due to its unique electrical and optical properties. Being a van der Waals substrate, the fabrication of few-layered graphene by stacking a...

  • Feature Paper
  • Article
  • Open Access
14 Citations
3,977 Views
14 Pages

30 August 2019

PHB is a biodegradable polymer based on renewable raw materials that could replace synthetic polymers in many applications. A big advantage is the resulting reduction of the waste problem, as well as the conservation of fossil resources. To arrange i...

  • Article
  • Open Access
16 Citations
3,595 Views
26 Pages

Exploring the Antitumor Potential of Copper Complexes Based on Ester Derivatives of Bis(pyrazol-1-yl)acetate Ligands

  • Maura Pellei,
  • Carlo Santini,
  • Luca Bagnarelli,
  • Chiara Battocchio,
  • Giovanna Iucci,
  • Iole Venditti,
  • Carlo Meneghini,
  • Simone Amatori,
  • Paolo Sgarbossa and
  • Cristina Marzano
  • + 2 authors

20 August 2022

Bis(pyrazol-1-yl)acetic acid (HC(pz)2COOH) and bis(3,5-dimethyl-pyrazol-1-yl)acetic acid (HC(pzMe2)2COOH) were converted into the methyl ester derivatives 1 (LOMe) and 2 (L2OMe), respectively, and were used for the preparation of Cu(I) and Cu(II) com...

  • Article
  • Open Access
23 Citations
6,288 Views
12 Pages

Silver Nanoparticles Functionalized by Fluorescein Isothiocyanate or Rhodamine B Isothiocyanate: Fluorescent and Plasmonic Materials

  • Ilaria Fratoddi,
  • Chiara Battocchio,
  • Giovanna Iucci,
  • Daniele Catone,
  • Antonella Cartoni,
  • Alessandra Paladini,
  • Patrick O’Keeffe,
  • Silvia Nappini,
  • Sara Cerra and
  • Iole Venditti

10 March 2021

This paper presents the synthesis of silver nanoparticles (AgNPs) functionalized with fluorescent molecules, in particular with xanthene-based dyes, i.e., fluorescein isothiocyanate (FITC, λmax = 485 nm) and rhodamine B isothiocyanate (RITC, λmax = 5...

  • Feature Paper
  • Article
  • Open Access
3 Citations
3,794 Views
15 Pages

30 July 2020

The substitution of petroleum-based polymers with naturally derived biopolymers may be a good alternative for the conservation of natural fossil resources and the alleviation of pollution and waste disposal problems. However, in order to be used in a...

  • Review
  • Open Access
2,557 Views
29 Pages

22 August 2025

Despite notable advancements in lithium-ion battery (LIB) technology, growing industrialization, rising energy demands, and evolving consumer electronics continue to raise performance requirements. As the primary determinant of battery performance, c...

  • Article
  • Open Access
4 Citations
2,135 Views
13 Pages

Gold Nanorods as Radiopharmaceutical Carriers: Preparation and Preliminary Radiobiological In Vitro Tests

  • Ludovica Binelli,
  • Valentina Dini,
  • Simone Amatori,
  • Teresa Scotognella,
  • Alessandro Giordano,
  • Barbara De Berardis,
  • Federica Bertelà,
  • Chiara Battocchio,
  • Giovanna Iucci and
  • Ilaria Fratoddi
  • + 2 authors

21 June 2023

Low-energy electrons (Auger electrons) can be produced via the interaction of photons with gold atoms in gold nanorods (AuNRs). These electrons are similar to those emitted during the decay of technetium-99m (99mTc), a radioactive nuclide widely used...

  • Article
  • Open Access
3 Citations
2,807 Views
12 Pages

The Activation of Mg Powder Promoted by Chloride and Activation Mechanism

  • Xiaoxuan Wang,
  • Xiaoyan Guo,
  • Lixiang Zhu,
  • Shuo Wang,
  • Meishuai Zou,
  • Xiaodong Li,
  • Xiaodong Zhang and
  • Tinglu Song

10 September 2021

Magnesium has bright market prospects such as generating thrust for under water engines and hydrogen production. However, the passive oxide film on the surface of magnesium powder prevents the further reaction of magnesium with water at room temperat...

  • Article
  • Open Access
1 Citations
2,225 Views
13 Pages

Scalable Precursor-Assisted Synthesis of a High Voltage LiNiyCo1−yPO4 Cathode for Li-Ion Batteries

  • Mobinul Islam,
  • Ghulam Ali,
  • Muhammad Faizan,
  • Daseul Han,
  • Basit Ali,
  • Sua Yun,
  • Haseeb Ahmad and
  • Kyung-Wan Nam

16 December 2023

A solid-solution cathode of LiCoPO4-LiNiPO4 was investigated as a potential candidate for use with the Li4Ti5O12 (LTO) anode in Li-ion batteries. A pre-synthesized nickel–cobalt hydroxide precursor is mixed with lithium and phosphate sources by...

  • Article
  • Open Access
36 Citations
5,549 Views
22 Pages

The Structure and Chemical Composition of the Cr and Fe Pyrolytic Coatings on the MWCNTs’ Surface According to NEXAFS and XPS Spectroscopy

  • Danil Sivkov,
  • Olga Petrova,
  • Alena Mingaleva,
  • Anatoly Ob’edkov,
  • Boris Kaverin,
  • Sergey Gusev,
  • Ilya Vilkov,
  • Sergey Isaenko,
  • Dmitriy Bogachuk and
  • Roman Skandakov
  • + 2 authors

21 February 2020

The paper is devoted to the structure and properties of the composite material based on multi-walled carbon nanotubes (MWCNTs) covered with pyrolytic iron and chromium. Fe/MWCNTs and Cr/MWCNTs nanocomposites have been prepared by the metal organic ch...