- Article
Natural Variability vs. Anthropic Input: A Geochemical Monitoring of Hydrocarbons in Coari Lake, Central Amazon, Brazil
- Jelmir Craveiro de Andrade,
- Vinicius Kartnaller and
- Celeste Yara dos Santos Siqueira
- + 4 authors
Coari Lake is a critical area in the Amazon due to the oil exploration that began in the 1980s. The present study evaluates the impact on Coari Lake and the Solimões River in order to identify the origin of the sedimentary organic matter. This research is of great importance as it constitutes a crucial follow-up assessment, conducted 13 years after the initial survey by the same research group. Aliphatic hydrocarbons found in the new collected samples ranged from n-C14 to n-C34, with Cmax at C29–C31 and CPI values between 2.5 and 5.1, suggesting predominantly terrestrial biogenic inputs. Although the total n-alkane concentrations increased from 2012 to 2025, values remained within natural background ranges and as well as those ones associated with contaminated sediments. Aromatic hydrocarbons were strongly dominated by perylene, further supporting a biogenic origin. Monoaromatic and polyaromatic triterpenoids derived from α-amyrin, β-amyrin and lupeol were consistently detected, reflecting contributions from higher-plant material. No petrogenic indicators such as hopanes, steranes or unresolved complex mixtures were identified in any sample. Principal Component Analysis confirmed a temporal increase in hydrocarbon abundance while maintaining stable source signatures. Overall, the results demonstrate that Coari Lake sediments are still dominated by natural organic matter.
11 February 2026



![Schematic Cross-Section of the Solimões Basin—five main stratigraphic sequences (Benjamim Constant, Jutaí, Marimari, Tefé, and Javari (Alter do Chão e Solimões formations))—groups and the Triassic Penatecaua Magmatism. Folding and anticlinal structures, resulting from a transpressive tectonic event, created traps for valuable oil and gas accumulations (e.g., Urucu and Juruá provinces). Modified from Eiras [23] and Caputo [24].](https://mdpi-res.com/cdn-cgi/image/w=470,h=317/https://mdpi-res.com/geosciences/geosciences-16-00078/article_deploy/html/images/geosciences-16-00078-g001-550.jpg)

![(a) Tectonic setting of the Colombian Andes, showing the location of the Eastern Cordillera (EC) and active faults [9]. Other features are: Central Cordillera (CC), Western Cordillera (WC), Magdalena Valley (MV), Santa Marta Massif (SMM), Alto del Trigo Fault (ATF), Bituima Fault (BF), Cambao Fault (CF), Guaicáramo–Cusiana–Yopal Fault System (GCYFS), and Caldas Tear (CT). Subduction rates from [10]. (b) Topography in the northern EC showing regional faults and some thrusting systems mentioned in the text. Regional faults from [11]; black polygons are seismic stations; colored circles are thermal gradient estimates from borehole temperature measurements at drilled wells by the oil and gas industry [12]; heat flux is depicted as colored diamonds from measured values [13] and rectangles for estimates using geothermal gradient and crustal thickness [14]; purple triangle depicts the Paipa–Iza volcanic complex; dashed purple lines represent the location of two stratigraphic and structural restoration profiles shown in (c) after [6]. (c) Sedimentary and structural restoration of profiles shown in (b) [6]. Sedimentary and volcano-sedimentary cover is shown in blue for Jurassic, green for Cretaceous, and yellow for Cenozoic units. In purple are shown pre-Mesozoic rocks.](https://mdpi-res.com/cdn-cgi/image/w=281,h=192/https://mdpi-res.com/geosciences/geosciences-16-00075/article_deploy/html/images/geosciences-16-00075-g001-550.jpg)


