Journal of Composites Science

This study investigates the effect of waste cement dust (CD) and rock wool (RW) inorganic fiber on the tribological performance of brake friction composite materials. Five formulations were fabricated by varying CD from 65 to 45 wt.% and RW from 5 to 25 wt.% and evaluated for tribological properties on a Chase friction testing machine in accordance with IS 2742 test procedures. The results show that composites containing higher CD and lower RW exhibited higher coefficients of friction, lower friction variability, and improved fade resistance. In contrast, composites containing higher RW and lower CD showed improved recovery characteristics and substantially enhanced wear resistance. The performance coefficient of friction decreased from about 0.521 to 0.442 as the formulation shifted from CD-rich to RW-rich compositions, while the variability coefficient increased from about 0.364 to 0.516. The highest wear was recorded for the composite containing 65 wt.% CD and 5 wt.% RW inorganic fiber, whereas the lowest friction fluctuations were obtained for the composite containing 55 wt.% CD and 15 wt.% RW inorganic fiber. Finally, a simple ranking process-based decision-making technique was employed to evaluate the overall performance of all the composites, suggesting 55 wt.% CD as the optimal content. These findings confirm the potential of waste CD as a viable functional constituent in brake friction composites when combined with RW inorganic fiber in an optimized manner. Full article

Infrastructure expansion in Indonesia has increased demand for paving blocks, raising concerns over cement production costs and environmental impact. This study investigates the comparative effectiveness of pineapple leaf fiber (PALF, Ananas comosus) and sisal fiber (Agave sisalana) as reinforcements in paving blocks, evaluating water absorption and 28-day compressive strength at fiber contents of 0%, 1%, 3%, 5%, and 7% by cement volume. A full-factorial two-way ANOVA with post-hoc Tukey HSD was employed. A dosage of 3% for both fiber types resulted in compressive strengths of 14.5 MPa (PALF, +59% vs. control) and 15.2 MPa (sisal, +67% vs. control), both of which met the requirements of SNI 03-0691-1996 Class B. Sisal fiber demonstrated superior compressive performance, consistent with its higher stiffness and tensile strength as reported in the literature. Water absorption increased monotonically with fiber content for both types, with SNI Class D compliance (≤10%) maintained only at 0% for PALF and 0–1% for sisal, a known consequence of the inherently hydrophilic nature of plant-based natural fibers. A statistically significant interaction term (F = 3.697, p = 0.012) confirmed that the two fibers respond differently to dosage increases, providing nuanced practical guidance beyond what single-factor studies can offer. These findings demonstrate the promising compressive strength of agricultural waste fiber-reinforced paving blocks, warranting further investigation of abrasion resistance, flexural strength, and long-term durability before practical deployment. Such utilization supports circular economy principles in the construction industry. Full article

This study analyzed the initial adsorption and activation of CO₂ on bimetallic Cu_nSc nanoclusters, with n = 3–7, using DFT calculations in ORCA with the r²SCAN-3c method. A total of 20 bare clusters and their corresponding Cu_nSc–CO₂ complexes were investigated, considering four structural configurations for each composition. To avoid classification based solely on adsorption energy, a global CO₂ activation index was developed and defined as IACO₂ = z(AG) + z(CTCO₂) + z(Bending) + z(ΔrC–O). In this index, AG = −ΔG_ads, CT_CO2 = −qCO₂, bending corresponds to (180° − ∠O–C–O), and (ΔrC–O) represents the average elongation of the C–O bonds. This descriptor enabled distinguishing complexes that only stabilize CO₂ from those that induce effective geometric and electronic activation. Although 5IV and 3IV exhibited favorable adsorption, with (ΔG_ads) values of −52.978 and −53.494 kcal mol⁻¹, respectively, their molecular activation was low, with nearly linear CO₂ and minimal or unfavorable charge transfer. In contrast, 7III and 7II showed the highest activation, with CT_CO2 values of 1.206 and 1.163, bending values of 69.867° and 68.869°, and C–O elongations of 0.208 and 0.195 Å, respectively. The standardized (IACO₂) ranking identified 7III, 7II, 3III, and 3II as the most relevant systems, with scores of 100.0, 93.8, 88.2, and 86.8, respectively. These results show that CO₂ activation on Cu_nSc nanoclusters should not be assessed solely by (ΔG_ads), but rather by a multi-criteria approach that accounts for stability, charge transfer, and molecular distortion. Full article

Graphene-reinforced aluminum-based materials perfectly combine the excellent properties of graphene and aluminum, achieving superior lightweight structural characteristics. This study focuses on 1:2 internal resonance, analyzing the amplitude–frequency and force–amplitude responses of a graphene-platelet-reinforced aluminum-based truncated conical shell under multiple external excitations. Considering three different graphene distributions, an improved Halpin–Tsai mechanical model is used to predict the effective Young’s modulus of the GPL-enhanced aluminum-based truncated conical shell. Under temperature effects, based on the Reissner–Mindlin theory and von-Karman geometric nonlinear strain–displacement relationships, Hamilton’s principle and the Galerkin method are employed to derive the motion equations of the GPL-enhanced aluminum-based truncated conical shell. Through multiscale perturbation analysis, the averaged equations in polar coordinates are further derived. Based on the combined averaged equations, the amplitude–frequency and force–amplitude response curves of the system are plotted, investigating the influence of graphene distribution, graphene content, external excitation amplitude, tuning parameters, and graphene plate geometrical dimensions on its vibration characteristics. The analysis results indicate that graphene content is one of the primary factors affecting the vibration characteristics of graphene-reinforced aluminum-based truncated cones. Full article

Pultrusion is an efficient continuous manufacturing process for fiber-reinforced polymer (FRP) composites, but conventional open-bath impregnation has limitations such as resin exposure, quality variation, and resin loss. To overcome these limitations, closed-injection pultrusion (CIP) and short-pot-life resin systems have recently been introduced. However, the effects of processing variables on the quality and properties of composites manufactured using such resin systems have not been fully clarified. In this study, the effects of resin viscosity and pulling speed on the quality and mechanical properties of carbon FRP (CFRP) and glass FRP (GFRP) composites manufactured by CIP were investigated. CFRP and GFRP composites were fabricated at resin temperatures of 30 and 40 °C and pulling speeds of 300, 400, and 500 mm/min. The manufactured composites were evaluated in terms of void content, microstructure, hardness, and tensile properties. The results showed that increasing pulling speed increased void content and promoted macrovoids and locally poor impregnation, whereas the influence of resin temperature was relatively limited. Hardness, tensile strength, and elastic modulus decreased as pulling speed increased. These results demonstrate that CFRP and GFRP composites can be successfully manufactured by CIP using short-pot-life resin systems, and that precise control of resin viscosity and pulling speed is essential for achieving high quality and mechanical performance. Full article

Cementitious materials are naturally brittle, which makes them prone to cracking. This study effectively employs autogenous healing techniques using microcapsules to solve this issue. The goals were twofold: first, to microencapsulate isophorone diisocyanate (IPDI) as a catalyst-free healing agent; and second, to evaluate how these microcapsules improve the healing abilities of cementitious materials. Polyurethane (PU) prepolymer with an NCO content of 19.8% was successfully created. Using interfacial polymerization, smooth, spherical microcapsules of IPDI with an average diameter of 38 to 62 micrometers were produced. The elastic modulus of the microcapsules ranged from 0.23 to 0.18 GPa, while their hardness varied between 5.29 and 4.15 MPa. Over six months, the microcapsules showed a weight loss of 9.72% to 12.47%, depending on their size, under ambient conditions. Specimens containing 3% of fabricated microcapsules demonstrated the ability to seal cracks less than 100 µm wide by up to 70%. Specimens that incorporated 3% of their cement weight in IPDI microcapsules achieved an impressive 74% recovery rate in compressive strength. In contrast, control mortars without microcapsules showed a recovery rate of less than 50%. Analysis using Energy Dispersive Spectroscopy (EDS) revealed a significant presence of carbon in areas where the microcapsules had ruptured and the cracks had healed. This confirms the effectiveness of the healing process, consistent with established self-healing theories. The water tightness recovery trace showed a recovery rate of up to 61%. Additionally, the specimens containing microcapsules exhibited higher initial compressive strength than the control specimens. However, this also indicates that some microcapsules may have ruptured unintentionally during preparation and molding. Therefore, further research on the mechanical properties of microcapsules, especially their stiffness in cementitious composites, is necessary. Full article

Moisture-induced damage is one of the primary causes of premature distress in asphalt pavements, leading to reduced service life and increased maintenance costs. Although nanomaterials have shown potential in enhancing asphalt performance, the underlying composite interaction mechanisms among nanomaterials, asphalt binder, and aggregate phases under moisture exposure are still not fully understood. In addition, comparative evaluations under consistent experimental conditions remain limited. This study investigates the influence of five nanomaterials: nano-silica (NS), nano-alumina (NA), nano-titanium dioxide (NT), nano-zinc oxide (NZ), and carbon nanotubes (CNT) on the physical and mechanical properties of asphalt binders and mixtures, with particular emphasis on moisture damage resistance. The nanomaterials were incorporated at dosages of 1.5%, 3.0%, 4.5%, and 6.0% by binder weight. Binder performance was evaluated using conventional and performance grading (PG) tests, while mixture performance was assessed through Marshall properties and moisture susceptibility indicators, including the tensile strength ratio (TSR) and the index of retained strength (IRS). Fluorescence microscopy (FM), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR) were employed to investigate nanomaterial dispersion characteristics, microstructural morphology, and physicochemical interactions within the asphalt composite system. The results indicate that nanomaterial modification reduced penetration and increased softening point and Marshall stability, reflecting enhanced stiffness and thermal resistance, although ductility decreased at higher dosages. Significant improvements in moisture resistance were observed, particularly under conditioned states. The TSR increased from 81.2% for the control mixture to 92.4% for NS and 91.7% for NA, while the IRS improved from 72.7% to 88.5% for NS. Statistical analysis indicated that both nanomaterial type and dosage significantly affected TSR and IRS performance, with dosage exhibiting comparatively greater influence on moisture resistance improvement. FM and SEM analyses revealed comparatively better dispersion and lower agglomeration tendency for NS and NA, which corresponded to their superior moisture resistance performance. FTIR analysis indicated that the modification process was predominantly physical, with no major formation of new chemical functional groups. Among the investigated nano materials, NS at 6% dosage exhibited the most pronounced improvement, followed by NA at similar dosage levels. Overall, the findings suggest that nanomaterial modification can considerably improve the moisture resistance and mechanical performance of asphalt mixtures under laboratory conditions. However, higher nanomaterial dosages may adversely affect binder workability due to increased viscosity, particularly in CNT-modified binders. Full article

Steel–concrete composite beams are widely used in bridge infrastructure but are vulnerable to deterioration due to uniform and pitting corrosion, particularly at the lower flange. This study investigates the flexural behavior of corroded steel–normal strength concrete (NSC) composite beams and evaluates rehabilitation using ultra-high-performance concrete (UHPC) slab replacement, with and without additional steel plate strengthening. A comprehensive finite element analysis was conducted considering three beam spans (5, 7, and 9 m), two corrosion types, and three corrosion levels. The results indicate that both corrosion types significantly reduce flexural capacity due to cross-sectional loss, with pitting corrosion causing greater strength reduction than uniform corrosion at the same weight loss because of stress concentration effects. Replacing the NSC slab with a UHPC slab effectively restores and often enhances load-carrying capacity beyond that of intact beams while reducing dead load, demonstrating the superiority of the proposed rehabilitation approach. The combined use of UHPC slab replacement and welded steel plate strengthening provides the greatest improvement, revealing a strong synergistic effect. A case study of a corroded steel bridge in Pennsylvania confirms the practical applicability of the method, showing that UHPC-based rehabilitation increases the load rating from below unity to above unity. These findings highlight UHPC as an efficient and sustainable solution for extending the service life of aging steel bridges. Full article

High-performance and ultra-high-performance fiber-reinforced concretes (HPFRC/UHPFRC) have emerged as advanced cementitious composites capable of achieving superior mechanical performance, durability, and structural efficiency compared with conventional concrete. However, their widespread adoption remains challenged by relatively high material costs and significant embodied environmental impacts associated with elevated binder and fiber contents. This study presents a comprehensive life-cycle review of advanced high-performance cementitious composites, evaluating their sustainability from raw material extraction and mix design to structural application, service life, and end-of-life considerations. The review synthesizes current knowledge on material composition, production processes, structural performance, durability characteristics, and environmental impacts through the framework of life-cycle assessment (LCA). Particular attention is given to the influence of mix-design parameters, including binder composition, supplementary cementitious materials (SCMs), aggregate systems, and fiber type, on embodied carbon, energy demand, and mechanical performance. A dataset compiled from published experimental studies covering high-performance and ultra-high-performance concrete mixtures is analyzed to examine relationships between compressive strength, embodied energy, and carbon footprint, highlighting the dominant role of cementitious binders and fiber production in environmental impacts. Although advanced fiber-reinforced concretes generally exhibit higher cradle-to-gate emissions than conventional concrete, their superior mechanical properties, improved durability, reduced material demand, and extended service life can substantially reduce life-cycle environmental impacts at the structural level. The review further discusses emerging strategies for developing low-carbon high-performance cementitious composites, including clinker reduction, recycled and alternative fibers, optimized particle packing, and AI-assisted mix design. Finally, key research gaps are identified, particularly regarding standardized LCA methodologies, long-term durability data, harmonized performance-based functional units, and circular-economy strategies for material recycling and reuse. The findings highlight that performance-based life-cycle evaluation is essential for accurately assessing the sustainability potential of advanced high-performance cementitious composites in resilient and low-carbon infrastructure systems. Full article

Thin-walled composite beams with unsymmetric laminates are attracting increasing attention in lightweight aerospace and mechanical structures because they enable enhanced stiffness tailoring and weight reduction beyond the limitations of conventional symmetric stacking sequences. However, despite their practical relevance, unsymmetric thin-walled laminates have received comparatively limited attention in the available buckling literature due to the additional complexity introduced by membrane–bending coupling effects. This study presents an efficient and physically transparent formulation for the buckling analysis of thin-walled composite beams with both symmetric and unsymmetric layups by combining Generalized Beam Theory (GBT) with the Ritz method. The proposed GBT-Ritz framework captures global, local, distortional, torsional, and shear-related deformation modes while consistently incorporating laminate coupling effects associated with unsymmetric configurations. The formulation is applicable to open, closed, branched, and unbranched cross-sections commonly encountered in aerospace structures. Validation against ABAQUS V2017 shell finite element models demonstrates excellent agreement (with discrepancies generally below 6%) in predicting critical buckling loads and mode shapes for various geometries and boundary conditions. The results show that unsymmetric laminates can significantly influence buckling behavior, particularly in open sections and intermediate beam lengths where coupling effects become dominant. Compared with conventional finite element approaches, the proposed method achieves substantially lower computational cost (providing speed-up factors of 1.5 to 2.5) while preserving clear physical insight into interacting instability mechanisms. Overall, the developed framework provides an efficient and practically relevant tool for the analysis and design of advanced thin-walled composite structures with tailored unsymmetric laminates. Full article

Adequate polymerization of resin-based composites is essential for marginal sealing and mechanical performance. This study evaluated the effects of different light-curing protocols on gingival microleakage and microhardness of a high-viscosity bulk-fill composite, Filtek™ One Bulk Fill Restorative (3M ESPE; AUDMA, AFM, UDMA, 1,12-dodecane-DMA; silica/zirconia fillers, 76.5 wt%, 58.4 vol%) and conventional nanohybrid composite, Filtek™ Z250 XT Universal Restorative (3M ESPE; Bis-EMA, UDMA; zirconia/silica fillers, 82 wt%, 68 vol%). Forty-eight extracted human second premolars and 48 cylindrical specimens were used for microleakage and Vickers microhardness testing, respectively. Specimens were cured using an O-Star LED unit in turbo mode (2700–3000 mW/cm², 3 s) or soft-start mode (0–1200 mW/cm², 20 s) at 2 mm and 5 mm distances. Data were analyzed using Kruskal–Wallis and Dunn’s tests (p < 0.05). Significant differences were found among groups. Soft-start curing at 2 mm produced the lowest microleakage, whereas turbo curing at 5 mm produced the highest. The conventional composite exhibited higher top and bottom microhardness values. Bottom-to-top hardness ratios were below 80% in most groups, except for the conventional composite cured with soft-start mode. Based on our findings, soft-start curing at short distances provides favorable outcomes, while turbo curing at 5 mm is not recommended. Full article

This study investigates the effect of mineral additives of different natures, namely blast-furnace slag, fly ash, and bentonite, on structure formation, phase composition, microstructure, and physicomechanical properties of cement matrices. The analysis included measurements of mass change and linear shrinkage during hardening, determination of density and microhardness, X-ray phase analysis, and microstructural examination by scanning electron microscopy. It was found that the introduction of mineral additives reduced linear shrinkage from 6.06 mm for the control composition to 0.25 mm for the composition with blast-furnace slag, 2.31 mm for the composition with fly ash, and 1.01 mm for the composition with bentonite. The maximum density and microhardness values were obtained for the matrix with blast-furnace slag and amounted to 1.99 ± 0.03 g/cm³ and 39.95 ± 1.12 HV1, respectively, whereas the overall range of values for the investigated compositions was 1.52–1.99 g/cm³ and 30.2–39.95 HV1. X-ray phase analysis showed that the amorphous component varied from 61 to 78%, reaching its maximum value in the composition with blast-furnace slag, which is associated with the formation of poorly crystalline C–S–H and aluminosilicate phases. According to the SEM data, the average size of visible pore-like defects was 2.4 μm for the control composition, 1.4 μm for the composition with blast-furnace slag, 1.3 μm for the composition with fly ash, and 1.7 μm for the composition with bentonite. The most favorable combination of high density, microhardness, developed amorphous component, and homogeneous microstructure was established for the composition with blast-furnace slag. The obtained results can be used as a materials-science basis for the development of cement matrices intended for further studies on the immobilization of solid radioactive waste. Full article

The growing demand for sustainable materials as alternatives to conventional petroleum-based plastics has accelerated research on alginate-based films. Alginate is a naturally occurring polysaccharide, mainly extracted from brown algae and widely used in the bioindustry due to its biodegradability, film-forming ability, biocompatibility, and functional versatility. However, a comprehensive understanding of global research trends and emerging directions in this field remains limited. This study presents a bibliometric analysis of global research on alginate-based films from 2001 to December 2024, aiming to identify key trends, collaboration patterns, thematic structures, and future directions. The dataset was retrieved from Scopus and analyzed using VOSviewer (v.1.6.20). A significant increase in publications has been observed over the past five years. The International Journal of Biological Macromolecules was identified as the leading journal. “Agricultural and Biological Sciences” dominated the field. China was the most productive country, while Jhong-Whan Rhim was the most prolific author. Jiangnan University was the most active institution. Keyword analysis revealed three themes: mechanical enhancement, food packaging, and biomedical applications. Recent trends indicate a growing focus on sustainable food packaging development. Full article

Lithium-ion batteries require cathode materials with high capacity and cycling stability. Li₃V₂(PO₄)₃ (LVP) offers a theoretical capacity of 197 mAh/g but suffers from poor electronic conductivity. In this study, a Li₃V₂(PO₄)₃/carbon (LVP/C) composite was synthesized via a citric acid-assisted sol–gel method. The effects of pyrolysis temperature (700–1000 °C) and citric acid-to-salt ratio (1:1, 0.5:1, 0.25:1) were systematically investigated. The optimal composite was obtained at 900 °C with a 1:1 ratio. This material exhibited a well-crystallized monoclinic structure (space group P2₁/c) with unit cell volume of 890.61 ų. The amorphous carbon coating provided a specific surface area of 33.03 m²/g. Electrochemically, the optimal LVP/C_1:1 composite delivered an initial specific capacity of 114 mAh/g at C/10 rate—twice that of samples with lower carbon content. It also demonstrated 100% capacity retention after 25 cycles with favorable coulombic efficiency (67%) and reduced charge-transfer resistance. These results show that pyrolysis at 900 °C with a 1:1 citric acid-to-salt ratio provides an optimal balance between crystallinity, carbon coating uniformity, and electrochemical performance for high-performance LVP/C composite cathodes. Full article

The study presents an approach to the synthesis of micro- and nano-sized biosilica from rice husk ash (RHA) and describes its effective incorporation into cementitious composites for 3D concrete printing (3DCP). It is demonstrated that the calcination of rice husk at 700 °C, followed by sonochemical treatment, leads to the formation of a nanoscale silica phase with high pozzolanic reactivity. X-ray powder diffraction (XRD), infrared spectroscopy (IR), differential thermogravimetric analysis (DTG), and scanning electron microscopy (SEM) show that the incorporation of nano-biosilica (NBS) into the cementitious composites accelerates the hydration process through a nucleation effect and pozzolanic reaction. This, in turn, densifies the hardened cement microstructure and improves compressive strength significantly. Laboratory 3D concrete printing tests demonstrate that adding 1.72 wt.% NBS improves shape retention, decreases layer slump, and improves interlayer bond strength. The results indicate the viability of rice husk ash-derived biosilica as a supplementary cementitious material (SCM) in 3DCP due to its positive influence on the concrete mortar properties and parameters. Full article

Unsaturated polyester (UP) composites are widely utilized in engineering applications, including vehicle body structures, due to their ease of processing and good interfacial compatibility with natural fibers. However, the inherent brittleness of UP limits its performance under impact or tensile loading, as it exhibits minimal plastic deformation and is prone to crack initiation and propagation. In this study, bamboo fiber was incorporated into the UP matrix at various mixing ratios to enhance its crack resistance. After achieving uniform dispersion, the composites were subjected to a splitting tensile test to evaluate their crack resistance behavior. The results indicate that the composite containing 80% polyester exhibits the highest fracture toughness, with a crack resistance value of K_1C = 1.396 MPa·m^0.5. This value represents a 192.03% improvement compared with neat polyester (K_1C = 0.713 MPa·m^0.5). The enhanced crack resistance is attributed to the fiber bridging and energy-absorption mechanisms introduced by the bamboo fibers. These findings demonstrate the effectiveness of bamboo fiber reinforcement in improving the fracture performance of UP-based composites, highlighting their potential for use in lightweight structural applications. Full article

Cellulosic fibers can impart many unique benefits into composite applications, such as reduced weight or structural reinforcement; however, these materials also increase hygroscopicity and decrease thermal stability, restricting broader applications. The present work adapted an experimental process for functionalizing the cellulose surface using citric acid (CA) for three fibers: a 100% cellulose bleached soft Kraft pulp (e.g., creafill) and two natural fibers with similar composition but different fiber morphology, flax fiber and banana fiber. The process uses CA with a sodium hypophosphite (SHP) catalyst to chemically functionalize fiber surfaces, and the reaction mechanism was investigated through Fourier Transform Infrared Spectroscopy (FTIR), which suggested a grafting mechanism rather than a surface-based crosslinking between neighboring sites. Functionalized fibers were compounded into polylactic acid (PLA) at 20 wt.% to better understand how this functionalization might impact critical performance properties like thermal stability, crystallization, thermal mechanical properties, and water uptake of these composites. The study demonstrated varying levels of efficacy for the functionalization of cellulosic fibers with CA/SHP and the fiber with the most open microstructure, e.g., banana fiber, exhibited the largest change in its properties with a 38% reduction in water uptake compared to untreated banana fiber composites. Parallel evaluation of the functionalization process for different fibers demonstrates the importance of fiber morphology on surface modification and can enable their use in composites by demonstrating the efficacy of this potentially low-cost, low-toxicity method for reducing hygroscopicity and improving thermal stability. Full article

Woven fabric-reinforced laminates (FRLs) are widely used in flexible composite structures where fabric-adhesive bonding strongly influences load transfer, energy dissipation, and structural integrity. Recently, our team developed a yarn pullout in laminate (YPiL) test for bonding assessment in woven FRLs to overcome the limitations of the cumbersome T-peel test, with a focus on maximum pullout force. This study advanced the YPiL with an energy-based framework in which the force–displacement curve is interpreted using three zones: bonding, interfacial debonding, and drag friction/sliding associated with four metrics: maximum pullout force (F_max), pre-peak energy (E₁), energy to the slope-break point (E₂), and total pullout energy (E_total). A dataset of 187 specimens covering four plain-woven Kevlar structures and five fabric-to-adhesive weight ratios (r = 0.67–2.83) was analyzed using a numeric general linear model (GLM). The dominant factor was r, with F_max, E₁, E₂, and E_total all decreasing as r increased. The interaction between pullout yarn width and r ranked second in every model, confirming a stronger r effect in fabrics with wider pullout yarns. The energy-based metrics, particularly E_total, were more sensitive than F_max to structural and bonding differences, and the E_total model achieved R² = 0.94 with Root Mean Square Error (RMSE) = 12.42 mJ. Full article