Editor’s Choice Articles

This review investigates recent progress in the field of PLA-based conductive composites for 3D printing. First, it introduces PLA as a biodegradable thermoplastic polymer, describing its processing and recycling methods and highlighting its environmental advantages over conventional polymers. In order to evaluate its printability, PLA is briefly compared to other commonly used thermoplastics in additive manufacturing. The review then examines the incorporation of conductive fillers such as carbon black, carbon nanotubes, graphene, and metal particles into the PLA matrix, with a particular focus on the percolation threshold and its effect on conductivity. Critical challenges such as filler dispersion, agglomeration, and conductivity anisotropy are also highlighted. Recent results are summarized to identify promising formulations that combine improved electrical performance with acceptable mechanical integrity, while also emphasizing the structural and morphological characteristics that govern these properties. Finally, potential applications in the fields of electronics, biomedicine, energy, and electromagnetic shielding are discussed. From an overall perspective, the review highlights that while PLA-based conductive composites show great potential for sustainable functional materials, further progress is needed to improve reproducibility, optimize processing parameters, and ensure reliable large-scale applications. Full article

Multi-material structures have great potential in high-end fields such as aerospace and energy. Which integrate the advantages of various metals and meet the demands of complex working conditions. Among additive manufacturing technologies for multi-material structures, wire-based processes have become a research hotspot due to their high material utilization, low cost, and high efficiency. This article systematically reviews the progress of research on this technology. The working principles and characteristics of common heat sources (WAAM, LWAM, EBAM) are introduced. Furthermore, the advantages and limitations of these heat sources for manufacturing multi-material structures are critically analyzed. Moreover, various metal wire combination systems (such as steel/Ni, Al/steel, Ti/Al, and Cu/Ti, etc.) were reviewed, and the differences and influences of different wire feeding methods and directions were discussed. The review highlights research findings on microstructure regulation, interfacial bonding mechanisms, and the mechanical property optimization of polymetallic structures. The influence laws of critical process parameters on structural properties are also elucidated. The existing problems in the current research were pointed out, and the future development trends were prospected. Unlike previous articles, this review establishes a more comprehensive process–structure–performance framework through the discussion of integrated heat source characteristics, wire feeding systems, and interface adjustment strategies. It aims to provide references for promoting the development and engineering application of additive manufacturing technology for wire-based multi-metal structures. Full article

Polyimide composites represent a class of advanced materials with remarkable mechanical robustness and thermal stability, making them highly suitable for applications in extreme environments. Their unique ability to maintain performance under high temperatures and corrosive conditions, combined with a favorable strength-to-weight ratio, positions them as critical components in aerospace, electronics, and automotive systems. Several leading aerospace and electronics corporations have made significant investments in incorporating polyimide composites into their products, indicating the material’s transformative potential. This review paper provides an overview of mechanical and thermal behaviors of polyimide composites, summarizing recent developments and research trends. It examines the influence of various reinforcements, processing techniques, and composite architectures on material performance under mechanical loading and thermal stress. The paper synthesizes findings from experimental studies and modeling efforts to highlight the critical factors affecting strength, durability, and thermal stability. Discussion and recommendations regarding applications in aerospace, electronics, and other high-temperature environments are provided, emphasizing the challenges and opportunities presented by these advanced materials. This review adopts a broad scope to reflect the interdisciplinary nature of polyimide research. Due to gaps in literature, this work aims to provide a foundational overview that supports future, more specialized investigations. Full article

Foams, as a type of porous materials, have found broad functional and structural application in heat and sound insulation, the mitigation of mechanical vibrations and impacts, packaging, etc. This paper aims to comprehensively review recently developed biobased foams (BBFs) with a comparison with their counterparts—namely, synthetic polymer foams—in terms of their foaming methods, physical and mechanical properties, and broad applications. A brief introduction to general foams, polymeric foams, and BBFs is provided, followed by a comparison of the related foaming methods; physical, mechanical, and chemical properties; and current and prospective applications. Several main polymer foaming methods (e.g., physical, chemical, and mechanical foaming) and their unique features are further examined in detail. The structure-related properties of polymeric foams (e.g., mass density, thermal conductivity, and rate effects in mechanical responses) are discussed, and the fundamental linearly viscoelastic models are summarized to account for the simple rate effect in the mechanical moduli of polymeric foams under varying loading rates. Furthermore, specific focus is placed on the foaming processes and material properties of sustainable BBFs (e.g., soybean-based, corn-based, and starch-based foams) and their potential to substitute conventional synthetic polymer foams. The technical challenges in processing BBFs are discussed, and the most promising applications of BBFs are then considered. Full article

This review is focused on glass fibers and natural fibers, exploring their applications in vehicles and buildings and emphasizing their significance in promoting sustainability and enhancing performance across various industries. Glass fibers, or fiberglass, are lightweight, have high-strength (3000–4500 MPa) and a Young’s modulus range of 70–85 GPa, and are widely used in automotive, aerospace, construction, and marine applications due to their excellent mechanical properties, thermal conductivity of ~0.045 W/m·K, and resistance to fire and corrosion. On the other hand, natural fibers, derived from plants and animals, are increasingly recognized for their environmental benefits and potential in sustainable construction, offering advantages such as biodegradability, lower carbon footprints, and reduced energy consumption, with a sound absorption coefficient (SAC) range of 0.7–0.8 at frequencies above 2000 Hz and thermal conductivity range of 0.07–0.09 W/m·K. Notably, the integration of these materials in construction and automotive sectors reflects a growing trend towards sustainable practices, driven by the need to mitigate carbon emissions associated with traditional building materials and enhance fuel efficiency, as seen in hybrid composites achieving 44.9 dB acoustic insulation at 10,000 Hz and a thermal conductivity range of 0.05–0.06 W/m·K in applications such as the BMW i3 door panels. Natural fibers contribute to reducing reliance on fossil fuels, supporting a circular economy through the recycling of agricultural waste, while glass fibers are instrumental in creating lightweight composites for improved vehicle performance and structural integrity. However, both materials face distinct challenges. Glass fibers, while offering superior strength, are vulnerable to chemical degradation and can pose recycling difficulties due to the complex processes involved. On the other hand, natural fibers may experience moisture absorption, affecting their durability and mechanical properties, necessitating innovations to enhance their application in demanding environments. The ongoing research into optimizing the performance of both materials highlights their relevance in future sustainable engineering practices. In summary, this review underscores the growing importance of glass and natural fibers in addressing modern environmental challenges while also improving product performance. As industries increasingly prioritize sustainability, these materials are poised to play crucial roles in shaping the future of construction and transportation, driving innovations that align with ecological goals and consumer expectations. Full article

Three-dimensional concrete printing (3DCP) is an emerging technology that improves design flexibility and material efficiency in construction. However, widespread adoption of 3DCP requires overcoming key material challenges. These include controlling rheology for pumpability and buildability and achieving sufficient mechanical strength. This paper provides a comprehensive review of the application of nanoclays (NCs) as a key admixture to address these challenges. The effects of three primary NCs (attapulgite (ATT), bentonite (BEN), and sepiolite (SEP)) on the fresh- and hardened-state properties of printable mortars are systematically analyzed. This review summarize findings on how NCs enhanced thixotropy, yield stress, and cohesion, which are critical for shape retention and the successful printing of multilayered structures. Quantitative analysis reveals that optimized dosages of NCs can increase compressive strength by up to 34% and flexural strength by up to 20%. For enhancing rheology and printability, a dosage of approximately 0.5% by binder weight is often suggested for ATT and SEP. In contrast, BEN can be used at higher replacement levels (up to 20%) to also function as a supplementary cementitious material (SCM), though this significantly impacts workability. This review consolidates the current knowledge to provide a clear framework for selecting appropriate NCs and dosages to develop high-performance, reliable, and sustainable materials for 3DCP applications. Full article

Conductive composites are a flexible class of engineered materials that combine conductive fillers with an insulating matrix—usually made of ceramic, polymeric, or a hybrid material—to customize a system’s electrical performance. By providing tunable electrical properties in addition to benefits like low density, mechanical flexibility, and processability, these materials are intended to fill the gap between conventional insulators and conductors. The increasing need for advanced technologies, such as energy storage devices, sensors, flexible electronics, and biomedical interfaces, has significantly accelerated their development. The electrical characteristics of composite materials, including metallic, ceramic, polymeric, and nanostructured systems, are thoroughly examined in this review. The impact of various reinforcement phases—such as ceramic fillers, carbon-based nanomaterials, and metallic nanoparticles—on the electrical conductivity and dielectric behavior of composites is highlighted. In addition to conduction models like correlated barrier hopping and Debye relaxation, the study investigates mechanisms like percolation thresholds, interfacial polarization, and electron/hole mobility. Because of the creation of conductive pathways and improved charge transport, developments in nanocomposite engineering, especially with regard to graphene derivatives and silver nanoparticles, have shown notable improvements in electrical performance. This work covers the theoretical underpinnings and physical principles of conductivity and permittivity in composites, as well as experimental approaches, characterization methods (such as SEM, AFM, and impedance spectroscopy), and real-world applications in fields like biomedical devices, sensors, energy storage, and electronics. This review provides important insights for researchers who want to create and modify multifunctional composite materials with improved electrical properties by bridging basic theory with technological applications. Full article

Carbon fiber-reinforced plastics (CFRPs) offer excellent in-plane mechanical performance, but their relatively low interlaminar fracture toughness makes them vulnerable to delamination, particularly around intralaminar discontinuities such as resin-rich regions or fiber gaps. This study investigates the effectiveness of polyamide (PA) mesh inserts in improving interlaminar toughness and suppressing delamination in CFRP laminates with such features. Two PA mesh configurations were evaluated: a fully embedded continuous layer and a 20 mm cut mesh strip placed between continuous and discontinuous plies near critical regions. Fracture toughness tests showed that PA mesh insertion improved interlaminar toughness approximately 2.4-fold compared to neat CFRP, primarily due to a mechanical interlocking mechanism that disrupts crack propagation and enhances energy dissipation. Uniaxial tensile tests with digital image correlation revealed that while initial matrix cracking occurred at similar stress levels, the stress at which complete delamination occurred was approximately 60% higher in specimens with a 20 mm mesh and up to 92% higher in specimens with fully embedded mesh. The fully embedded mesh provided consistent delamination resistance across the laminate, while the 20 mm insert localized strain redistribution and preserved global mechanical performance. These findings demonstrate that PA mesh is an effective interleaving material for enhancing damage tolerance in CFRP laminates with internal discontinuities. Full article

Tissue-engineered scaffolds, particularly composite scaffolds composed of polymers combined with ceramics, bioactive glasses, or nanomaterials, play a vital role in regenerative medicine by providing structural and biological support for tissue repair. As scaffold designs grow increasingly complex, the need for non-invasive imaging modalities capable of monitoring scaffold integration, degradation, and tissue regeneration in real-time has become critical. This review summarizes current non-invasive imaging techniques used to evaluate tissue-engineered constructs, including optical methods such as near-infrared fluorescence imaging (NIR), optical coherence tomography (OCT), and photoacoustic imaging (PAI); magnetic resonance imaging (MRI); X-ray-based approaches like computed tomography (CT); and ultrasound-based modalities. It discusses the unique advantages and limitations of each modality. Finally, the review identifies major challenges—including limited imaging depth, resolution trade-offs, and regulatory hurdles—and proposes future directions to enhance translational readiness and clinical adoption of imaging-guided tissue engineering (TE). Emerging prospects such as multimodal platforms and artificial intelligence (AI) assisted image analysis hold promise for improving precision, scalability, and clinical relevance in scaffold monitoring. Full article

This study comprehensively compares the performance of two non-destructive testing (NDT) techniques—active thermography (AT) and digital shearography (DS)—for identifying various damage types in composite structures. Three distinct composite specimens were inspected: a carbon-fiber-reinforced polymer (CFRP) plate with flat-bottom holes, an aluminum honeycomb core sandwich plate with a circular skin-core disbond, and a CFRP plate with two low-energy impacts damage. The research highlights the significant role of post-processing methods in enhancing damage detectability. For AT, algorithms such as fast Fourier transform (FFT) for temperature phase extraction and principal component thermography (PCT) for identifying significant temperature components were employed, generally making anomalies brighter and easier to locate and size. For DS, a novel band-pass filtering approach applied to phase maps, followed by summing the filtered maps, remarkably improved the visualization and precision of damage-induced anomalies by suppressing background noise. Qualitative image-based comparisons revealed that DS consistently demonstrated superior performance. The sum of DS filtered phase maps provided more detailed and precise information regarding damage location and size compared to both pulsed thermography (PT) and lock-in thermography (LT) temperature phase and amplitude. Notably, DS effectively identified shallow flat-bottom holes and subtle imperfections that AT struggled to clearly resolve, and it provided a more comprehensive representation of the impacts damage location and extent. This enhanced capability of DS is attributed to the novel phase map filtering approach, which significantly improves damage identification compared to the thermogram post-processing methods used for AT. Full article

Carbon nanotubes (CNTs) and graphene nanoplatelets (GNPs) have attracted significant interest as hybrid reinforcements in epoxy (Ep) composites for enhancing mechanical performance in structural applications, such as aerospace and automotive. These 1D and 2D nanofillers possess exceptionally high aspect ratios and intrinsic mechanical properties, substantially improving composite stiffness and tensile strength. In this study, epoxy nanocomposites were fabricated with 0.1 wt.% and 0.3 wt.% of CNTs and GNPs individually, and with 1:1 CNT:GNP hybrid fillers at equivalent total loadings. Scanning electron microscopy of fracture surfaces confirmed that the CNTGNP hybrids dispersed uniformly, forming an interconnected nanostructured network. Notably, the 0.3 wt.% CNTGNP hybrid system exhibited minimal agglomeration and voids, preventing crack initiation and propagation. Mechanical testing revealed that the 0.3 wt.% CNTGNP/Ep composite achieved the highest tensile strength of approximately 84.5 MPa while maintaining a well-balanced stiffness profile (elastic modulus ≈ 4.62 GPa). The hybrid composite outperformed both due to its synergistic reinforcement mechanisms and superior dispersion despite containing only half the concentration of each nanofiller relative to the individual 0.3 wt.% CNT or GNP systems. In addition to mechanical performance, electrical conductivity analysis revealed that the 0.3 wt.% CNTGNP hybrid composite exhibited the highest conductivity of 0.025 S/m, surpassing the 0.3 wt.% CNT-only system (0.022 S/m), owing to forming a well-connected three-dimensional conductive network. The 0.1 wt.% CNT-only composite also showed enhanced conductivity (0.0004 S/m) due to better dispersion at lower filler loadings. These results highlight the dominant role of CNTs in charge transport and the effectiveness of hybrid networks in minimizing agglomeration. These findings demonstrate that CNTGNP hybrid fillers can deliver optimally balanced mechanical enhancement in epoxy matrices, offering a promising route for designing lightweight, high-performance structural composites. Further optimization of nanofiller dispersion and interfacial chemistry may yield even greater improvements. Full article

This study aimed to optimize the performance of pervious concrete (PC) while promoting sustainability using recycled concrete aggregates (RCAs), styrene butadiene rubber (SBR) waste, and silica fume (SF). The mixtures were developed using the Taguchi approach with four mix design factors, each at three levels: the water-to-binder ratio (w/b), RCA replacement percentage by weight of natural aggregates, the cement substitution rate with SF, and the SBR addition rate by binder mass. Thus, a total of nine mixes were prepared and tested for density, porosity, permeability, compressive strength, splitting tensile strength, abrasion resistance, and resistance to freezing and thawing. The results revealed that incorporating RCA and SBR decreased density and compressive strength but increased porosity and permeability. The performance of PC enhanced with SF addition and reduced w/b. TOPSIS was then employed to find the optimum mixture design proportions by considering multiple performance criteria. The results indicated that a high-performing sustainable PC mixture, with enhanced strength and durability characteristics, was formulated with a w/b ratio of 0.30, 25% RCA, 5% SF replacement, and 4% SBR addition. Full article

Conventional adhesively bonded joints, such as single-lap, curved-lap, wavy-lap, double-lap, stepped-lap, and scarf joints, are widely used for aerospace, automotive, and medical applications. These adhesively bonded joints exhibit different load transfer mechanisms and stress distributions within adhesive layers, which depend primarily on their geometries and mechanical properties of bonded materials. As such, joint geometry and material properties play a critical role in determining the capability of the joints to withstand high loads, resist fatigue, and absorb energy under impact loading. This paper investigates the effects of geometry and material dissimilarity on the performance of both conventional bonded and interlocking joints under tensile loading based on the information available in the literature. In addition, bonding and load transfer mechanisms were analysed in detail. It was found that stress concentration often occurs at free edges of the adhesive layer due to geometric discontinuities, while most of the load is carried by these regions rather than its centre. Sharp corners further intensify resulting stresses, thereby increasing the risk of joint failure. Adhesives typically resist shear loads better than peel loads, and stiffness mismatches between adherents induce an asymmetric stress distribution. Nonetheless, similar materials promote symmetric load sharing. Among conventional joints, scarf joints provide the most uniform load distribution. In interlocking joints such as dovetail, T-slot, gooseneck, and elliptical types, the outward bending of the female component under tension can lead to mechanical failure. Full article

This perspective explores the use of biochar, a carbon-rich material derived from biomass, as a sustainable solution for mitigating volatile organic compounds (VOCs) emitted during asphalt production and use. VOCs from asphalt contribute to ozone formation and harmful secondary organic aerosols (SOAs), which negatively impact air quality and public health. Biochar, with its high surface area and capacity to adsorb VOCs, provides an effective means of addressing these challenges. By tailoring biochar’s surface chemistry, it can efficiently capture VOCs, while also offering long-term carbon sequestration benefits. Additionally, biochar enhances the durability of asphalt, extending road lifespan and reducing maintenance needs, making it a promising material for sustainable infrastructure. Despite these promising benefits, several challenges remain. Variations in biochar properties, driven by differences in feedstock and production methods, can affect its performance in asphalt. Moreover, the integration of biochar into existing plant operations requires the further development of methods to streamline the process and ensure consistency in biochar’s quality and cost-effectiveness. Standardizing production methods and addressing logistical hurdles will be crucial for biochar’s widespread adoption. Research into improving its long-term stability in asphalt is also needed to ensure sustained efficacy over time. Overcoming these challenges will be essential for fully realizing biochar’s potential in sustainable infrastructure development Full article

During the machining of unidirectional carbon fiber-reinforced polymers (UD-CFRPs), their anisotropic characteristics and the complex cutting conditions often lead to defects such as delamination, burrs, and surface/subsurface damage. This study systematically investigates the effects of different fiber orientation angles (0°, 45°, 90°, and 135°) on cutting force, chip formation, stress distribution, and damage characteristics using a coupled macro–micro finite element model. The model successfully captures key microscopic failure mechanisms, such as fiber breakage, resin cracking, and fiber–matrix interface debonding, by integrating the anisotropic mechanical properties and heterogeneous microstructure of UD-CFRPs, thereby more realistically replicating the actual machining process. The cutting speed is kept constant at 480 mm/s. Experimental validation using T700S/J-133 laminates (with a 70% fiber volume fraction) shows that, on a macro scale, the cutting force varies non-monotonically with the fiber orientation angle, following the order of 0° < 45° < 135° < 90°. The experimental values are 24.8 N/mm < 35.8 N/mm < 36.4 N/mm < 44.1 N/mm, and the simulation values are 22.9 N/mm < 33.2 N/mm < 32.7 N/mm < 42.6 N/mm. The maximum values occur at 90° (44.1 N/mm, 42.6 N/mm), while the minimum values occur at 0° (24.8 N/mm, 22.9 N/mm). The chip morphology significantly changes with fiber orientation: 0° produces strip-shaped chips, 45° forms block-shaped chips, 90° results in particle-shaped chips, and 135° produces fragmented chips. On a micro scale, the microscopic morphology of the chips and the surface damage characteristics also exhibit gradient variations consistent with the experimental results. The developed model demonstrates high accuracy in predicting damage mechanisms and material removal behavior, providing a theoretical basis for optimizing CFRP machining parameters. Full article

Soft body armor (SBA) remains an essential component of first responder protection. However, most SBA design concepts do not adequately address the unique performance, morphological, and psychological needs of women as first responders. In this review, female-specific designs of ballistic-resistant panels, material systems, and SBA performance testing are critically examined. The paper also explores innovations in shaping and design techniques, including darting, dartless shape construction, modular assembly, and body scanning with CAD integration to create contoured and structurally stable panels with improved coverage, reduced bulk, and greater mobility. In addition, the review addresses broadly used and emerging dry textile fabrics and fiber-reinforced polymers, considering various innovations, such as 3D warp interlock weave, shear thickening fluid (STF) coating, nanomaterials, and smart composites that improve energy dissipation and impact tolerance without sacrificing flexibility. In addition, the paper also examines various emerging ballistic performance testing standards and their revisions to incorporate gender-specific standards and measures their ability to decrease trauma effects and maintain flexibility and practical protection. Finally, it identifies existing challenges and areas of future research, such as optimizing multi-layer systems, addressing fatigue behavior, and improving multi-angle and low-velocity impact performance while providing avenues for future sustainable, adaptive, and performance-optimized body armor. Full article

This review explores the latest developments in the study of friction, wear, and degradation mechanisms in the case of biocomposites, including either natural fibers or bio-based matrices or both, intended for marine applications. Biocomposites are increasingly favored, especially for their environmental benefits and sustainability potential. However, they often exhibit inferior mechanical properties compared to traditional composites, especially under demanding conditions. In marine environments, their performance is further challenged by factors such as high humidity, saltwater exposure, fluctuating temperatures, and biofouling. All of the above significantly impact their durability and functionality. This paper examines the performance and degradation characteristics of biocomposites subjected to seawater exposure, especially considering aspects such as friction, wear, and degradation. Additionally, it discusses the recent advancements in surface treatments and material formulations aimed at enhancing the resistance of biocomposites under marine conditions. The review also highlights the critical role of testing methodologies in simulating real-life conditions to better predict the material behavior. By providing a detailed analysis of current research and emerging trends, this paper aims to guide future studies and technological innovations in the field of marine biocomposites. Full article

In recent years, industries have prioritized low-cost, biodegradable, long-lasting materials. Businesses are focusing on composite materials using the world’s abundant natural fibers. Researchers and academics are considering using plant and animal fibers as polymer composite reinforcement to enhance their sustainability. In this context, finding new plant fibers for polymer composite reinforcement is important. This study hybridizes jute and acacia fibers using compression molding and changing epoxy fiber weight percentages to create novel polymer composites. This article examines how fiber orientation affects mechanical and morphological analysis for manufactured jute–acacia hybrid composites. The composite had the highest tensile strength of 33.59 MPa, a flexural strength of 66.42 MPa, an impact strength of 3.22 J/m, and a hardness of 85 Shore D. The scanning electron microscope (SEM) showed that alkali treatment filled microscopic cracks, gaps, and pores in natural fiber composites, improving their tensile, flexural, and impact strength. Sandwich composites had better mechanical and morphological qualities than two-layer stack patterned composites. The research findings of jute–acacia fiber-based composites can be applied in various industrial applications. Full article

Chitosan–hydroxyapatite (CS-HAp) biocomposites, combining the biocompatibility and bioactivity of chitosan with the osteoconductive properties of hydroxyapatite, are emerging as promising candidates for tissue engineering applications. These materials consistently exhibit excellent cytocompatibility, with cell viability rates greater than 95% in MTT and Neutral Red Uptake assays, and minimal cytotoxicity, as demonstrated by low levels of cell death in DAPI and Trypan blue staining. More importantly, CS-HAp biocomposites modulate the immune environment by enhancing the expression of anti-inflammatory cytokines (IL-10 and IL-4) and the pro-inflammatory cytokine TGF-β, while avoiding significant increases in TNF-α, IL-6, or NF-κB expression in fibroblast cells exposed to HAC and HACF scaffolds. In an in vivo dermatitis model, these biocomposites reduced mast cell counts and plasma histamine levels and significantly decreased pro-inflammatory cytokines (TNF-α, IL-1β, IL-6), JAK1/3, VEGF, and AnxA1 levels. Structurally, HACF scaffolds demonstrated larger average pore sizes (95 µm) compared to HAC scaffolds (74 µm), with porosities of 77.37 ± 2.4% and 65.26 ± 3.1%, respectively. These materials exhibited high swelling ability, equilibrium water content, and controlled degradation over a week in culture media. In addition to their immunomodulatory effects, CS-HAp composites promote essential cellular activities, such as attachment, proliferation, and differentiation, thereby supporting tissue integration and healing. Despite these promising findings, significant gaps remain in understanding the underlying mechanisms of immune modulation by CS-HAp biocomposites, and formulation-dependent variability raises concerns about reproducibility and clinical application. Therefore, a comprehensive review is essential to consolidate existing data, identify key knowledge gaps, and standardize the design of CS/HAp composites for broader clinical use, particularly in immunomodulatory and regenerative medicine contexts. Full article

Alkali-activated materials, as a low-carbon cementitious material, are widely known for their excellent durability and mechanical properties. In recent years, the modification of alkali-activated materials using biochar has gradually attracted attention. Fibrous biochar has a highly porous structure and large specific surface area, which can effectively adsorb alkaline ions in alkali-activated materials, thereby improving their pore structure and density. Additionally, the surface of the biochar contains abundant functional groups and chemically reactive sites. These can interact with the active components in alkali-activated materials, forming stable composite phases. This interaction further enhances the material’s mechanical strength and durability. Moreover, the incorporation of biochar endows alkali-activated materials with special adsorption capabilities and environmental remediation functions. For instance, they can adsorb heavy metal ions and organic pollutants from water, offering significant environmental benefits. However, research on biochar-modified alkali-activated materials is still in the exploratory phase. There are several challenges, such as the unclear mechanisms of how biochar preparation conditions and performance parameters affect the modification outcomes, and the need for further investigation into the compatibility and long-term stability of biochar with alkali-activated materials. Future research should focus on these issues to promote the widespread application of biochar-modified alkali-activated materials. Full article

Three-dimensional concrete printing (3DCP) represents a paradigm shift in construction technology, enabling the automated, formwork-free fabrication of intricate geometries. Despite its rapid growth, successful implementation remains dependent on the precise control of material rheology and printing parameters. This review critically analyzes the foundational rheological properties of static yield stress, dynamic yield stress, plastic viscosity, and thixotropy and their influence on three core printability attributes, i.e., pumpability, extrudability, and buildability. Furthermore, it explores the role of critical process parameters, such as print speed, nozzle dimensions, layer deposition intervals, and standoff distance, in shaping interlayer bonding and structural integrity. Special emphasis is given to modeling frameworks by Suiker, Roussel, and Kruger, which provide robust tools for evaluating structural stability under plastic yield and elastic buckling conditions. The integration of these rheological and process-based insights offers a comprehensive roadmap for optimizing the performance, quality, and scalability of 3DCP. Full article

Fused Deposition Modeling (FDM) has evolved from a rapid prototyping technique to an established manufacturing process for various industrial applications, including aerospace, robotics, biomedical engineering, and food production. Despite its versatility, the surface quality and dimensional accuracy of FDM-printed parts remain significant challenges, limiting their applicability in high-performance and precision-driven industries. Some of the primary limitations of FDM are volumetric error, shape deviation, and surface roughness, which directly affect the mechanical properties and functional performance of printed components. Post-processing techniques are available to mitigate these problems. Among the available post-processing techniques, CNC machining has emerged as a viable solution for improving the surface finish and dimensional precision of FDM parts. The integration of subtractive CNC machining with additive FDM printing enables the development of hybrid manufacturing strategies, leveraging the design freedom of 3D printing while ensuring superior surface quality. This paper presents a comprehensive review of recent studies on CNC post-processing of FDM-printed parts, analyzing its impact on surface roughness, dimensional accuracy, and material properties. Additionally, key process parameters influencing the effectiveness of CNC machining are discussed. Full article

This review presents a comprehensive analysis of polypropylene (PP) fibre incorporation in three-dimensional printed concrete (3DPC), focusing on the material behaviour in both fresh and hardened states. PP fibres play a critical role in improving rheological properties such as buildability, flowability, and extrudability. While increased fibre content enhances interlayer bonding and shape retention through the fibre bridging mechanism, it also raises yield stress and viscosity, which may compromise extrudability. In the hardened state, PP fibres contribute to improvements in compressive and flexural strength up to an optimal dosage, beyond which performance may decline due to fibre clustering and reduced packing density. When aligned with the printing direction, fibres are particularly effective in mitigating shrinkage-induced cracking by redistributing internal tensile stress. However, their inclusion can lead to a slight increase in porosity and promote mechanical anisotropy. This review also discusses mix design parameters, fibre characteristics, and experimental protocols, while identifying key research gaps including the lack of standardized testing methods, limited understanding of fibre orientation effects, and insufficient exploration of hybrid fibre systems. Based on the synthesis of reported studies, optimal print quality and structural consistency have been associated with the use of 6 mm long fibres, nozzle diameters of 4 to 6 mm, and printing speeds ranging from 40 to 60 mm/s. Overall, PP fibre reinforcement shows strong potential for enhancing the structural integrity and dimensional stability of 3D-printed concrete, while emphasizing the need for further studies to optimize its use in practice. Full article

Polymer concrete (PC) is recognized for its lightweight nature, wear resistance, and rapid curing, making it well-suited for the repair of deteriorated infrastructure. This research critically addresses the challenge of enhancing overlay adhesion to compromised substrates by uniquely evaluating the role of pristine versus functionalized multi-walled carbon nanotubes (MWCNTs) in improving polymer concrete (PC) bond strength, particularly on concrete deteriorated by sulfate attack. PC mixtures containing varying concentrations of MWCNTs (0%, 0.25%, and 0.5% by weight) were prepared and tested for their mechanical properties, including compressive strength, modulus of rupture, and pull-off strength. Pull-off tests were conducted to assess the bond between PC overlays and Portland cement concrete (PCC) substrates. To examine the effects of substrate deterioration, PCC specimens were cured under two conditions: standard and sulfate-exposed environments. The results showed that neat polymer concrete (PC-Neat) achieved a high average pull-off strength of 2.82 MPa under normal conditions. Incorporating 0.25% pristine MWCNTs (PC-P25) significantly reduced the bond strength to 0.039 MPa. In contrast, improved performance was observed with functionalized MWCNTs. The addition of 0.5% COOH-functionalized MWCNTs (PC-FC50) yielded a pull-off strength of 2.22 MPa under normal conditions and 1.65 MPa in sulfate environments. Notably, under sulfate exposure, functionalized MWCNTs enhanced the bond strength by up to 15% compared to PC-Neat, highlighting their potential in aggressive environments. This distinct improvement in bond strength presents a significant finding, demonstrating a novel pathway for developing more resilient repair materials for infrastructure exposed to aggressive chemical environments. Full article

This study investigates the mechanical performance of epoxy resin composites reinforced with silane coupling agent-modified Al₂O₃ nanoparticles (m-Nano-Al₂O₃/epoxy). Three silane coupling agents (KH550, KH560, and KH570) were employed to functionalize the Al₂O₃ nanoparticles, and their chemical structures were confirmed via Fourier transform infrared spectroscopy (FTIR). The microstructure and elemental distribution of the composites were characterized using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). Mechanical properties, including tensile strength and hardness, were evaluated using a universal testing machine and a Rockwell hardness tester, respectively. The incorporation of m-Nano-Al₂O₃ significantly enhances the mechanical properties of the epoxy matrix. Compared to pure epoxy, the KH570-modified composites demonstrate a remarkable 49.1% improvement in tensile strength and an 8.8% increase in hardness. These findings highlight the potential of surface-modified Al₂O₃ nanoparticles as effective reinforcements for high-performance epoxy composites. Full article

Biocomposites are defined as eco-friendly materials from an environmental point of view. Because of the importance of this class of materials, their study is important, especially in moist and heated conditions. In this sense, this work aims to evaluate the transient behavior of moisture absorption and mechanical performance of biocomposites composed of a matrix of high-density biopolyethylene (originated from ethanol produced from sugarcane) filled with curauá vegetable fiber and organophilic montmorillonite clay. For this purpose, dry biocomposites filled with organophilic montmorillonite clay and curauá fiber (1, 3, and 5 wt.%) were prepared using a hand lay-up technique and subjected to moisture absorption and mechanical (flexural and impact tests) characterizations at different times. The experiments were carried out at water bath temperatures of 30 °C and 70 °C. The results have proven the strong influence of chemical composition and temperature on the moisture absorption behavior of biocomposites across time. For a higher percentage of reinforcement on the polymeric matrix, a higher moisture migration rate was verified, reaching a higher hygroscopic equilibrium condition at 16.9% for 5 wt.% of curauá fiber and 10.25% for 5 wt.% of montmorillonite clay particles. In contrast, the mechanical properties of all of the biocomposites were strongly reduced with an increasing moisture content, especially at higher fiber content and water bath temperature conditions. The innovative aspects of this research are related to the study of a new material and its transient mechanical behavior in dry and wet conditions. Full article

An electrochemically active and promising binary composite that is made up of titanium-based MXene (Ti₃C₂T_x) and rGO is developed to simultaneously detect the Cd²⁺ and Cu²⁺, in water. XRD, FTIR, Raman, XPS, FESEM, elemental mapping, and EDX analysis affirmed the successful formation of the Ti₃C₂T_x-rGO composite. The produced Ti₃C₂T_x-rGO electrode exhibited a homogeneous rGO sheet covering the Ti₃C₂T_x MXene plates with all the detailed Ti2p, C1s, and O1s XPS peaks. The high-performance Ti₃C₂T_x-rGO composite was successfully tested for the Cd²⁺ and Cu²⁺ ions via differential pulse voltammetry (DPV), altering the pH, concentration, and the real water sample’s quality. The electrochemical performances revealed that the proposed Ti₃C₂T_x-rGO composite depicted excellent detection and quantification limits (LOD and LOQ) for both Cd²⁺ (LOD = 0.31 nM, LOQ = 1.02 nM) and Cu²⁺ (LOD = 0.18 nM, LOQ = 0.62 nM) ions, where the result is highly comparable with the reported literature. The Ti₃C₂T_x-rGO was proven highly sensitive towards Cd²⁺ (0.345 μMμA⁻¹) and Cu²⁺ (0.575 μMμA⁻¹) with great repeatability and reproducibility properties. The Ti₃C₂T_x-rGO electrode also exhibited excellent stability over four weeks with a retention of 97.86% and 98.01% for Cd²⁺ and Cu²⁺, respectively. This simple modification of Ti₃C₂T_x with rGO can potentially be advantageous in the development of highly sensitive electrochemical sensors for the simultaneous detection of heavy metal ions. Full article

In this research paper, the ±45 biaxially oriented woven flax and its hybrid flax/carbon composite laminates are manufactured by the vacuum bag technique using vinyl ester as the resin binder and the samples are characterized to evaluate their tensile, flexural and impact properties. Combining natural fibers with conventional materials typically creates a hybrid composite that shows optimal mechanical properties with partial sustainability. The flax/carbon variant exhibited superior tensile strength values of 383.88 MPa and 32.60 GPa, which are about 3.5 and 2.7 times higher than the flax composites, their flexural strengths are around 415.57 MPa and 25.02 GPa, respectively, and they have an impact resistance of 12.67 J. Full article

Within the context of the increasing use of additive manufacturing techniques and the corresponding need to understand the behavior of 3D-printed materials, this paper analyzes the fracture behavior of additively manufactured carbon fiber reinforced (10 wt.%) acrylonitrile-styrene-acrylate (ASA) with three different raster orientations (90/0, 45/−45, 30/−60). The analyzed material (ASA-CF10) combines the remarkable resistance to weathering agents typical of ASA with the enhanced mechanical properties resulting from the inclusion of carbon fiber reinforcement. The analysis is performed on single-edge-notched bending (SENB) specimens containing different types of defects, from cracks to U-notches with notch radii of 0.5 mm, 1 mm and 2 mm. When compared to non-reinforced ASA, the fracture resistance is noticeably higher (nearly double) for the reinforced material in all raster orientations. The notch effect, defined as the increase in the fracture resistance when the notch radius increases, is analyzed through the Theory of Critical Distances (TCD), and it is mostly higher in the reinforced material than in the pristine polymer. These observations are supported by Scanning Electron Microscopy analyses. Full article

The growing demand for sustainable composites has increased interest in natural fiber reinforcements as alternatives to synthetic materials. This study evaluates the bending properties of sandwich structures with flax fibers and 3D-printed lightweight foaming PLA cores compared to conventional designs using glass fibers and traditional cores. Three-point bending tests (EN 310) and density profile analysis showed that, despite its lower density, the 3D-printed foaming PLA core achieved a modulus of elasticity of 2269.19 MPa and a bending strength of 31.46 MPa, demonstrating its potential for lightweight applications. However, natural fibers influenced resin absorption, affecting core saturation compared to glass fibers. The use of bio-based epoxy and foaming PLA contributes to a lower environmental footprint, while 3D printing enables precise material optimization. These findings confirm that 3D-printed cores offer a competitive and sustainable alternative, with future research focusing on further optimization of internal structure to enhance mechanical performance. Full article

Polylactic acid (PLA) is widely used in 3D printing for its biodegradability and ease of processing, but its brittleness and low impact strength often restrict its suitability for more demanding applications. The novelty of this work lies in its direct comparative approach: we systematically reinforce PLA with two distinct agricultural residues—rice husk and rice straw—under identical conditions to clarify how particle size (100 vs. 200 mesh) and NaOH surface treatment affect mechanical performance. Composite filaments containing 5–20 wt% of each fiber were produced and 3D-printed into standard tensile and flexural specimens. The results show that, although tensile strength declines at higher fiber loadings, tensile modulus, flexural strength, and impact resistance can improve significantly—particularly with 200-mesh and NaOH-treated fibers. Fourier transform infrared (FTIR) spectroscopy confirms partial lignin removal and enhanced cellulose exposure, improving fiber–matrix adhesion, which is corroborated by scanning electron microscopy (SEM) observations of reduced voids. This comparative study demonstrates that surface-treated, finely milled rice husk and rice straw significantly enhance PLA’s stiffness and toughness, offering a sustainable alternative to conventional polymeric additives. The insights gained here on fiber content, chemical treatment, and 3D printing parameters can guide the broader industrial adoption of these natural fiber-reinforced PLA composites, particularly in automotive and construction applications that require lightweight, durable materials. Full article

This paper reviews the performance of low-grade calcined clay as a partial substitute for Portland cement in concrete, emphasizing its potential to enhance sustainability in construction. Thermal treatment of naturally occurring clays at optimal temperatures produces amorphous siliceous materials with pozzolanic properties. Clays with substantial kaolinite content exhibit significant pozzolanic reactivity when calcined at temperatures between 700 and 850 °C, with effective firing possible up to 1000 °C. Research shows that replacing Portland cement with calcined clays improves the mechanical and durability properties of concrete, with replacement levels ranging from 10% to 60%, depending on factors such as chemical composition, mineralogy, and reactivity. This paper synthesizes recent findings on low-grade calcined clays with 60–80% purity, which are more abundant, cost-effective, and easier to produce, particularly in developing regions lacking the resources and technology to process high-purity clays (>95% purity). Key aspects explored include calcination methods, optimal firing temperatures, and their effects on particle size distribution and pozzolanic activity. This study also examines the impact of low-grade calcined clay on fresh and hardened concrete and the durability properties of concrete and mortar. By providing a comprehensive analysis, this review highlights the potential of low-grade calcined clays to contribute to more sustainable and durable concrete production, emphasizing the need to optimize calcination processes and fully harness their pozzolanic properties. Full article

With the rapid expansion of electronic information technology and rising material safety needs, the creation of composite materials that perform both electromagnetic microwave absorption (EMA) and flame retardancy has arisen as a materials science research hotspot. Metal–organic frameworks (MOFs) have great potential for developing novel multifunctional composite materials due to their unique structural characteristics and customizable functions. This work presents a comprehensive assessment of the most recent research findings on MOF-based EMA-flame retardant dual-functional composites. The fundamental mechanisms of EMA and flame retardancy are covered, including dielectric loss, magnetic loss, and both condensed-phase and gas-phase flame retardancy mechanisms. The development of composites based on Fe-MOF, Co-MOF, Ni-MOF, and polymetallic MOF in terms of EMA and flame retardancy is highlighted. These materials offer exceptional EMA performance and strong flame retardancy effects thanks to their unique structural designs and component regulations. In addition, some materials have great infrared stealth, thermal insulation, hydrophobic, and mechanical qualities. Ultimately, the problems of MOF-based dual-functional composites and their development possibilities are reviewed, giving valuable references for the development of new multifunctional composite materials. Full article

As an important neurotransmitter, the concentration of dopamine (DA) reflects certain physiological conditions and DA-related diseases. Rapid monitoring of DA levels is of great significance in regulating body health. However, regular electrochemical DA sensors suffer from poor sensitivity, low selectivity and interference immunity, as well as a complex preparation process. Herein, we developed an accessible and cost-effective electrochemical sensor with a copper indium selenide (CuInSe₂ or CIS)-modified screen-printed carbon electrode for DA discrimination. This DA sensor was developed using a facile one-step hydrothermal method without high-temperature quenching. Benefitting from the inherent merits of CIS and the conversion of Cu²⁺ and Cu⁺ during the catalytic reaction, the sensor attained both excellent sensitivity (2.511 μA·µM⁻¹·cm⁻¹) and selectivity among multiple substances interfering with DA. This work demonstrates the potential to improve the analytical performance of traditional electrochemical sensors. Full article

The use of 3D printing is expanding in manufacturing wind turbine blades for renewable energy. This study examines the relationship between geometric parameters, mechanical strength, and aerodynamic performance in blades made from short carbon fiber-reinforced PLA (SCFR-PLA) composites. To achieve this, it includes a comparative evaluation of innovative blade designs and materials, aiming to enhance both the energy efficiency and mechanical durability of horizontal axis wind turbines (HAWTs). The numerical model of the wind turbine blade is validated against experimental results, which employed a NACA geometry and ABS polymer. Building upon this validation, a design of experiments (DOE) analysis is employed to explore the influence of fused filament fabrication (FFF) parameters on the mechanical properties of SCFR-PLA composites. A novel blade design, referred to as HAWTSav, is numerically evaluated using 3D-printed SCFR-PLA composites. Numerical simulations are conducted to evaluate the energy efficiency and structural integrity of the HAWTSav blade. A comparative analysis is then performed, contrasting the performance of the conventional NACA blade in ABS with the HAWTSav blade in SCFR-PLA composites. The findings highlight the potential of SCFR-PLA composites in the development of efficient and durable wind turbine blades, highlighting their applicability, particularly in small-scale wind energy systems. Full article

Natural fiber composites have gained significant attention in recent years due to their environmental benefits and unique mechanical properties. These materials combine natural fibers with polymer matrices to create sustainable alternatives to traditional synthetic composites. In addition to natural fiber reinforcement, the usage of recycled aggregates in concrete has been proposed as a remedy to combat the rapidly increasing amount of construction and demolition waste in recent years. However, the accurate prediction of the structural performance metrics, such as tensile strength, remains a challenge for concrete composites reinforced with natural fibers and containing recycled aggregates. This study aims to develop predictive models of natural-fiber-reinforced recycled aggregate concrete based on experimental results collected from the literature. The models have been trained on a dataset consisting of 482 data points. Each data point consists of the amounts of cement, fine and coarse aggregate, water-to-binder ratio, percentages of recycled coarse aggregate and natural fiber, and the fiber length. The output feature of the dataset is the splitting tensile strength of the concrete. Extreme gradient boosting (XGBoost), light gradient boosting machine (LightGBM) and extra trees regressor models were trained to predict the tensile strength of the specimens. For optimum performance, the hyperparameters of these models were optimized using the blended search strategy (BlendSearch) and cost-related frugal optimization (CFO). The tensile strength could be predicted with a coefficient of determination greater than 0.95 by the XGBoost model. To make the predictive models accessible, an online graphical user interface was also made available on the Streamlit platform. A feature importance analysis was carried out using the Shapley additive explanations (SHAP) approach. Full article

The objective of this study is to demonstrate the feasibility of producing SiC–aluminum composites by the binder jetting 3D printing of SiC preforms and spontaneous infiltration by aluminum. SiC preforms fabricated using binder jetting 3D printing were subjected to several post-processing steps (including curing, depowdering, debinding, and sintering). Sintering was conducted at 1700 °C, and aluminum infiltrating was conducted at 1000 °C, with both carried out in a controlled nitrogen environment under a pressure of 25 psi. The bulk density of the sintered SiC preforms was increased by 14% after infiltration. X-ray diffraction and energy-dispersive X-ray spectroscopy confirmed the presence of aluminum in the SiC matrix. This paper is the first to report fabricating SiC–aluminum composites by binder jetting and infiltrating, providing a new approach to producing these composites with potential applications in the aerospace and automotive industries. Full article

Since composite materials are light and corrosion-resistant, they have replaced many traditional materials in the aviation and marine industries. Composite materials have the advantages of a much higher strength–weight ratio, lower maintenance requirements, and the ability to form complex shapes, such as bodies, compared to carbon steel. In this study, the mechanical properties of glass fiber reinforced (GFRP) and carbon fiber reinforced (CFRP) composite materials were investigated in marine applications in which composite materials had been used. In this study, 0/90 oriented twill weave eight-ply GFRP and eight-ply CFRP composite materials were used, incorporating the hand lay-up method and hot-pressing method. Seawater was taken from the Aegean Sea, Izmir Province (Balçova/İnciraltı), and had an average temperature of 22.43 °C. This seawater was kept in different containers for 30 days and 60 days (a total of 1440 h of keeping in seawater) with the intent to test the GFRP and CFRP composite samples separately. The produced CFRP and GFRP sheets were then cut with a wet (circular) saw in accordance with the standard procedure in the Composite Research and Testing Laboratory of the Dokuz Eylul University Department of Mechanical Engineering. Moisture retention percentages and Charpy impact tests were carried out. Then, three-point bending tests were carried out according to TS EN ISO 14125. The damage in the material was examined using a ZEISS Stereo Discovery.V12 imaging microscope (Oberkochen, Germany). The mechanical properties of CFRP- and GFRP-reinforced composite samples before and after aging were investigated using the Charpy impact test and three-point bending test. Then, the effects of the seawater environment on the mechanical properties of the CFRP and GFRP composite materials were evaluated by comparing the results. The aim was to better understand what kind of damage would occur in GFRP and CFRP composite materials given the effects of seawater and at what stages changes would occur in the mechanical properties of these materials. Moisture retention rates (%) in the tested samples after the Charpy impact test were 2.56% in GFRP and 0.47% in CFRP after 30 days. In the tested samples after the three-point bending test, these values were 1.41% in GFRP and 0.31% in CFRP after 30 days. Subsequent to the Charpy impact tests, the fracture toughness values of the CFRP samples tested at the 30 J impact energy level before aging in seawater conditions for 30 days or 60 days were found to be increased by 15.79% and 21.08%, respectively. The fracture toughness values of the GFRP tested at the 30 J impact energy level in dry conditions and kept in seawater for 30 days or 60 days were found to be 27.69% and 29.23%, respectively. The energy absorbed during the impact tests by the GFRP samples was higher than in the CFRP samples. This showed that the GFRP samples were more brittle. Subsequent to the three-point bending tests, the CFRP composite samples kept in seawater for periods of 30 days and 60 days showed changes in the modulus of elasticity of 7.48% and 7.46%, respectively, compared to the dry samples. The GFRP composite samples kept in seawater for periods of 30 days and 60 days showed changes in the modulus of elasticity of 7.015% and 11.53%, respectively, compared to the dry samples. The change in the modulus of elasticity was less in the CFRP samples than in GFRP. All of these results showed that the mechanical properties of CFRP were better than those of GFRP. Full article

Bio-based composites offer potential environmental benefits over fossil-based materials, but limited research exists on manufacturing processes with varying material combinations. This study performs a cradle-to-grave Life Cycle Assessment of five composite types to evaluate the role of fully and partially bio-based composites, focusing on the manufacturing stage. The composite materials include glass or flax fiber-based reinforcements embedded in polymer matrices based on a fossil epoxy, a partially bio-based epoxy, or epoxidized linseed oil, fabricated using vacuum-assisted resin infusion. Flax fibers in a partially bio-based epoxy achieve the lowest environmental impacts in most categories when assessed at equal geometry. Glass fiber composites exhibit a higher fiber volume content and material properties and thus demonstrate competitive environmental performance at equal absolute and normalized tensile strength. Composites using epoxidized linseed oil are the least advantageous, with the manufacturing stage contributing a majority of the environmental impacts due to their comparatively long curing times. These results are based on methodological choices and technical constraints which are discussed together with benchmarking against previous studies. While partially bio-based materials can provide a middle ground for enhancing composite environmental performance, the further optimization of bio-based material functionality regarding material properties and processability is pivotal to exploit the full potential of bio-based composites. Full article

The environment presently contains greater amounts of heavy metals due to human activities, causing toxicity, mutagenicity, and carcinogenicity. This study evaluated a chitosan (CS) composite material combined with 1,3-dichlorocetone to extract heavy metals from affected waters, integrating experimental and computational analyses. The synthesis of chitosan, obtained from shrimp waste chitin, reached a yield of 85%. FTIR analysis confirmed key functional groups (NH₂ and OH), and XRD showed high crystallinity with peaks at 2θ = 8° and 20°. The physicochemical properties evaluated included a moisture content of 7.3%, ash content of 2.4%, and a deacetylation degree of 73%, consistent with commercial standards. Chitosan exhibited significant solubility in 1.5% acetic acid, moderate solubility in water, and insolubility in NaOH, demonstrating its versatility for environmental applications. In adsorption tests, heavy metal concentrations were reduced by CS derivatives, with Cr and Pb dropping to 0.03 mg/L, and Cu and Zn to less than 0.05 mg/L. CS cross-linked with 1,3-dichlorocetone proved the most efficient, outperforming other derivatives such as glutaraldehyde and epichlorohydrin. Computational analysis evaluated key molecular interactions using DFT and the B3LYP/LANLD2Z method. The band gap energies (HOMO–LUMO) decreased to 0.09753 eV for Zn and 0.01485 eV for Pb, indicating high affinity, while Cd showed lower interaction (0.11076 eV). The total dipole moment increased remarkably for Zn (14.693 Debye) and Pb (7.449 Debye), in contrast to Cd (4.515 Debye). Other descriptors, such as chemical hardness (η), reflected a higher reactivity for Zn (0.04877 eV) and Pb (0.00743 eV), which favors adsorption. The correlation between experimental and computational results validates the efficiency and selectivity of CS/1,3-dichlorocetone for removing heavy metals, especially Pb and Zn. This material stands out for its adsorbent capacity, sustainability, and economic viability, positioning it as a promising solution for wastewater remediation. Full article

In order to achieve hydrophobic properties in textiles, per- and poly-fluoroalkyl substances (PFAS) are often used. These chemicals represent a class of synthetic compounds that have found wide application in numerous industries because of their advantageous properties, such as hydrophobicity, lipophobicity, chemical inertness, remarkable lubricity, non-stickiness, exceptional fire resistance, resistance to high temperatures, and high resistance to various weathering conditions. However, recent scientific research has demonstrated that these compounds possess persistent, accumulative, and highly mobile properties that make them an environmental hazard. Since the toxicity of PFAS is now recognized, ongoing research has been initiated to explore new substitutes. This comprehensive review focuses on the exploration of natural-based hydrophobic coatings for natural textiles, which include materials such as natural waxes, fatty acids, naturally occurring polymeric compounds (including proteins, carbohydrates, complex aromatic polymers, and polymers like natural rubber), and other naturally occurring substances. The role of each compound in the hydrophobic coating is also highlighted. This review aims to evaluate the potential of natural compounds as viable replacements for PFAS, focusing on their efficiency and durability. Full article

This study investigates the fresh state and hardened state mechanical and durability properties of 3D-printed concrete. The mechanical tests focused on its anisotropic behavior in response to different load orientations. Compressive, flexural, and splitting tensile strengths were evaluated relative to the print layers orientation. Results showed that compressive strength varied significantly, achieving 85% of cast sample strength when the load was applied parallel to the print layers ([u] direction), 71% when the load was applied perpendicular to the print object’s side plane ([v] direction), while only reaching 59% when applied perpendicular to the top plane ([w] direction). Similar trends were observed for flexural strength, with average values reaching 75% of cast sample strength when the load was applied perpendicular to the print layers ([v.u] and [w.u] directions), but decreasing to 53% when the load was applied parallel to print layers ([u.w] direction), underscoring the weaknesses at interlayer interfaces. The splitting tensile strength remained relatively consistent across print orientations, reaching 90% of the cast sample strength. Durability assessment tests revealed that 3D-printed concrete exhibits reduced resistance to environmental factors, particularly at the layer interfaces where the cold joint was formed, which are prone to moisture penetration and crack formation. These findings contribute valuable insights into the mechanical and durability properties of 3D-printed concrete, emphasizing the importance of print orientation and interlayer bonding in its performance. This understanding helps guide the optimal use of 3D-printed elements in real-life applications by aligning load or exposure to environmental factors with the material’s strength and durability characteristics. Full article

The construction sector’s reliance on traditional cement significantly contributes to CO₂ emissions, underscoring the urgent need for sustainable alternatives. This study investigates fine (0–4 mm), rounded, uncoated, porous-surfaced lightweight expanded clay aggregate (LECA)-based geopolymers, which combine the low-carbon benefits of geopolymers with LECA’s lightweight and insulating properties. Geopolymers were synthesized using lignite-rich fly ash with varying ratios of LECA to aggregate. Mechanical testing revealed that the reference mixture without LECA (REF-GEO) achieved the highest compressive strength of 37.89 ± 0.75 MPa and flexural strength of 7.62 ± 0.11 MPa, while complete substitution of the aggregate with LECA (LECA-100%) reduced the compressive strength to 17.31 ± 0.88 MPa and flexural strength to 3.41 ± 0.11 MPa. The density of the samples decreased from 2.06 g/cm³ for REF-GEO to 1.31 g/cm³ for LECA-100%, and thermal conductivity dropped significantly from 1.15 ± 0.07 W/mK to 0.38 ± 0.01 W/mK. Microstructural analysis using XRD and SEM-EDX highlighted changes in the material’s internal structure and the increase in porosity with higher LECA content. Water vapor permeability increases over time, particularly in samples with higher LECA content. These findings suggest that LECA-based geopolymers are suitable for low-load or non-structural elements. They are ideal for sustainable, energy-efficient construction that requires lightweight, insulating, and breathable materials. Full article

TiO₂ is widely utilized as an excellent photocatalyst in energy production. However, its rapid electron and hole recombination confers poor photocatalytic activity. Cocatalysts are essential for increasing photocatalytic efficacy by introducing improved electron transmission and enlarging the active site. Herein, the photocatalytic degradation of aqueous methanol solution to generate hydrogen was studied with the simultaneous in situ deposition of metals (M = Ag, Cu, Ni, Pd, and Pt) on the TiO₂ surface. Adding methanol to water and incorporating a bimetallic cocatalyst enhanced hydrogen production by reducing the electron–hole pair recombination. The studied metal ions could be reduced by the conduction band electrons of TiO₂ for the in situ simultaneous deposition of metal. The larger work function value of the studied metals favored the Schottky junction formation, which contributed to increasing photocatalytic efficiency. Among these simultaneous metal-deposited photocatalysts, maximal photocatalytic hydrogen production was achieved with NiPt/TiO₂. The optimal component was 0.01 wt.% Ni/1.0 wt.% Pt for TiO₂. The hydrogen evolution with NiPt/TiO₂ was approximately 341 and 1.3 times better than that with pure TiO₂ and Pt/TiO₂, respectively. A potential reaction pathway for photocatalytic hydrogen production from an aqueous methanol solution over NiPt/TiO₂ photocatalyst has also been proposed. Full article

The aim of the present study is to investigate the performance of two carbon fiber-reinforced composite polymers used to manufacture end-use parts via the fused filament fabrication (FFF) method. The materials under investigation were carbon fiber-reinforced Polyamide-6 (PA6-CF15) and carbon fiber-reinforced polyphenylene sulfide (PPS-CF15). To evaluate their mechanical properties and vibrational behavior, specimens were fabricated with four distinct infill patterns: grid, gyroid, triangle and hexagon. In particular, the vibrational behavior of the 3D-printed composites was determined by conducting cyclic compression testing, as well as modal tests. Additionally, the mechanical behavior of the reinforced polymers was determined by conducting both uniaxial tensile and compression tests, as well as three-point bending tests. The results of the mechanical experiments revealed that the grid pattern exhibited the best overall performance, while the gyroid pattern exhibited the greatest strength-to-weight ratio, making it the most durable infill for use with composite filaments. In vibration experiments, PA6-CF15 structures exhibited higher damping ratios than PPS-CF15, indicating superior damping capacity. Among the infill patterns, the hexagon pattern provided the greatest vibration isolation performance. Full article

Accurate relative humidity (RH) measurement is critical in many applications, from process control and material preservation to ensuring human comfort and well-being. This study presents high-performance humidity sensors based on titanium oxide nanoparticles/graphene oxide (TiO₂/GO) composites, which demonstrate excellent sensing capabilities compared to pure GO-based sensors. The multilayer structure of the TiO₂/GO composites enables the enhanced adsorption of water molecules and improved dynamic properties while providing dual-mode sensing capability through both resistive and capacitive measurements. Sensors with different TiO₂/GO ratios were systematically investigated to optimize performance over different humidity ranges. The TiO₂/GO sensor achieved remarkable sensitivity (8.66 × 10⁴ Ω/%RH), a fast response time (0.61 s), and fast recovery (0.87 s) with minimal hysteresis (4.09%). In particular, the sensors demonstrated excellent mechanical stability, maintaining reliable performance under bending conditions, together with excellent cyclic stability and long-term durability. Temperature dependence studies showed consistent performance under controlled temperature conditions, with the potential for temperature-compensated measurements. These results highlight TiO₂/GO nanocomposites as promising candidates for next-generation humidity sensing applications, offering enhanced sensitivity, mechanical flexibility, and operational stability. The dual-mode sensing capability combined with mechanical durability opens up new possibilities for flexible and wearable humidity-sensing devices. Full article

The rapid developments in conductive polymers with flexible electronics over the past years have generated noteworthy attention among researchers and entrepreneurs. Conductive polymers have the distinctive capacity to conduct electricity while still maintaining the lightweight, flexible, and versatile characteristics of polymers. They are crucial for the creation of flexible electronics or gadgets that can stretch, bend, and adapt to different surfaces have sparked momentous interest in electronics, energy storage, sensors, smart textiles, and biomedical applications. This review article offers a comprehensive overview of recent advancements in conductive polymers over the last 15 years, including a bibliometric analysis. The properties of conductive polymers are summarized. Additionally, the fabrication processes of conductive polymer-based materials are discussed, including vacuum filtering, hydrothermal synthesis, spray coating, electrospinning, in situ polymerization, and electrochemical polymerization. The techniques have been presented along with their advantages and limitations. The multifunctional applications of conductive polymers are also discussed, including their roles in energy storage and conversion (e.g., supercapacitors, lithium-ion batteries (LIBs), and sodium-ion batteries (SIBs)), as well as in organic light-emitting diodes (OLEDs), organic solar cells (OSCs), conductive textiles, healthcare monitoring, and sensors. Future scope and associated challenges have also been mentioned for further development in this field. Full article

This study investigates the structural, optical, and photocatalytic properties of cadmium oxide (CdO) nanoparticles (NPs) and indium–tin oxide (ITO)-doped CdO NPs. The synthesis of CdO NPs and ITO NPs was accomplished through the co-precipitation method. Scanning electron microscopy (SEM) analysis indicates that pure CdO NPs exhibit agglomerated structures, whereas ITO doping introduces porosity and roughness, thereby improving particle dispersion and facilitating electron transport. Energy dispersive spectroscopy (EDS) corroborates the successful incorporation of tin (Sn) and indium (In) within indium–tin oxide (ITO)-doped cadmium oxide (CdO) nanoparticles (NPs) in addition to cadmium (Cd) and oxygen (O). X-ray diffraction (XRD) analysis demonstrates that an increase in ITO doping results in a reduction of the crystallite size, decreasing from 23.43 nm for pure CdO to 18.42 nm at a 10% doping concentration, which can be attributed to lattice distortion. Simultaneously, the band gap exhibits a narrowing from 2.92 eV to 2.52 eV, achieving an optimal value at 10% ITO doping before experiencing a slight increase at higher doping concentrations. This tuneable band gap improves light absorption, which is crucial for photocatalysis. The photocatalytic degradation of rhodamine B (RhB) highlights the superior efficiency of ITO-doped CdO nanoparticles, achieving a remarkable 94.68% degradation under sunlight within 120 min, up 81.01%, significantly surpassing the performance of pure CdO. The optimal RhB concentration for achieving maximum degradation was determined to be 5 mg/L. This enhanced catalytic activity demonstrates the effectiveness of ITO-doped CdO NPs under both UV and visible light, showcasing their potential for efficient pollutant degradation in sunlight-driven applications. Full article

Bioinspired composites for thermal energy storage have gained much attention all over the world. Bioinspired structures have several advantages as the skeleton for preparing thermal energy storage materials, including preventing leakage and improving thermal conductivity. Phase change materials (PCMs) play an important role in the development of energy storage materials because of their stable chemical/thermal properties and high latent heat storage capacity. However, their applications have been compromised, owing to low thermal conductivity and leakage. The plant-derived scaffolds (i.e., wood-derived SiC/Carbon) in the composites can not only provide higher thermal conductivity but also prevent leakage. In this paper, we review recent progress in the preparation, microstructures, properties and applications of bioinspired composites for thermal energy storage. Two methods are generally used for producing bioinspired composites, including the direct introduction of biomass-derived templates and the imitation of biological structures templates. Some of the key technologies for introducing PCMs into templates involves melting, vacuum impregnation, physical mixing, etc. Continuous and orderly channels inside the skeleton can improve the overall thermal conductivity, and the thermal conductivity of composites with biomass-derived, porous, silicon carbide skeleton can reach as high as 116 W/m*K. In addition, the tightly aligned microporous structure can cover the PCM well, resulting in good leakage resistance after up to 2500 hot and cold cycles. Currently, bioinspired composites for thermal energy storage hold the greatest promise for large-scale applications in the fields of building energy conservation and solar energy conversion/storage. This review provides guidance on the preparation methods, performance improvements and applications for the future research strategies of bioinspired composites for thermal energy storage. Full article

The recycling of carbon-fiber reinforced polymers (CFRPs) presents significant challenges due to their thermosetting matrix, which complicates end-of-life management and often results in energy-intensive disposal or significant waste accumulation. Despite advancements in recycling methods, knowledge gaps remain regarding their sustainability and economic viability. This study undertakes a comprehensive Life Cycle Assessment and Environmental Life Cycle Costing analysis of four key recycling techniques: mechanical recycling, pyrolysis, solvolysis, and high-voltage fragmentation (HVF). By using the SimaPro software, this study identifies mechanical recycling and HVF as the most sustainable options, with the lowest cumulative energy demand (CED) of 5.82 MJ/kg and 4.97 MJ/kg and global warming potential (GWP) of 0.218 kg CO₂eq and 0.0796 kg CO₂eq, respectively. In contrast, pyrolysis imposes the highest environmental burdens, requiring 66.3 MJ/kg and emitting 2.84 kg CO₂eq. Subcritical solvolysis shows more balanced environmental impacts compared to its supercritical counterpart. Cost analysis reveals that for mechanical recycling and pyrolysis, material costs are negligible or zero. In contrast, solvolysis and HVF incur material costs primarily due to the need for deionized water. Regarding energy costs, pyrolysis stands out as the most expensive method due to its high energy demands, followed closely by solvolysis with supercritical water. Full article