Minerals

13 pages, 1500 KiB

Open AccessArticle

Influence of Oxyanions on the Structural Memory Effect of Layered Double Hydroxides Under Aqueous Condition

by Jingchao Li, Yide Xu, Tingting Chen, Yijun Cao and Guixia Fan

Minerals 2025, 15(8), 772; https://doi.org/10.3390/min15080772 - 22 Jul 2025

The structural memory effect is normally considered one of the most important properties of LDHs. However, certain anions can have adverse effects on it. In this study, three types of CLDHs (Mg2Al1-CLDH, Mg2Al0.5Fe0.5-CLDH, Mg2Fe1-CLDH) were obtained and used to observe their regeneration behaviors [...] Read more.

The structural memory effect is normally considered one of the most important properties of LDHs. However, certain anions can have adverse effects on it. In this study, three types of CLDHs (Mg2Al1-CLDH, Mg2Al0.5Fe0.5-CLDH, Mg2Fe1-CLDH) were obtained and used to observe their regeneration behaviors in the presence of sulfate, silicate, and phosphate, respectively, at initial pH values of 10 and 13. The samples were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA-DTG), scanning electron microscope (SEM), and N2 adsorption–desorption isotherm (BET). The results suggested that silicate and phosphate have significant impacts on the regeneration of CLDHs, while sulfate does not. Specifically, phosphate and silicate reacted with MgO to generate magnesium silicate and magnesium phosphate dibasic, which were covered on the surface of particles and hindered the hydroxylation of metal oxides. However, a higher pH can suppress the formation of new substances and promote the regeneration of LDHs. Moreover, the CLDHs with high specific surface area had a stronger anti-interference performance regarding the effects of phosphate and silicate. Full article

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12 pages, 1897 KiB

Open AccessArticle

Enhanced Extraction of Valuable Metals from Copper Slags by Disrupting Fayalite and Spinel Structures Using Sodium Sulfate

by Shafiq Alam, Behzod Tolibov, Madat Akhmedov, Umidjon Khujamov and Sardor Yarlakabov

Minerals 2025, 15(8), 771; https://doi.org/10.3390/min15080771 - 22 Jul 2025

Abstract

This study investigates the effects of sodium sulfate (Na₂SO₄) dosage, reaction temperature, and processing time on the structural decomposition of complex compounds in copper slag. Experimental results demonstrated that applying 20% Na₂SO₄ achieves an impressive decomposition [...] Read more.

This study investigates the effects of sodium sulfate (Na₂SO₄) dosage, reaction temperature, and processing time on the structural decomposition of complex compounds in copper slag. Experimental results demonstrated that applying 20% Na₂SO₄ achieves an impressive decomposition rate of 89%, highlighting its effectiveness in liberating valuable metals from the slag matrix. The optimal temperature for maximizing fayalite decomposition is determined to be 900 °C, which significantly enhances reaction kinetics and efficiency. Furthermore, extending the reaction time to 90 min resulted in the highest observed decomposition efficiency. Subsequent leaching experiments in sulfuric acid confirmed that the liberated metal transitioned into the solution phase was very effective, ensuring high metal recovery rates. The treated samples demonstrated metal recovery rates of 97% for copper (Cu), 96% for iron (Fe), and 93% for zinc (Zn). In contrast, the untreated samples exhibited considerably lower recovery rates, with copper at 61%, iron at 59%, and zinc at 65%. Additionally, this approach mitigates filtration challenges by preventing the formation of silica gel. These findings provide key operational parameters for optimizing metal recovery from copper slag and establish a solid foundation for advancing sustainable and efficient resource extraction research. Full article

(This article belongs to the Special Issue Hydrometallurgical Treatments of Copper Ores, By-Products and Waste)

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14 pages, 3742 KiB

Open AccessArticle

Modeling and Analyzing Air Supply Control to Optimize Thermal Pattern in Iron-Ore-Sintering Process

by Xiaoxian Huang, Zongping Li, Pengfei Zou, Jun Yuan, Xuling Chen, Zhenxiang Feng and Xiaohui Fan

Minerals 2025, 15(8), 770; https://doi.org/10.3390/min15080770 - 22 Jul 2025

Abstract

This research proposes optimizing the thermal pattern in the sintering bed by manipulating the air supply. The impact of the air supply on the distribution of heat in the upper and lower layers of the material bed is investigated based on a numerical [...] Read more.

This research proposes optimizing the thermal pattern in the sintering bed by manipulating the air supply. The impact of the air supply on the distribution of heat in the upper and lower layers of the material bed is investigated based on a numerical simulation model. An optimized air supply scheme is proposed to enhance the thermal distribution of the sintering bed. The simulation results suggest that decreasing the air supply during sintering in the upper layer leads to an increase in bed temperature and an extension of the melting zone thickness from 5 mm to 16 mm. Similarly, reducing the air supply during sintering of the lower layer prevents over-melting of the sintering material by reducing heat accumulation. However, both decrease the speed of vertical sintering. To optimize the sintering process, it is suggested to decrease the air supply during the early and late stages and increase it during the middle stage. This optimized air supply leads to a uniform temperature distribution, with a 30 °C decrease in the gap between the highest temperatures. Additionally, the melting zone thickness in the early sintering stage increases from 0 mm to 14 mm, and the average vertical sintering speed remains comparable. Full article

(This article belongs to the Section Mineral Processing and Extractive Metallurgy)

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23 pages, 12729 KiB

Open AccessArticle

Genetic Mineralogical Characteristics of Pyrite and Quartz from the Qiubudong Silver Deposit, Central North China Craton: Implications for Ore Genesis and Exploration

by Wenyan Sun, Jianling Xue, Zhiqiang Tong, Xueyi Zhang, Jun Wang, Shengrong Li and Min Wang

Minerals 2025, 15(8), 769; https://doi.org/10.3390/min15080769 - 22 Jul 2025

Abstract

The Qiubudong silver deposit on the western margin of the Fuping ore cluster in the central North China Craton is a representative breccia-type deposit characterized by relatively high-grade ores, thick mineralized zones, and extensive alteration, indicating considerable potential for economic resource development and [...] Read more.

The Qiubudong silver deposit on the western margin of the Fuping ore cluster in the central North China Craton is a representative breccia-type deposit characterized by relatively high-grade ores, thick mineralized zones, and extensive alteration, indicating considerable potential for economic resource development and further exploration. Previous studies on this deposit have not addressed its genetic mineralogical characteristics. This study focuses on pyrite and quartz to investigate their typomorphic features, such as crystal morphology, trace element composition, thermoelectric properties, and luminescence characteristics, and their implications for ore-forming processes. Pyrite crystals are predominantly cubic in early stages, while pentagonal dodecahedral and cubic–dodecahedral combinations peak during the main mineralization stage. The pyrite is sulfur-deficient and iron-rich, enriched in Au, and relatively high in Ag, Cu, Pb, and Bi contents during the main ore-forming stage. Rare earth element (REE) concentrations are low, with weak LREE-HREE fractionation and a strong negative Eu anomaly. The thermoelectric coefficient of pyrite ranges from −328.9 to +335.6 μV/°C, with a mean of +197.63 μV/°C; P-type conduction dominates, with an occurrence rate of 58%–100% and an average of 88.78%. A weak–low temperature and a strong–high temperature peak characterize quartz thermoluminescence during the main mineralization stage. Fluid inclusions in quartz include liquid-rich, vapor-rich, and two-phase types, with salinities ranging from 10.11% to 12.62% NaCl equiv. (average 11.16%) and densities from 0.91 to 0.95 g/cm³ (average 0.90 g/cm³). The ore-forming fluids are interpreted as F-rich, low-salinity, low-density hydrothermal fluids of volcanic origin at medium–low temperatures. The abundance of pentagonal dodecahedral pyrite, low Co/Ni ratios, high Cu contents, and complex quartz thermoluminescence signatures are key mineralogical indicators for deep prospecting. Combined with thermoelectric data and morphological analysis, the depth interval around 800 m between drill holes ZK3204 and ZK3201 has high mineralization potential. This study fills a research gap on the genetic mineralogy of the Qiubudong deposit and provides a scientific basis for deep exploration. Full article

(This article belongs to the Special Issue Using Mineral Chemistry to Characterize Ore-Forming Processes)

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32 pages, 32586 KiB

Open AccessArticle

Magmatic Evolution at the Saindak Cu-Au Deposit: Implications for the Formation of Giant Porphyry Deposits

by Jun Hong, Yasir Shaheen Khalil, Asad Ali Narejo, Xiaoyong Yang, Tahseenullah Khan, Zhihua Wang, Huan Tang, Haidi Zhang, Bo Yang and Wenyuan Li

Minerals 2025, 15(8), 768; https://doi.org/10.3390/min15080768 - 22 Jul 2025

Abstract

The Chagai porphyry copper belt is a major component of the Tethyan metallogenic domain, which spans approximately 300 km and hosts several giant porphyry copper deposits. The tectonic setting, whether subduction-related or post-collisional, and the deep dynamic processes governing the formation of these [...] Read more.

The Chagai porphyry copper belt is a major component of the Tethyan metallogenic domain, which spans approximately 300 km and hosts several giant porphyry copper deposits. The tectonic setting, whether subduction-related or post-collisional, and the deep dynamic processes governing the formation of these giant deposits remain poorly understood. Mafic microgranular enclaves (MMEs), mafic dikes, and multiple porphyries have been documented in the Saindak mining area. This work examines both the ore-rich and non-ore intrusions in the Saindak porphyry Cu-Au deposit, using methods like molybdenite Re-Os dating, U-Pb zircon ages, Hf isotopes, and bulk-rock geochemical data. Geochronological results indicate that ore-fertile and barren porphyries yield ages of 22.15 ± 0.22 Ma and 22.21 ± 0.33 Ma, respectively. Both MMEs and mafic dikes have zircons with nearly identical ²⁰⁶Pb/²³⁸U weighted mean ages (21.21 ± 0.18 Ma and 21.21 ± 0.16 Ma, respectively), corresponding to the age of the host rock. Geochemical and Sr–Nd–Hf isotopic evidence indicates that the Saindak adakites were generated by the subduction of the Arabian oceanic lithosphere under the Eurasian plate, rather than through continental collision. The adakites were mainly formed by the partial melting of a metasomatized mantle wedge, induced by fluids from the dehydrating subducting slab, with minor input from subducted sediments and later crust–mantle interactions during magma ascent. We conclude that shallow subduction of the Arabian plate during the Oligocene–Miocene may have increased the flow of subducted fluids into the sub-arc mantle source of the Chagai arc. This process may have facilitated the widespread deposition of porphyry copper and copper–gold mineralization in the region. Full article

(This article belongs to the Section Mineral Deposits)

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18 pages, 1052 KiB

Open AccessArticle

Assessment of Tailings Contamination Potential in One of the Most Important Gold Mining Districts of Ecuador

by Daniel Garcés, Samantha Jiménez-Oyola, Yolanda Sánchez-Palencia, Fredy Guzmán-Martínez, Raúl Villavicencio-Espinoza, Sebastián Jaramillo-Zambrano, Victoria Rosado, Bryan Salgado-Almeida and Josué Marcillo-Guillén

Minerals 2025, 15(8), 767; https://doi.org/10.3390/min15080767 - 22 Jul 2025

Abstract

Mining waste presents significant environmental and public health risks due to the potential release of toxic substances when improperly managed. In this study, four tailings samples were taken to evaluate the environmental risks in the Ponce Enríquez mining area in Ecuador. Chemical characterization [...] Read more.

Mining waste presents significant environmental and public health risks due to the potential release of toxic substances when improperly managed. In this study, four tailings samples were taken to evaluate the environmental risks in the Ponce Enríquez mining area in Ecuador. Chemical characterization and X-ray Fluorescence Spectrometry (XRF) were used to analyze the content of potentially toxic elements (PTEs) of interest (As, Cd, Cr, Cu, Ni, Pb, and Zn), and X-ray Diffraction (XRD) for mineralogical characterization. The contamination index (IC) was calculated to assess the potential hazard associated with the content of PTEs in the mining wastes. To assess environmental risks, leaching tests were carried out to evaluate the potential release of PTEs, and Acid-Base Accounting (ABA) tests were conducted to determine the likelihood of acid mine drainage formation. The results revealed that the PETs concentration exceeded the maximum permissible limits in all samples, according to Ecuadorian regulations: As, Pb, and Cd were identified as critical contaminants. Mineralogically, quartz was the dominant phase, followed by carbonates (calcite, dolomite and magnesite), phyllosilicates (chlorite and illite), and minor amounts of pyrite and talc. The IC indicated high to very high contamination risk levels, with As being the predominant contributor. Although leaching tests met the established limits for non-hazardous mining waste, the ABA test showed that all samples had a high potential for long-term acid generation. These results underscore the need for implementing management strategies to mitigate the environmental impacts and the development of plans to protect local ecosystems and communities from the adverse effects of mining activities. Full article

(This article belongs to the Special Issue Risks Assessment, Management and Control of Mining Contamination, 2nd Edition)

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16 pages, 11535 KiB

Open AccessArticle

Sedimentary Stylolites Roughness Inversion Enables the Quantification of the Eroded Thickness of Deccan Trap Above the Bagh Group, Narmada Basin, India

by Dhiren Kumar Ruidas, Nicolas E. Beaudoin, Srabani Thakur, Aniruddha Musib and Gourab Dey

Minerals 2025, 15(8), 766; https://doi.org/10.3390/min15080766 - 22 Jul 2025

Abstract

Stylolites, common dissolution surfaces in carbonate rocks, form due to localized stress-induced pressure-solution during burial compaction or tectonic contraction. Their morphology and growth are influenced by dissolution kinetics, rock heterogeneity, clay content, burial depth, stress evolution, diagenesis, and pore fluid availability. This study [...] Read more.

Stylolites, common dissolution surfaces in carbonate rocks, form due to localized stress-induced pressure-solution during burial compaction or tectonic contraction. Their morphology and growth are influenced by dissolution kinetics, rock heterogeneity, clay content, burial depth, stress evolution, diagenesis, and pore fluid availability. This study applies the stylolite roughness inversion technique (SRIT), a proven paleopizometer that quantifies the principal vertical stress (σ_v = σ₁) prevailing in strata in the last moments of bedding-parallel stylolites (BPS) formation, to the Late Cretaceous Bagh Group carbonates in the Narmada Basin, India, to estimate their burial paleo-depth. Using the Fourier Power Spectrum (FPS), we obtained 18 σ₁ values from a collection of 30 samples, enabling us to estimate paleo-burial depths for the Bagh Group ranging from 660 to 1320 m. As the Bagh Group burial history is unknown, but as there is no subsequent sedimentary deposition above it, we relate this ca. 1.3 km burial depth to the now eroded thickness of the deposits related to Deccan volcanism at the end of the Cretaceous time, implying a quasi-instantaneous development of the BPS population in the strata. This research highlights the robustness of SRIT for reconstructing burial histories in carbonate sequences and that it can be a reliable way to reconstruct the thickness of eroded deposits in well-constrained geological history. Full article

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16 pages, 1589 KiB

Open AccessArticle

Optimising Nature-Based Treatment Systems for Management of Mine Water

by Catherine J. Gandy, Beate Christgen and Adam P. Jarvis

Minerals 2025, 15(7), 765; https://doi.org/10.3390/min15070765 - 21 Jul 2025

Abstract

Deployment of nature-based systems for mine water treatment is constrained by system size, and the evidence suggests decreasing hydraulic conductivity (K_sat) of organic substrates over time compromises performance. In lab-scale continuous-flow reactors, we investigated (1) the geochemical and hydraulic performance [...] Read more.

Deployment of nature-based systems for mine water treatment is constrained by system size, and the evidence suggests decreasing hydraulic conductivity (K_sat) of organic substrates over time compromises performance. In lab-scale continuous-flow reactors, we investigated (1) the geochemical and hydraulic performance of organic substrates used in nature-based systems for metals removal (via bacterial sulfate reduction) from mine water, and then (2) the potential to operate systems modestly contaminated with Zn (0.5 mg/L) at reduced hydraulic residence times (HRTs). Bioreactors containing limestone, straw, and wood chips, with and without compost and/or sewage sludge all achieved 88%–90% Zn removal, but those without compost/sludge had higher K_sat (929–1546 m/d). Using a high K_sat substrate, decreasing the HRT from 15 to 9 h had no impact on Zn removal (92.5% to 97.5%). Although the sulfate reduction rate decreased at a shorter HRT, microbial analysis showed high relative abundance (2%–7%) of sulfate reducing bacteria, and geochemical modelling pointed to ZnS(s) precipitation as the main attenuation mechanism (mean ZnS saturation index = 3.91–4.23). High permeability organic substrate treatment systems operated at a short HRT may offer potential for wider deployment of such systems, but pilot-scale testing under ambient environmental conditions is advisable. Full article

(This article belongs to the Special Issue Characterization and Management of Mine Waters)

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23 pages, 5215 KiB

Open AccessArticle

Analysis and Modeling of Elastic and Electrical Response Characteristics of Tight Sandstone in the Kuqa Foreland Basin of the Tarim Basin

by Juanli Cui, Kui Xiang, Xiaolong Tong, Yanling Shi, Zuzhi Hu and Liangjun Yan

Minerals 2025, 15(7), 764; https://doi.org/10.3390/min15070764 - 21 Jul 2025

Abstract

This study addresses the limitations of conventional evaluation methods caused by low porosity, strong heterogeneity, and complex pore structures in tight sandstone reservoirs. Through integrated rock physics experiments and multi-physical field modeling, the research systematically investigates the coupled response mechanisms between electrical and [...] Read more.

This study addresses the limitations of conventional evaluation methods caused by low porosity, strong heterogeneity, and complex pore structures in tight sandstone reservoirs. Through integrated rock physics experiments and multi-physical field modeling, the research systematically investigates the coupled response mechanisms between electrical and elastic parameters. The experimental approach includes pore structure characterization, quantitative mineral composition analysis, resistivity and polarizability measurements under various saturation conditions, P- and S-wave velocity testing, and scanning electron microscopy (SEM) imaging. The key findings show that increasing porosity leads to significant reductions in resistivity and elastic wave velocities, while also increasing surface conductivity. Specifically, clay minerals enhance surface conductivity through interfacial polarization effects and decrease rock stiffness, which exacerbates wave velocity attenuation. Furthermore, resistivity exhibits a nonlinear negative correlation with water saturation, with sharp increases at low saturation levels due to the disruption of conductive pathways. By integrating the Modified Generalized Effective Medium Theory of Induced Polarization (MGEMTIP) and Kuster–Toksöz models, this study establishes quantitative relationships between porosity, saturation, and electrical/elastic parameters, and constructs cross-plot templates that correlate elastic wave velocities with resistivity and surface conductivity. These analyses reveal that high-porosity, high-saturation zones are characterized by lower resistivity and wave velocities, coupled with significantly higher surface conductivity. The proposed methodology significantly improves the accuracy of reservoir evaluation and enhances fluid identification capabilities, providing a solid theoretical foundation for the efficient exploration and development of tight sandstone reservoirs. Full article

(This article belongs to the Special Issue Electromagnetic Inversion for Deep Ore Explorations)

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12 pages, 4221 KiB

Open AccessArticle

The Effects of Amino Acids on the Polymorphs and Magnesium Content of Calcium–Magnesium Carbonate Minerals

by Chonghong Zhang, Yuyang Jiang and Shuhao Qian

Minerals 2025, 15(7), 763; https://doi.org/10.3390/min15070763 - 21 Jul 2025

Abstract

Calcium–magnesium (Ca–Mg) carbonates are among the most widely distributed carbonates in the Earth’s surface environment, and their formation mechanisms are of great significance for revealing geological environmental changes and carbon sequestration processes. In this study, the gas diffusion method was employed with L-glutamic [...] Read more.

Calcium–magnesium (Ca–Mg) carbonates are among the most widely distributed carbonates in the Earth’s surface environment, and their formation mechanisms are of great significance for revealing geological environmental changes and carbon sequestration processes. In this study, the gas diffusion method was employed with L-glutamic acid, L-glycine, and L-lysine as nucleation templates for carbonate minerals to systematically investigate their regulatory effects on the mineralization of Ca–Mg carbonates. The results demonstrated that L-glycine, with the shortest length, was more conducive to forming aragonite, whereas acidic L-glutamic acid, which contains more carboxyl groups, was more beneficial for the structural stability of aragonite. The morphology of the Ca-Mg carbonate minerals became more diverse and promoted the formation of spherical and massive mineral aggregates under the action of amino acids. Moreover, the amino acids significantly increased the MgCO₃ content in Mg calcite (L-glutamic acid: 10.86% > L-glycine: 7.91% > L-lysine: 6.63%). The acidic L-glutamic acid likely promotes the dehydration and incorporation of Mg²⁺ into the Mg calcite lattice through the preferential adsorption of Mg²⁺ via its side-chain carboxyl groups. This study shows how amino acid functional groups influence Ca–Mg carbonate mineralization and provides insights into biogenic Mg-rich mineral origins and advanced mineral material synthesis. Full article

(This article belongs to the Section Biomineralization and Biominerals)

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Graphical abstract

10 pages, 404 KiB

Open AccessArticle

Flotation Separation of Chalcopyrite and Molybdenite by Eco-Friendly Microorganism Depressant Bacillus tropicus

by Guanghua Ai, Guosheng Xiao and Bo Feng

Minerals 2025, 15(7), 762; https://doi.org/10.3390/min15070762 - 21 Jul 2025

Abstract

In this study, Bacillus tropicus (BT), a non-toxic and eco-friendly microorganism, was employed to substitute traditional inorganic depressants in the flotation separation of copper-molybdenum sulfides. Single mineral flotation tests were performed to examine BT’s impact on the flotation behavior of molybdenite and chalcopyrite. [...] Read more.

In this study, Bacillus tropicus (BT), a non-toxic and eco-friendly microorganism, was employed to substitute traditional inorganic depressants in the flotation separation of copper-molybdenum sulfides. Single mineral flotation tests were performed to examine BT’s impact on the flotation behavior of molybdenite and chalcopyrite. The results indicated that excessive BT inhibited the flotation of both minerals, reducing their recoveries below 40%. At a BT dosage of 2.5 kg/t and pH 9.0, chalcopyrite recovery was 74.10%, while molybdenite recovery was 20.47%, achieving an effective separation of the two minerals. BT’s adsorption mechanism on molybdenite and chalcopyrite was analyzed through contact angle tests, thermogravimetric analysis, and Fourier transform infrared spectroscopy. These analyses revealed that increased BT absorption on molybdenite enhanced its surface hydrophilicity. This research offers a novel perspective on utilizing microorganisms as efficient flotation reagents. Full article

(This article belongs to the Section Mineral Processing and Extractive Metallurgy)

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24 pages, 30355 KiB

Open AccessArticle

Controls on Stylolite Formation in the Upper Cretaceous Kometan Formation, Zagros Foreland Basin, Iraqi Kurdistan

by Hussein S. Hussein, Ondřej Bábek, Howri Mansurbeg, Juan Diego Martín-Martín and Enrique Gomez-Rivas

Minerals 2025, 15(7), 761; https://doi.org/10.3390/min15070761 - 20 Jul 2025

Abstract

Stylolites are ubiquitous diagenetic products in carbonate rocks. They play a significant role in enhancing or reducing fluid flow in subsurface reservoirs. This study unravels the relationship between stylolite networks, carbonate microfacies, and the elemental geochemistry of Upper Cretaceous limestones of the Kometan [...] Read more.

Stylolites are ubiquitous diagenetic products in carbonate rocks. They play a significant role in enhancing or reducing fluid flow in subsurface reservoirs. This study unravels the relationship between stylolite networks, carbonate microfacies, and the elemental geochemistry of Upper Cretaceous limestones of the Kometan Formation (shallow to moderately deep marine) in Northern Iraq. Stylolites exhibit diverse morphologies across mud- and grain-supported limestone facies. Statistical analyses of stylolite spacing, wavelength, amplitude, and their intersections and connectivity indicate that grain size, sorting, and mineral composition are key parameters that determine the geometrical properties of the stylolites and stylolite networks. Stylolites typically exhibit weak connectivity and considerable vertical spacing when hosted in packstone facies with moderate grain sorting. Conversely, mud-supported limestones, marked by poor sorting and high textural heterogeneity, host well-developed stylolite networks characterized by high amplitude and frequent intersections, indicating significant dissolution and deformation processes. Stylolites in mud-supported facies are closely spaced and present heightened amplitudes and intensified junctions, with suture and sharp-peak type. This study unveils that stylolites can potentially enhance porosity in the studied formation. Full article

(This article belongs to the Special Issue Stylolites: Development, Properties, Inversion and Scaling)

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20 pages, 16432 KiB

Open AccessArticle

Application of Clustering Methods in Multivariate Data-Based Prospecting Prediction

by Xiaopeng Chang, Minghua Zhang, Liang Chen, Sheng Zhang, Wei Ren and Xiang Zhang

Minerals 2025, 15(7), 760; https://doi.org/10.3390/min15070760 - 20 Jul 2025

Abstract

Mining and analyzing information from multiple sources—such as geophysics and geochemistry—is a key aspect of big data-driven mineral prediction. Clustering, which groups large datasets based on distance metrics, is an essential method in multidimensional data analysis. The Two-Step Clustering (TSC) approach offers advantages [...] Read more.

Mining and analyzing information from multiple sources—such as geophysics and geochemistry—is a key aspect of big data-driven mineral prediction. Clustering, which groups large datasets based on distance metrics, is an essential method in multidimensional data analysis. The Two-Step Clustering (TSC) approach offers advantages by handling both categorical and continuous variables and automatically determining the optimal number of clusters. In this study, we applied the TSC method to mineral prediction in the northeastern margin of the Jiaolai Basin by: (i) converting residual gravity and magnetic anomalies into categorical variables using Ward clustering; and (ii) transforming 13 stream sediment elements into independent continuous variables through factor analysis. The results showed that clustering is sensitive to categorical variables and performs better with fewer categories. When variables share similar distribution characteristics, consistency between geophysical discretization and geochemical boundaries also influences clustering results. In this study, the (3 × 4) and (4 × 4) combinations yielded optimal clustering results. Cluster 3 was identified as a favorable zone for gold deposits due to its moderate gravity, low magnetism, and the enrichment in F1 (Ni–Cu–Zn), F2 (W–Mo–Bi), and F3 (As–Sb), indicating a multi-stage, shallow, hydrothermal mineralization process. This study demonstrates the effectiveness of combining Ward clustering for variable transformation with TSC for the integrated analysis of categorical and numerical data, confirming its value in multi-source data research and its potential for further application. Full article

(This article belongs to the Special Issue Application of Big Data Mining, Machine Learning and Artificial Intelligence in Geoscience, 2nd Edition)

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24 pages, 6323 KiB

Open AccessArticle

Study on Creep Characteristics of High-Volume Fly Ash-Cement Backfill Considering Initial Damage

by Shuokang Wang, Jingjing Yan, Zihui Dong, Hua Guo, Yuanzhong Yang and Naseer Muhammad Khan

Minerals 2025, 15(7), 759; https://doi.org/10.3390/min15070759 - 19 Jul 2025

Abstract

To reveal the long-term deformation behavior of high-volume fly ash-based backfill under continuous mining and backfilling, a fly ash–cement backfill material with 73.0% fly ash content was developed, and creep characteristic tests considering initial damage were conducted. The results demonstrate that: (1) A [...] Read more.

To reveal the long-term deformation behavior of high-volume fly ash-based backfill under continuous mining and backfilling, a fly ash–cement backfill material with 73.0% fly ash content was developed, and creep characteristic tests considering initial damage were conducted. The results demonstrate that: (1) A calculation method for the initial damage of backfill based on stress–strain hysteresis loop cycles is proposed, with cumulative characteristics of initial damage across mining phases analyzed; (2) Creep behaviors of backfill affected by initial damage are investigated, revealing the weakening effect of initial damage on long-term bearing capacity; (3) An enhanced, nonlinear plastic damage element is developed, enabling the construction of an HKBN constitutive model capable of characterizing the complete creep behavior of backfill materials. The research establishes a theoretical framework for engineering applications of backfill materials with early-age strength below 5 MPa, while significantly enhancing the utilization efficiency of coal-based solid wastes. Full article

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22 pages, 15718 KiB

Open AccessArticle

Trace and Rare-Earth-Element Chemistry of Quartz from the Tuztaşı Low-Sulfidation Epithermal Au-Ag Deposit, Western Türkiye: Implications for Gold Exploration from Quartz Mineral Chemistry

by Fatih Özbaş, Essaid Bilal and Ahmed Touil

Minerals 2025, 15(7), 758; https://doi.org/10.3390/min15070758 - 19 Jul 2025

Abstract

The Tuztaşı low-sulfidation epithermal Au–Ag deposit (Biga Peninsula, Türkiye) records a multi-stage hydrothermal history that can be interpreted through the trace and rare-earth-element (REE) chemistry of quartz. High-precision LA-ICP-MS analyses of five representative quartz samples (23 ablation spots; 10 analytically robust) reveal two [...] Read more.

The Tuztaşı low-sulfidation epithermal Au–Ag deposit (Biga Peninsula, Türkiye) records a multi-stage hydrothermal history that can be interpreted through the trace and rare-earth-element (REE) chemistry of quartz. High-precision LA-ICP-MS analyses of five representative quartz samples (23 ablation spots; 10 analytically robust) reveal two fluid stages. Early fluids were cold, dilute meteoric waters (δ¹⁸O₍H₂O₎ ≈ −6.8 to +0.7‰), whereas later fluids circulated deeper, interacted with felsic basement rocks, and evolved in composition. Mineralized quartz displays marked enrichment in As (raw mean = 2854 ± 6821 ppm; filtered mean = 70 ± 93 ppm; one spot 16,775 ppm), K (498 ± 179 ppm), and Sb (57.8 ± 113 ppm), coupled with low Ti/Al (<0.005) and elevated Ge/Si (0.14–0.65 µmol mol⁻¹). Chondrite-normalized REE patterns show pronounced but variable LREE enrichment ((La/Yb)_n ≤ 45.3; ΣLREE/ΣHREE up to 10.8) and strongly positive Eu anomalies (δEu ≤ 9.3) with slightly negative Ce anomalies (δCe ≈ 0.29); negligible Ce–Eu covariance (r² ≈ 0.05) indicates discrete redox pulses. These signatures indicate chemically evolved, reducing fluids conducive to Au–Ag deposition. By contrast, barren quartz is characterized by lower pathfinder-element contents, less fractionated REE profiles, higher Ti/Al, and weaker Eu anomalies. A composite exploration toolkit emerges: As > 700 ppm, As/Sb > 25, Ti/Al < 0.005, Ge/Si > 0.15 µmol mol⁻¹, and δEu ≫ 1 reliably identify ore-bearing zones when integrated with δ¹⁸O data and fluid-inclusion microthermometry from earlier studies on the same vein system. This study provides one of the first systematic applications of integrated trace-element and REE analysis of quartz to a Turkish low-sulfidation epithermal system, offering an applicable model for vectoring mineralization in analogous settings worldwide. Full article

(This article belongs to the Section Mineral Deposits)

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18 pages, 7598 KiB

Open AccessArticle

Recovery of Fine Rare Earth Minerals from Simulated Tin Tailings by Carrier Magnetic Separation: Selective Heterogeneous Agglomeration with Coarse Magnetite Particles

by Ilhwan Park, Topan Satria Gumilang, Rinaldi Yudha Pratama, Sanghee Jeon, Carlito Baltazar Tabelin, Theerayut Phengsaart, Muhammad Bilal, Youhei Kawamura and Mayumi Ito

Minerals 2025, 15(7), 757; https://doi.org/10.3390/min15070757 - 19 Jul 2025

Abstract

The demand for rare earth elements (REEs) is continuously increasing due to the important roles they play in low-carbon and green energy technologies. Unfortunately, the global REE reserves are limited and concentrated in only a few countries, so the reprocessing of alternative resources [...] Read more.

The demand for rare earth elements (REEs) is continuously increasing due to the important roles they play in low-carbon and green energy technologies. Unfortunately, the global REE reserves are limited and concentrated in only a few countries, so the reprocessing of alternative resources like tailings is of critical importance. This study investigated carrier magnetic separation using coarse magnetite particles as a carrier to recover finely ground monazite from tailings. The monazite and carrier surfaces were modified by sodium oleate (NaOL) to improve the hydrophobic interactions between them. The results of zeta potential and contact angle measurements implied the selective adsorption of NaOL onto the surfaces of the monazite and magnetite particles. Although their hydrophobicity increased, heterogenous agglomeration between them was not substantial. To improve heterogenous agglomeration, emulsified kerosene was utilized as a bridging liquid, resulting in more extensive attachment of fine monazite particles onto the surfaces of carrier particles and a dramatic improvement in monazite recovery by magnetic separation—from 0% (without carrier) to 70% (with carrier). A rougher–scavenger–cleaner carrier magnetic separation can produce REE concentrates with a total rare earth oxide (TREO) recovery of 80% and a grade of 9%, increased from 3.4%, which can be further increased to 23.2% after separating REEs and the carrier. Full article

(This article belongs to the Special Issue Recent Advances in Separation Techniques for Critical Minerals/Metals, Circular Economy, and Sustainability)

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17 pages, 1653 KiB

Open AccessArticle

Evaluation of Binderless Briquettes as Potential Feed for the Electric Arc Furnaces at Barro Alto, Brazil

by Johnny Obakeng Mogalanyane, Natasia Naudé and Andrie Mariana Garbers-Craig

Minerals 2025, 15(7), 756; https://doi.org/10.3390/min15070756 - 19 Jul 2025

Abstract

Barro Alto processes nickel laterite ore using rotary kilns and six-in-line rectangular electric arc furnaces. This study evaluated the briquetting of ferronickel ore to reduce kiln fines, improve furnace charge permeability, and enhance process safety. Binderless briquettes were produced from screened ore at [...] Read more.

Barro Alto processes nickel laterite ore using rotary kilns and six-in-line rectangular electric arc furnaces. This study evaluated the briquetting of ferronickel ore to reduce kiln fines, improve furnace charge permeability, and enhance process safety. Binderless briquettes were produced from screened ore at two size fractions (−6.3 mm and −12.5 mm), with moisture contents of 16% and 24%, cured under closed and open conditions. The physical and metallurgical properties of the briquettes were assessed using ISO standard tests. The results confirmed successful agglomeration of the ore into binderless briquettes. Screening the run-of-mine (ROM) ore improved the feed quality, increasing the NiO grade from 2.0% to 2.2% in the −6.3 mm fraction. The briquettes from the −6.3 mm ore at 16% moisture exhibited the highest green strength (559 N). Higher moisture content reduced the briquette strength and increased both the reduction disintegration and decrepitation indices. The decrepitation index increased from 0.33% to 0.61% for the −6.3 mm briquettes when the moisture increased from 16% to 24%. The reduction levels were 33.4% and 39.2% for −6.3 mm and −12.5 mm briquettes with 16% moisture, respectively. This study concludes that optimal performance was achieved using −6.3 mm ore, 16% moisture, and open curing, thereby balancing reduction efficiency and mechanical stability. Full article

(This article belongs to the Section Mineral Processing and Extractive Metallurgy)

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23 pages, 8957 KiB

Open AccessArticle

Geometallurgical Cluster Creation in a Niobium Deposit Using Dual-Space Clustering and Hierarchical Indicator Kriging with Trends

by João Felipe C. L. Costa, Fernanda G. F. Niquini, Claudio L. Schneider, Rodrigo M. Alcântara, Luciano N. Capponi and Rafael S. Rodrigues

Minerals 2025, 15(7), 755; https://doi.org/10.3390/min15070755 - 19 Jul 2025

Abstract

Alkaline carbonatite complexes are formed by magmatic, hydrothermal, and weathering geological events, which modify the minerals present in the rocks, resulting in ores with varied metallurgical behavior. To better spatially distinguish ores with distinct plant responses, creating a 3D geometallurgical block model was [...] Read more.

Alkaline carbonatite complexes are formed by magmatic, hydrothermal, and weathering geological events, which modify the minerals present in the rocks, resulting in ores with varied metallurgical behavior. To better spatially distinguish ores with distinct plant responses, creating a 3D geometallurgical block model was necessary. To establish the clusters, four different algorithms were tested: K-Means, Hierarchical Agglomerative Clustering, dual-space clustering (DSC), and clustering by autocorrelation statistics. The chosen method was DSC, which can consider the multivariate and spatial aspects of data simultaneously. To better understand each cluster’s mineralogy, an XRD analysis was conducted, shedding light on why each cluster performs differently in the plant: cluster 0 contains high magnetite content, explaining its strong magnetic yield; cluster 3 has low pyrochlore, resulting in reduced flotation yield; cluster 2 shows high pyrochlore and low gangue minerals, leading to the best overall performance; cluster 1 contains significant quartz and monazite, indicating relevance for rare earth elements. A hierarchical indicator kriging workflow incorporating a stochastic partial differential equation (SPDE) trend model was applied to spatially map these domains. This improved the deposit’s circular geometry reproduction and better represented the lithological distribution. The elaborated model allowed the identification of four geometallurgical zones with distinct mineralogical profiles and processing behaviors, leading to a more robust model for operational decision-making. Full article

(This article belongs to the Special Issue Geostatistical Methods and Practices for Specific Ore Deposits)

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18 pages, 2330 KiB

Open AccessArticle

Adaptive Differential Evolution Algorithm for Induced Polarization Parameters in Frequency-Domain Controlled-Source Electromagnetic Data

by Lei Zhou, Tianjun Cheng, Min Yao, Jianzhong Cheng, Xingbing Xie, Yurong Mao and Liangjun Yan

Minerals 2025, 15(7), 754; https://doi.org/10.3390/min15070754 - 18 Jul 2025

Abstract

The frequency-domain controlled-source electromagnetic method (CSEM) has been widely used in fields such as oil and gas and mineral resource exploration. In areas with a significant IP response, the CSEM signals will be modified by the IP response of the subsurface. Accurately extracting [...] Read more.

The frequency-domain controlled-source electromagnetic method (CSEM) has been widely used in fields such as oil and gas and mineral resource exploration. In areas with a significant IP response, the CSEM signals will be modified by the IP response of the subsurface. Accurately extracting resistivity and polarization information from CSEM signals may significantly improve the exploration interpretations. In this study, we replaced real resistivity with the Cole–Cole complex resistivity model in a forward simulation of the CSEM to obtain electric field responses that included both induced polarization and electromagnetic effects. Based on this, we used the adaptive differential evolution algorithm to perform a 1-d inversion of these data to extract both the resistivity and IP parameters. Inversion of the electric field responses from representative three-layer geoelectric models, as well as from a more realistic seven-layer model, showed that the inversions were able to effectively recover resistivity and polarization information from the modeled responses, validating our methodology. The electric field response of the real geoelectric model, with 20% random noise added, was then used to simulate actual measured CSEM signals, as well as subjected to multiple inversion tests. The results of these tests continued to accurately reflect the resistivity and polarization information of the model, confirming the applicability and reliability of the algorithm. These results have significant implications for the processing and interpretation of CSEM data when induced polarization effects merit consideration and are expected to promote the use of the CSEM in more fields. Full article

(This article belongs to the Special Issue Electromagnetic Inversion for Deep Ore Explorations)

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