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Batteries, Volume 8, Issue 8

2022 August - 28 articles

Cover Story: LiNi0.8Co0.1Mn0.1O2 (NMC811) is one of the most promising cathode materials for high energy density lithium-ion batteries. However, its chemical instability in contact with ambient air can be a problem for cell manufacturers. In this study, NMC811 fresh powder and electrode were exposed to ambient air to analyze the influence of such storage conditions. The aged NMC811 powder was used to prepare electrodes. Electrochemical and material characterization experiments were conducted on all fresh and aged samples, revealing the significant impact of storage on the material’s chemistry and performance, particularly in aged electrodes. On the other hand, the electrode processing of aged NMC811 powder significantly mitigates such a detrimental effect. These novel results are of interest to determine the most suitable storage conditions of NMC811 materials. View this paper
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Articles (28)

  • Article
  • Open Access
2 Citations
2,893 Views
14 Pages

Influence of the Ni Catalyst on the Properties of the Si-C Composite Material for LIB Anodes

  • Darina A. Lozhkina,
  • Vladimir P. Ulin,
  • Mikhail E. Kompan,
  • Aleksander M. Rumyantsev,
  • Irina S. Kondrashkova,
  • Andrei A. Krasilin and
  • Ekaterina V. Astrova

21 August 2022

The subject of this study was Si-C composites for lithium-ion battery (LIB) anodes obtained by carbonization of nanodispersed silicon with carbon monofluoride. To determine the possibility of increasing the degree of graphitization of nanodispersed c...

  • Article
  • Open Access
25 Citations
12,470 Views
13 Pages

The Effect of Electrode Thickness on the High-Current Discharge and Long-Term Cycle Performance of a Lithium-Ion Battery

  • Dongjian Li,
  • Qiqi Lv,
  • Chunmei Zhang,
  • Wei Zhou,
  • Hongtao Guo,
  • Shaohua Jiang and
  • Zhuan Li

21 August 2022

Six groups of electrodes with different thickness are prepared in the current study by using Li[Ni1/3Co1/3MN1/3]O2 as the active substance; the electrode thicknesses are 71.8, 65.4, 52.6, 39.3, 32.9, and 26.2 μm, respectively, with similar interna...

  • Article
  • Open Access
12 Citations
3,880 Views
13 Pages

Binder-Free Ge-Co-P Anode Material for Lithium-Ion and Sodium-Ion Batteries

  • Tatiana L. Kulova,
  • Alexander M. Skundin,
  • Il’ya M. Gavrilin,
  • Yulia O. Kudryashova,
  • Irina K. Martynova and
  • Svetlana A. Novikova

Nanostructure composites Ge-Co-P with brutto-composition CoGe2P0.1, or CoGe2@GeP were manufactured via electrolysis of aqueous electrolyte. Such composites are able to reversible insertion of lithium and sodium with specific capacities up to 855 and...

  • Article
  • Open Access
9 Citations
3,393 Views
14 Pages

Nickel-Doped Ceria Bifunctional Electrocatalysts for Oxygen Reduction and Evolution in Alkaline Media

  • Jadranka Milikić,
  • Rodolfo O. Fuentes,
  • Julia E. Tasca,
  • Diogo M. F. Santos,
  • Biljana Šljukić and
  • Filipe M. L. Figueiredo

19 August 2022

Nickel-doped ceria (Ce1−xNixO2−δ) nanopowders (7 to 5 nm in size) synthesized by the cation complexation method with 5, 10, 15, and 20 Ni at.% are studied with respect to their electrochemical activity for the oxygen reduction (ORR)...

  • Review
  • Open Access
27 Citations
6,353 Views
16 Pages

The current mainstream energy storage systems are in urgent need of performance improvements to meet novel application requirements. In pursuit of a higher energy density in Li-ion and Na-ion batteries, the conventional electrode materials have reach...

  • Feature Paper
  • Article
  • Open Access
5 Citations
6,773 Views
15 Pages

Insights into the Electrochemical Performance of 1.8 Ah Pouch and 18650 Cylindrical NMC:LFP|Si:C Blend Li-ion Cells

  • Imanol Landa-Medrano,
  • Aitor Eguia-Barrio,
  • Susan Sananes-Israel,
  • Willy Porcher,
  • Khiem Trad,
  • Arianna Moretti,
  • Diogo Vieira Carvalho,
  • Stefano Passerini and
  • Iratxe de Meatza

Silicon has become an integral negative electrode component for lithium-ion batteries in numerous applications including electric vehicles and renewable energy sources. However, its high capacity and low cycling stability represent a significant trad...

  • Feature Paper
  • Review
  • Open Access
57 Citations
7,561 Views
26 Pages

Echelon Utilization of Retired Power Lithium-Ion Batteries: Challenges and Prospects

  • Ningbo Wang,
  • Akhil Garg,
  • Shaosen Su,
  • Jianhui Mou,
  • Liang Gao and
  • Wei Li

The explosion of electric vehicles (EVs) has triggered massive growth in power lithium-ion batteries (LIBs). The primary issue that follows is how to dispose of such large-scale retired LIBs. The echelon utilization of retired LIBs is gradually occup...

  • Article
  • Open Access
4 Citations
4,970 Views
17 Pages

Scalable Silicone Composites for Thermal Management in Flexible Stretchable Electronics

  • George-Theodor Stiubianu,
  • Adrian Bele,
  • Marian Grigoras,
  • Codrin Tugui,
  • Bianca-Iulia Ciubotaru,
  • Mirela-Fernanda Zaltariov,
  • Firuța Borza,
  • Leandru-Gheorghe Bujoreanu and
  • Maria Cazacu

Hexagonal boron nitride (hBN) has been incorporated, as an active filler, in a customized silicone matrix to obtain high thermal conductivity composites, maintaining high flexibility and low dielectric permittivity, which are of interest for heat dis...

  • Communication
  • Open Access
1 Citations
2,594 Views
10 Pages

Although research in the field of lithium-oxygen (air) batteries (LOB) is rapidly developing, few comprehensive studies on the dependence of the catalytic properties of positive electrode materials on LOB test conditions are present. In this paper, t...

  • Article
  • Open Access
23 Citations
5,373 Views
18 Pages

A Novel Synchronized Multiple Output DC-DC Converter Based on Hybrid Flyback-Cuk Topologies

  • Khaled A. Mahafzah,
  • Mohammad A. Obeidat,
  • Ali Q. Al-Shetwi and
  • Taha Selim Ustun

This paper proposes a new hybrid flyback-Cuk (HFC) converter. The new converter consists of a single switch, a single isolated input, and dual output based on flyback and Cuk topologies. The new HFC topology is proposed to reduce switching losses and...

  • Article
  • Open Access
19 Citations
7,744 Views
18 Pages

Effects of Cell Design Parameters on Zinc-Air Battery Performance

  • Cian-Tong Lu,
  • Zhi-Yan Zhu,
  • Sheng-Wen Chen,
  • Yu-Ling Chang and
  • Kan-Lin Hsueh

Zn-air batteries have attracted considerable attention from researchers owing to their high theoretical energy density and the abundance of zinc on Earth. The modification of battery component materials represent a common approach to improve battery...

  • Article
  • Open Access
6 Citations
3,664 Views
13 Pages

Here, we study an effect of FEC addition to TC-E918 electrolyte on the electrochemical performance of Si/C negative electrodes. The anodes were fabricated from nanosilicon powder coated with a carbon shell by means of a standard slurry technique. The...

  • Feature Paper
  • Article
  • Open Access
12 Citations
4,663 Views
20 Pages

Parameter Identification Method for a Fractional-Order Model of Lithium-Ion Batteries Considering Electrolyte-Phase Diffusion

  • Yanbo Jia,
  • Lei Dong,
  • Geng Yang,
  • Feng Jin,
  • Languang Lu,
  • Dongxu Guo and
  • Minggao Ouyang

The physics-based fractional-order model (FOM) for lithium-ion batteries has shown good application prospects due to its mechanisms and simplicity. To adapt the model to higher-level applications, this paper proposes an improved FOM considering elect...

  • Article
  • Open Access
4 Citations
3,649 Views
18 Pages

Effect of Si-Based Anode Lithiation on Charging Characteristics of All-Solid-State Lithium-Ion Battery

  • Alexander S. Rudy,
  • Sergei V. Kurbatov,
  • Alexander A. Mironenko,
  • Victor V. Naumov,
  • Alexander M. Skundin and
  • Yulia S. Egorova

The description of the design, manufacturing technology, and test results of thin-film solid-state lithium-ion batteries with a nanocomposite negative electrode Si@O@Al is given herein. This electrochemical system features the hike on the charging cu...

  • Article
  • Open Access
14 Citations
5,006 Views
17 Pages

Development of an Innovative Procedure for Lithium Plating Limitation and Characterization of 18650 Cycle Aged Cells for DCFC Automotive Applications

  • Matteo Dotoli,
  • Emanuele Milo,
  • Mattia Giuliano,
  • Arianna Tiozzo,
  • Marcello Baricco,
  • Carlo Nervi,
  • Massimiliano Ercole and
  • Mauro Francesco Sgroi

Since lithium-ion batteries seem to be the most eligible technology to store energy for e-mobility applications, it is fundamental to focus attention on kilometric ranges and charging times. The optimization of the charging step can provide the appro...

  • Article
  • Open Access
4 Citations
3,362 Views
9 Pages

Nanocomposite Janus Gel Polymer Electrolytes for Lithium Metal Batteries

  • Riccardo Morina,
  • Rebecca Baroni,
  • Daniele Callegari,
  • Eliana Quartarone and
  • Piercarlo Mustarelli

Lithium metal batteries (LMBs) are a key product for sustainable and efficient electric transport. Long-life and safe LMBs require the development of solid or semisolid (e.g., gel polymer) electrolytes capable of blocking lithium dendrites. In this c...

  • Feature Paper
  • Article
  • Open Access
12 Citations
4,977 Views
15 Pages

Differential capacity dQ/dU (capacitance) can be used for the instant diagnosis of battery performance in common constant current applications. A novel criterion allows state-of-charge (SOC) and state-of-health (SOH) monitoring of lithium-ion batteri...

  • Article
  • Open Access
14 Citations
5,618 Views
16 Pages

A method for estimating the stack rating of vanadium redox flow batteries (VRFBs) through constant power characterization was developed. A stack of 22 cells, each with 1500 cm2 of nominal electrode area, was constructed and tested using constant curr...

  • Article
  • Open Access
12 Citations
4,309 Views
11 Pages

Multi-Functional Potassium Ion Assists Ammonium Vanadium Oxide Cathode for High-Performance Aqueous Zinc-Ion Batteries

  • Dan He,
  • Tianjiang Sun,
  • Qiaoran Wang,
  • Tao Ma,
  • Shibing Zheng,
  • Zhanliang Tao and
  • Jing Liang

Ammonium vanadium oxide (NH4V4O10) is a promising layered cathode for aqueous zinc-ion batteries owing to its high specific capacity (>300 mA h g−1). However, the structural instability causes serious cycling degradation through irreversible...

  • Feature Paper
  • Article
  • Open Access
45 Citations
19,775 Views
24 Pages

In response to the increasing expansion of the electric vehicles (EVs) market and demand, billions of dollars are invested into the battery industry to increase the number and production volume of battery cell manufacturing plants across the world, e...

  • Article
  • Open Access
5 Citations
4,899 Views
14 Pages

We demonstrate that dispersion stability and excellent coating quality are achieved in polyethylene (PE) separators by premixing heterogeneous ceramics such as silica (SiO2) and alumina (Al2O3) in an aqueous solution, without the need for functional...

  • Feature Paper
  • Article
  • Open Access
2 Citations
2,910 Views
12 Pages

Generating useful chemicals from CO2 is driving research into carbon capture and utilization. In this work, hard carbons are electrodeposited on various substrates from molten carbonate melts in CO2 atmospheres. These electrodeposited carbons are sub...

  • Feature Paper
  • Article
  • Open Access
5 Citations
3,200 Views
16 Pages

Nanomechanical, Structural and Electrochemical Investigation of Amorphous and Crystalline MoO3 Thin-Film Cathodes in Rechargeable Li-Ion Batteries

  • Wissem Methani,
  • Edit Pál,
  • Sándor Lipcsei,
  • Dávid Ugi,
  • Zoltán Pászti,
  • István Groma,
  • Péter Jenei,
  • Zoltán Dankházi and
  • Robert Kun

In this work, a comprehensive investigation of amorphous and crystalline modification of identical electrode active material as a thin-film electrode for a future all-solid-state Li-ion battery application is presented and discussed. Using the propos...

  • Feature Paper
  • Article
  • Open Access
12 Citations
6,795 Views
18 Pages

Influence of the Ambient Storage of LiNi0.8Mn0.1Co0.1O2 Powder and Electrodes on the Electrochemical Performance in Li-ion Technology

  • Iratxe de Meatza,
  • Imanol Landa-Medrano,
  • Susan Sananes-Israel,
  • Aitor Eguia-Barrio,
  • Oleksandr Bondarchuk,
  • Silvia Lijó-Pando,
  • Iker Boyano,
  • Verónica Palomares,
  • Teófilo Rojo and
  • Idoia Urdampilleta
  • + 1 author

Nickel-rich LiNi0.8Mn0.1Co0.1O2 (NMC811) is one of the most promising Li-ion battery cathode materials and has attracted the interest of the automotive industry. Nevertheless, storage conditions can affect its properties and performance. In this work...

  • Article
  • Open Access
7 Citations
4,854 Views
12 Pages

Large cations such as potassium ion (K+) and sodium ion (Na+) could be introduced into the lithium-ion (Li-ion) battery system during material synthesis or battery assembly. However, the effect of these cations on charge storage or electrochemical pe...

  • Feature Paper
  • Article
  • Open Access
28 Citations
18,277 Views
15 Pages

Open circuit voltage relaxation to a steady state value occurs, and is measured, at the terminals of a lithium-ion battery when current stops flowing. It is of interest for use in determining state of charge and state of health. As voltage relaxation...

  • Article
  • Open Access
10 Citations
10,840 Views
24 Pages

Life Cycle Assessment of a Lithium-Ion Battery Pack Unit Made of Cylindrical Cells

  • Morena Falcone,
  • Nicolò Federico Quattromini,
  • Claudio Rossi and
  • Beatrice Pulvirenti

Saving energy is a fundamental topic considering the growing energy requirements with respect to energy availability. Many studies have been devoted to this question, and life cycle assessment (LCA) is increasingly acquiring importance in several fie...

  • Article
  • Open Access
4 Citations
3,403 Views
17 Pages

Nonaqueous redox flow batteries are promising candidates for large-scale energy storage technologies. However, the effect of structural design and key factors limiting the performance are still not thoroughly understood. In this work, we constructed...

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Batteries - ISSN 2313-0105