Development of an Innovative Procedure for Lithium Plating Limitation and Characterization of 18650 Cycle Aged Cells for DCFC Automotive Applications
Abstract
:1. Introduction
2. Materials and Methods
2.1. Battery Cells
2.2. Cycling Condition and Experimental Setup
2.2.1. Testing Facilities
2.2.2. Electrochemical Testing
2.2.3. Incremental Capacity Analysis
2.3. Teardown and Sampling
2.4. XRD Analysis
2.5. SEM/EDX
2.6. Particle Size Analysis
2.7. ICP-OES Analysis
2.8. Lab Scale Cells Preparation and Electrochemical Performances Tests
2.8.1. Samples Dismantling Procedure
2.8.2. Samples Selection
2.8.3. Lab Scale Cell Building
3. Results
3.1. Cycle Aging Campaing
3.2. Non-Disruptive Characterization Techniques
3.3. Disruptive Characterization Techniques
3.3.1. Visual Inspection
3.3.2. Scanning Electron Microscopy, ICP-OES, and Particle Size Analysis
3.3.3. Three Electrode Lab Scale Cell–Incremental Capacity Analysis
3.3.4. X-ray Diffraction Analysis
- -
- Low a (Å) lattice parameter values for the most aged cells (Reference and MCCFast2);
- -
- High c (Å) lattice parameter values for the most aged cells (Reference and MCCFast2);
- -
- Absence of Li/Ni mixing.
4. Discussion
4.1. Cycle Aging Campaign
4.2. Non-Disruptive Characterization Techniques
4.2.1. Incremental Capacity Analysis (ICA) on Full 18650 Cells
4.2.2. Internal Resistance Evolution
4.3. Disruptive Characterization Techniques
4.3.1. Visual Inspection
4.3.2. SEM, ICP-OES, and Particle Size Analysis
4.3.3. Three-Electrode Lab Scale Cell—ICA
4.3.4. XRD Measurements
5. Conclusions
- The use of ICA in the present study confirms the general good health of the tested cells, indeed no significant degradation on the NMC811 electrode was observed and localized degradation on the Si-C electrode, where lithium plating occurs, was noticed. Physicochemical characterization, along with visual inspection, confirms data obtained from ICA, both in full cells and in lab scale three-electrode cells. Where no evident damage is visible on the electrode samples, ICA responses confirm the absence of significant degradation;
- Among the new implemented approaches, internal resistance test (Rint vs. SoH%) can be considered as a useful “in situ” methodology to control the current (and voltage) limits on the cell, during the aging cycle.
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Abbreviations
MCC | Multistage Constant Current |
Ref | Reference |
SEM | Scanning Electron Microscopy |
XRD | X-Ray Diffraction |
ICE | Internal Combustion Engine |
BMS | Battery Management System |
DoD | Depth of Discharge |
LLI | Loss of Lithium Inventory |
SEI | Solid Electrolyte Interphase |
LAM | Loss of Active Material |
ORI | Ohmic Resistance Increase |
SoH | State of Health |
ICA | Incremental Capacity Analysis |
EC:DMC | Ethylen carbonate:Dymethyl carbonate |
LiPF6 | Lithium exafluorophosfate |
DCFC | Direct Current Fast Charging |
EOL | End of Life |
C-rate | Charging rate |
SoD | State of Discharge |
WD | Working Distance |
EDX | Energy Dispersive X-Ray Analysis |
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Lattice Parameters from the Rietveld Refinement for EOL 1000 Cycles Cells | |||||
---|---|---|---|---|---|
Reference | MCC1 | MCC2 | MCCFast1 | MCCFast2 | |
a (Å) | 2.867 | 2.871 | 2.870 | 2.870 | 2.868 |
c (Å) | 14.258 | 14.252 | 14.249 | 14.252 | 14.257 |
I003/I104 | 1.49 | 1.54 | 1.59 | 1.54 | 1.53 |
Reference | MCC1 | MCC2 | MCCFast1 | MCCFast2 | |
---|---|---|---|---|---|
SoH % | 88.48 | 91.53% | 91.74% | 90.88% | 87.55% |
Time for Charge [Minute] | 5 | 10 | 15 | 20 | 25 | 30 |
---|---|---|---|---|---|---|
Reference | 16% | 25% | 33% | 41% | 50% | 58% |
MCC1 | 16% | 25% | 35% | 44% | 53% | 60% |
MCC2 | 17% | 26% | 35% | 44% | 53% | 60% |
MCCFast1 | 19% | 30% | 41% | 50% | 58% | 64% |
MCCFast2 | 25% | 40% | 53% | 59% | 65% | 70% |
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Dotoli, M.; Milo, E.; Giuliano, M.; Tiozzo, A.; Baricco, M.; Nervi, C.; Ercole, M.; Sgroi, M.F. Development of an Innovative Procedure for Lithium Plating Limitation and Characterization of 18650 Cycle Aged Cells for DCFC Automotive Applications. Batteries 2022, 8, 88. https://doi.org/10.3390/batteries8080088
Dotoli M, Milo E, Giuliano M, Tiozzo A, Baricco M, Nervi C, Ercole M, Sgroi MF. Development of an Innovative Procedure for Lithium Plating Limitation and Characterization of 18650 Cycle Aged Cells for DCFC Automotive Applications. Batteries. 2022; 8(8):88. https://doi.org/10.3390/batteries8080088
Chicago/Turabian StyleDotoli, Matteo, Emanuele Milo, Mattia Giuliano, Arianna Tiozzo, Marcello Baricco, Carlo Nervi, Massimiliano Ercole, and Mauro Francesco Sgroi. 2022. "Development of an Innovative Procedure for Lithium Plating Limitation and Characterization of 18650 Cycle Aged Cells for DCFC Automotive Applications" Batteries 8, no. 8: 88. https://doi.org/10.3390/batteries8080088