Magnetochemistry, Volume 10, Issue 12

In this study, we investigate the magnetic properties of the molecular compound [Mn(mal)(H₂O)]ₙ (mal = dianion of malonic acid) by integrating microscopic and macroscopic characterization, combining unpolarized neutron diffraction and magnetome...

Magnetic nanomaterials, in which non-bulk magnetic properties emerge because of their low dimension, are a class of materials with huge application potential in several areas, providing, at the same time, an exciting field of fundamental research [...]

Spin-crossover (SCO) and single-ion magnets (SIMs), or their mixed SCO-SIM derivatives, are a convenient solution in the evolution from molecular magnetism toward molecular spintronics and quantum computing. Herein, we report on the current trends an...

In granular media for perpendicular magnetic recording, zigzag-shaped magnetic domain boundaries form between magnetic grains isolated by a non-magnetic grain boundary phase. They are the main source of jitter noise caused by the position fluctuation...

This article reports the preparation of a novel functionalized magnetic nanoadsorbent through an addition reaction between Fe₃O₄ nanoparticles coated with allyl silica gel and 4-pyridinyl ethylene. A detailed characterization of Fe₃O₄@SiO₂-yl-VP was...

We report here the synthesis of a series of nine coordinated mononuclear Ln^III complexes [LnL₁Cl₂(DMF)]Cl·2.5DMF and [LnL¹(L₂)₂]Cl·4CH₃OH (Ln^III = Gd^III, Dy^III, Er^III and Yb^III, HL₂ = 9-anthracenecarboxylic acid), where L1 is a hexadent...

In this work, we describe the synthesis, crystal structures and magnetic properties of four air-stable mononuclear lanthanide(III) complexes with the N-(2,4,6-trimethylphenyl)oxamate (Htmpa) of formula: n-Bu₄N[Nd(Htmpa)₄(H₂O)]·4H₂O (1), n-Bu₄N...

A trinuclear Co(II)-containing complex was assembled using the non-innocent hexahydroxytriphenylene bridging ligand. Cyclovoltammetry and spectroelectrochemistry studies revealed that the central ligand sustained four reversible redox events, leading...

Surface quality control of hot-dip galvanized sheets is a critical research topic in the metallurgical industry. Zinc dross, the most common surface defect in the hot-dip galvanizing process, significantly affects the sheet’s service performanc...

Since the discovery of graphene in 2004, two-dimensional (2D) van der Waals (vdW) layered materials have attracted extensive attention for their great potential for application in the electronic, optoelectronic, and electrochemical fields [...]

The intrinsic characteristic features of metal–organic frameworks offer unique, great opportunities to develop novel materials with applications in very diverse fields. Aiming to take advantage of these, the application of post-synthetic method...

Microcantilevers (MCs) are highly sensitive sensors capable of detecting mass changes on the surface at the nanogram and even picogram scale. In this study, microcantilevers were fabricated for the first time using the Sodick AP250L Wire electrical d...

We have investigated the phase formation, microstructure, and permeability of stoichiometric and Fe-deficient Ni-Cu-Zn ferrites of composition Ni_0.30Cu_0.20Zn_0.50+zFe_2−zO_4−(z/2) with 0 ≤ z ≤ 0.06 sintered at 1000 °C in various ox...

The heterobimetallic 15-MC-5 metallacrown of formula [CeCu₅(5mpzHA)₅(NO₃)(H₂O)₇]·2NO₃·7H₂O, designated MC-Ce, was synthesized using 5-methyl-2-pyrazinehydroxamic acid (5mpzHA) as a linker, reacting with Ce^III and Cu^II salts under mild c...

This research examined the elimination of methyl orange (MO) utilizing a novel magnetic biochar adsorbent (MLPB) derived from lemon peels via an impregnation-pyrolysis method. Material characterization was conducted using SEM, XRD, TGA, FTIR, and nit...

The synthesis, structural, and magnetic characterization of a novel neutral copper(II) hexanuclear complex [Cu₆(en)₄(OCH₂CH₂O)₂(pyox)₄]·3eg·en·12H₂O (1) was investigated [en = ethylenediamine, eg = ethylene glycol, and H₂pyox = 4...

Two new compounds, (NH₄)₄[Cu₇(Hmesox)₆(H₂O)₈]∙10H₂O (1) and [Ru(bpy)₃]₄[Cu₇(Hmesox)₆Cl₂]Cl₂∙2CH₃CN∙12H₂O (2), were prepared and their structures were solved by single-crystal X-ray diffraction (mesoxalic acid = dihydroxypropanedioic...

The magnetic properties of various types of structures based on iron oxides and the other ferri- or ferromagnets strongly correlate with their origin [...]