2019 June - 77 articles
Heterogeneous enantioselective hydrogenation is an ideal method for synthesizing important chiral compounds in pesticides and pharmaceuticals. Up to the present, supported noble-metal catalysts are most widely studied in heterogeneous enantioselectiv...
Here, we report the tripeptide-catalyzed asymmetric aldol reaction between α-ketoesters and acetone under acidic cocatalysts-free conditions. H-Pro-Tle-Gly-OH 3g-catalyzed reactions between α-ketoesters and acetone resulted in up to 95% y...
Carbon dioxide produced by human activities is one of the main contributions responsible for the greenhouse effect, which is modifying the Earth’s climate. Therefore, post-combustion CO2 capture and its conversion into high value-added chemical...
Much has been written about the fundamental aspects of the metal–organic frameworks (MOFs). Still, details concerning the MOFs with structural flexibility are not comprehensively understood. However, a dramatic increase in research activities c...
Sugar esters are bioactive compounds derived from renewable resources. They consist of a sugar moiety with attached non-polar part – usually a fatty acid. These compounds find uses in cosmetic, food and pharmaceutical industries as surfactants...
Highly-dispersed Ni-NiO nanoparticles was successfully anchored on an SiO2 support via a one-pot synthesis and used as heterogeneous catalysts for CO methanation. The as-obtained Ni-NiO/SiO2 catalyst possessed a high Ni content of 87.8 wt.% and exhib...
Mass and heat transfer coefficients (MTC and HTC) in automotive exhaust catalytic monolith channels are estimated and correlated for a wide range of gas velocities and prevailing conditions of small up to real size converters. The coefficient estimat...
This work describes research on the isomerization of R(+)-limonene over the Ti-MCM-41 catalyst. The studies showed that the Ti-MCM-41 catalyst is an active catalyst in the isomerization of R(+)-limonene. As a result of the isomerization of this compo...
Textile industries produce a complex wastewater which is difficult to be treated. In this work, a catalytic degradation of wastewater effluent composed of sulphur black coloring agent discharged by industry was studied. UV lamp power, peroxide concen...
Kinetics and reactor modeling for heterogeneous catalytic reactions are prominent tools for investigating, and understanding, the catalyst functionalities at nanoscale, and related rates of complex reaction networks [...]
A modified zeolite/TiO2 composite (MZTC) was prepared through a method of saturated infiltration and synthesis in situ. The crystalline phase, micromorphology, elementary composition, specific surface area, pore size distribution, chemical bond and b...
A new catalytic system for transfer hydrogenation of carbonyl compounds using glucose as a hydrogen donor was developed. Various ketones and aldehydes were efficiently converted to corresponding alcohols with two equivalents of glucose in the presenc...
We studied the acetylene hydrochlorination in gas–liquid phase reactions using ionic liquids (IL) as the reaction media and CuCl2 as the catalyst. The Cu-IL catalyst showed strong synergy between the IL and the Cu(II) active catalytic species....
Ammonium iron citrate was used as an iron precursor in order to prepare N-doped catalysts supported on KMnO4 pretreated activated carbon (10MnK-AC). Iron nitride was synthesized in company with the formation of α-Fe2O3 on 10MnK-AC. The characte...
High acidic vacuum gas oil (VGO) decreases product quality and causes corrosions. To overcome these problems, catalytic esterification was utilized for the deacidification of VGO. A series of Al2O3-supported ZnO catalysts, undoped and doped with Fe2O...
Application of solar photocatalysis for water treatment is intensively studied. In this work, we investigated TiO2 modified with platinum (Pt/TiO2) and palladium (Pd/TiO2) using sulfamethoxazole (SMX) as the model contaminant. We considered the follo...
A series of CeOx catalysts supported by commercial porous cordierite ceramics (CPCC) and synthesized porous cordierite ceramics (SPCC) from fly ash were prepared for selective catalytic reduction of NOx with ammonia (NH3-SCR). A greater than 90% NOx...
Co-containing Beta zeolite catalysts prepared by a wet impregnation and two-step postsynthesis method were investigated. The activity of the catalysts was examined in Fischer-Tropsch synthesis (FTS), performed at 30 atm and 260 °C. The physicoche...
An efficient photocatalyst, ZnO–single-walled carbon nanotube (ZnO–SWCNT) nanocomposite was successfully fabricated through a straightforward one-pot–two-chemical recrystallization technique followed by thermal decomposition. The ph...
Energy and fuels derived from biomass pose lesser impact on the environmental carbon footprint than those derived from fossil fuels. In order for the biomass-to-energy and biomass-to-chemicals processes to play their important role in the loop of the...
The development of efficient methodologies for production of amines attracts significant attention from synthetic chemists, because amines serve as essential building blocks in the synthesis of many pharmaceuticals, natural products, and agrochemical...
One of the most important issues in photocatalysis research has been the development of TiO2-based photocatalysts that work efficiently under visible light conditions. Here, we report the monodispersed, spherical TiO2 particles with disordered rutile...
In the present work, a series of different materials was investigated in order to enhance the understanding of the role of modern lean NOx trap (LNT) components on the sulfur poisoning and regeneration characteristics. Nine different types of model c...
The resistance to sintering of Ni/Al2O3 catalysts with different additives for methanation reaction was modeled and predicted by data mining. In the screening, the resistance to sintering of Na, Ca, Ce, Mg, La, Cu, Zn, Zr, In, Mo, and Ti promoted Ni/...
Diverse methods have been employed to synthesize MoS2 and MoSe2 catalyst systems. Herein, a combined photoelectrochemical (PEC) deposition and rapid-thermal annealing process has first been employed to fabricate MoS2 and MoSe2 thin films on Si substr...
Enzymatic membrane bioreactors (EMBRs) possess the characteristic of combining catalysis with separation, and therefore have promising application potentials. In order to achieve a high-performance EMBR, membrane property, as well as operating parame...
Seawater scrubbing of nitrogen oxides and sulfur oxide from marine emissions was simulated in packed-bed columns exposed to static inclination and heaving/oscillating motions. Fourth generation random packings (Raschig super-Rings) while providing mu...
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