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Editor’s Choice Articles

Editor’s Choice articles are based on recommendations by the scientific editors of MDPI journals from around the world. Editors select a small number of articles recently published in the journal that they believe will be particularly interesting to readers, or important in the respective research area. The aim is to provide a snapshot of some of the most exciting work published in the various research areas of the journal.

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19 pages, 989 KiB  
Review
Probiotics in Fish Nutrition—Long-Standing Household Remedy or Native Nutraceuticals?
by Sven Wuertz, Arne Schroeder and Konrad M. Wanka
Water 2021, 13(10), 1348; https://doi.org/10.3390/w13101348 - 13 May 2021
Cited by 60 | Viewed by 18313
Abstract
Over the last decades, aquaculture production increased rapidly. The future development of the industry highly relies on the sustainable utilization of natural resources. The need for improving disease resistance, growth performance, food conversion, and product safety for human consumption has stimulated the application [...] Read more.
Over the last decades, aquaculture production increased rapidly. The future development of the industry highly relies on the sustainable utilization of natural resources. The need for improving disease resistance, growth performance, food conversion, and product safety for human consumption has stimulated the application of probiotics in aquaculture. Probiotics increase growth and feed conversion, improve health status, raise disease resistance, decrease stress susceptibility, and improve general vigor. Currently, most probiotics still originate from terrestrial sources rather than fish. However, host-associated (autochthonous) probiotics are likely more persistent in the gastrointestinal tract of fish and may, therefore, exhibit longer-lasting effects on the host. Probiotic candidates are commonly screened in in vitro assays, but the transfer to in vivo assessment is often problematic. In conclusion, modulation of the host-associated microbiome by the use of complex probiotics is promising, but a solid understanding of the interactions involved is only in its infancy and requires further research. Probiotics could be used to explore novel ingredients such as chitin-rich insect meal, which cannot be digested by the fish host alone. Most importantly, probiotics offer the opportunity to improve stress and disease resistance, which is among the most pressing problems in aquaculture. Full article
(This article belongs to the Section Water, Agriculture and Aquaculture)
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27 pages, 987 KiB  
Review
An Overview of Multi-Criteria Decision Analysis (MCDA) Application in Managing Water-Related Disaster Events: Analyzing 20 Years of Literature for Flood and Drought Events
by Mohammad Fikry Abdullah, Sajid Siraj and Richard E. Hodgett
Water 2021, 13(10), 1358; https://doi.org/10.3390/w13101358 - 13 May 2021
Cited by 73 | Viewed by 11212
Abstract
This paper provides an overview of multi-criteria decision analysis (MCDA) applications in managing water-related disasters (WRD). Although MCDA has been widely used in managing natural disasters, it appears that no literature review has been conducted on the applications of MCDA in the disaster [...] Read more.
This paper provides an overview of multi-criteria decision analysis (MCDA) applications in managing water-related disasters (WRD). Although MCDA has been widely used in managing natural disasters, it appears that no literature review has been conducted on the applications of MCDA in the disaster management phases of mitigation, preparedness, response, and recovery. Therefore, this paper fills this gap by providing a bibliometric analysis of MCDA applications in managing flood and drought events. Out of 818 articles retrieved from scientific databases, 149 articles were shortlisted and analyzed using a Preferred Reporting Items for Systematic Reviews and Meta-analyses (PRISMA) approach. The results show a significant growth in MCDA applications in the last five years, especially in managing flood events. Most articles focused on the mitigation phase of DMP, while other phases of preparedness, response, and recovery remained understudied. The analytical hierarchy process (AHP) was the most common MCDA technique used, followed by mixed-method techniques and TOPSIS. The article concludes the discussion by identifying a number of opportunities for future research in the use of MCDA for managing water-related disasters. Full article
(This article belongs to the Section Water Resources Management, Policy and Governance)
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17 pages, 7134 KiB  
Article
PATs Behavior in Pressurized Irrigation Hydrants towards Sustainability
by Modesto Pérez-Sánchez, João F. P. Fernandes, P. J. Costa Branco, P. Amparo López-Jiménez and Helena M. Ramos
Water 2021, 13(10), 1359; https://doi.org/10.3390/w13101359 - 13 May 2021
Cited by 5 | Viewed by 3806
Abstract
Sustainability and efficiency in irrigation are essential in the management of the water–energy–food nexus to reach the Sustainable Development Goals in 2030. In irrigation systems, the reduction of energy consumption is required to improve the system efficiency and consequently the sustainability indicators of [...] Read more.
Sustainability and efficiency in irrigation are essential in the management of the water–energy–food nexus to reach the Sustainable Development Goals in 2030. In irrigation systems, the reduction of energy consumption is required to improve the system efficiency and consequently the sustainability indicators of the water network. The use of pumps working as turbines (PATs) has been a feasible solution to recover the excess of energy where pressure reduction valves are installed. This research demonstrates the use of PATs under steady and unsteady conditions by analyzing the application in a real irrigation networks located in Vallada (Valencia, Spain). The study shows the possibility of recovering 44 MWh/year using PATs installed upstream of the irrigation hydrants. The real behavior of the PAT operation in a stand-alone recovery energy solution allowed analysis of the flow, head and efficiency variation as a function of the rotational speed, as well as the minimum capacitance to self-excite the generator and the resistive load of the electrical circuit. The PAT limit is examined in terms of the overpressure induced by a fast closure manoeuvre of hydrants, and the runaway conditions due to the disconnection from the electrical load. Full article
(This article belongs to the Special Issue Energy Recovery and Hybrid Solutions in the Water Sector)
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23 pages, 10423 KiB  
Article
Sediment Distribution, Retention and Morphodynamic Analysis of a River-Dominated Deltaic System
by Ehab Meselhe, Kazi Sadid and Ashok Khadka
Water 2021, 13(10), 1341; https://doi.org/10.3390/w13101341 - 12 May 2021
Cited by 14 | Viewed by 4225
Abstract
River deltas have received considerable attention due to coastal land loss issues caused by subsidence, storms, and sea level rise. Improved understanding of deltaic processes and dynamics is vital to coastal restoration efforts. This paper describes the application of process-based morphodynamic models to [...] Read more.
River deltas have received considerable attention due to coastal land loss issues caused by subsidence, storms, and sea level rise. Improved understanding of deltaic processes and dynamics is vital to coastal restoration efforts. This paper describes the application of process-based morphodynamic models to a prograding river delta. The analysis focuses on the flow and sediment dynamics amongst the interconnected channel network of the delta. The models were validated against observations of velocity and sediment concentrations for the Wax Lake Delta (WLD) of the Atchafalaya River system in Louisiana, USA. The WLD provides an opportunity as a natural laboratory for studying the processes associated with river dominated deltaic growth. It includes a network of bifurcated channels that self-organize and dynamically adjust, as the delta grows seaward to the Gulf of Mexico. The model results for a flood event show that 47% of the flow exits the system as channelized flow and the remaining 53% exits as overbank flow. The fine sediment (silt and clay) distribution was proportional with water fluxes throughout the channel network, whereas sand distribution was influenced by geometric attributes (size, invert elevation, and alignment) of the distributary channels. The long-term deltaic growth predicted by the model compares well with the observations for the period 1998–2012. This paper provides insights on how the distribution of flow and sediment amongst the interconnected delta channels influences the morphodynamics of the delta to reach a dynamic equilibrium within this relatively young deltaic system. Full article
(This article belongs to the Section Water Erosion and Sediment Transport)
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17 pages, 5300 KiB  
Article
Energy Dissipation in Stilling Basins with Side Jets from Highly Convergent Chutes
by Rafael Moran, Miguel Ángel Toledo, Javier Peraita and Raffaella Pellegrino
Water 2021, 13(10), 1343; https://doi.org/10.3390/w13101343 - 12 May 2021
Cited by 6 | Viewed by 4079
Abstract
Spillways with Highly Converging Chutes (HCCs) are a non-conventional alternative that can be applied to achieve a higher outflow capacity when the weir length exceeds the width of the valley at the toe of gravity or arch dams. This kind of spillway has [...] Read more.
Spillways with Highly Converging Chutes (HCCs) are a non-conventional alternative that can be applied to achieve a higher outflow capacity when the weir length exceeds the width of the valley at the toe of gravity or arch dams. This kind of spillway has been used in the past, but no general studies have yet been published. This article summarizes experimental research work aiming to increase the knowledge of the effect of some design parameters of HCCs on the energy dissipation in the stilling basin at the toe of the dam. As a comparison reference, we use the Type I stilling basins, widely known by the technical dam engineering community. The obtained results show that spillways with HCCs are a promising alternative to traditional designs, combining the ability to increase the weir length with a high capacity to dissipate energy through the impingement effect of the frontal and the side jets inside the stilling basin. Full article
(This article belongs to the Special Issue Dam Safety. Overtopping and Geostructural Risks)
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37 pages, 380 KiB  
Review
A Comprehensive Review on Membrane Fouling: Mathematical Modelling, Prediction, Diagnosis, and Mitigation
by Nour AlSawaftah, Waad Abuwatfa, Naif Darwish and Ghaleb Husseini
Water 2021, 13(9), 1327; https://doi.org/10.3390/w13091327 - 11 May 2021
Cited by 222 | Viewed by 27160
Abstract
Membrane-based separation has gained increased popularity over the past few decades, particularly reverse osmosis (RO). A major impediment to the improved performance of membrane separation processes, in general, is membrane fouling. Fouling has detrimental effects on the membrane’s performance and integrity, as the [...] Read more.
Membrane-based separation has gained increased popularity over the past few decades, particularly reverse osmosis (RO). A major impediment to the improved performance of membrane separation processes, in general, is membrane fouling. Fouling has detrimental effects on the membrane’s performance and integrity, as the deposition and accumulation of foulants on its surface and/or within its pores leads to a decline in the permeate flux, deterioration of selectivity, and permeability, as well as a significantly reduced lifespan. Several factors influence the fouling-propensity of a membrane, such as surface morphology, roughness, hydrophobicity, and material of fabrication. Generally, fouling can be categorized into particulate, organic, inorganic, and biofouling. Efficient prediction techniques and diagnostics are integral for strategizing control, management, and mitigation interventions to minimize the damage of fouling occurrences in the membranes. To improve the antifouling characteristics of RO membranes, surface enhancements by different chemical and physical means have been extensively sought after. Moreover, research efforts have been directed towards synthesizing membranes using novel materials that would improve their antifouling performance. This paper presents a review of the different membrane fouling types, fouling-inducing factors, predictive methods, diagnostic techniques, and mitigation strategies, with a special focus on RO membrane fouling. Full article
(This article belongs to the Section Water and One Health)
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14 pages, 2870 KiB  
Article
Assessment of Microplastics in a Municipal Wastewater Treatment Plant with Tertiary Treatment: Removal Efficiencies and Loading per Day into the Environment
by Javier Bayo, Sonia Olmos and Joaquín López-Castellanos
Water 2021, 13(10), 1339; https://doi.org/10.3390/w13101339 - 11 May 2021
Cited by 45 | Viewed by 8180
Abstract
This study investigates the removal of microplastics from wastewater in an urban wastewater treatment plant located in Southeast Spain, including an oxidation ditch, rapid sand filtration, and ultraviolet disinfection. A total of 146.73 L of wastewater samples from influent and effluent were processed, [...] Read more.
This study investigates the removal of microplastics from wastewater in an urban wastewater treatment plant located in Southeast Spain, including an oxidation ditch, rapid sand filtration, and ultraviolet disinfection. A total of 146.73 L of wastewater samples from influent and effluent were processed, following a density separation methodology, visual classification under a stereomicroscope, and FTIR analysis for polymer identification. Microplastics proved to be 72.41% of total microparticles collected, with a global removal rate of 64.26% after the tertiary treatment and within the average retention for European WWTPs. Three different shapes were identified: i.e., microfiber (79.65%), film (11.26%), and fragment (9.09%), without the identification of microbeads despite the proximity to a plastic compounding factory. Fibers were less efficiently removed (56.16%) than particulate microplastics (90.03%), suggesting that tertiary treatments clearly discriminate between forms, and reporting a daily emission of 1.6 × 107 microplastics to the environment. Year variability in microplastic burden was cushioned at the effluent, reporting a stable performance of the sewage plant. Eight different polymer families were identified, LDPE film being the most abundant form, with 10 different colors and sizes mainly between 1–2 mm. Future efforts should be dedicated to source control, plastic waste management, improvement of legislation, and specific microplastic-targeted treatment units, especially for microfiber removal. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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20 pages, 3596 KiB  
Review
A Review of SWAT Model Application in Africa
by George Akoko, Tu Hoang Le, Takashi Gomi and Tasuku Kato
Water 2021, 13(9), 1313; https://doi.org/10.3390/w13091313 - 8 May 2021
Cited by 155 | Viewed by 16298
Abstract
The soil and water assessment tool (SWAT) is a well-known hydrological modeling tool that has been applied in various hydrologic and environmental simulations. A total of 206 studies over a 15-year period (2005–2019) were identified from various peer-reviewed scientific journals listed on the [...] Read more.
The soil and water assessment tool (SWAT) is a well-known hydrological modeling tool that has been applied in various hydrologic and environmental simulations. A total of 206 studies over a 15-year period (2005–2019) were identified from various peer-reviewed scientific journals listed on the SWAT website database, which is supported by the Centre for Agricultural and Rural Development (CARD). These studies were categorized into five areas, namely applications considering: water resources and streamflow, erosion and sedimentation, land-use management and agricultural-related contexts, climate-change contexts, and model parameterization and dataset inputs. Water resources studies were applied to understand hydrological processes and responses in various river basins. Land-use and agriculture-related context studies mainly analyzed impacts and mitigation measures on the environment and provided insights into better environmental management. Erosion and sedimentation studies using the SWAT model were done to quantify sediment yield and evaluate soil conservation measures. Climate-change context studies mainly demonstrated streamflow sensitivity to weather changes. The model parameterization studies highlighted parameter selection in streamflow analysis, model improvements, and basin scale calibrations. Dataset inputs mainly compared simulations with rain-gauge and global rainfall data sources. The challenges and advantages of the SWAT model’s applications, which range from data availability and prediction uncertainties to the model’s capability in various applications, are highlighted. Discussions on considerations for future simulations such as data sharing, and potential for better future analysis are also highlighted. Increased efforts in local data availability and a multidimensional approach in future simulations are recommended. Full article
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18 pages, 2595 KiB  
Article
Micropollutants in Urban Stormwater Runoff of Different Land Uses
by Daniel Wicke, Andreas Matzinger, Hauke Sonnenberg, Nicolas Caradot, Rabea-Luisa Schubert, Robert Dick, Bernd Heinzmann, Uwe Dünnbier, Dörthe von Seggern and Pascale Rouault
Water 2021, 13(9), 1312; https://doi.org/10.3390/w13091312 - 7 May 2021
Cited by 50 | Viewed by 8304
Abstract
The main aim of this study was a survey of micropollutants in stormwater runoff of Berlin (Germany) and its dependence on land-use types. In a one-year monitoring program, event mean concentrations were measured for a set of 106 parameters, including 85 organic micropollutants [...] Read more.
The main aim of this study was a survey of micropollutants in stormwater runoff of Berlin (Germany) and its dependence on land-use types. In a one-year monitoring program, event mean concentrations were measured for a set of 106 parameters, including 85 organic micropollutants (e.g., flame retardants, phthalates, pesticides/biocides, polycyclic aromatic hydrocarbons (PAH)), heavy metals and standard parameters. Monitoring points were selected in five catchments of different urban land-use types, and at one urban river. We detected 77 of the 106 parameters at least once in stormwater runoff of the investigated catchment types. On average, stormwater runoff contained a mix of 24 µg L−1 organic micropollutants and 1.3 mg L−1 heavy metals. For organic micropollutants, concentrations were highest in all catchments for the plasticizer diisodecyl phthalate. Concentrations of all but five parameters showed significant differences among the five land-use types. While major roads were the dominant source of traffic-related substances such as PAH, each of the other land-use types showed the highest concentrations for some substances (e.g., flame retardants in commercial area, pesticides in catchment dominated by one family homes). Comparison with environmental quality standards (EQS) for surface waters shows that 13 micropollutants in stormwater runoff and 8 micropollutants in the receiving river exceeded German quality standards for receiving surface waters during storm events, highlighting the relevance of stormwater inputs for urban surface waters. Full article
(This article belongs to the Special Issue Research on Urban Runoff Pollution)
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24 pages, 1963 KiB  
Article
Unraveling the Water-Energy-Food-Environment Nexus for Climate Change Adaptation in Iran: Urmia Lake Basin Case-Study
by Hossein Nasrollahi, Rasool Shirazizadeh, Reza Shirmohammadi, Omid Pourali and Majid Amidpour
Water 2021, 13(9), 1282; https://doi.org/10.3390/w13091282 - 1 May 2021
Cited by 30 | Viewed by 6763
Abstract
A holistic approach to the management of water, energy, food, and the environment is required to both meet the socioeconomic demands of the future as well as sustainable development of these limited resources. The Urmia Lake Basin has faced environmental, social, and economic [...] Read more.
A holistic approach to the management of water, energy, food, and the environment is required to both meet the socioeconomic demands of the future as well as sustainable development of these limited resources. The Urmia Lake Basin has faced environmental, social, and economic challenges in recent years, and this situation is likely to worsen under the impacts of climate change. For this study, an adaptability analysis of this region is proposed for the 2040 horizon year. Two models, the water evaluation and planning (WEAP (Stockholm Environmental Institute, Stockholm, Sweden)) and the low emissions analysis platform (LEAP (Stockholm Environmental Institute, Boston, MA, USA)), are integrated to simulate changes in water, energy, food, and the environment over these 20 years. Two climate scenarios and nine policy scenarios are combined to assess sustainable development using a multi-criteria decision analysis (MCDA) approach. Results show that, through pursuing challenging goals in agricultural, potable water, energy, and industrial sectors, sustainable development will be achieved. In this scenario, the Lake Urmia water level will reach its ecological water level in 2040. However, social, technical, and political challenges are considered obstacles to implementing the goals of this scenario. In addition, industry growth and industry structure adjustment have the most impact on sustainable development achievement. Full article
(This article belongs to the Special Issue Water Systems Using Affordable and Clean Energy)
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26 pages, 45029 KiB  
Article
A Flood Inundation Modeling Approach for Urban and Rural Areas in Lake and Large-Scale River Basins
by George Papaioannou, Lampros Vasiliades, Athanasios Loukas, Angelos Alamanos, Andreas Efstratiadis, Antonios Koukouvinos, Ioannis Tsoukalas and Panagiotis Kossieris
Water 2021, 13(9), 1264; https://doi.org/10.3390/w13091264 - 30 Apr 2021
Cited by 20 | Viewed by 5046
Abstract
Fluvial floods are one of the primary natural hazards to our society, and the associated flood risk should always be evaluated for present and future conditions. The European Union’s (EU) Floods Directive highlights the importance of flood mapping as a key stage for [...] Read more.
Fluvial floods are one of the primary natural hazards to our society, and the associated flood risk should always be evaluated for present and future conditions. The European Union’s (EU) Floods Directive highlights the importance of flood mapping as a key stage for detecting vulnerable areas, assessing floods’ impacts, and identifying damages and compensation plans. The implementation of the EU Flood Directive in Greece is challenging because of its geophysical and climatic variability and diverse hydrologic and hydraulic conditions. This study addressed this challenge by modeling of design rainfall at the sub-watershed level and subsequent estimation of flood design hydrographs using the Natural Resources Conservation Service (NRCS) Unit Hydrograph Procedure. The HEC-RAS 2D model was used for flood routing, estimation of flood attributes (i.e., water depths and flow velocities), and mapping of inundated areas. The modeling approach was applied at two complex and ungauged representative basins: The Lake Pamvotida basin located in the Epirus Region of the wet Western Greece, and the Pinios River basin located in the Thessaly Region of the drier Central Greece, a basin with a complex dendritic hydrographic system, expanding to more than 1188 river-km. The proposed modeling approach aimed at better estimation and mapping of flood inundation areas including relative uncertainties and providing guidance to professionals and academics. Full article
(This article belongs to the Special Issue Management of Hydro-Meteorological Hazards)
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19 pages, 6821 KiB  
Article
Water Quality Prediction in the Luan River Based on 1-DRCNN and BiGRU Hybrid Neural Network Model
by Jianzhuo Yan, Jiaxue Liu, Yongchuan Yu and Hongxia Xu
Water 2021, 13(9), 1273; https://doi.org/10.3390/w13091273 - 30 Apr 2021
Cited by 69 | Viewed by 5303
Abstract
The current global water environment has been seriously damaged. The prediction of water quality parameters can provide effective reference materials for future water conditions and water quality improvement. In order to further improve the accuracy of water quality prediction and the stability and [...] Read more.
The current global water environment has been seriously damaged. The prediction of water quality parameters can provide effective reference materials for future water conditions and water quality improvement. In order to further improve the accuracy of water quality prediction and the stability and generalization ability of the model, we propose a new comprehensive deep learning water quality prediction algorithm. Firstly, the water quality data are cleaned and pretreated by isolation forest, the Lagrange interpolation method, sliding window average, and principal component analysis (PCA). Then, one-dimensional residual convolutional neural networks (1-DRCNN) and bi-directional gated recurrent units (BiGRU) are used to extract the potential local features among water quality parameters and integrate information before and after time series. Finally, a full connection layer is used to obtain the final prediction results of total nitrogen (TN), total phosphorus (TP), and potassium permanganate index (COD-Mn). Our prediction experiment was carried out according to the actual water quality data of Daheiting Reservoir, Luanxian Bridge, and Jianggezhuang at the three control sections of the Luan River in Tangshan City, Hebei Province, from 5 July 2018 to 26 March 2019. The minimum mean absolute percentage error (MAPE) of this method was 2.4866, and the coefficient of determination (R2) was able to reach 0.9431. The experimental results showed that the model proposed in this paper has higher prediction accuracy and generalization than the existing LSTM, GRU, and BiGRU models. Full article
(This article belongs to the Section Water Quality and Contamination)
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22 pages, 6304 KiB  
Article
Roadmap for Determining Natural Background Levels of Trace Metals in Groundwater
by Denitza D. Voutchkova, Vibeke Ernstsen, Jörg Schullehner, Klaus Hinsby, Lærke Thorling and Birgitte Hansen
Water 2021, 13(9), 1267; https://doi.org/10.3390/w13091267 - 30 Apr 2021
Cited by 18 | Viewed by 4477
Abstract
Determining natural background levels (NBLs) is a fundamental step in assessing the chemical status of groundwater bodies in the EU, as stipulated by the Water Framework and Groundwater Directives. The major challenges in deriving NBLs for trace metals are understanding the interaction of [...] Read more.
Determining natural background levels (NBLs) is a fundamental step in assessing the chemical status of groundwater bodies in the EU, as stipulated by the Water Framework and Groundwater Directives. The major challenges in deriving NBLs for trace metals are understanding the interaction of natural and anthropogenic processes and identifying the boundary between pristine and polluted groundwater. Thus, the purpose of this paper is to present a roadmap guiding the process of method selection for setting meaningful NBLs of trace metals in groundwater. To develop the roadmap, we compared and critically assessed how three methods for excluding polluted sampling points affect the NBLs for As, Cd, Cr, Cu, Ni, and Zn in Danish aquifers. These methods exclude sampling points based on (1) the primary use of the well (or sampling purpose), (2) the dominating anthropogenic pressure in the vicinity of the well, or (3) a combination of pollution indicators (NO3, pesticides, organic micropollutants). Except for Ni, the NBLs derived from the three methods did not differ significantly, indicating that the data pre-selection based on the primary use of the wells is an important step in assuring the removal of anthropogenically influenced points. However, this pre-selection could limit the data representativity with respect to the different groundwater types. The roadmap (a step-by-step guideline) can be used at the national scale in countries with varying data availability. Full article
(This article belongs to the Special Issue Natural Background Levels in Groundwater)
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12 pages, 4947 KiB  
Article
Characterization of PVDF/Graphene Nanocomposite Membranes for Water Desalination with Enhanced Antifungal Activity
by Emilia Gontarek-Castro, Maria Krystyna Rybarczyk, Roberto Castro-Muñoz, Monica Morales-Jiménez, Blanca Barragán-Huerta and Marek Lieder
Water 2021, 13(9), 1279; https://doi.org/10.3390/w13091279 - 30 Apr 2021
Cited by 44 | Viewed by 4208
Abstract
Seawater desalination is a worldwide concern for the sustainable production of drinking water. In this regard, membrane distillation (MD) has shown the potential for effective brine treatment. However, the lack of appropriate MD membranes limits its industrial expansion since they experience fouling and [...] Read more.
Seawater desalination is a worldwide concern for the sustainable production of drinking water. In this regard, membrane distillation (MD) has shown the potential for effective brine treatment. However, the lack of appropriate MD membranes limits its industrial expansion since they experience fouling and wetting issues. Therefore, hydrophobic membranes are promising candidates to successfully deal with such phenomena that are typical for commercially available membranes. Here, several graphene/polyvinylidene (PVDF_G) membranes with different graphene loading (0–10 wt%) were prepared through a phase inversion method. After full characterization of the resulting membranes, the surface revealed that the well-dispersed graphene in the polymer matrix (0.33 and 0.5 wt% graphene loading) led to excellent water repellence together with a rough structure, and a large effective surface area. Importantly, antifungal activity tests of films indicated an increase in the inhibition percentage for PVDF_G membranes against the Curvularia sp. fungal strain. However, the antifungal surface properties were found to be the synergistic result of graphene toxicity and surface topography. Full article
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26 pages, 1126 KiB  
Review
Heat Recovery from Wastewater—A Review of Available Resource
by Himanshu Nagpal, Jan Spriet, Madhu Krishna Murali and Aonghus McNabola
Water 2021, 13(9), 1274; https://doi.org/10.3390/w13091274 - 30 Apr 2021
Cited by 84 | Viewed by 22836
Abstract
The EU Directive 2018/2001 recognized wastewater as a renewable heat source. Wastewater from domestic, industrial and commercial developments maintains considerable amounts of thermal energy after discharging into the sewer system. It is possible to recover this heat by using technologies like heat exchangers [...] Read more.
The EU Directive 2018/2001 recognized wastewater as a renewable heat source. Wastewater from domestic, industrial and commercial developments maintains considerable amounts of thermal energy after discharging into the sewer system. It is possible to recover this heat by using technologies like heat exchangers and heat pumps; and to reuse it to satisfy heating demands. This paper presents a review of the literature on wastewater heat recovery (WWHR) and its potential at different scales within the sewer system, including the component level, building level, sewer pipe network level, and wastewater treatment plant (WWTP) level. A systematic review is provided of the benefits and challenges of WWHR across each of these levels taking into consideration technical, economic and environmental aspects. This study analyzes important attributes of WWHR such as temperature and flow dynamics of the sewer system, impacts of WWHR on the environment, and legal regulations involved. Existing gaps in the WWHR field are also identified. It is concluded that WWHR has a significant potential to supply clean energy at a scale ranging from buildings to large communities and districts. Further attention to WWHR is needed from the research community, policymakers and other stakeholders to realize the full potential of this valuable renewable heat source. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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28 pages, 4785 KiB  
Article
Worldwide Research on Socio-Hydrology: A Bibliometric Analysis
by Gricelda Herrera-Franco, Néstor Montalván-Burbano, Paúl Carrión-Mero and Lady Bravo-Montero
Water 2021, 13(9), 1283; https://doi.org/10.3390/w13091283 - 30 Apr 2021
Cited by 49 | Viewed by 8153
Abstract
The technical and scientific analysis regarding studies of the water surface or groundwater has increasingly taken on a great social impact, which has led to the creation of the term socio-hydrology. Since decision making has a greater weight, considering the social perspective, its [...] Read more.
The technical and scientific analysis regarding studies of the water surface or groundwater has increasingly taken on a great social impact, which has led to the creation of the term socio-hydrology. Since decision making has a greater weight, considering the social perspective, its study has become more important in the past 20 years. This article aims to carry out a bibliometric analysis related to socio-hydrology using the Scopus database and the application of VOSviewer software for the evaluation of the intellectual structure of socio-hydrology, its conceptual evolution, and its tendencies. The methodology considers (i) search criteria of the research field, (ii) search and document selection, (iii) software and data extraction, and (iv) analysis of results and trends. The results show us the term socio-hydrology as a new scientific discipline that has traces in the Scopus database in the past two decades. However, its application stems from recognising ancestral knowledge alongside other forms of knowledge. Socio-hydrology practice requires participatory models, where the community has a great influence, and for the most part, it guarantees results for the common good. The trend of this topic is growing and open to the criteria of sustainability. Full article
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20 pages, 4358 KiB  
Article
Using the InVEST Model to Assess the Impacts of Climate and Land Use Changes on Water Yield in the Upstream Regions of the Shule River Basin
by Peijie Wei, Shengyun Chen, Minghui Wu, Yanfang Deng, Haojie Xu, Yinglan Jia and Fang Liu
Water 2021, 13(9), 1250; https://doi.org/10.3390/w13091250 - 29 Apr 2021
Cited by 72 | Viewed by 7937
Abstract
Water yield is a key ecosystem function index, directly impacting the sustainable development of the basin economy and ecosystem. Climate and land use/land cover (LULC) changes are the main driving factors affecting water yield. In the context of global climate change, assessing the [...] Read more.
Water yield is a key ecosystem function index, directly impacting the sustainable development of the basin economy and ecosystem. Climate and land use/land cover (LULC) changes are the main driving factors affecting water yield. In the context of global climate change, assessing the impacts of climate and LULC changes on water yield in the alpine regions of the Qinghai–Tibet Plateau (QTP) is essential for formulating rational management and development strategies for water resources. On the basis of the Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) model, we simulated and analyzed the spatiotemporal variations and the impacts of LULC and climate changes on water yield from 2001 to 2019 in the upstream regions of the Shule River Basin (USRB) on the northeastern margin of the QTP. Three scenarios were designed in the InVEST model to clearly analyze the contributions of climate and LULC changes on the variation of water yield. The first scenario integrated climate and LULC change into the model according to the actual conditions. The second scenario was simulation without LULC change, and the third scenario was without climate change. The results showed that (1) the InVEST model had a good performance in estimating water yield (coefficient of determination (R2) = 0.986; root mean square error (RMSE) = 3.012, p < 0.05); (2) the water yield significantly increased in the temporal scale from 2001 to 2019, especially in the high altitude of the marginal regions (accounting for 32.01%), while the northwest regions significantly decreased and accounted for only 8.39% (p < 0.05); (3) the spatial distribution of water yield increased from the middle low-altitude regions to the marginal high-altitude regions; and (4) through the analysis of the three scenarios, the impact of climate change on water yield was 90.56%, while that of LULC change was only 9.44%. This study reveals that climate warming has a positive impact on water yield, which will provide valuable references for the integrated assessment and management of water resources in the Shule River Basin. Full article
(This article belongs to the Special Issue Integrated Watershed Management Modeling)
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14 pages, 2168 KiB  
Article
Deep Learning Based Approach to Classify Saline Particles in Sea Water
by Mohammed Alshehri, Manoj Kumar, Akashdeep Bhardwaj, Shailendra Mishra and Jayadev Gyani
Water 2021, 13(9), 1251; https://doi.org/10.3390/w13091251 - 29 Apr 2021
Cited by 32 | Viewed by 4319
Abstract
Water is an essential resource that facilitates the existence of human life forms. In recent years, the demand for the consumption of freshwater has substantially increased. Seawater contains a high concentration of salt particles and salinity, making it unfit for consumption and domestic [...] Read more.
Water is an essential resource that facilitates the existence of human life forms. In recent years, the demand for the consumption of freshwater has substantially increased. Seawater contains a high concentration of salt particles and salinity, making it unfit for consumption and domestic use. Water treatment plants used to treat seawater are less efficient and reliable. Deep learning systems can prove to be efficient and highly accurate in analyzing salt particles in seawater with higher efficiency that can improve the performance of water treatment plants. Therefore, this work classified different concentrations of salt particles in water using convolutional neural networks with the implementation of transfer learning. Salt salinity concentration images were captured using a designed Raspberry Pi based model and these images were further used for training purposes. Moreover, a data augmentation technique was also employed for the state-of-the-art results. Finally, a deep learning neural network was used to classify saline particles of varied concentration range images. The experimental results show that the proposed approach exhibited superior outcomes by achieving an overall accuracy of 90% and f-score of 87% in classifying salt particles. The proposed model was also evaluated using other evaluation metrics such as precision, recall, and specificity, and showed robust results. Full article
(This article belongs to the Special Issue Machine Learning for Hydro-Systems)
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27 pages, 9737 KiB  
Article
Integrative Approach for Groundwater Pollution Risk Assessment Coupling Hydrogeological, Physicochemical and Socioeconomic Conditions in Southwest of the Damascus Basin
by Nazeer Asmael, Jessica D. Villanueva, Nicolas Peyraube, Mohamed Baalousha, Frédéric Huneau, Alain Dupuy and Philippe Le Coustumer
Water 2021, 13(9), 1220; https://doi.org/10.3390/w13091220 - 28 Apr 2021
Cited by 7 | Viewed by 3975
Abstract
Groundwater is the main resource for irrigation and drinking supply in most parts of Syria, as for most Mediterranean countries, however this resource suffers from mismanagement. In the study area (northeast of Mt. Hermon), the lack of information makes water management in this [...] Read more.
Groundwater is the main resource for irrigation and drinking supply in most parts of Syria, as for most Mediterranean countries, however this resource suffers from mismanagement. In the study area (northeast of Mt. Hermon), the lack of information makes water management in this area extremely difficult. Assessing groundwater pollution risk is the most essential issue for water resources management, especially in the regions where complex interaction between climate, geology, geomorphology, hydrogeology, water scarcity and water resource mismanagement exist. This complexity leads to significant complication in determining pollution risk of studied system. In the present work, we adopted an integrative approach to assess groundwater pollution risk in the study area. This methodology is based on the analysis of hydrogeological characteristics of aquifer systems and the available information about socioeconomic context and physiochemical groundwater conditions that might affect this system. This approach allowed us to delineate the groundwater pollution risk map based on the analysis of concerning parameters/indicators. The degree of risk was assessed as the sum and average of rating of these parameters and indicators for each subarea. Typically, very high pollution risk index was identified over the Quaternary/Neogene horizon, i.e., shallow and unconfined aquifer and in the lower part of Jurassic aquifer. In these two parts, the majority of anthropogenic activities are concentrated. Low pollution risk index was found for the outcropping of low permeable Quaternary basalt at the Southern part of the study area. A moderate pollution index was identified for the low/moderate permeability of silt, clay and marly limestone-rich horizons of the major part of Neogene aquifer outside of the intersected zones with Quaternary aquifer and for the Paleogene formations. The spatial analysis shows that about 50% of the study area is characterized as being at very high and high pollution risk index. Hence, the overall natural protective capacity of this area is still poor. This study demonstrates the flexibility of the proposed approach to assess groundwater pollution risk in local complex aquifer system characterized by lack of information and data in order to reduce the risk of future groundwater pollution. Full article
(This article belongs to the Special Issue Application of Smart Technologies in Water Resources Management)
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22 pages, 3703 KiB  
Article
Comparing Evapotranspiration Estimates from the GEOframe-Prospero Model with Penman–Monteith and Priestley-Taylor Approaches under Different Climate Conditions
by Michele Bottazzi, Marialaura Bancheri, Mirka Mobilia, Giacomo Bertoldi, Antonia Longobardi and Riccardo Rigon
Water 2021, 13(9), 1221; https://doi.org/10.3390/w13091221 - 28 Apr 2021
Cited by 19 | Viewed by 4154
Abstract
Evapotranspiration (ET) is a key variable in the hydrological cycle and it directly impacts the surface balance and its accurate assessment is essential for a correct water management. ET is difficult to measure, since the existing methods for its direct estimate, such as [...] Read more.
Evapotranspiration (ET) is a key variable in the hydrological cycle and it directly impacts the surface balance and its accurate assessment is essential for a correct water management. ET is difficult to measure, since the existing methods for its direct estimate, such as the weighing lysimeter or the eddy-covariance system, are often expensive and require well-trained research personnel. To overcome this limit, different authors developed experimental models for indirect estimation of ET. However, since the accuracy of ET prediction is crucial from different points of view, the continuous search for more and more precise modeling approaches is encouraged. In light of this, the aim of the present work is to test the efficiency in predicting ET fluxes in a newly introduced physical-based model, named Prospero, which is based on the ability to compute the ET using a multi-layer canopy model, solving the energy balance both for the sunlight and shadow vegetation, extending the recently developed Schymanski and Or method to canopy level. Additionally, Prospero is able to compute the actual ET using a Jarvis-like model. The model is integrated as a component in the hydrological modelling system GEOframe. Its estimates were validated against observed data from five Eddy covariance (EC) sites with different climatic conditions and the same vegetation cover. Then, its performances were compared with those of two already consolidated models, the Priestley–Taylor model and Penman FAO model, using four goodness-of-fit indices. Subsequently a calibration of the three methods has been carried out using LUCA calibration within GEOframe, with the purpose of prediction errors. The results showed that Prospero is more accurate and precise with respect to the other two models, even if no calibrations were performed, with better performances in dry climatic conditions. In addition, Prospero model turned to be the least affected by the calibration procedure and, therefore, it can be effectively also used in a context of data scarcity. Full article
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14 pages, 2792 KiB  
Review
The Fate of Stationary Tools for Environmental Flow Determination in a Context of Climate Change
by André St-Hilaire, Habiba Ferchichi, Laureline Berthot and Daniel Caissie
Water 2021, 13(9), 1203; https://doi.org/10.3390/w13091203 - 27 Apr 2021
Cited by 6 | Viewed by 3792
Abstract
Environmental flows (eflows) refer to the amount of water required to sustain aquatic ecosystems. In its formal definition, three flow characteristics need to be minimally maintained: quantity, timing and quality. This overview paper highlights the challenges of some of the current methods used [...] Read more.
Environmental flows (eflows) refer to the amount of water required to sustain aquatic ecosystems. In its formal definition, three flow characteristics need to be minimally maintained: quantity, timing and quality. This overview paper highlights the challenges of some of the current methods used for eflow determination in the context of an evolving climate. As hydrological methods remain popular, they are first analyzed by describing some of the potential caveats associated with their usage when flow time series are non-stationarity. The timing of low-flow events will likely change within a season but will also likely shift in seasonality in some regions. Flow quality is a multi-faceted concept. It is proposed that a first simple step to partly incorporate flow quality in future analyses is to include the water temperature as a covariate. Finally, holistic approaches are also critically revisited, and simple modifications to the Ecological Limits of Flow Alteration (ELOHA) framework are proposed. Full article
(This article belongs to the Special Issue Past and Future Trends and Variability in Hydro-Climatic Processes)
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14 pages, 270 KiB  
Article
WaterCoG: Evidence on How the Use of Tools, Knowledge, and Process Design Can Improve Water Co-Governance
by Ilke Borowski-Maaser, Morten Graversgaard, Natalie Foster, Madeleine Prutzer, Allard Hans Roest and Floris Boogaard
Water 2021, 13(9), 1206; https://doi.org/10.3390/w13091206 - 27 Apr 2021
Cited by 11 | Viewed by 4608
Abstract
The European Union Water Framework Directive (WFD) encourages water managers to implement active stakeholder involvement to achieve sustainable water management. However, the WFD does not describe in detail how member states should operationalize participation. The need for local experience and local understanding of [...] Read more.
The European Union Water Framework Directive (WFD) encourages water managers to implement active stakeholder involvement to achieve sustainable water management. However, the WFD does not describe in detail how member states should operationalize participation. The need for local experience and local understanding of collaborative governance (co-governance) processes remains. The WaterCoG project evaluated 11 local pilot schemes. Building on the participatory, qualitative evaluation of pilot schemes from Sweden, United Kingdom, Denmark, The Netherlands, and Germany, the authors take a closer look at how co-governance can improve water governance, how water managers can make best use of tools and knowledge, and how they can improve process designs. The results reflect how social learning and successful co-governance are linked. Social learning as a shared understanding of complex ecosystem and water-management issues can be supported with active stakeholder involvement and citizen science. As such, in co-governance processes, stakeholders need technical access to data and knowledge and a shared process memory. This enables them to develop a shared understanding and facilitates bringing together competing interests and finding new solutions. Participatory tools became part of successful processes by building trust and knowledge based on commitment. However, proficient process design and facilitation make these tools more effective. Full article
(This article belongs to the Special Issue Social Learning for Sustainable Water Resource Management)
36 pages, 9397 KiB  
Review
A Review of Photoelectrocatalytic Reactors for Water and Wastewater Treatment
by Stuart McMichael, Pilar Fernández-Ibáñez and John Anthony Byrne
Water 2021, 13(9), 1198; https://doi.org/10.3390/w13091198 - 26 Apr 2021
Cited by 51 | Viewed by 10589
Abstract
The photoexcitation of suitable semiconducting materials in aqueous environments can lead to the production of reactive oxygen species (ROS). ROS can inactivate microorganisms and degrade a range of chemical compounds. In the case of heterogeneous photocatalysis, semiconducting materials may suffer from fast recombination [...] Read more.
The photoexcitation of suitable semiconducting materials in aqueous environments can lead to the production of reactive oxygen species (ROS). ROS can inactivate microorganisms and degrade a range of chemical compounds. In the case of heterogeneous photocatalysis, semiconducting materials may suffer from fast recombination of electron–hole pairs and require post-treatment to separate the photocatalyst when a suspension system is used. To reduce recombination and improve the rate of degradation, an externally applied electrical bias can be used where the semiconducting material is immobilised onto an electrically conducive support and connected to a counter electrode. These electrochemically assisted photocatalytic systems have been termed “photoelectrocatalytic” (PEC). This review will explain the fundamental mechanism of PECs, photoelectrodes, the different types of PEC reactors reported in the literature, the (photo)electrodes used, the contaminants degraded, the key findings and prospects in the research area. Full article
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18 pages, 558 KiB  
Article
The Effect of Social Behavior on Residential Water Consumption
by Daniel Morales Martínez and Alexandre Gori Maia
Water 2021, 13(9), 1184; https://doi.org/10.3390/w13091184 - 25 Apr 2021
Cited by 10 | Viewed by 5760
Abstract
We analyze how residential water consumption is influenced by the consumption of households belonging to the same social group (peer effect). Analyses are based on household-level data provided by the Brazilian Household Budget Survey and use an innovative strategy that estimates the spatial [...] Read more.
We analyze how residential water consumption is influenced by the consumption of households belonging to the same social group (peer effect). Analyses are based on household-level data provided by the Brazilian Household Budget Survey and use an innovative strategy that estimates the spatial dependence of water consumption while simultaneously controlling for potential sources of sample selectivity and endogeneity. The estimates of our quantile regression models highlight that, conditional on household characteristics, the greater the household water consumption, the greater the peer effect. In other words, the overconsumption of residential water seems to be influenced mainly by the behavior of social peers. Full article
(This article belongs to the Special Issue Urban Water Economics)
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20 pages, 826 KiB  
Article
Characterization and Use of Char Produced from Pyrolysis of Post-Consumer Mixed Plastic Waste
by M. A. Martín-Lara, A. Piñar, A. Ligero, G. Blázquez and M. Calero
Water 2021, 13(9), 1188; https://doi.org/10.3390/w13091188 - 25 Apr 2021
Cited by 47 | Viewed by 9319
Abstract
In this work, the pyrolysis of post-consumer mixed plastic waste (polypropylene (PP), polystyrene (PS) and polyethylene film (PE)) is carried out. The solid product of the pyrolysis is characterized and tested for its use as adsorbent of lead present in aqueous media. The [...] Read more.
In this work, the pyrolysis of post-consumer mixed plastic waste (polypropylene (PP), polystyrene (PS) and polyethylene film (PE)) is carried out. The solid product of the pyrolysis is characterized and tested for its use as adsorbent of lead present in aqueous media. The pyrolysis temperature has a great influence on the solid product yield, decreasing when the temperature increases. The highest yield to solid product obtained is from the pyrolysis of film at lower temperature (450 °C), reaching almost 14%. The results of product solid characterization reveal that the carbon, hydrogen and nitrogen content decreases with increasing pyrolysis temperature. Furthermore, both the ash and the volatile content are related to the pyrolysis temperature. The ash content is higher when the pyrolysis temperature is higher, while when the temperature increases, a solid product with lower volatile content is obtained. In respect to specific surface area, a higher pyrolysis temperature improves the properties of the solid product as an adsorbent. The adsorption capacity increases as the pyrolysis temperature increases, with the highest value of 7.91 mg/g for the solid obtained in the pyrolysis at 550 °C. In addition, adsorption capacity increases as the initial concentration of lead rises, reaching a maximum value close to 26 mg/g for an initial concentration of 40 mg/L. The Sips model is the one that best reproduces the experimental results of the adsorption process equilibrium study. Full article
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19 pages, 3992 KiB  
Article
Tide Prediction in the Venice Lagoon Using Nonlinear Autoregressive Exogenous (NARX) Neural Network
by Fabio Di Nunno, Giovanni de Marinis, Rudy Gargano and Francesco Granata
Water 2021, 13(9), 1173; https://doi.org/10.3390/w13091173 - 24 Apr 2021
Cited by 35 | Viewed by 4262
Abstract
In the Venice Lagoon some of the highest tides in the Mediterranean occur, which have influenced the evolution of the city of Venice and the surrounding lagoon for centuries. The forecast of “high waters” in the lagoon has always been a matter of [...] Read more.
In the Venice Lagoon some of the highest tides in the Mediterranean occur, which have influenced the evolution of the city of Venice and the surrounding lagoon for centuries. The forecast of “high waters” in the lagoon has always been a matter of considerable practical interest. In this study, tide prediction models were developed for the entire lagoon based on Nonlinear Autoregressive Exogenous (NARX) neural networks. The NARX-based model development was performed in two different stages. The first stage was the training and testing of the NARX network, performed on data collected in a given time interval at the tide gauge of Punta della Salute, at the end of Canal Grande. The second stage consisted of a comprehensive validation of the model in the entire Venice Lagoon, with a detailed analysis of data from three measuring stations located in points of the lagoon with different characteristics. Good predictions were achieved regardless of whether the meteorological parameters were considered among input parameters, even with considerable time advance. Furthermore, the forecasting model based on NARX has proved capable of predicting even exceptional high tides. The proposed model could be a useful support tool for the management of the MOSE system, which will protect Venice from high waters. Full article
(This article belongs to the Section Hydrology)
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14 pages, 1935 KiB  
Article
Effects of Supplement Irrigation and Nitrogen Application Levels on Soil Carbon–Nitrogen Content and Yield of One-Year Double Cropping Maize in Subtropical Region
by Gui-Yang Wang, Yu-Xin Hu, Yong-Xin Liu, Shakeel Ahmad and Xun-Bo Zhou
Water 2021, 13(9), 1180; https://doi.org/10.3390/w13091180 - 24 Apr 2021
Cited by 35 | Viewed by 4117
Abstract
Inappropriate irrigation conditions and nitrogen application can negatively affect soil carbon–nitrogen content and yield of maize, as well as can lead to underground water pollution and soil degradation. A two year (2018, 2019) field experiment was carried out to determine the effect of [...] Read more.
Inappropriate irrigation conditions and nitrogen application can negatively affect soil carbon–nitrogen content and yield of maize, as well as can lead to underground water pollution and soil degradation. A two year (2018, 2019) field experiment was carried out to determine the effect of irrigation and N, alone and in combination on maize grain yield, grain nitrogen content, soil inorganic N and MBC of one-year double cropping maize (Zea mays L.) in a subtropical region. Split plot design was adopted, with main plots consisting of two water regimes: drip irrigation (drip irrigation to keep soil water content no less than 70% of maximum field capacity) and rainfed (no irrigation during growing period). Split-plot treatments consisted of five nitrogen application levels, including 0 (N0), 150 (N150), 200 (N200), 250 (N250), and 300 kg/ha (N300). The results of two-year field experiment showed that soil irrigation nitrogen interaction had a significant influence on the all measured parameters. In detail, soil NH4+-N and NO3-N content, total nitrogen (TN), soil organic carbon (SOC) and grain nitrogen contents under the combined treatment of N250 and supplementary irrigation were higher relative to other treatments. Compared with rainfed, maize yield, thousand grains weight (TGW) and harvest index increased by 22.0%, 7.7%, and 15.2% under supplemental irrigation. Yield and TGW N300 were 287 kg/ha and 3.1 g higher than those of N250, and yield and TGW of N250 were 59.4% and 23.1% higher than those of N0, respectively. The yield of spring maize was 24.0% significantly higher than that of autumn maize. Therefore, we suggested that 250 kg/ha nitrogen application fertilizer combined with supplementary irrigation can improve soil fertility and annual maize yield in subtropical one-year double cropping region. Full article
(This article belongs to the Special Issue Development and Application of Subsurface Irrigation Techniques)
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34 pages, 3441 KiB  
Article
Hydrochemical Zoning and Chemical Evolution of the Deep Upper Jurassic Thermal Groundwater Reservoir Using Water Chemical and Environmental Isotope Data
by Florian Heine, Kai Zosseder and Florian Einsiedl
Water 2021, 13(9), 1162; https://doi.org/10.3390/w13091162 - 22 Apr 2021
Cited by 23 | Viewed by 5074
Abstract
A comprehensive hydrogeological understanding of the deep Upper Jurassic carbonate aquifer, which represents an important geothermal reservoir in the South German Molasse Basin (SGMB), is crucial for improved and sustainable groundwater resource management. Water chemical data and environmental isotope analyses of δD, δ [...] Read more.
A comprehensive hydrogeological understanding of the deep Upper Jurassic carbonate aquifer, which represents an important geothermal reservoir in the South German Molasse Basin (SGMB), is crucial for improved and sustainable groundwater resource management. Water chemical data and environmental isotope analyses of δD, δ18O and 87Sr/86Sr were obtained from groundwater of 24 deep Upper Jurassic geothermal wells and coupled with a few analyses of noble gases (3He/4He, 40Ar/36Ar) and noble gas infiltration temperatures. Hierarchical cluster analysis revealed three major water types and allowed a hydrochemical zoning of the SGMB, while exploratory factor analyses identified the hydrogeological processes affecting the water chemical composition of the thermal water. Water types 1 and 2 are of Na-[Ca]-HCO3-Cl type, lowly mineralised and have been recharged under meteoric cold climate conditions. Both water types show 87Sr/86Sr signatures, stable water isotopes values and calculated apparent mean residence times, which suggest minor water-rock interaction within a hydraulically active flow system of the Northeastern and Southeastern Central Molasse Basin. This thermal groundwater have been most likely subglacially recharged in the south of the SGMB in close proximity to the Bavarian Alps with a delineated northwards flow direction. Highly mineralised groundwater of water type 3 (Na-Cl-HCO3 and Na-Cl) occurs in the Eastern Central Molasse Basin. In contrast to water types 1 and 2, this water type shows substantial water-rock interaction with terrestrial sediments and increasing 40Ar/36Ar ratios, which may also imply a hydraulic exchange with fossil formation waters of overlying Tertiary sediments. Full article
(This article belongs to the Section Hydrology)
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10 pages, 2600 KiB  
Review
Ecological Degradation of the Yangtze and Nile Delta-Estuaries in Response to Dam Construction with Special Reference to Monsoonal and Arid Climate Settings
by Zhongyuan Chen, Hao Xu and Yanna Wang
Water 2021, 13(9), 1145; https://doi.org/10.3390/w13091145 - 21 Apr 2021
Cited by 10 | Viewed by 3245
Abstract
This study reviews the monsoonal Yangtze and the arid Nile deltas with the objective of understanding how the process–response between river-basin modifications and delta-estuary ecological degradation are interrelated under contrasting hydroclimate dynamics. Our analysis shows that the Yangtze River had a long-term stepwise [...] Read more.
This study reviews the monsoonal Yangtze and the arid Nile deltas with the objective of understanding how the process–response between river-basin modifications and delta-estuary ecological degradation are interrelated under contrasting hydroclimate dynamics. Our analysis shows that the Yangtze River had a long-term stepwise reduction in sediment and silicate fluxes to estuary due to dam construction since the 1960s, especially after the Three Gorges Dam (TGD) closed in 2003. By contrast, the Nile had a drastic reduction of sediment, freshwater, and silicate fluxes immediately after the construction of the Aswan High Dam (AHD) in 1964. Seasonal rainfall in the mid-lower Yangtze basin (below TGD) complemented riverine materials to its estuary, but little was available to the Nile coast below the AHD in the hyper-arid climate setting. Nitrogen (N) and phosphate (P) fluxes in both river basins have increased because of the overuse of N- and P-fertilizer, land-use changes, urbanization, and industrialization. Nutrient ratios (N:P:Si) in both delta-estuaries was greatly altered, i.e., Yangtze case: 75:1:946 (1960s–1970s), 86:1:272 (1980s–1990s) and 102:1:75 (2000s–2010s); and Nile case: 6:1:32 (1960s–1970s), 8:1:9 (1980s–1990s), and 45:1:22 (2013), in the context of the optimum of Redfield ratio (N:P:Si = 16:1:16). This led to an ecological regime shift evidenced by a long-term change in phytoplankton communities in the Yangtze estuary, where silicious algae tended to lose dominance since the end of the 1990s, when more toxic dinoflagellates began to emerge. In the Nile estuary, such a regime shift was indicated by the post-dam dramatic reduction in zooplankton standing crop and fish landings until the early 2000s when biological recovery occurred due to nutrient inputs from anthropogenic sources. Although the Yangtze had higher human impacts than the Nile in terms of population, industrialization, and fertilizer application, N concentrations in the Nile estuarine waters surpassed the Yangtze in recent decades. However, eutrophication in the Yangtze estuary is much more intensive than in the Nile, leading to the likelihood of its estuarine water becoming more acidic than ever before. Therefore, ecological degradation in both delta-estuaries does not follow a linear trajectory, due not only to different climate dynamics but also to human forcings. The comparative insights of this study should be incorporated into future integrated coastal management of these two important systems. Full article
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26 pages, 2608 KiB  
Review
Removal of Heavy Metals during Primary Treatment of Municipal Wastewater and Possibilities of Enhanced Removal: A Review
by Ida Sylwan and Eva Thorin
Water 2021, 13(8), 1121; https://doi.org/10.3390/w13081121 - 19 Apr 2021
Cited by 59 | Viewed by 10563
Abstract
Resource reuse has become an important aspect of wastewater management. At present, use of sludge in agriculture is one of the major reuse routes. Conventional municipal wastewater treatment does not involve any designated process for removal of heavy metals, and these distribute mainly [...] Read more.
Resource reuse has become an important aspect of wastewater management. At present, use of sludge in agriculture is one of the major reuse routes. Conventional municipal wastewater treatment does not involve any designated process for removal of heavy metals, and these distribute mainly between effluent and sludge. Enhanced removal of heavy metals during primary treatment may decrease the heavy metal concentrations in both effluent and sludge from secondary treatment and promote long-term reuse of secondary sludge. This review considers heavy metal occurrence and removal during primary settling, together with possible treatment technologies for heavy metal removal in primary settlers and their theoretical performance. The variation in total heavy metal concentrations and dissolved fraction in raw municipal wastewater points to a need for site-specific assessments of appropriate technologies for improved heavy metal removal. Studies examining the heavy metal speciation beyond dissolved/particulate are few. Missing or disparate information on process parameters such as hydraulic retention time, pH and composition of return flows makes it hard to generalize the findings from studies concerning heavy metal removal in primary settlers. Coagulation/flocculation and use of low-cost sorbents were identified as the most promising methods for enhancing heavy metal removal during primary settling. Based on the available data on heavy metal speciation and removal during primary settling, sorption technologies may be most effective for enhancing the removal of Cu and Ni, while coagulation may be efficient for Cd, Cr, Cu, Pb, Zn and Hg removal (but not as efficient for Ni removal). Full article
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19 pages, 2457 KiB  
Article
Evaluating the Collaborative Security of Water–Energy–Food in China on the Basis of Symbiotic System Theory
by Xiao Li, Cuishan Liu, Guoqing Wang, Zhenxin Bao, Yanfang Diao and Jing Liu
Water 2021, 13(8), 1112; https://doi.org/10.3390/w13081112 - 17 Apr 2021
Cited by 14 | Viewed by 3569
Abstract
Water, energy, and food are essential resources for humanity. The growing shortages of these resources and serious deterioration of river environments are having a big impact on the sustainable development of the economy and society in China. Water, energy, and food support human [...] Read more.
Water, energy, and food are essential resources for humanity. The growing shortages of these resources and serious deterioration of river environments are having a big impact on the sustainable development of the economy and society in China. Water, energy, and food support human life and yet coexist in different ways, and therefore it is critical to find a way for all three key elements to be secured in order to support high standards of sustainable development in China. We used the criteria of stability, coordination, and sustainability of symbiotic systems to select 33 indexes that were then used to establish an index system. The weight of index was determined by using the entropy weight method combined with Analytic Hierarchy Process. The fuzzy comprehensive evaluation method was used to calculate the collaborative security index, which was the basis of our evaluation of the collaborative water–energy–food security of China in time and space. The results show that North China and Northwest China are at high water–food–energy security risk, while East, Central, and South China are at moderate risk. With the exception of Southwest China and South China, risk in most parts of the country has risen over the past decades, while it has fallen in Shandong, Henan, Sichuan, and Yunnan provinces. Full article
(This article belongs to the Special Issue The Water-Energy-Food Nexus: Sustainable Development)
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14 pages, 271 KiB  
Article
Water ‘Apartheid’ and the Significance of Human Rights Principles of Affirmative Action in South Africa
by Ademola Oluborode Jegede and Pumzile Shikwambane
Water 2021, 13(8), 1104; https://doi.org/10.3390/w13081104 - 16 Apr 2021
Cited by 18 | Viewed by 11803
Abstract
Water is an essential necessity for human beings; however, South Africa has a long history of inequalities dating back to apartheid politics and legislation which denied access to water to disadvantaged black populations mostly residing in rural areas. Although apartheid has officially ended, [...] Read more.
Water is an essential necessity for human beings; however, South Africa has a long history of inequalities dating back to apartheid politics and legislation which denied access to water to disadvantaged black populations mostly residing in rural areas. Although apartheid has officially ended, whether the lack of access to water by such populations who still cannot afford it exists and aligns with international human rights principles of equality and non-discrimination merits an examination. To redress the injustices of the apartheid regime, the right to have access to sufficient water is entrenched in section 27(1)(b) of the 1996 South African Constitution. In addition to embracing equality and non-discrimination, the Constitution informs other instruments and measures such as free basic water policy and pre-paid meters meant to ensure access to water. However, the plight of these populations persists in post-apartheid South Africa, but it is rarely a subject of academic scrutiny how the notion of affirmative action as grounded in the principles of equality and non-discrimination under human rights law can be deployed as a response. Using a doctrinal research approach, this article argues that the continuing struggle of disadvantaged communities with access to water does not only constitute water apartheid, it negates the human rights principles of equality and non-discrimination. The principle of affirmative action is useful in responding to inadequate access to sufficient water by disadvantaged populations in post-apartheid South Africa. Full article
(This article belongs to the Special Issue The Politics of the Human Right to Water)
20 pages, 3844 KiB  
Article
An Empirical Analysis of Sediment Export Dynamics from a Constructed Landform in the Wet Tropics
by Shahla Yavari, Neil McIntyre and Thomas Baumgartl
Water 2021, 13(8), 1087; https://doi.org/10.3390/w13081087 - 15 Apr 2021
Cited by 1 | Viewed by 2734
Abstract
Although plot-scale erosion experiments are numerous, there are few studies on constructed landforms. This limits the understanding of their long-term stability, which is especially important for planning mined land rehabilitation. The objective of this study was to gain insight into the erosion processes [...] Read more.
Although plot-scale erosion experiments are numerous, there are few studies on constructed landforms. This limits the understanding of their long-term stability, which is especially important for planning mined land rehabilitation. The objective of this study was to gain insight into the erosion processes in a 30 × 30 m trial plot on a mine waste rock dump in tropical northern Australia. The relationships between rainfall, runoff and suspended and bedload sediment export were assessed at annual, seasonal, inter-event and intra-event timescales. During a five-year study period, 231 rainfall–runoff–sediment export events were examined. The measured bedload and suspended sediments (mainly represented in nephelometric turbidity units (NTU)) showed the dominance of the wet season and heavy rainfall events. The bedload dominated the total mass, although the annual bedload diminished by approximately 75% over the five years, with greater flow energy required over time to mobilise the same bedload. The suspended load was more sustained, though it also exhibited an exhaustion process, with equal rainfall and runoff volumes and intensities, leading to lower NTU values over time. Intra-event NTU dynamics, including runoff-NTU time lags and hysteretic behaviours, were somewhat random from one event to the next, indicating the influence of the antecedent distribution of mobilisable sediments. The value of the results for supporting predictive modelling is discussed. Full article
(This article belongs to the Section Water Erosion and Sediment Transport)
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34 pages, 16266 KiB  
Article
Laboratory Investigations of the Bending Rheology of Floating Saline Ice and Physical Mechanisms of Wave Damping in the HSVA Hamburg Ship Model Basin Ice Tank
by Aleksey Marchenko, Andrea Haase, Atle Jensen, Ben Lishman, Jean Rabault, Karl-Ulrich Evers, Mark Shortt and Torsten Thiel
Water 2021, 13(8), 1080; https://doi.org/10.3390/w13081080 - 14 Apr 2021
Cited by 12 | Viewed by 4061
Abstract
An experimental investigation of flexural-gravity waves was performed in the Hamburg Ship Model Basin HSVA ice tank. Physical characteristics of the water-ice system were measured in several locations of the tank with a few sensors deployed in the water and on the ice [...] Read more.
An experimental investigation of flexural-gravity waves was performed in the Hamburg Ship Model Basin HSVA ice tank. Physical characteristics of the water-ice system were measured in several locations of the tank with a few sensors deployed in the water and on the ice during the tests. The three-dimensional motion of ice was measured with the optical system Qualisys; water pressure was measured by several pressure sensors mounted on the tank wall, in-plane deformations of the ice and the temperatures of the ice and water were measured by fiber optic sensors; and acoustic emissions were recorded with compressional crystal sensors. The experimental setup and selected results of the tests are discussed in this paper. Viscous-elastic model (Burgers material) is adopted to describe the dispersion and attenuation of waves propagating below the ice. The elastic modulus and the coefficient of viscosity are calculated using the experimental data. The results of the measurements demonstrated the dependence of wave characteristics from the variability of ice properties during the experiment caused by the brine drainage. We showed that the cyclic motion of the ice along the tank, imitating ice drift, and the generation of under ice turbulence cause an increase of wave damping. Recorded acoustic emissions demonstrated cyclic microcracking occurring with wave frequencies and accompanying bending deformations of the ice. This explains the viscous and anelastic rheology of the model ice. Full article
(This article belongs to the Special Issue The Occurrence, Physics and Impact of Wave–Ice Interaction)
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18 pages, 7023 KiB  
Article
Experimental Investigations of a Solar Water Treatment System for Remote Desert Areas of Pakistan
by Muhammad Ahmad Jamil, Haseeb Yaqoob, Muhammad Umar Farooq, Yew Heng Teoh, Ben Bin Xu, Khamid Mahkamov, Muhammad Sultan, Kim Choon Ng and Muhammad Wakil Shahzad
Water 2021, 13(8), 1070; https://doi.org/10.3390/w13081070 - 13 Apr 2021
Cited by 11 | Viewed by 4596
Abstract
Pakistan is among the countries that have already crossed the water scarcity line, and the situation is worsened due to the recent pandemic. This is because the major budget of the country is shifted to primary healthcare activities from other development projects that [...] Read more.
Pakistan is among the countries that have already crossed the water scarcity line, and the situation is worsened due to the recent pandemic. This is because the major budget of the country is shifted to primary healthcare activities from other development projects that included water treatment and transportation infrastructure. Consequently, water-borne diseases have increased drastically in the past few months. Therefore, there is a dire need to address this issue on a priority basis to ameliorate the worsening situation. One possible solution is to shift the focus/load from mega-projects that require a plethora of resources, money, and time to small domestic-scale systems for water treatment. For this purpose, domestic-scale solar stills are designed, fabricated, and tested in one of the harshest climatic condition areas of Pakistan, Rahim Yar Khan. A comprehensive overview of the regional climatology, including wind speed, solar potential, and ambient temperature is presented for the whole year. The analysis shows that the proposed system can adequately resolve the drinking water problems of deprived areas of Pakistan. The average water productivity of 1.5 L/d/m2 is achieved with a total investment of PKR 3000 (<$20). This real site testing data will serve as a guideline for similar system design in other arid areas globally. Full article
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22 pages, 3212 KiB  
Article
Pricing Strategy for Residential Water in Drought Years. Application to the City of Tianjin, China
by Bing Yu, Yu Li, Jinggang Chu, Wei Ding, Guangtao Fu, Xiangyang Leng and Tiantian Yang
Water 2021, 13(8), 1073; https://doi.org/10.3390/w13081073 - 13 Apr 2021
Cited by 2 | Viewed by 3112
Abstract
In drought years, most residents fail to improve water use efficiency due to residential water supply normally being prioritized in many regions, which makes other low-priority industrial water users suffer more from water shortage. This paper proposes a Pricing Strategy for Residential Water [...] Read more.
In drought years, most residents fail to improve water use efficiency due to residential water supply normally being prioritized in many regions, which makes other low-priority industrial water users suffer more from water shortage. This paper proposes a Pricing Strategy for Residential Water (PSRW), a water tariff that changes on annual time scale, based on the scarcity value of water resources, aiming to promote residential water conservation and reallocate water resources across the residential and industrial sectors during droughts. An optimization model to maximize the total benefit of residents and industrial sectors is introduced based on marginal benefit and price elasticity. The water shortage of industrial sectors is used to reflect the scarcity of water resources, and the lowest water supply standard for households and the maximum proportion of household water fee expenditure (HWFE) to household disposable income (HDI) are used to ensure the residents’ acceptability to price raising. It shows an “S-type” relationship between the optimal price raising coefficient and industrial water shortage, and two turning points are found in the curve, which are the starting and stopping points of price raising. The appearance of starting point depends on the non-negative net benefit, and the stopping point is affected by the factors that represent the residents’ acceptability to price raising. The application to Tianjin, a city in northern China with the rapid growth of population and economy but scarce water resources, shows PSRW is a potential means to improve water efficiency and optimize water resource allocation in water scarcity situations. Full article
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19 pages, 5235 KiB  
Article
Solution Selection from a Pareto Optimal Set of Multi-Objective Reservoir Operation via Clustering Operation Processes and Objective Values
by Yanjun Kong, Yadong Mei, Xianxun Wang and Yue Ben
Water 2021, 13(8), 1046; https://doi.org/10.3390/w13081046 - 10 Apr 2021
Cited by 8 | Viewed by 2970
Abstract
Multi-objective evolutionary algorithms (MOEAs) are widely used to optimize multi-purpose reservoir operations. Considering that most outcomes of MOEAs are Pareto optimal sets with a large number of incomparable solutions, it is not a trivial task for decision-makers (DMs) to select a compromise solution [...] Read more.
Multi-objective evolutionary algorithms (MOEAs) are widely used to optimize multi-purpose reservoir operations. Considering that most outcomes of MOEAs are Pareto optimal sets with a large number of incomparable solutions, it is not a trivial task for decision-makers (DMs) to select a compromise solution for application purposes. Due to the increasing popularity of data-driven decision-making, we introduce a clustering-based decision-making method into the multi-objective reservoir operation optimization problem. Traditionally, solution selection has been conducted based on trade-off ranking in objective space, and solution characteristics in decision space have been ignored. In our work, reservoir operation processes were innovatively clustered into groups with unique properties in decision space, and the trade-off surfaces were analyzed via clustering in objective space. To attain a suitable performance, a new similarity measure, referred to as the Mei–Wang fluctuation similarity measure (MWFSM), was tailored to reservoir operation processes. This method describes time series in terms of both their shape and quantitative variation. Then, a compromise solution was selected via the joint use of two clustering results. A case study of the Three Gorges cascade reservoirs system under small and medium floods was investigated to verify the applicability of the proposed method. The results revealed that the MWFSM effectively distinguishes reservoir operation processes. Two more operation patterns with similar positions but different shapes were identified via MWFSM when compared with Euclidean distance and the dynamic time warping method. Furthermore, the proposed method decreased the selection range from the whole Pareto optimal set to a set containing relatively few solutions. Finally, a compromise solution was selected. Full article
(This article belongs to the Section Water Resources Management, Policy and Governance)
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34 pages, 6522 KiB  
Review
Restoration of Seagrass Meadows in the Mediterranean Sea: A Critical Review of Effectiveness and Ethical Issues
by Charles-François Boudouresque, Aurélie Blanfuné, Gérard Pergent and Thierry Thibaut
Water 2021, 13(8), 1034; https://doi.org/10.3390/w13081034 - 9 Apr 2021
Cited by 66 | Viewed by 14136
Abstract
Some species of seagrasses (e.g., Zostera marina and Posidonia oceanica) have declined in the Mediterranean, at least locally. Others are progressing, helped by sea warming, such as Cymodocea nodosa and the non-native Halophila stipulacea. The decline of one seagrass can favor [...] Read more.
Some species of seagrasses (e.g., Zostera marina and Posidonia oceanica) have declined in the Mediterranean, at least locally. Others are progressing, helped by sea warming, such as Cymodocea nodosa and the non-native Halophila stipulacea. The decline of one seagrass can favor another seagrass. All in all, the decline of seagrasses could be less extensive and less general than claimed by some authors. Natural recolonization (cuttings and seedlings) has been more rapid and more widespread than was thought in the 20th century; however, it is sometimes insufficient, which justifies transplanting operations. Many techniques have been proposed to restore Mediterranean seagrass meadows. However, setting aside the short-term failure or half-success of experimental operations, long-term monitoring has usually been lacking, suggesting that possible failures were considered not worthy of a scientific paper. Many transplanting operations (e.g., P. oceanica) have been carried out at sites where the species had never previously been present. Replacing the natural ecosystem (e.g., sandy bottoms, sublittoral reefs) with P. oceanica is obviously inappropriate in most cases. This presupposes ignorance of the fact that the diversity of ecosystems is one of the bases of the biodiversity concept. In order to prevent the possibility of seagrass transplanting from being misused as a pretext for further destruction, a guide for the proper conduct of transplanting is proposed. Full article
(This article belongs to the Special Issue Restore Degraded Marine Coastal Areas in the Mediterranean Sea)
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24 pages, 18598 KiB  
Article
Phosphorus Transport in a Lowland Stream Derived from a Tracer Test with 32P
by Damian Zięba and Przemysław Wachniew
Water 2021, 13(8), 1030; https://doi.org/10.3390/w13081030 - 9 Apr 2021
Cited by 5 | Viewed by 4785
Abstract
Small streams in urbanized rural areas receive loads of P from various, often episodic, sources. This paper addresses, through a tracer test with 32P, retention and transport of a pulse input of phosphorus in a 2.6 km long stretch of a channelized [...] Read more.
Small streams in urbanized rural areas receive loads of P from various, often episodic, sources. This paper addresses, through a tracer test with 32P, retention and transport of a pulse input of phosphorus in a 2.6 km long stretch of a channelized second-order lowland stream. Tritiated water was introduced alongside the 32P-labelled ortophosphate in order to isolate the influence of the hydrodynamic factors on P behavior. Tracer concentrations in unfiltered water samples were measured by liquid scintillation counting. Four in-stream and five hyporheic breakthrough curves were collected at four points along the stream, two of which encompass a beaver dam impoundment. The overall retention efficiency of 32P along the studied reach was 46%. The transient storage transport model OTIS-P provided reasonable fits for in-stream breakthrough curves (BTCs) but failed at reproducing the hyporheic BTCs. The overall small effect of transient storage on solute transport was higher in the stretch with a more pronounced surface storage. Transient storage and phosphorus retention were not enhanced in the beaver dam impoundment. Full article
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22 pages, 5416 KiB  
Article
Introducing Non-Stationarity Into the Development of Intensity-Duration-Frequency Curves under a Changing Climate
by Daniele Feitoza Silva, Slobodan P. Simonovic, Andre Schardong and Joel Avruch Goldenfum
Water 2021, 13(8), 1008; https://doi.org/10.3390/w13081008 - 7 Apr 2021
Cited by 23 | Viewed by 3802
Abstract
Intensity-duration-frequency (IDF) relationships are traditional tools in water infrastructure planning and design. IDFs are developed under a stationarity assumption which may not be realistic, neither in the present nor in the future, under a changing climatic condition. This paper introduces a framework for [...] Read more.
Intensity-duration-frequency (IDF) relationships are traditional tools in water infrastructure planning and design. IDFs are developed under a stationarity assumption which may not be realistic, neither in the present nor in the future, under a changing climatic condition. This paper introduces a framework for generating non-stationary IDFs under climate change, assuming that probability of occurrence of quantiles changes over time. Using Extreme Value Theory, eight trend combinations in Generalized Extreme Value (GEV) parameters using time as covariate are compared with a stationary GEV, to identify the best alternative. Additionally, a modified Equidistance Quantile Matching (EQMNS) method is implemented to develop IDFs for future conditions, introducing non-stationarity where justified, based on the Global Climate Models (GCM). The methodology is applied for Moncton and Shearwater gauges in Northeast Canada. From the results, it is observed that EQMNS is able to capture the trends in the present and to translate them to estimated future rainfall intensities. Comparison of present and future IDFs strongly suggest that return period can be reduced by more than 50 years in the estimates of future rainfall intensities (e.g., historical 100-yr return period extreme rainfall may have frequency smaller than 50-yr under future conditions), raising attention to emerging risks to water infrastructure systems. Full article
(This article belongs to the Section Water Resources Management, Policy and Governance)
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26 pages, 7741 KiB  
Article
Spatial and Temporal Shifts in Historic and Future Temperature and Precipitation Patterns Related to Snow Accumulation and Melt Regimes in Alberta, Canada
by Brandi W. Newton, Babak Farjad and John F. Orwin
Water 2021, 13(8), 1013; https://doi.org/10.3390/w13081013 - 7 Apr 2021
Cited by 30 | Viewed by 5883
Abstract
Shifts in winter temperature and precipitation patterns can profoundly affect snow accumulation and melt regimes. These shifts have varying impacts on local to large-scale hydro-ecological systems and freshwater distribution, especially in cold regions with high hydroclimatic heterogeneity. We evaluate winter climate changes in [...] Read more.
Shifts in winter temperature and precipitation patterns can profoundly affect snow accumulation and melt regimes. These shifts have varying impacts on local to large-scale hydro-ecological systems and freshwater distribution, especially in cold regions with high hydroclimatic heterogeneity. We evaluate winter climate changes in the six ecozones (Mountains, Foothills, Prairie, Parkland, Boreal, and Taiga) in Alberta, Canada, and identify regions of elevated susceptibility to change. Evaluation of historic trends and future changes in winter climate use high-resolution (~10 km) gridded data for 1950–2017 and projections for the 2050s (2041–2070) and 2080s (2071–2100) under medium (RCP 4.5) and high (RCP 8.5) emissions scenarios. Results indicate continued declines in winter duration and earlier onset of spring above-freezing temperatures from historic through future periods, with greater changes in Prairie and Mountain ecozones, and extremely short or nonexistent winter durations in future climatologies. Decreases in November–April precipitation and a shift from snow to rain dominate the historic period. Future scenarios suggest winter precipitation increases are expected to predominantly fall as rain. Additionally, shifts in precipitation distributions are likely to lead to historically-rare, high-precipitation extreme events becoming more common. This study increases our understanding of historic trends and projected future change effects on winter snowpack-related climate and can be used inform adaptive water resource management strategies. Full article
(This article belongs to the Special Issue Past and Future Trends and Variability in Hydro-Climatic Processes)
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20 pages, 7299 KiB  
Article
Nexus Thinking at River Basin Scale: Food, Water and Welfare
by Roberto D. Ponce Oliva, Francisco J. Fernández, Felipe Vasquez-Lavín, Esteban Arias Montevechio, Natalia Julio and Alejandra Stehr
Water 2021, 13(7), 1000; https://doi.org/10.3390/w13071000 - 5 Apr 2021
Cited by 1 | Viewed by 4559
Abstract
Water resources face an unparalleled confluence of pressures, with agriculture and urban growth as the most relevant human-related stressors. In this context, methodologies using a Nexus framework seem to be suitable to address these challenges. However, the urban sector has been commonly ignored [...] Read more.
Water resources face an unparalleled confluence of pressures, with agriculture and urban growth as the most relevant human-related stressors. In this context, methodologies using a Nexus framework seem to be suitable to address these challenges. However, the urban sector has been commonly ignored in the Nexus literature. We propose a Nexus framework approach, considering the economic dimensions of the interdependencies and interconnections among agriculture (food production) and the urban sector as water users within a common basin. Then, we assess the responses of both sectors to climatic and demographic stressors. In this setting, the urban sector is represented through an economic water demand at the household level, from which economic welfare is derived. Our results show that the Nexus components here considered (food, water, and welfare) will be negatively affected under the simulated scenarios. However, when these components are decomposed to their particular elements, we found that the less water-intensive sector—the urban sector—will be better off since food production will leave significant amounts of water available. Moreover, when addressing uncertainty related to climate-induced shocks, we could identify the basin resilience threshold. Our approach shows the compatibilities and divergences between food production and the urban sector under the Nexus framework. Full article
(This article belongs to the Special Issue The Water-Energy-Food Nexus: Sustainable Development)
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18 pages, 3738 KiB  
Article
Modeling and Optimization of Biochar Based Adsorbent Derived from Kenaf Using Response Surface Methodology on Adsorption of Cd2+
by Anwar Ameen Hezam Saeed, Noorfidza Yub Harun, Suriati Sufian, Muhammad Roil Bilad, Baiq Asma Nufida, Noor Maizura Ismail, Zaki Yamani Zakaria, Ahmad Hussaini Jagaba, Aiban Abdulhakim Saeed Ghaleb and Baker Nasser Saleh Al-Dhawi
Water 2021, 13(7), 999; https://doi.org/10.3390/w13070999 - 5 Apr 2021
Cited by 48 | Viewed by 5806
Abstract
Cadmium is one of the most hazardous metals in the environment, even when present at very low concentrations. This study reports the systematic development of Kenaf fiber biochar as an adsorbent for the removal of cadmium (Cd) (II) ions from water. The adsorbent [...] Read more.
Cadmium is one of the most hazardous metals in the environment, even when present at very low concentrations. This study reports the systematic development of Kenaf fiber biochar as an adsorbent for the removal of cadmium (Cd) (II) ions from water. The adsorbent development was aided by an optimization tool. Activated biochar was prepared using the physicochemical activation method, consisting of pre-impregnation with NaOH and nitrogen (N2) pyrolysis. The influence of the preparation parameters—namely, chemical impregnation (NaOH: KF), pyrolysis temperature, and pyrolysis time on biochar yield, removal rate, and the adsorption capacity of Cd (II) ions—was investigated. From the experimental data, some quadratic correlation models were developed according to the central composite design. All models demonstrated a good fit with the experimental data. The experimental results revealed that the pyrolysis temperature and heating time were the main factors that affected the yield of biochar and had a positive effect on the Cd (II) ions’ removal rate and adsorption capacity. The impregnation ratio also showed a positive effect on the specific surface area of the biochar, removal rate, and adsorption capacity of cadmium, with a negligible effect on the biochar yield. The optimal biochar-based adsorbent was obtained under the following conditions: 550 °C of pyrolysis temperature, 180 min of heating time, and a 1:1 NaOH impregnation ratio. The optimum adsorbent showed 28.60% biochar yield, 69.82% Cd (II) ions removal, 23.48 mg/g of adsorption capacity, and 160.44 m2/g of biochar-specific area. Full article
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16 pages, 972 KiB  
Review
Aquaculture and Restoration: Perspectives from Mediterranean Sea Experiences
by Adriana Giangrande, Maria Flavia Gravina, Sergio Rossi, Caterina Longo and Cataldo Pierri
Water 2021, 13(7), 991; https://doi.org/10.3390/w13070991 - 4 Apr 2021
Cited by 23 | Viewed by 6340
Abstract
In this paper, the different possibilities and innovations related to sustainable aquaculture in the Mediterranean area are discussed, while different maricultural methods, and the role of Integrated Multi-Trophic Aquaculture (IMTA) in supporting the exploitation of the ocean’s resources, are also reviewed. IMTA, and [...] Read more.
In this paper, the different possibilities and innovations related to sustainable aquaculture in the Mediterranean area are discussed, while different maricultural methods, and the role of Integrated Multi-Trophic Aquaculture (IMTA) in supporting the exploitation of the ocean’s resources, are also reviewed. IMTA, and mariculture in general, when carefully planned, can be suitable for environmental restoration and conservation purposes. Aquaculture, especially mariculture, is a sector that is progressively increasing in parallel with the increase in human needs; however, several problems still affect its development, mainly in relation to the choice of suitable sites, fodder production, and the impact on the surrounding environment. A current challenge that requires suitable solutions is the implementation of IMTA. Unfortunately, some criticisms still affect this approach, mostly concerning the commercialization of new products such as invertebrates and seaweeds, notwithstanding their environmentally friendly character. Regarding the location of a suitable site, mariculture plans are currently displaced from inshore to offshore, with the aim of reducing the competition for space with other human activities carried out within coastal waters. Moreover, in open water, waste loading does not appear to be a problem, but high-energy waters increase maintenance costs. Some suggestions are given for developing sustainable mariculture in the Mediterranean area, where IMTA is in its infancy and where the scarce nutrients that characterize offshore waters are not suitable for the farming of both filter feeder invertebrates and macroalgae. From the perspective of coupling mariculture activity with restoration ecology, the practices suggested in this review concern the implementation of inshore IMTA, creating artificially controlled gardens, as well as offshore mussel farming coupled with artificial reefs, while also hypothesizing the possibility of the use of artificially eutrophized areas. Full article
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18 pages, 6292 KiB  
Article
Analytical Solution of Saltwater Intrusion in Costal Aquifers Considering Climate Changes and Different Boundary Conditions
by Ismail Abd-Elaty, Martina Zeleňáková, Katarína Krajníková and Hany F. Abd-Elhamid
Water 2021, 13(7), 995; https://doi.org/10.3390/w13070995 - 4 Apr 2021
Cited by 19 | Viewed by 5304
Abstract
Groundwater contamination due to saltwater intrusion (SWI) has an extreme effect on freshwater quality. Analytical and numerical models could be used to investigate SWI. This study aims to develop an analytical solution to investigate SWI into coastal aquifers which was applied to a [...] Read more.
Groundwater contamination due to saltwater intrusion (SWI) has an extreme effect on freshwater quality. Analytical and numerical models could be used to investigate SWI. This study aims to develop an analytical solution to investigate SWI into coastal aquifers which was applied to a real case study at the Middle Nile Delta aquifer (MNDA). The study presented a new formula to predict the difference in depth of freshwater to seawater interface due to a change in boundary conditions. A Computer Program for Simulation of Three-Dimensional Variable-Density Ground-Water Flow and Transport (SEAWAT) is used for groundwater flow simulation and SWI and the results compared with the developed analytical solution. Four scenarios are considered in the study, including; the sea-level rise (SLR), reduction in recharge, over abstraction, and combination after 50 years (2070). The analytical solution gave good results compared to the numerical one where Equiline 1 intruded to 103 and 101.66 km respectively at the base case. The results also gave a good agreement between numerical and the analytical solution for SLR due to climate changes by 52.80 cm where the Equiline 1 reached to 105 and 103.45 km. However, the reduction in aquifer recharge by 18.50% resulted in an intrusion for the Equiline-1 to 111 and 108.25 km from the shoreline. Over pumping due to the increase in population by 89% has increased the SWI to reach 121,110.31 km, while it reached 131 and 111.32 km at a combination of the three scenarios, which represents the highest threatening scenario. Also, the difference between the two solutions reached 1.30%, 1.48%, 2.48%, 8.84%, and 15.02%, respectively for the base case and four scenarios. For the current case study, the analytical model gave good results compared to the numerical one, so that the analytical solution is recommended for similar studies, which could save the time and capabilities of computer required for the numerical solutions. Full article
(This article belongs to the Special Issue Assessment and Management of Flood Risk in Urban Areas)
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35 pages, 3903 KiB  
Review
Oily Wastewater Treatment: Overview of Conventional and Modern Methods, Challenges, and Future Opportunities
by Khaled Abuhasel, Mohamed Kchaou, Mohammed Alquraish, Yamuna Munusamy and Yong Tzyy Jeng
Water 2021, 13(7), 980; https://doi.org/10.3390/w13070980 - 2 Apr 2021
Cited by 243 | Viewed by 33738
Abstract
Industrial developments in the oil and gas, petrochemical, pharmaceutical and food sector have contributed to the large production of oily wastewater worldwide. Oily wastewater pollution affects drinking water and groundwater resources, endangers aquatic life and human health, causes atmospheric pollution, and affects crop [...] Read more.
Industrial developments in the oil and gas, petrochemical, pharmaceutical and food sector have contributed to the large production of oily wastewater worldwide. Oily wastewater pollution affects drinking water and groundwater resources, endangers aquatic life and human health, causes atmospheric pollution, and affects crop production. Several traditional and conventional methods were widely reported, and the advantages and limitations were discussed. However, with the technology innovation, new trends of coupling between techniques, use of new materials, optimization of the cleaning process, and multiphysical approach present new paths for improvement. Despite these trends of improvement and the encouraging laboratory results of modern and green methods, many challenges remain to be raised, particularly the commercialization and the global aspect of these solutions and the reliability to reduce the system’s maintenance and operational cost. In this review, the well-known oily wastewater cleaning methods and approaches are being highlighted, and the obstacles faced in the practical use of these technologies are discussed. A critical review on the technologies and future direction as the road to commercialization is also presented to persevere water resources for the benefit of mankind and all living things. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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23 pages, 10376 KiB  
Article
Time Series Analysis of Monthly and Annual Precipitation in The State of Texas Using High-Resolution Radar Products
by Dawit Ghebreyesus and Hatim O. Sharif
Water 2021, 13(7), 982; https://doi.org/10.3390/w13070982 - 2 Apr 2021
Cited by 7 | Viewed by 3582
Abstract
Precipitation is the main source for replenishing groundwater stored in aquifers for a myriad of beneficial purposes, especially in arid and semi-arid regions. A significant portion of the municipal and agricultural water demand is satisfied through groundwater withdrawals in Texas. These withdrawals have [...] Read more.
Precipitation is the main source for replenishing groundwater stored in aquifers for a myriad of beneficial purposes, especially in arid and semi-arid regions. A significant portion of the municipal and agricultural water demand is satisfied through groundwater withdrawals in Texas. These withdrawals have to be monitored and regulated to be in balance with the recharge amount from precipitation in order to ensure water security. The main goal of this study is to understand the spatio-temporal variability of precipitation in the 21st century using high spatial resolution stage-IV radar data over the state of Texas and examine some climatic controls behind this variability. The results will shed light on the trends of precipitation and hence will contribute to improving water resources management strategies and policies. Pettit’s test and Standard Normal Homogeneity Test (SNHT), tools for detecting change-point in the monthly precipitation, suggested change-points have occurred across the state around the years 2013 and 2014. The test for the homogeneity of the data before and after 2013 revealed that, in over 64% of the state, the precipitation means were significantly different. The Panhandle region (northern part) is the only part of the state that did not show a significant difference in the mean precipitation before and after 2013. Theil-Sen’s slope test, Correlated Seasonal Mann-Kendall Test, and Cox and Stuart Trend Test all indicated that there were no significant trends in the monthly precipitation after 2013 in over 98% of the area of the state. Texas precipitation was found to be influenced significantly by the El Niño-Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO). A significant correlation in more than 82% and 60% of the state was found with ENSO at two-month and with PDO at four-month lag, respectively. Full article
(This article belongs to the Section Hydrology)
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24 pages, 6693 KiB  
Article
Testing the Efficiency of Parameter Disaggregation for Distributed Rainfall-Runoff Modelling
by Sotirios Moustakas and Patrick Willems
Water 2021, 13(7), 972; https://doi.org/10.3390/w13070972 - 1 Apr 2021
Cited by 4 | Viewed by 2596
Abstract
A variety of hydrological models is currently available. Many of those employ physically based formulations to account for the complexity and spatial heterogeneity of natural processes. In turn, they require a substantial amount of spatial data, which may not always be available at [...] Read more.
A variety of hydrological models is currently available. Many of those employ physically based formulations to account for the complexity and spatial heterogeneity of natural processes. In turn, they require a substantial amount of spatial data, which may not always be available at sufficient quality. Recently, a top-down approach for distributed rainfall-runoff modelling has been developed, which aims at combining accuracy and simplicity. Essentially, a distributed model with uniform model parameters (base model) is derived from a calibrated lumped conceptual model. Subsequently, selected parameters are disaggregated based on links with the available spatially variable catchment properties. The disaggregation concept is now adjusted to better account for non-linearities and extended to incorporate more model parameters (and, thus, larger catchment heterogeneity). The modelling approach is tested for a catchment including several flow gauging stations. The disaggregated model is shown to outperform the base model with respect to internal catchment dynamics, while performing similarly at the catchment outlet. Moreover, it manages to bridge on average 44% of the Nash–Sutcliffe efficiency difference between the base model and the lumped models calibrated for the internal gauging stations. Nevertheless, the aforementioned improvement is not necessarily sufficient for reliable model results. Full article
(This article belongs to the Section Hydrology)
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30 pages, 1194 KiB  
Review
Microplastics in the Aquatic Environment: Occurrence, Persistence, Analysis, and Human Exposure
by Maria Ricciardi, Concetta Pironti, Oriana Motta, Ylenia Miele, Antonio Proto and Luigi Montano
Water 2021, 13(7), 973; https://doi.org/10.3390/w13070973 - 1 Apr 2021
Cited by 86 | Viewed by 12107
Abstract
Microplastics (MP) have recently been considered as emerging contaminants in the water environment. In the last number of years, the number of studies on MP has grown quickly due to the increasing consciousness of the potential risks for human health related to MP [...] Read more.
Microplastics (MP) have recently been considered as emerging contaminants in the water environment. In the last number of years, the number of studies on MP has grown quickly due to the increasing consciousness of the potential risks for human health related to MP exposure. The present review article discusses scientific literature regarding MP occurrence and accumulation on the aquatic compartment (river, lake, wastewater, seafood), the analytical methods used to assess their concentration, their fate and transport to humans, and delineates the urgent areas for future research. To better analogize literature data regarding MP occurrence in the aquatic compartment we subdivided papers based on sampling, analytical methods, and concentration units with the aim to help the reader identify the similarities and differences of the considered research papers, thus making the comparison of literature data easier and the individuation of the most relevant articles for the reader’s interests faster. Furthermore, we argued about several ways for MP transport to humans, highlighting some gaps in analytical methods based on the reviewed publications. We suggest improving studies on developing standardized protocols to collect, process, and analyze samples. Full article
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18 pages, 4131 KiB  
Article
Hydroclimatic Variability and Land Cover Transformations in the Central Italian Alps
by Matteo Balistrocchi, Massimo Tomirotti, Alessandro Muraca and Roberto Ranzi
Water 2021, 13(7), 963; https://doi.org/10.3390/w13070963 - 31 Mar 2021
Cited by 7 | Viewed by 4354
Abstract
Extreme streamflow nonstationarity has probably attracted more attention than mean streamflow nonstationarity in the assessment of the impacts of climate change on the water cycle. Nonetheless, a significant decrease in mean streamflow could lead to conditions of scarcity of freshwater in the long-term [...] Read more.
Extreme streamflow nonstationarity has probably attracted more attention than mean streamflow nonstationarity in the assessment of the impacts of climate change on the water cycle. Nonetheless, a significant decrease in mean streamflow could lead to conditions of scarcity of freshwater in the long-term period, seriously compromising the sustainability of the demand for civil, agricultural, and industrial uses. Regional analyses are useful to better characterize an area’s nonstationarity, since a clear trend at a global scale has not been detected yet. In this article, long-term and high-quality series of streamflow discharges observed in five rivers in the Central Italian Alps, including two multicentury series and two new precipitation and streamflow series not analyzed before, are investigated to statistically characterize individual trends of mean annual runoff volumes. Nonparametric pooled statistics are also introduced to assess the regional trend. Additional climatic and nonclimatic factors, namely, precipitation trends and land cover transformations, have also been considered as potential change drivers. Unlike precipitation, runoff volumes show a marked and statistically significant decrease of −1.45 mm/year, which appears to be homogeneous in the region. The land cover transformation analysis presented here revealed extensive woodland expansions of 510 km2 in 2018 out of the 2650 km2 area measured in 1954, representing 38% of the area investigated in this study: this anthropic driver of enhanced hydrologic losses can be recognized as an additional likely cause for the regional runoff volume decrease. Full article
(This article belongs to the Special Issue Climate Change Impact and Adaptation in Water Resources Management)
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