- Article
Diasteromeric Effect on the Homolysis of the C–ON Bond in Alkoxyamines: A DFT Investigation of 1,3-Diphenylbutyl-TEMPO
- Alexandra Blachon,
- Sylvain R. A. Marque,
- Valérie Roubaud and
- Didier Siri
The rate constants kd of the homolysis of the C–ON bond in styryl dyads TEMPO-based alkoxyamines have recently been published (Li et al. Macromolecules 2006, 39, 9201). The diastereoisomers exhibited different values which were higher than for the un...

