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Polymers, Volume 10, Issue 12

2018 December - 121 articles

Cover Story: Molecular fillers for lowering refractive indices and enhancing the thermal stability and rigidity of polymer films were designed based on polyhedral oligomeric silsesquioxane (POSS). By introducing two types of functional groups, such as fluoroalkyl and reactive groups, this trade-off relationship can be consistent. View this paper.
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Articles (121)

  • Article
  • Open Access
30 Citations
5,131 Views
10 Pages

19 December 2018

Because flammable organic solvents are emitted during the construction process, oil-based conductive coatings generally result in potential safety problems. A high content of conductive mediums can also weaken the adhesive and protective abilities of...

  • Review
  • Open Access
270 Citations
17,138 Views
31 Pages

Biological Activity and Pharmacological Application of Pectic Polysaccharides: A Review

  • Salima T. Minzanova,
  • Vladimir F. Mironov,
  • Daria M. Arkhipova,
  • Anna V. Khabibullina,
  • Lubov G. Mironova,
  • Yulia M. Zakirova and
  • Vasili A. Milyukov

19 December 2018

Pectin is a polymer with a core of alternating α-1,4-linked d-galacturonic acid and α-1,2-l-rhamnose units, as well as a variety of neutral sugars such as arabinose, galactose, and lesser amounts of other sugars. Currently, native pectins have been c...

  • Article
  • Open Access
28 Citations
5,858 Views
19 Pages

19 December 2018

This article describes a facile low-cost synthesis of polyaniline nanotube (PANINT)–carbon nano-onion (CNO) composites for solid-state supercapacitors. Scanning electron microscopic (SEM) analyses indicate a uniform and ordered composition for...

  • Article
  • Open Access
20 Citations
5,707 Views
13 Pages

Dynamic High-Pressure Microfluidization-Treated Pectin under Different Ethanol Concentrations

  • Cheng-Mei Liu,
  • Lu Liang,
  • Xi-Xiang Shuai,
  • Rui-Hong Liang and
  • Jun Chen

19 December 2018

We previously reported that dynamic high-pressure microfluidization (DHPM) can degrade pectin in aqueous solution. In this study, we further investigated the effect of DHPM on pectin in water-ethanol systems. In the absence of DHPM treatment, it was...

  • Article
  • Open Access
17 Citations
8,094 Views
13 Pages

19 December 2018

In this study, a novel composite separator based on polytetrafluoroethylene (PTFE) coating layers and a commercial polyethylene (PE) separator is developed for high performance Li-ion batteries. This composite separator is prepared by immersing a PE...

  • Article
  • Open Access
33 Citations
4,854 Views
18 Pages

19 December 2018

A novel concept based on advanced particle-grafting technology to tailor performance, damping, and surface properties of the magnetorheological elastomers (MREs) is introduced. In this work, the carbonyl iron (CI) particles grafted with poly(trimethy...

  • Communication
  • Open Access
29 Citations
4,526 Views
7 Pages

19 December 2018

Electronic devices are increasingly dense, underscoring the need for effective thermal management. A polyimide (PI) matrix nanocomposite film combining boron nitride (BN)-coated copper nanoparticles (CuNPs@BN) and nanowires (CuNWs@BN) was fabricated...

  • Article
  • Open Access
21 Citations
5,278 Views
12 Pages

Over-Stretching Tolerant Conductors on Rubber Films by Inkjet-Printing Silver Nanoparticles for Wearables

  • Andreas Albrecht,
  • Marco Bobinger,
  • José F. Salmerón,
  • Markus Becherer,
  • Gordon Cheng,
  • Paolo Lugli and
  • Almudena Rivadeneyra

19 December 2018

The necessity to place sensors far away from the processing unit in smart clothes or artificial skins for robots may require conductive wirings on stretchable materials at very low-cost. In this work, we present an easy method to produce wires using...

  • Article
  • Open Access
44 Citations
6,240 Views
13 Pages

Inkjet Printable and Self-Curable Disperse Dyes/P(St-BA-MAA) Nanosphere Inks for Both Hydrophilic and Hydrophobic Fabrics

  • Yawei Song,
  • Kuanjun Fang,
  • Yanfei Ren,
  • Zhiyuan Tang,
  • Rongqing Wang,
  • Weichao Chen,
  • Ruyi Xie,
  • Zhen Shi and
  • Longyun Hao

18 December 2018

Low-water-soluble disperse dyes possess a broad color gamut and good durability, but they need chemical or physical modification before being used in inks and can only be applied to several kinds of hydrophobic fabrics. In this work, disperse dyes/P(...

  • Article
  • Open Access
6 Citations
4,792 Views
16 Pages

18 December 2018

The performance of aptamer-based biosensors is crucially impacted by their interactions with physiological metal ions, which can alter their structures and chemical properties. Therefore, elucidating the nature of these interactions carries the utmos...

  • Article
  • Open Access
11 Citations
6,793 Views
11 Pages

18 December 2018

In this study, we investigated direct-controlled/living cationic polymerization and copolymerization of 4-vinylguaiacol (4VG), i.e., 4-hydroxy-3-methoxystyrene, which can be derived from naturally-occurring ferulic acid, to develop novel bio-based am...

  • Article
  • Open Access
15 Citations
4,318 Views
13 Pages

18 December 2018

A controlled-release system for drug delivery allows the continuous supply of a drug to the target region at a predetermined rate for a specified period of time. Herein, the sustained release behavior of a drug-containing tablet fabricated through CO...

  • Review
  • Open Access
43 Citations
6,738 Views
12 Pages

17 December 2018

The fuel cell, as one of the most promising electrochemical devices, is sustainable, clean, and environmentally benign. The sluggish oxygen reduction reaction (ORR) is an important fuel cell cathodic reaction that decides the efficiency of the overal...

  • Article
  • Open Access
8 Citations
6,475 Views
13 Pages

Paddlewheel SBU based Zn MOFs: Syntheses, Structural Diversity, and CO2 Adsorption Properties

  • Ting-Ru Lin,
  • Cheng-Hua Lee,
  • Yi-Chen Lan,
  • Shruti Mendiratta,
  • Long-Li Lai,
  • Jing-Yun Wu,
  • Kai-Ming Chi and
  • Kuang-Lieh Lu

17 December 2018

Four Zn metal–organic frameworks (MOFs), {[Zn2(2,6-ndc)2(2-Pn)]·DMF}n (1), {[Zn2(cca)2(2-Pn)]·DMF}n (2), {[Zn2(thdc)2(2-Pn)]·3DMF}n (3), and {[Zn2(1,4-ndc)2(2-Pn)]·1.5DMF}n (4), were synthesized from zinc nitrate and...

  • Article
  • Open Access
12 Citations
6,057 Views
14 Pages

Evaluation of Exfoliated Graphite to Graphene in Polyamide 66 Using Novel High Shear Elongational Flow

  • Justin W. Hendrix,
  • Ryan Szeto,
  • Thomas Nosker,
  • Jennifer Lynch-Branzoi and
  • Thomas J. Emge

17 December 2018

Graphene has been publicized as the game changing material of this millennium. To this day, scalable production leading to exceptional material properties has been difficult to attain. Most methods require harsh chemicals, which result in destroying...

  • Article
  • Open Access
31 Citations
4,860 Views
17 Pages

17 December 2018

A series of anion exchange membranes composed of partially fluorinated poly(arylene ether sulfone)s (PAESs) multiblock copolymers bearing quaternary ammonium groups were synthesized with controlled lengths of the hydrophilic precursor and hydrophobic...

  • Article
  • Open Access
44 Citations
6,089 Views
15 Pages

17 December 2018

As is an excellent bio-based polymer material, poly(lactic acid) (PLA)’s brittle nature greatly restricts its extensive applications. Herein, poly(butylene succinate) (PBS) was introduced to toughening PLA by melt blending using a self-made tri...

  • Communication
  • Open Access
13 Citations
6,016 Views
8 Pages

Fast Screening of Diol Impurities in Methoxy Poly(Ethylene Glycol)s (mPEG)s by Liquid Chromatography on Monolithic Silica Rods

  • Michaela Brunzel,
  • Tobias C. Majdanski,
  • Jürgen Vitz,
  • Ivo Nischang and
  • Ulrich S. Schubert

16 December 2018

The determination of diol impurities in methoxy poly(ethylene glycol)s (mPEG)s is of high importance, e.g., in the area of pharmaceutical applications, since mPEGs are considered the gold standard—based on properties of biocompatibility, stealt...

  • Article
  • Open Access
24 Citations
6,367 Views
11 Pages

The Chemical Compatibility and Adhesion of Energetic Materials with Several Polymers and Binders: An Experimental Study

  • Trung Toan Nguyen,
  • Duc Nhan Phan,
  • Duy Chinh Nguyen,
  • Van Thom Do and
  • Long Giang Bach

16 December 2018

The chemical compatibility and the adhesion of energetic materials and additive materials exert a strong influence on the sensitivity, safety and performance of a polymer-bonded explosive (PBX). In this study, the chemical compatibility of hexahydro-...

  • Article
  • Open Access
33 Citations
9,082 Views
13 Pages

15 December 2018

Wood chips from furniture-manufacturing byproducts, which do not include adhesive or paint in the waste wood, were used for the flouring process and chemical modification of wood flour (WF). After chemical modification, the WF was mixed with polyprop...

  • Article
  • Open Access
46 Citations
6,444 Views
13 Pages

Self-Healing Cellulose Nanocrystals-Containing Gels via Reshuffling of Thiuram Disulfide Bonds

  • Wenyan Li,
  • Shengchang Lu,
  • Mengchan Zhao,
  • Xinxing Lin,
  • Min Zhang,
  • He Xiao,
  • Kai Liu,
  • Liulian Huang,
  • Lihui Chen and
  • Hui Wu
  • + 2 authors

15 December 2018

Self-healing gels based on reshuffling disulfide bonds have attracted great attention due to their ability to restore structure and mechanical properties after damage. In this work, self-healing gels with different cellulose nanocrystals (CNC) conten...

  • Article
  • Open Access
10 Citations
5,375 Views
25 Pages

Confined Polymers as Self-Avoiding Random Walks on Restricted Lattices

  • Javier Benito,
  • Nikos Ch. Karayiannis and
  • Manuel Laso

15 December 2018

Polymers in highly confined geometries can display complex morphologies including ordered phases. A basic component of a theoretical analysis of their phase behavior in confined geometries is the knowledge of the number of possible single-chain confo...

  • Article
  • Open Access
20 Citations
5,609 Views
15 Pages

15 December 2018

The pollution of water resources has become a worldwide concern. The primary pollutants including insoluble oil, toxic dyes, and heavy metal ions. Herein, we report a polymer adsorbent, named SPCT, to remove the above three contaminants from water si...

  • Article
  • Open Access
17 Citations
4,392 Views
8 Pages

14 December 2018

Metal-organic frameworks (MOFs) have been regarded as an ideal material for the development of functional textiles with filtration function. Such functional textiles with filtration function can be further used to develop personal protective equipmen...

  • Article
  • Open Access
77 Citations
9,220 Views
14 Pages

Electrospun Polycaprolactone Nanofibers as a Reaction Membrane for Lateral Flow Assay

  • Chee Hong Takahiro Yew,
  • Pedram Azari,
  • Jane Ru Choi,
  • Farina Muhamad and
  • Belinda Pingguan-Murphy

14 December 2018

Electrospun polycaprolactone (PCL) nanofibers have emerged as a promising material in diverse biomedical applications due to their various favorable features. However, their application in the field of biosensors such as point-of-care lateral flow as...

  • Article
  • Open Access
13 Citations
5,626 Views
18 Pages

Preparation of Pt-Catalyst by Poly(p-phenylenediamine) Nanocomposites Assisted by Microwave Radiation for Proton Exchange Membrane Fuel Cell

  • Yen-Zen Wang,
  • Tsung-Han Ko,
  • Wen-Yao Huang,
  • Tar-Hwa Hsieh,
  • Ko-Shan Ho,
  • Yi-Yin Chen and
  • Siang-Jhih Hsieh

14 December 2018

The Pt elements are prepared via the redox reaction with microwave (MW) irradiation in the presence of poly(p-phenylenediamine) (PpPD) which is polymerized on XC72 carbon matrix (PpPD/XC72), behaving as reducing agent. The free primary amines of PpPD...

  • Article
  • Open Access
26 Citations
5,762 Views
17 Pages

14 December 2018

Spermidine is a functional ingredient that can extend the lifespan of many foods and indicate meat safety. However, its synthesis and enrichment is expensive and complex. To develop an effective separation material that can offer highly selective rec...

  • Article
  • Open Access
24 Citations
7,917 Views
12 Pages

14 December 2018

High density and high quality interconnects are necessary for the preparation of miniaturized and lightweight electronic products. Therefore, small-diameter and high-density through-holes in FPCs (Flexible Printed Circuits) are required. However, the...

  • Article
  • Open Access
36 Citations
7,038 Views
13 Pages

Solid-Phase Synthesis of Cellulose Acetate Butyrate as Microsphere Wall Materials for Sustained Release of Emamectin Benzoate

  • Aimin Huang,
  • Xuanhai Li,
  • Xingtang Liang,
  • Yanjuan Zhang,
  • Huayu Hu,
  • Yanzhen Yin and
  • Zuqiang Huang

13 December 2018

Emamectin benzoate (EB), a widely used pesticide, is prone to decomposition by ultraviolet light and suffers from the corresponding loss of efficacy. The timed release of EB based on microspheres is one of the effective methods to solve this issue. A...

  • Article
  • Open Access
21 Citations
6,182 Views
16 Pages

Microporous Materials Based on Norbornadiene-Based Cross-Linked Polymers

  • Dmitry A. Alentiev,
  • Dariya M. Dzhaparidze,
  • Natalia N. Gavrilova,
  • Victor P. Shantarovich,
  • Elena V. Kiseleva,
  • Maxim A. Topchiy,
  • Andrey F. Asachenko,
  • Pavel S. Gribanov,
  • Mikhail S. Nechaev and
  • Maxim V. Bermeshev
  • + 2 authors

13 December 2018

New microporous homopolymers were readily prepared from norbornadiene-2,5, its dimer and trimer by addition (vinyl) polymerization of the corresponding monomers with 60–98% yields. As a catalyst Pd-N-heterocyclic carbene complex or Ni(II) 2-eth...

  • Article
  • Open Access
49 Citations
5,916 Views
16 Pages

13 December 2018

Composite adsorption materials combine the advantages of various adsorptive materials and compensate for the defects of single adsorbents. Magnetic montmorillonite (MMMT) shows good adsorption properties for Pb(II). In order to further improve the ad...

  • Article
  • Open Access
20 Citations
4,436 Views
15 Pages

Single Local Injection of Epigallocatechin Gallate-Modified Gelatin Attenuates Bone Resorption and Orthodontic Tooth Movement in Mice

  • Yuta Katsumata,
  • Hiroyuki Kanzaki,
  • Yoshitomo Honda,
  • Tomonari Tanaka,
  • Yuuki Yamaguchi,
  • Kanako Itohiya,
  • Sari Fukaya,
  • Yutaka Miyamoto,
  • Tsuyoshi Narimiya and
  • Yoshiki Nakamura
  • + 1 author

13 December 2018

Osteoclastic bone resorption enables orthodontic tooth movement (OTM) in orthodontic treatment. Previously, we demonstrated that local epigallocatechin gallate (EGCG) injection successfully slowed the rate of OTM; however, repeat injections were requ...

  • Article
  • Open Access
17 Citations
5,796 Views
15 Pages

13 December 2018

The low-cost, heavy metal ion (Cu(II)) adsorptive multi-structured nanofibrous membranes of silicon oxide naonoparticles in-situ anchored polyvinylidene fluoride-hexafluoropropylene (SiO2@PVDF-HFP) fibers were fabricated by the facile electrospinning...

  • Article
  • Open Access
17 Citations
4,608 Views
16 Pages

Polymeric Composites with Embedded Nanocrystalline Cellulose for the Removal of Iron(II) from Contaminated Water

  • Anayet Kabir,
  • Matthew J. Dunlop,
  • Bishnu Acharya,
  • Rabin Bissessur and
  • Marya Ahmed

12 December 2018

The exponential increase in heavy metal usage for industrial applications has led to the limited supply of clean water for human needs. Iron is one of the examples of heavy metals, which is responsible for an unpleasant taste of water and its discolo...

  • Review
  • Open Access
352 Citations
31,778 Views
24 Pages

Implantable Polymeric Drug Delivery Devices: Classification, Manufacture, Materials, and Clinical Applications

  • Sarah A. Stewart,
  • Juan Domínguez-Robles,
  • Ryan F. Donnelly and
  • Eneko Larrañeta

12 December 2018

The oral route is a popular and convenient means of drug delivery. However, despite its advantages, it also has challenges. Many drugs are not suitable for oral delivery due to: first pass metabolism; less than ideal properties; and side-effects of t...

  • Article
  • Open Access
44 Citations
5,984 Views
11 Pages

Improvement of Adhesion Properties of Polyamide 6 and Polyoxymethylene-Copolymer by Atmospheric Cold Plasma Treatment

  • Zoltán Károly,
  • Gábor Kalácska,
  • László Zsidai,
  • Miklós Mohai and
  • Szilvia Klébert

12 December 2018

A study is presented on cold plasma treatment of the surfaces of two engineering polymers, polyamide 6 (PA6) and polyoxymethylene (POM-C), by diffuse coplanar surface barrier discharges under atmospheric air conditions. We found that plasma treatment...

  • Article
  • Open Access
35 Citations
4,943 Views
12 Pages

12 December 2018

The core-shell structured polyaniline-functionalized-BaTiO3 (BT@PANI) nanoparticles with controllable shell layer thicknesses are developed via in-situ aniline polymerization technology and characterized in detail. The results prove that the PANI she...

  • Article
  • Open Access
106 Citations
8,134 Views
17 Pages

Polymeric Nanocomposites Membranes with High Permittivity Based on PVA-ZnO Nanoparticles for Potential Applications in Flexible Electronics

  • Roberto Ambrosio,
  • Amanda Carrillo,
  • Maria L. Mota,
  • Karla De la Torre,
  • Richard Torrealba,
  • Mario Moreno,
  • Hector Vazquez,
  • Javier Flores and
  • Israel Vivaldo

11 December 2018

This study reports the optical, structural, electrical and dielectric properties of Poly (vinyl alcohol) thin films membranes with embedded ZnO nanoparticles (PVA/ZnO) obtained by the solution casting method at low temperature of deposition. Fourier...

  • Article
  • Open Access
8 Citations
3,096 Views
15 Pages

Sometimes the Same, Sometimes Different: Understanding Self-Assembly Algorithms in Coordination Networks

  • Y. Maximilian Klein,
  • Alessandro Prescimone,
  • Mariia Karpacheva,
  • Edwin C. Constable and
  • Catherine E. Housecroft

11 December 2018

The syntheses and characterizations of three new ligands containing two 4,2′:6′,4″-tpy or two 3,2′:6′,3″-tpy metal-binding domains are reported. The ligands possess different alkyloxy functionalities attached to th...

  • Article
  • Open Access
21 Citations
5,388 Views
22 Pages

11 December 2018

Biobased fillers, such as bio-derived cellulose, lignin byproducts, and biochar, can be used to modify the thermal, mechanical, and electrical properties of polymer composites. Biochar (BioC), in particular, is of interest for enhancing thermal and e...

  • Article
  • Open Access
27 Citations
4,919 Views
12 Pages

Photocurable Bioinks for the 3D Pharming of Combination Therapies

  • Giovanny F. Acosta-Vélez,
  • Chase S. Linsley,
  • Timothy Z. Zhu,
  • Willie Wu and
  • Benjamin M. Wu

11 December 2018

Combination therapies mediate drug synergy to improve treatment efficacy and convenience, leading to higher levels of compliance. However, there are challenges with their manufacturing as well as reduced flexibility in dosing options. This study repo...

  • Article
  • Open Access
38 Citations
8,206 Views
22 Pages

Spherical Polybutylene Terephthalate (PBT)—Polycarbonate (PC) Blend Particles by Mechanical Alloying and Thermal Rounding

  • Maximilian A. Dechet,
  • Juan S. Gómez Bonilla,
  • Lydia Lanzl,
  • Dietmar Drummer,
  • Andreas Bück,
  • Jochen Schmidt and
  • Wolfgang Peukert

11 December 2018

In this study, the feasibility of co-grinding and the subsequent thermal rounding to produce spherical polymer blend particles for selective laser sintering (SLS) is demonstrated for polybutylene terephthalate (PBT) and polycarbonate (PC). The polyme...

  • Article
  • Open Access
20 Citations
9,707 Views
16 Pages

11 December 2018

Palm fatty acid distillate (PFAD), is a by-product of the crude palm oil refining process. It comprises mainly of free fatty acids—around 45% palmitic and 33% oleic acids—as the major components. Ultra-violet (UV) curable urethane acrylat...

  • Article
  • Open Access
38 Citations
5,420 Views
12 Pages

Study on Foaming Quality and Impact Property of Foamed Polypropylene Composites

  • Wei Gong,
  • Hai Fu,
  • Chun Zhang,
  • Daming Ban,
  • Xiaogang Yin,
  • Yue He,
  • Li He and
  • Xianglin Pei

11 December 2018

In the present work, foamed polypropylene (PP) composites were prepared by chemical foaming technology, and the foaming quality and impact property of the foamed PP composites were studied. The results showed that the foaming quality was significantl...

  • Review
  • Open Access
12 Citations
4,003 Views
10 Pages

11 December 2018

Glycosaminoglycans (GAGs) are a class of linear polysaccharides that are ubiquitous in the extracellular matrix (ECM) and on cell surfaces. Due to their key role in development, homeostasis, pathogenesis, and regeneration, GAGs are increasingly used...

  • Article
  • Open Access
5 Citations
3,335 Views
13 Pages

Fluorescent Amorphous Distyrylnaphthalene-Based Polymers: Synthesis, Characterization and Thin-Film Nanomolar Sensing of Nitroaromatics in Water

  • Raúl O. Garay,
  • Ana B. Schvval,
  • Marcela F. Almassio,
  • Pablo G. Del Rosso,
  • Maria J. Romagnoli and
  • Rosana S. Montani

10 December 2018

Two new fluorescent segmented conjugated polymers with either 1,4- or 2,6-distyrylnaphthalene chromophores and their model compounds were synthesized and the chemosensing abilities of the polymeric thin films to detect nitroaromatics (NACs) in aqueou...

  • Article
  • Open Access
5 Citations
4,418 Views
16 Pages

10 December 2018

Nanoscale tailoring the filler morphology in experiment offers new opportunities to modulate the mechanical properties of polymer nanocomposites. Based on the conventical rod and experimentally available tetrapod filler, I compare the nanofiller disp...

  • Article
  • Open Access
40 Citations
5,433 Views
15 Pages

10 December 2018

Sulfonated poly(arylene biphenylether sulfone)-poly(arylene ether) (SPABES-PAE) block copolymers by controlling the molar ratio of SPABES and PAE oligomers were successfully synthesized, and the performances of SPABES-PAE (1:2, 1:1, and 2:1) membrane...

  • Review
  • Open Access
166 Citations
13,212 Views
29 Pages

Thermoplastic Processing of PLA/Cellulose Nanomaterials Composites

  • T. C. Mokhena,
  • J. S. Sefadi,
  • E. R. Sadiku,
  • M. J. John,
  • M. J. Mochane and
  • A. Mtibe

9 December 2018

Over the past decades, research has escalated on the use of polylactic acid (PLA) as a replacement for petroleum-based polymers. This is due to its valuable properties, such as renewability, biodegradability, biocompatibility and good thermomechanica...

  • Article
  • Open Access
25 Citations
9,367 Views
16 Pages

9 December 2018

Considering the safety issues of Li ion batteries, an all-solid-state polymer electrolyte has been one of the promising solutions. Achieving a Li ion conductivity of a solid-state electrolyte comparable to that of a liquid electrolyte (>1 mS/cm) i...

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Polymers - ISSN 2073-4360