All-Solid-State Lithium Battery Working without an Additional Separator in a Polymeric Electrolyte
Abstract
:1. Introduction
1.1. Oxide Solid Electrolytes
1.2. Succinonitrile (SN) Introduction
2. Experimental Section
2.1. Chemicals
2.2. Synthesis of LATP
2.3. Preparation of Hybrid Solid Electrolytes (HSE) and Hybrid Solid Electrolyte Cathode (HSC)
2.4. Characterizations
3. Results
3.1. Design of Hybrid Solid Electrolytes (HSE) and Hybrid Solid Cathode (HSC)
3.2. Structure of the All-Solid-State Battery System
3.3. Conductivity of the Designed Systems
3.4. Solid Electrolyte Interface (SEI)
3.5. Electrochemical Stability
3.6. Property of the Designed Electrolytes
3.7. Capacity and 1st Coulomb Efficiency of the Designed Coin Cells
4. Discussion and Conclusions
Supplementary Files
Supplementary File 1Author Contributions
Acknowledgments
Conflicts of Interest
References
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LATP (g) | PEO * (g) | LiPF6 | LiTFSI | SN (g) | LMO+LCO (g) | EO:Li (Mole ratio) | Ion. Con. @23 °C [S/cm] | Ion. Con. @55 °C [S/cm] | ||
---|---|---|---|---|---|---|---|---|---|---|
HSE | HSE-1 | - | 100 | ● | - | - | - | 8:1 | 1.7 × 10−7 | - |
HSE-2 | 80 | 20 | ● | - | - | - | 8:1 | 1.2 ×1 0−4 | 2.4 × 10−3 | |
HSE-3 | 80 | 20 | - | ● | - | - | 8:1 | 1.5 × 10−4 | 1.4 × 10−3 | |
HSE-4 | 80 | 20 | - | ● | 5 | - | 8:1 | 2.0 × 10−4 | 1.6 × 10−3 | |
HSC | HSC-1 | 12.8 | 12.8 | - | ● | - | 30 + 30 | 10:1 | - | - |
HSC-2 | 12.8 | 12.8 | - | ● | 5 | 30 + 30 | 10:1 | - | - |
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Cho, S.; Kim, S.; Kim, W.; Kim, S.; Ahn, S. All-Solid-State Lithium Battery Working without an Additional Separator in a Polymeric Electrolyte. Polymers 2018, 10, 1364. https://doi.org/10.3390/polym10121364
Cho S, Kim S, Kim W, Kim S, Ahn S. All-Solid-State Lithium Battery Working without an Additional Separator in a Polymeric Electrolyte. Polymers. 2018; 10(12):1364. https://doi.org/10.3390/polym10121364
Chicago/Turabian StyleCho, Seonggyu, Shinho Kim, Wonho Kim, Seok Kim, and Sungsook Ahn. 2018. "All-Solid-State Lithium Battery Working without an Additional Separator in a Polymeric Electrolyte" Polymers 10, no. 12: 1364. https://doi.org/10.3390/polym10121364