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Materials, Volume 9, Issue 12

2016 December - 76 articles

Cover Story: Synthetic and natural ligands that bind IgG are detailed in this paper. Bacterial proteins such as Protein G, A, and L are traditionally used as affinity ligands for antibody purification. Small synthetic Fc-binding peptides (FcBPs) are emerging as promising alternatives to bacterial proteins. The figure shows that a humanized IgG, trastuzumab, is complexed onto clustered FcBPs on a protein nanocage which is formed by self-assembly of 24 ferritin monomers carrying a C-terminal FcBP. View the paper
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Articles (76)

  • Article
  • Open Access
16 Citations
6,461 Views
20 Pages

A Size and Boundary Effects Model for Quasi-Brittle Fracture

  • Xiaofeng Gao,
  • Georg Koval and
  • Cyrille Chazallon

21 December 2016

The fracture behaviors of quasi-brittle materials are commonly specimen size (size effect) and crack size (boundary effect) dependent. In this study, a new failure model is developed for characterizing the size and boundary effects. The derivative of...

  • Article
  • Open Access
30 Citations
7,372 Views
21 Pages

21 December 2016

The efficiency of polyfunctional monomers as cross-linking co-agents on the chemical properties of natural rubber vulcanized by electron beam irradiation was studied. The following polyfunctional monomers were used: trimethylolpropane-trimethacrylate...

  • Article
  • Open Access
28 Citations
6,873 Views
24 Pages

An Experimental Study of Mortars with Recycled Ceramic Aggregates: Deduction and Prediction of the Stress-Strain

  • Francisca Guadalupe Cabrera-Covarrubias,
  • José Manuel Gómez-Soberón,
  • Jorge Luis Almaral-Sánchez,
  • Susana Paola Arredondo-Rea,
  • María Consolación Gómez-Soberón and
  • Ramón Corral-Higuera

21 December 2016

The difficult current environmental situation, caused by construction industry residues containing ceramic materials, could be improved by using these materials as recycled aggregates in mortars, with their processing causing a reduction in their use...

  • Article
  • Open Access
95 Citations
8,722 Views
16 Pages

20 December 2016

Self-healing cementitious materials containing a microencapsulated healing agent are appealing due to their great application potential in improving the serviceability and durability of concrete structures. In this study, poly(phenol–formaldehyde) (P...

  • Article
  • Open Access
12 Citations
6,536 Views
15 Pages

20 December 2016

Performing diverse application tests on synthesized metal oxides is critical for identifying suitable application areas based on the material performances. In the present study, Ni-oxide@TiO2 core-shell materials were synthesized and applied to photo...

  • Article
  • Open Access
1 Citations
4,842 Views
9 Pages

20 December 2016

The two-photon absorption and optical limiting properties of two dibenzylideneacetone derivatives with different substituent positions have been theoretically investigated by solving the coupled rate equations-field intensity equation in the nanoseco...

  • Article
  • Open Access
23 Citations
5,148 Views
8 Pages

Ceramic Ti—B Composites Synthesized by Combustion Followed by High-Temperature Deformation

  • Pavel M. Bazhin,
  • Alexander M. Stolin,
  • Alexander S. Konstantinov,
  • Elena V. Kostitsyna and
  • Andrey S. Ignatov

20 December 2016

Long compact cylindrical rods, which consist of a titanium monoboride-based TiB—30 wt % Ti ceramic composite material, are synthesized during combustion of the initial components (titanium, boron) followed by high-temperature deformation. High-temper...

  • Article
  • Open Access
66 Citations
7,426 Views
15 Pages

Synthesis and Structural Characterization of Silver Nanoparticles Stabilized with 3-Mercapto-1-Propansulfonate and 1-Thioglucose Mixed Thiols for Antibacterial Applications

  • Francesco Porcaro,
  • Laura Carlini,
  • Andrea Ugolini,
  • Daniela Visaggio,
  • Paolo Visca,
  • Ilaria Fratoddi,
  • Iole Venditti,
  • Carlo Meneghini,
  • Laura Simonelli and
  • Chiara Battocchio
  • + 4 authors

20 December 2016

The synthesis, characterization and assessment of the antibacterial properties of hydrophilic silver nanoparticles (AgNPs) were investigated with the aim to probe their suitability for innovative applications in the field of nanobiotechnology. First,...

  • Article
  • Open Access
3 Citations
5,868 Views
15 Pages

19 December 2016

A novel series of the title compound 4-(5-arylazo-2-hydroxystyryl)-1-methylpyridinium iodide 6 has been synthesized via condensation reactions of the arylazosalicylaldehyde derivatives 4ai with 1-methyl-picolinium iodide 5. The structures of the new...

  • Article
  • Open Access
38 Citations
8,253 Views
15 Pages

Effect of Repetition Rate on Femtosecond Laser-Induced Homogenous Microstructures

  • Sanchari Biswas,
  • Adya Karthikeyan and
  • Anne-Marie Kietzig

19 December 2016

We report on the effect of repetition rate on the formation and surface texture of the laser induced homogenous microstructures. Different microstructures were micromachined on copper (Cu) and titanium (Ti) using femtosecond pulses at 1 and 10 kHz. W...

  • Article
  • Open Access
49 Citations
9,027 Views
15 Pages

17 December 2016

The objective of this study is to estimate multiple-cycles of the soil-water characteristic curve (SWCC) using an innovative volumetric pressure plate extractor (VPPE), which is incorporated with a membrane and time domain reflectometry (TDR). The pr...

  • Article
  • Open Access
14 Citations
4,788 Views
17 Pages

17 December 2016

Measured by harmonic tests, the viscoelastic properties of Chinese fir during moisture sorption processes were examined under three relative humidity (RH) modes: RHramp, RHisohume, and RHstep. The stiffness decreased and damping increased as a functi...

  • Article
  • Open Access
5 Citations
6,431 Views
13 Pages

17 December 2016

A method to prepare novel organic-inorganic hydrophobic nanocomposite films was proposed by a site-specific polymerization process. The inorganic part, the core of the nanocomposite, is a ternary SiO2–Al2O3–TiO2 nanoparticles, which is grafted with m...

  • Review
  • Open Access
70 Citations
14,161 Views
18 Pages

16 December 2016

Secondary electron emission materials are reviewed with the aim of providing guidelines for the future development of novel transmission dynodes. Materials with reflection secondary electron yield higher than three and transmission secondary electron...

  • Article
  • Open Access
3 Citations
5,622 Views
14 Pages

16 December 2016

The adsorption properties of water molecules on TiO2 nanotubes (TiO2NT) and the interaction mechanisms between water molecules are studied by first principles calculations. The adsorption preferences of water molecules in molecular or dissociated sta...

  • Review
  • Open Access
94 Citations
11,705 Views
30 Pages

Nano-Inclusions Applied in Cement-Matrix Composites: A Review

  • Guillermo Bastos,
  • Faustino Patiño-Barbeito,
  • Faustino Patiño-Cambeiro and
  • Julia Armesto

16 December 2016

Research on cement-based materials is trying to exploit the synergies that nanomaterials can provide. This paper describes the findings reported in the last decade on the improvement of these materials regarding, on the one hand, their mechanical per...

  • Article
  • Open Access
7 Citations
5,434 Views
11 Pages

16 December 2016

Understanding the adsorption properties of DNA bases on metal surfaces is fundamental for the rational control of surface functionalization leading to the realisation of biocompatible devices for biosensing applications, such as monitoring of particu...

  • Article
  • Open Access
43 Citations
7,640 Views
10 Pages

15 December 2016

The strain rate effect of reinforcing steel bars is generally indispensable for modeling the dynamic responses of reinforced concrete structures in blast and impact events. A systematic experimental investigation was conducted on the strain rate beha...

  • Article
  • Open Access
15 Citations
4,771 Views
11 Pages

15 December 2016

The ZnO-CdS core-shell composite nanorods with CdS shell layer thicknesses of 5 and 20 nm were synthesized by combining the hydrothermal growth of ZnO nanorods with the sputtering thin-film deposition of CdS crystallites. The microstructures and opti...

  • Article
  • Open Access
1 Citations
6,247 Views
10 Pages

The Non-Steady State Growth of Pearlite outside the Hultgren Extrapolation

  • Maria Martin-Aranda,
  • Rosalia Rementeria,
  • Robert Hackenberg,
  • Esteban Urones-Garrote,
  • Shao Pu Tsai,
  • Jen Ren Yang and
  • Carlos Capdevila

14 December 2016

The goal of this paper is to analyse the effect of adding Al on the non-steady pearlite growth occurring in a Fe–C–Mn system. The results are discussed in terms of the partitioning of elements across the austenite/ferrite and austenite/cementite inte...

  • Article
  • Open Access
30 Citations
7,556 Views
15 Pages

14 December 2016

TiO2-coated boron particles were prepared by a wet ball milling method, with the particle size distribution and average particle size being easily controlled by varying the milling operation time. Based on the results from X-ray photoelectron spectro...

  • Article
  • Open Access
4 Citations
6,074 Views
9 Pages

13 December 2016

Electromagnetic metamaterials are constructed with sub-wavelength structures that exhibit particular electromagnetic properties under a certain frequency range. Because the form-factor of the substructures has to be comparable to the wavelength of th...

  • Article
  • Open Access
14 Citations
5,581 Views
13 Pages

Two-Level Micro-to-Nanoscale Hierarchical TiO2 Nanolayers on Titanium Surface

  • Elena G. Zemtsova,
  • Andrei Yu. Arbenin,
  • Ruslan Z. Valiev,
  • Evgeny V. Orekhov,
  • Valentin G. Semenov and
  • Vladimir M. Smirnov

13 December 2016

Joint replacement is being actively developed within modern orthopedics. One novel material providing fast implantation is bioactive coatings. The synthesis of targeted nanocoatings on metallic nanotitanium surface is reported in this paper. TiO2-bas...

  • Article
  • Open Access
5 Citations
6,565 Views
22 Pages

13 December 2016

The evolution of the thermal conductivities of the unidirectional, 2D woven and 3D braided composites during the CVI (chemical vapor infiltration) process have been numerically studied by the finite element method. The results show that the dual-scal...

  • Feature Paper
  • Article
  • Open Access
50 Citations
9,272 Views
15 Pages

Cellulose Nanocrystal Membranes as Excipients for Drug Delivery Systems

  • Ananda M. Barbosa,
  • Eduardo Robles,
  • Juliana S. Ribeiro,
  • Rafael G. Lund,
  • Neftali L. V. Carreño and
  • Jalel Labidi

12 December 2016

In this work, cellulose nanocrystals (CNCs) were obtained from flax fibers by an acid hydrolysis assisted by sonochemistry in order to reduce reaction times. The cavitation inducted during hydrolysis resulted in CNC with uniform shapes, and thus furt...

  • Article
  • Open Access
26 Citations
7,097 Views
14 Pages

Floating Hydrogel with Self-Generating Micro-Bubbles for Intravesical Instillation

  • Tingsheng Lin,
  • Xiaozhi Zhao,
  • Yifan Zhang,
  • Huibo Lian,
  • Junlong Zhuang,
  • Qing Zhang,
  • Wei Chen,
  • Wei Wang,
  • Guangxiang Liu and
  • Hongqian Guo
  • + 3 authors

12 December 2016

Intravesical instillation is the main therapy for bladder cancer and interstitial cystitis. However, most drug solutions are eliminated from bladder after the first voiding of urine. To solve this problem, we proposed a floating hydrogel with self-ge...

  • Article
  • Open Access
44 Citations
5,935 Views
7 Pages

Fabrication of Fe-Based Diamond Composites by Pressureless Infiltration

  • Meng Li,
  • Youhong Sun,
  • Qingnan Meng,
  • Haidong Wu,
  • Ke Gao and
  • Baochang Liu

12 December 2016

A metal-based matrix is usually used for the fabrication of diamond bits in order to achieve favorable properties and easy processing. In the effort to reduce the cost and to attain the desired bit properties, researchers have brought more attention...

  • Review
  • Open Access
128 Citations
29,849 Views
20 Pages

Atomic Layer Deposition of Silicon Nitride Thin Films: A Review of Recent Progress, Challenges, and Outlooks

  • Xin Meng,
  • Young-Chul Byun,
  • Harrison S. Kim,
  • Joy S. Lee,
  • Antonio T. Lucero,
  • Lanxia Cheng and
  • Jiyoung Kim

12 December 2016

With the continued miniaturization of devices in the semiconductor industry, atomic layer deposition (ALD) of silicon nitride thin films (SiNx) has attracted great interest due to the inherent benefits of this process compared to other silicon nitrid...

  • Article
  • Open Access
17 Citations
7,297 Views
15 Pages

Spark Plasma Sintering of a Gas Atomized Al7075 Alloy: Microstructure and Properties

  • Orsolya Molnárová,
  • Přemysl Málek,
  • František Lukáč and
  • Tomáš Chráska

12 December 2016

The powder of an Al7075 alloy was prepared by gas atomization. A combination of cellular, columnar, and equiaxed dendritic-like morphology was observed in individual powder particles with continuous layers of intermetallic phases along boundaries. Th...

  • Article
  • Open Access
21 Citations
7,569 Views
15 Pages

Intrinsic Flame-Retardant and Thermally Stable Epoxy Endowed by a Highly Efficient, Multifunctional Curing Agent

  • Chunlei Dong,
  • Alvianto Wirasaputra,
  • Qinqin Luo,
  • Shumei Liu,
  • Yanchao Yuan,
  • Jianqing Zhao and
  • Yi Fu

12 December 2016

It is difficult to realize flame retardancy of epoxy without suffering much detriment in thermal stability. To solve the problem, a super-efficient phosphorus-nitrogen-containing reactive-type flame retardant, 10-(hydroxy(4-hydroxyphenyl)methyl)-5,10...

  • Article
  • Open Access
17 Citations
5,865 Views
20 Pages

Synthesis and Drug Delivery Application of Thermo- and pH-Sensitive Hydrogels: Poly(β-CD-co-N-Isopropylacrylamide-co-IAM)

  • Syang-Peng Rwei,
  • Tuan Huynh Nguyen Anh,
  • Whe-Yi Chiang,
  • Tun-Fun Way and
  • Yung-Jia Hsu

11 December 2016

Copolymerization of N-isopropylacrylamide (NIPAM), itaconamic acid (IAM; 4-amino-2-methylene-4-oxobutanoic acid) and β-cyclodextrin was investigated in this study. β-cyclodextrin was at first modified by reacting with allyl glycidyl ether to substitu...

  • Article
  • Open Access
40 Citations
6,901 Views
13 Pages

The Refining Mechanism of Super Gravity on the Solidification Structure of Al-Cu Alloys

  • Yuhou Yang,
  • Bo Song,
  • Zhanbing Yang,
  • Gaoyang Song,
  • Zeyun Cai and
  • Zhancheng Guo

10 December 2016

There is far less study of the refining effect of super gravity fields on solidification structures of metals than of the effects of electrical currents, magnetic and ultrasonic fields. Moreover, the refining mechanisms of super gravity are far from...

  • Article
  • Open Access
6 Citations
5,287 Views
15 Pages

Synthesis of Fluorescent Core-Shell Metal Nanohybrids: A Versatile Approach

  • Marina Alloisio,
  • Melania Rusu,
  • Stefano Ottonello,
  • Massimo Ottonelli,
  • Sergio Thea and
  • Davide Comoretto

9 December 2016

A flexible way of fabricating core-shell noble metal-organic nanohybrids with tailored chemical and spectroscopic properties is proposed here. The synthetic protocol consists of a multi-step procedure able to guarantee acceptable reproducibility of c...

  • Article
  • Open Access
21 Citations
6,329 Views
12 Pages

Effects of Perforation on Rigid PU Foam Plates: Acoustic and Mechanical Properties

  • Jia-Horng Lin,
  • Yu-Chun Chuang,
  • Ting-Ting Li,
  • Chen-Hung Huang,
  • Chien-Lin Huang,
  • Yueh-Sheng Chen and
  • Ching-Wen Lou

9 December 2016

Factories today are equipped with diverse mechanical equipment in response to rapid technological and industrial developments. Industrial areas located near residential neighborhoods cause massive environmental problems. In particular, noise pollutio...

  • Review
  • Open Access
173 Citations
29,124 Views
17 Pages

8 December 2016

The rapidly increasing application of antibodies has inspired the development of several novel methods to isolate and target antibodies using smart biomaterials that mimic the binding of Fc-receptors to antibodies. The Fc-binding domain of antibodies...

  • Article
  • Open Access
17 Citations
4,947 Views
10 Pages

8 December 2016

In this paper, a nanocrystalline surface layer without impurities was fabricated on Ti-6Al-4V alloy by means of surface mechanical attrition treatment (SMAT). The grain size in the nanocrystalline layer is about 10 nm and grain morphology displays a...

  • Article
  • Open Access
5 Citations
6,279 Views
11 Pages

8 December 2016

In this study, we fabricated organic photovoltaics (OPVs) by introducing the polymer additive HTh6BT into the photoactive layer of a poly(3-hexylthiophene):phenyl-C61-butyric acid methyl ester (P3HT:PCBM) system. The HTh6BT had a relatively low band...

  • Article
  • Open Access
19 Citations
5,714 Views
12 Pages

8 December 2016

Porous carbon materials are used for many electrochemical applications due to their outstanding properties. However, research on controlling the pore structure and analyzing the carbon structures is still necessary to achieve enhanced electrochemical...

  • Article
  • Open Access
4 Citations
5,836 Views
17 Pages

Electroconductive Composites from Polystyrene Block Copolymers and Cu–Alumina Filler

  • QuratulAin Nadeem,
  • Tasneem Fatima,
  • Pepijn Prinsen,
  • Aziz Ur Rehman,
  • Rohama Gill,
  • Rashid Mahmood and
  • Rafael Luque

7 December 2016

Technological advancements and development of new materials may lead to the manufacture of sustainable energy-conducting devices used in the energy sector. This research attempts to fabricate novel electroconductive and mechanically stable nanocompos...

  • Article
  • Open Access
80 Citations
8,438 Views
8 Pages

Luminescence Properties and Mechanisms of CuI Thin Films Fabricated by Vapor Iodization of Copper Films

  • Guochen Lin,
  • Fengzhou Zhao,
  • Yuan Zhao,
  • Dengying Zhang,
  • Lixin Yang,
  • Xiaoe Xue,
  • Xiaohui Wang,
  • Chong Qu,
  • Qingshan Li and
  • Lichun Zhang

7 December 2016

Copper iodide (CuI) thin films were grown on Si(100) substrates using a copper film iodination reaction method. It was found that γ-CuI films have a uniform and dense microstructure with (111)-orientation. Transmission spectra indicated that CuI thin...

  • Article
  • Open Access
310 Citations
15,177 Views
11 Pages

Enhancing the Hydrophilicity and Cell Attachment of 3D Printed PCL/Graphene Scaffolds for Bone Tissue Engineering

  • Weiguang Wang,
  • Guilherme Caetano,
  • William Stephen Ambler,
  • Jonny James Blaker,
  • Marco Andrey Frade,
  • Parthasarathi Mandal,
  • Carl Diver and
  • Paulo Bártolo

7 December 2016

Scaffolds are physical substrates for cell attachment, proliferation, and differentiation, ultimately leading to the regeneration of tissues. They must be designed according to specific biomechanical requirements, i.e., certain standards in terms of...

  • Review
  • Open Access
185 Citations
19,437 Views
32 Pages

Fabrication of Porous Materials from Natural/Synthetic Biopolymers and Their Composites

  • Udeni Gunathilake T.M. Sampath,
  • Yern Chee Ching,
  • Cheng Hock Chuah,
  • Johari J. Sabariah and
  • Pai-Chen Lin

7 December 2016

Biopolymers and their applications have been widely studied in recent years. Replacing the oil based polymer materials with biopolymers in a sustainable manner might give not only a competitive advantage but, in addition, they possess unique properti...

  • Article
  • Open Access
5 Citations
5,457 Views
14 Pages

Microstructure and Tribological Properties of Mo–40Ni–13Si Multiphase Intermetallic Alloy

  • Chunyan Song,
  • Shuhuan Wang,
  • Yongliang Gui,
  • Zihao Cheng and
  • Guolong Ni

6 December 2016

Intermetallic compounds are increasingly being expected to be utilized in tribological environments, but to date their implementation is hindered by insufficient ductility at low and medium temperatures. This paper presents a novel multiphase interme...

  • Article
  • Open Access
46 Citations
6,184 Views
20 Pages

A General Accelerated Degradation Model Based on the Wiener Process

  • Le Liu,
  • Xiaoyang Li,
  • Fuqiang Sun and
  • Ning Wang

6 December 2016

Accelerated degradation testing (ADT) is an efficient tool to conduct material service reliability and safety evaluations by analyzing performance degradation data. Traditional stochastic process models are mainly for linear or linearization degradat...

  • Article
  • Open Access
17 Citations
5,773 Views
9 Pages

Optoelectronic Properties and the Electrical Stability of Ga-Doped ZnO Thin Films Prepared via Radio Frequency Sputtering

  • Shien-Uang Jen,
  • Hui Sun,
  • Hai-Pang Chiang,
  • Sheng-Chi Chen,
  • Jian-Yu Chen and
  • Xin Wang

6 December 2016

In this work, Ga-doped ZnO (GZO) thin films were deposited via radio frequency sputtering at room temperature. The influence of the Ga content on the film’s optoelectronic properties as well as the film’s electrical stability were investigated. The r...

  • Article
  • Open Access
11 Citations
4,831 Views
10 Pages

6 December 2016

Sorption technique is one of the most effective methods for recovering precious metals from wastewater solutions; however, its main drawbacks of the traditional sorbents are the slow kinetics and relatively low sorption capacities. As a solution, thi...

  • Article
  • Open Access
10 Citations
5,362 Views
14 Pages

5 December 2016

Vacuum-induced surface freezing has been used to produce uni-directional freezing of colloidal aluminum oxide dispersions. It leads to zones of different structure within the resulting sintered monoliths that are highly similar to those known for fre...

  • Article
  • Open Access
11 Citations
8,840 Views
13 Pages

Fretting Fatigue Experiment and Analysis of AlSi9Cu2Mg Alloy

  • Jun Wang,
  • Hong Xu,
  • Tiexiong Su,
  • Yi Zhang,
  • Zhen Guo,
  • Huping Mao and
  • Yangang Zhang

5 December 2016

An investigation was carried out in order to study the fretting fatigue behavior of an AlSi9Cu2Mg aluminum alloy. The fretting fatigue tests of AlSi9Cu2Mg were performed using a specially designed testing machine. The failure mechanism of fretting fa...

  • Article
  • Open Access
13 Citations
7,395 Views
14 Pages

5 December 2016

This study predicts the frictional moments at the head-cup interface and frictional torques and bending moments acting on the head-neck interface of a modular total hip replacement across a range of activities of daily living. The predicted moment an...

  • Article
  • Open Access
6 Citations
4,829 Views
14 Pages

Strontium-Substituted Bioceramics Particles: A New Way to Modulate MCP-1 and Gro-α Production by Human Primary Osteoblastic Cells

  • Julien Braux,
  • Frédéric Velard,
  • Christine Guillaume,
  • Marie-Laure Jourdain,
  • Sophie C. Gangloff,
  • Edouard Jallot,
  • Jean-Marie Nedelec,
  • Patrice Laquerrière and
  • Dominique Laurent-Maquin

5 December 2016

Background: To avoid morbidity and limited availability associated with autografts, synthetic calcium phosphate (CaP) ceramics were extensively developed and used as bone filling materials. Controlling their induced-inflammatory response nevertheless...

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Materials - ISSN 1996-1944