This review is devoted to an analysis of currently known heterometallic molecular magnets based on an orbitally degenerate 5d metalloligand, [ReIV(CN)7]3−. Heptacyanidometallates with a pentagonal bipyramidal structure of the coordination site...
The first neutral 2D heterometallic assemblies based on orbitally degenerate heptacyanidorhenate(IV) were prepared and structurally characterized. An analysis of the magnetic data for the polycrystalline samples of Ph4P[{Mn(acacen)}2Re(CN)7]·S...
The first neutral 0D and 1D heterometallic assemblies based on orbitally degenerate heptacyanidorhenate(IV) were prepared and structurally characterized. An analysis of the magnetic data of polycrystalline samples showed that both compounds display s...
Two novel 1D heterobimetallic compounds {[MnIII(SB2+)MIII(CN)6]·4H2O}n (SB2+ = N,N′-ethylenebis(5-trimethylammoniomethylsalicylideneiminate) based on orbitally degenerate cyanidometallates [OsIII(CN)6]3− (1) and [RuIII(CN)6]3&minus...
Rational, fine tuning of magnetic anisotropy is critical to obtain new coordination compounds with enhanced single molecule magnet properties. For mononuclear transition metal complexes, the largest contribution to zero-field splitting is usually rel...
Functional dependence of the axial zero-field splitting parameter D with respect to a properly chosen geometrical parameter (Dstr) in metal complexes is termed the magnetostructural D-correlation. In mononuclear hexacoordinate Ni(II) complexes with t...
A recent broadband rotational spectroscopic investigation of the cross-association mechanisms of CO2 with monoethanolamine (MEA) in molecular beams [F. Xie et al., Angew. Chem. Int. Ed., 2023, 62, e202218539] revealed an intriguing affinity of CO2 to...