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Inorganics 2018, 6(1), 24;

Effect of Low Spin Excited States for Magnetic Anisotropy of Transition Metal Mononuclear Single Molecule Magnets

Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile (USACH), Casilla 40, Correo 33, Santiago 9170022, Chile
Author to whom correspondence should be addressed.
Received: 14 December 2017 / Revised: 17 January 2018 / Accepted: 25 January 2018 / Published: 27 January 2018
(This article belongs to the Special Issue Single-Molecule Magnets)
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Rational, fine tuning of magnetic anisotropy is critical to obtain new coordination compounds with enhanced single molecule magnet properties. For mononuclear transition metal complexes, the largest contribution to zero-field splitting is usually related to the excited states of the same spin as the ground level. Thus, the contribution of lower multiplicity roots tends to be overlooked due to its lower magnitude. In this article, we explore the role of lower multiplicity excited states in zero-field splitting parameters in model structures of Fe(II) and Co(II). Model aquo complexes with coordination numbers ranging from 2 to 6 were constructed. The magnetic anisotropy was calculated by state of the art ab initio methodologies, including spin-orbit coupling effects. For non-degenerate ground states, contributions to the zero-field splitting parameter (D) from highest and lower multiplicity roots were of the same sign. In addition, their relative magnitude was in a relatively narrow range, irrespective of the coordination geometry. For degenerate ground states, the contribution from lower multiplicity roots was significantly smaller. Results are rationalized in terms of general expressions for D and are expected to be reasonably transferable to real molecular systems. View Full-Text
Keywords: CASSCF calculations; magnetic anisotropy; single molecule magnets CASSCF calculations; magnetic anisotropy; single molecule magnets

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Llanos, L.; Aravena, D. Effect of Low Spin Excited States for Magnetic Anisotropy of Transition Metal Mononuclear Single Molecule Magnets. Inorganics 2018, 6, 24.

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