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12 pages, 260 KiB

Open AccessEditorial

Gas, Water and Solid Waste Treatment Technology

by Wenxiang Zhang, Zhien Zhang and Avelino Núñez-Delgado

Processes 2021, 9(8), 1397; https://doi.org/10.3390/pr9081397 - 12 Aug 2021

Cited by 2 | Viewed by 2932

Abstract

The increasing trends in gas pollution, water pollution, and solid waste pollution have an adverse impact on human health and ecological habitats [...] Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

Research

Jump to: Editorial, Review

14 pages, 1367 KiB

Open AccessFeature PaperArticle

Adsorption of Tetracycline and Sulfadiazine onto Three Different Bioadsorbents in Binary Competitive Systems

by Raquel Cela-Dablanca, Manuel Conde-Cid, Gustavo Ferreira-Coelho, Manuel Arias-Estévez, David Fernández-Calviño, Avelino Núñez-Delgado, María J. Fernández-Sanjurjo and Esperanza Álvarez-Rodríguez

Processes 2021, 9(1), 28; https://doi.org/10.3390/pr9010028 - 24 Dec 2020

Cited by 10 | Viewed by 2773

Abstract

Different antibiotics contained in manure, slurry, wastewater or sewage sludge are spread into the environment. The harmful effects of these antibiotics could be minimized by means of immobilization onto bioadsorbent materials. This work investigates the competitive adsorption/desorption of tetracycline (TC) and sulfadiazine (SDZ) [...] Read more.

Different antibiotics contained in manure, slurry, wastewater or sewage sludge are spread into the environment. The harmful effects of these antibiotics could be minimized by means of immobilization onto bioadsorbent materials. This work investigates the competitive adsorption/desorption of tetracycline (TC) and sulfadiazine (SDZ) onto pine bark, oak ash and mussel shell. The study was carried out using batch-type experiments in binary systems (with both antibiotics present simultaneously), adding 5 equal concentrations of the antibiotics (between 1 and 50 µmol L⁻¹). The adsorption percentages were higher for TC (close to 100% onto pine bark and oak ash, and between 40 and 85% onto mussel shell) than for SDZ (75–100% onto pine bark, and generally less than 10% on oak ash and mussel shell). Pine bark performed as the best adsorbent since TC adsorption remained close to 100% throughout the entire concentration range tested, while it was between 75 and 100% for SDZ. Desorption was always higher for SDZ than for TC. The results of this study could be useful to design practices to protected environmental compartments receiving discharges that simultaneously contain the two antibiotics here evaluated, and therefore could be relevant in terms of protection of the environment and public health. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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20 pages, 11712 KiB

Open AccessFeature PaperArticle

Novel Study for Energy Recovery from the Cooling–Solidification Stage of Synthetic Slag Manufacturing: Estimation of the Potential Energy Recovery

by Francisco M. Baena-Moreno, Mónica Rodríguez-Galán, Benito Navarrete and Luis F. Vilches

Processes 2020, 8(12), 1590; https://doi.org/10.3390/pr8121590 - 2 Dec 2020

Cited by 1 | Viewed by 1868

Abstract

Herein, a novel method for energy recovery from molten synthetic slags is analyzed. In this work, the potential energy that could be recovered from the production of synthetic slag is estimated by means of an integrated experimental–theoretical study. The energy to be recovered [...] Read more.

Herein, a novel method for energy recovery from molten synthetic slags is analyzed. In this work, the potential energy that could be recovered from the production of synthetic slag is estimated by means of an integrated experimental–theoretical study. The energy to be recovered comes from the cooling–solidification stage of the synthetic slag manufacturing. Traditionally, the solidification stage has been carried out through quick cooling with water, which does not allow the energy recovery. In this paper, a novel cooling method based on metal spheres is presented, which allows the energy recovery from the molten slags. Two points present novelty in this work: (1) the method for measuring the metal spheres temperature (2) and the estimation of the energy that could be recovered from these systems in slag manufacturing. The results forecasted that the temperature achieved by the metal spheres was in the range of 295–410 °C in the center and 302–482 °C on the surface. Furthermore, we estimated that 325–550 kJ/kg of molten material could be recovered, of which 15% of the energy consumption is in the synthetic slag manufacturing process. Overall, the results obtained confirmed the potential of our proposal for energy recovery from the cooling–solidification stage of synthetic slag manufacturing. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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19 pages, 5829 KiB

Open AccessArticle

Equilibrium, Kinetic and Thermodynamic Studies for Sorption of Phosphate from Aqueous Solutions Using ZnO Nanoparticles

by Tra Huong Do, Van Tu Nguyen, Quoc Dung Nguyen, Manh Nhuong Chu, Thi Cam Quyen Ngo and Lam Van Tan

Processes 2020, 8(11), 1397; https://doi.org/10.3390/pr8111397 - 2 Nov 2020

Cited by 8 | Viewed by 3311

Abstract

In this study, ZnO nanoparticles were fabricated by using the hydrothermal method for adsorption of phosphate from wastewater. The obtained ZnO nanorods were characterized by powder X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), specific surface area (BET) and energy dispersive X-ray spectroscopy [...] Read more.

In this study, ZnO nanoparticles were fabricated by using the hydrothermal method for adsorption of phosphate from wastewater. The obtained ZnO nanorods were characterized by powder X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), specific surface area (BET) and energy dispersive X-ray spectroscopy (EDS). The ZnO materials were applied for adsorption of phosphate from water using batch experiments. The effects of pH (4–10), adsorption time (30–240 min), the amount of adsorbent (0.1–0.7 g/L) and initial concentration of phosphate (147.637–466.209 mg/L) on the adsorption efficiency were investigated. The optimum condition was found at pH = 5 and at an adsorption time of 150 min. The adsorption was fitted well with the Langmuir isotherm and the maximum adsorption capacity was calculated to be 769.23 mg/g. These results show that ZnO nanomaterial would highly promising for adsorbing phosphate from water. The adsorption of phosphate on ZnO nanomaterials follows the isothermal adsorption model of Langmuir, Tempkin and Freundlich with single-layer adsorption. There is weak interaction between the adsorbent and the adsorbate. Phosphate adsorption of the ZnO nanomaterials follows Lagergren’s apparent second-order kinetic model and was spontaneous and exothermic. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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11 pages, 3262 KiB

Open AccessArticle

Influences of Ash-Existing Environments and Coal Structures on CO₂ Gasification Characteristics of Tri-High Coal

by Lang Liu, Qingrui Jiao, Jian Yang, Bowen Kong, Shan Ren and Qingcai Liu

Processes 2020, 8(11), 1367; https://doi.org/10.3390/pr8111367 - 28 Oct 2020

Cited by 3 | Viewed by 2075

Abstract

Two kinds of tri-high coals were selected to determine the influences of ash-existing environments and coal structures on CO₂ gasification characteristics. The TGA results showed that the gasification of ash-free coal (AFC) chars was more efficient than that of corresponding raw coal [...] Read more.

Two kinds of tri-high coals were selected to determine the influences of ash-existing environments and coal structures on CO₂ gasification characteristics. The TGA results showed that the gasification of ash-free coal (AFC) chars was more efficient than that of corresponding raw coal (RC) chars. To uncover the reasons, the structures of RCs and AFCs, and their char samples prepared at elevated temperatures were investigated with SEM, BET, XRD, Raman and FTIR. The BET, SEM and XRD results showed that the Ash/mineral matter is associated with coal, carbon forms the main structural framework and mineral matters are found embedded in the coal structure in the low-rank tri-high coal. The Raman and FTIR results show that the ash can hinder volatile matters from exposing to the coal particles. Those results indicate that the surface of AFC chars has more free active carbon sites than raw coal chars, which are favorable for mass transfer between C and CO₂, thereby improving reactivity of the AFC chars. However, the gasification reactivity was dominated by pore structure at elevated gasification temperatures, even though the microcrystalline structure, functional group structure, and increase in the disorder carbon were improved by acid pickling. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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13 pages, 2015 KiB

Open AccessArticle

Exploring E-Waste Resources Recovery in Household Solid Waste Recycling

by Muhammad Mobin Siddiqi, Muhammad Nihal Naseer, Yasmin Abdul Wahab, Nor Aliya Hamizi, Irfan Anjum Badruddin, Mohd Abul Hasan, Zaira Zaman Chowdhury, Omid Akbarzadeh, Mohd Rafie Johan and Sarfaraz Kamangar

Processes 2020, 8(9), 1047; https://doi.org/10.3390/pr8091047 - 27 Aug 2020

Cited by 14 | Viewed by 5547

Abstract

The ecosystem of earth, the habitation of 7.53 billion people and more than 8.7 million species, is being imbalanced by anthropogenic activities. The ever-increasing human population and race of industrialization is an exacerbated threat to the ecosystem. At present, the global average waste [...] Read more.

The ecosystem of earth, the habitation of 7.53 billion people and more than 8.7 million species, is being imbalanced by anthropogenic activities. The ever-increasing human population and race of industrialization is an exacerbated threat to the ecosystem. At present, the global average waste generation per person is articulated as 494 kg/year, an enormous amount of household waste (HSW) that ultimately hits

3.71 \times 10^{12}

kg of waste in one year. The ultimate destination of HSW is a burning issue because open dumping and burning as the main waste treatment and final disposal systems create catastrophic environmental limitations. This paper strives to contribute to this issue of HSW management that matters to everyone’s business, specifically to developing nations. The HSW management system of the world’s 12th largest city and 24th most polluted city, Karachi, was studied with the aim of generating possible economic gains by recycling HSWs. In this regard, the authors surveyed dumping sites for sample collection. The sample was segregated physically to determine the content type (organic, metals, and many others). Afterward, chemical analysis on AAS (Atomic Absorption Spectrophotometry) of debris and soil from a landfill site was performed. HSW is classified and quantified into major classes of household materials. The concentrations of e-waste [Cu], industrial development indicator [Fe], and the main component of lead-acid storage batteries [Pb] are quantified as 199.5, 428.5, and 108.5 ppm, respectively. The annual generation of the aforementioned metals as waste recovery is articulated as 1.2 × 10⁶, 2.6 × 10⁶ and 6.5 × 10⁵ kg, respectively. Significantly, this study concluded that a results-based metal recovery worth 6.1 million USD is discarded every year in HSW management practices. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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9 pages, 3192 KiB

Open AccessCommunication

Kinetic Analysis of Algae Gasification by Distributed Activation Energy Model

by Guozhao Ji, Abdul Raheem, Xin Wang, Weng Fu, Boyu Qu, Yuan Gao, Aimin Li, Ming Zhao, Weiguo Dong and Zhien Zhang

Processes 2020, 8(8), 927; https://doi.org/10.3390/pr8080927 - 2 Aug 2020

Cited by 7 | Viewed by 2932

Abstract

Conversion of algal biomass into energy products via gasification has attracted increasing research interests. A basic understanding of the gasification kinetics of algal biomass is of fundamental importance. Distributed activation energy model (DAEM), which provides the information of energy barrier distribution during the [...] Read more.

Conversion of algal biomass into energy products via gasification has attracted increasing research interests. A basic understanding of the gasification kinetics of algal biomass is of fundamental importance. Distributed activation energy model (DAEM), which provides the information of energy barrier distribution during the gasification process, is a promising tool to study the kinetic process of algae gasification. In this study, DAEM model was used to investigate Chlorella vulgaris and Spirulina gasification. The activation energy of Chlorella vulgaris gasification was in the range from 370 to 650 kJ mol⁻¹. The range of activation energy for Spirulina gasification was a bit wider, spanning from 330 to 670 kJ mol⁻¹. The distribution of activation energy for both Chlorella vulgaris and Spirulina showed that 500 kJ mol⁻¹ had the most components, and these components were gasified at around 300 °C. The DAEM algorithm was validated by the conversion and conversion rate from experimental measurement, demonstrating that DAEM is accurate to describe the kinetics of algal biomass gasification. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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14 pages, 1342 KiB

Open AccessFeature PaperArticle

Is Recycling Always the Best Option? Environmental Assessment of Recycling of Seashell as Aggregates in Noise Barriers

by Begoña Peceño, Carlos Leiva, Bernabé Alonso-Fariñas and Alejandro Gallego-Schmid

Processes 2020, 8(7), 776; https://doi.org/10.3390/pr8070776 - 2 Jul 2020

Cited by 17 | Viewed by 5182

Abstract

Waste recycling is an essential part of waste management. The concrete industry allows the use of large quantities of waste as a substitute for a conventional raw material without sacrificing the technical properties of the product. From a circular economy point of view, [...] Read more.

Waste recycling is an essential part of waste management. The concrete industry allows the use of large quantities of waste as a substitute for a conventional raw material without sacrificing the technical properties of the product. From a circular economy point of view, this is an excellent opportunity for waste recycling. Nevertheless, in some cases, the recycling process can be undesirable because it does not involve a net saving in resource consumption or other environmental impacts when compared to the conventional production process. In this study, the environmental performance of conventional absorption porous barriers, composed of 86 wt % of natural aggregates and 14 wt % cement, was compared with barriers composed of 80 wt % seashell waste and 20 wt % cement through an attributional cradle-to-grave life cycle assessment. The results show that, for the 11 environmental impact categories considered, the substitution of the natural aggregates with seashell waste involves higher environmental impacts, between 32% and 267%. These results are justified by the high contribution to these impacts of the seashell waste pre-treatment and the higher cement consumption. Therefore, the recycling of seashells in noise barrier manufacturing is not justified from an environmental standpoint with the current conditions. In this sense, it could be concluded that life cycle assessments should be carried out simultaneously with the technical development of the recycling process to ensure a sustainable solution. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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18 pages, 1773 KiB

Open AccessArticle

The Development of a Waste Tyre Pyrolysis Production Plant Business Model for the Gauteng Region, South Africa

by Nhlanhla Nkosi, Edison Muzenda, Tirivaviri A. Mamvura, Mohamed Belaid and Bilal Patel

Processes 2020, 8(7), 766; https://doi.org/10.3390/pr8070766 - 30 Jun 2020

Cited by 12 | Viewed by 10840

Abstract

Some of today’s modern life challenges include addressing the increased waste generation and energy deficiencies. Waste tyres have been identified as one of the key environmental concerns due to their non-biodegradable nature and bulk storage space demand. Pyrolysis is a thermochemical process with [...] Read more.

Some of today’s modern life challenges include addressing the increased waste generation and energy deficiencies. Waste tyres have been identified as one of the key environmental concerns due to their non-biodegradable nature and bulk storage space demand. Pyrolysis is a thermochemical process with the potential to address the growing waste tyre problem, energy deficits, and material recovery by converting waste tyres to pyrolysis oil that can be used as a fuel. This study seeks to critically evaluate the feasibility of constructing and operating a waste tyre processing facility and then subsequently marketing and selling the pyrolysis secondary end products by developing a financial business model. The model encompasses costing, procurement, installation, commissioning, and operating a batch pyrolysis plant in Gauteng, South Africa. To achieve the study objectives, an order of magnitude costing method was used for model construction. The results showed the feasibility and sustainability of operating a 3.5 tonne per day batch waste tyre pyrolysis plant in Gauteng Province, South Africa, with a 15-year life span and a projected payback period of approximately 5 years. It was concluded that for the pyrolysis plant to be successful, further treatment steps are required to improve the process economics; also, a stable and sustainable product market should exist and be regulated in South Africa. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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14 pages, 2216 KiB

Open AccessFeature PaperArticle

The Effects of pH Change through Liming on Soil N₂O Emissions

by Muhammad Shaaban, Yupeng Wu, Lei Wu, Ronggui Hu, Aneela Younas, Avelino Nunez-Delgado, Peng Xu, Zheng Sun, Shan Lin, Xiangyu Xu and Yanbin Jiang

Processes 2020, 8(6), 702; https://doi.org/10.3390/pr8060702 - 17 Jun 2020

Cited by 23 | Viewed by 5126

Abstract

Nitrous oxide (N₂O) is an overwhelming greenhouse gas and agricultural soils, particularly acidic soils, are the main source of its release to the atmosphere. To ameliorate acidic soil condition, liming materials are added as an amendment. However, the impact of liming [...] Read more.

Nitrous oxide (N₂O) is an overwhelming greenhouse gas and agricultural soils, particularly acidic soils, are the main source of its release to the atmosphere. To ameliorate acidic soil condition, liming materials are added as an amendment. However, the impact of liming materials has not been well addressed in terms of exploring the effect of soil pH change on N₂O emissions. In the present study, a soil with pH 5.35 was amended with liming materials (CaMg(CO₃)₂, CaCO₃, Ca(OH)₂ and CaO) to investigate their effects on N₂O emissions. The results indicate that application of liming materials reduced the magnitudes of N₂O emissions. The maximum reduction of soil N₂O emissions took place for Ca(OH)₂ treatment when compared to the other liming materials, and was related to increasing soil pH. Mineral N, dissolved organic C, and microbial biomass C were also influenced by liming materials, but the trend was inconsistent to the soil pH change. The results suggest that N₂O emission mitigation is more dependent on soil pH than C and N dynamics when comparing the different liming materials. Moreover, ameliorating soil acidity is a promising option to mitigate N₂O emissions from acidic soils. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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17 pages, 2125 KiB

Open AccessArticle

Characterizations of Biomasses for Subsequent Thermochemical Conversion: A Comparative Study of Pine Sawdust and Acacia Tortilis

by Gratitude Charis, Gwiranai Danha and Edison Muzenda

Processes 2020, 8(5), 546; https://doi.org/10.3390/pr8050546 - 8 May 2020

Cited by 19 | Viewed by 3792

Abstract

The bioenergy production potential from biomasses is dependent on their characteristics. This study characterized pine sawdust samples from Zimbabwe and acacia tortilis samples from Botswana using conventional and spectrometry techniques. The ultimate analysis results for pine were 45.76% carbon (C), 5.54% hydrogen (H), [...] Read more.

The bioenergy production potential from biomasses is dependent on their characteristics. This study characterized pine sawdust samples from Zimbabwe and acacia tortilis samples from Botswana using conventional and spectrometry techniques. The ultimate analysis results for pine were 45.76% carbon (C), 5.54% hydrogen (H), 0.039% nitrogen (N), 0% sulphur (S) and 48.66% oxygen (O) and, for acacia, were 41.47% C, 5.15% H, 1.23% N, 0% S and 52.15% O. Due to the low N and S in the biomasses, they promise to provide cleaner energy than fossil-based sources. Proximate analysis results, on a dry basis, for acacia were 3.90% ash, 15.59% fixed carbon and 76.51% volatiles matter and 0.83%, 20% and 79.16%, respectively, for pine. A calorific value of 17.57 MJ/kg was obtained for pine, compared with 17.27 MJ/kg for acacia, suggesting they are good thermochemical feedstocks. Acacia’s bulk energy density is five times that of pine, making it excellent for compressed wood applications. Though the ash content in acacia was much higher than in pine, it fell below the fouling and slagging limit of 6%. In pyrolysis, however, high ash contents lead to reduced yields or the quality of bio-oil through catalytic reactions. Fourier transform infrared spectrometry indicated the presence of multiple functional groups, as expected for a biomass and its derivatives. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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12 pages, 3381 KiB

Open AccessArticle

Utilization of Steel-Making Dust in Drilling Fluids Formulations

by Musaab I. Magzoub, Mohamed H. Ibrahim, Mustafa S. Nasser, Muftah H. El-Naas and Mahmood Amani

Processes 2020, 8(5), 538; https://doi.org/10.3390/pr8050538 - 3 May 2020

Cited by 8 | Viewed by 4089

Abstract

Steelmaking is an energy-intensive process that generates considerable amounts of by-products and wastes, which often pose major environmental and economic challenges to the steel-making industry. One of these by-products is steel dust that is produced during the separation of impurities in the smelting [...] Read more.

Steelmaking is an energy-intensive process that generates considerable amounts of by-products and wastes, which often pose major environmental and economic challenges to the steel-making industry. One of these by-products is steel dust that is produced during the separation of impurities in the smelting and refining of metals in steel-making furnaces. In this study, electric arc furnace (EAF) dust has been evaluated as a potential, low-cost additive to increase the viscosity and weight of drilling muds. Currently, the cost of drilling operations typically accounts for 50 to 80% of the exploration costs and about 30 to 80% of the subsequent field development costs. Utilization of steelmaking waste in drilling fluids formulations is aimed to produce new and optimized water-based drilling formulations, which is expected to reduce the amount of bentonite and other viscosifier additives used in the drilling formulations. The results showed that in a typical water-based drilling fluid of 8.6 ppg (1030.51 kg/m³), the amount of standard drilling grade bentonite could be reduced by 30 wt.% with the addition of the proposed new additive to complete the required mud weight. The mixture proved to be stable with no phase separation. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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22 pages, 3253 KiB

Open AccessArticle

Modeling the Municipal Waste Collection Using Genetic Algorithms

by Elisabete Alberdi, Leire Urrutia, Aitor Goti and Aitor Oyarbide-Zubillaga

Processes 2020, 8(5), 513; https://doi.org/10.3390/pr8050513 - 27 Apr 2020

Cited by 5 | Viewed by 4088

Abstract

Calculating adequate vehicle routes for collecting municipal waste is still an unsolved issue, even though many solutions for this process can be found in the literature. A gap still exists between academics and practitioners in the field. One of the apparent reasons why [...] Read more.

Calculating adequate vehicle routes for collecting municipal waste is still an unsolved issue, even though many solutions for this process can be found in the literature. A gap still exists between academics and practitioners in the field. One of the apparent reasons why this rift exists is that academic tools often are not easy to handle and maintain by actual users. In this work, the problem of municipal waste collection is modeled using a simple but efficient and especially easy to maintain solution. Real data have been used, and it has been solved using a Genetic Algorithm (GA). Computations have been done in two different ways: using a complete random initial population, and including a seed in this initial population. In order to guarantee that the solution is efficient, the performance of the genetic algorithm has been compared with another well-performing algorithm, the Variable Neighborhood Search (VNS). Three problems of different sizes have been solved and, in all cases, a significant improvement has been obtained. A total reduction of 40% of itineraries is attained with the subsequent reduction of emissions and costs. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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16 pages, 4125 KiB

Open AccessArticle

Fabrication of Ultrathin MoS₂ Nanosheets and Application on Adsorption of Organic Pollutants and Heavy Metals

by Siyi Huang, Ziyun You, Yanting Jiang, Fuxiang Zhang, Kaiyang Liu, Yifan Liu, Xiaochen Chen and Yuancai Lv

Processes 2020, 8(5), 504; https://doi.org/10.3390/pr8050504 - 26 Apr 2020

Cited by 37 | Viewed by 4592

Abstract

Owing to their peculiar structural characteristics and potential applications in various fields, the ultrathin MoS₂ nanosheets, a typical two-dimensional material, have attracted numerous attentions. In this paper, a hybrid strategy with combination of quenching process and liquid-based exfoliation was employed to fabricate [...] Read more.

Owing to their peculiar structural characteristics and potential applications in various fields, the ultrathin MoS₂ nanosheets, a typical two-dimensional material, have attracted numerous attentions. In this paper, a hybrid strategy with combination of quenching process and liquid-based exfoliation was employed to fabricate the ultrathin MoS₂ nanosheets (MoS₂ NS). The obtained MoS₂ NS still maintained hexagonal phase (2H-MoS₂) and exhibited evident thin layer-structure (1–2 layers) with inconspicuous wrinkle. Besides, the MoS₂ NS dispersion showed excellent stability (over 60 days) and high concentration (0.65 ± 0.04 mg mL⁻¹). The MoS₂ NS dispersion also displayed evident optical properties, with two characteristic peaks at 615 and 670 nm, and could be quantitatively analyzed with the absorbance at 615 nm in the range of 0.01–0.5 mg mL⁻¹. The adsorption experiments showed that the as-prepared MoS₂ NS also exhibited remarkable adsorption performance on the dyes (344.8 and 123.5 mg g⁻¹ of q_m for methylene blue and methyl orange, respectively) and heavy metals (185.2, 169.5, and 70.4 mg g⁻¹ of q_m for Cd²⁺, Cu²⁺, and Ag⁺). During the adsorption, the main adsorption mechanisms involved the synergism of physical hole-filling effects and electrostatic interactions. This work provided an effective way for the large-scale fabrication of the two-dimensional nanosheets of transition metal dichalcogenides (TMDs) by liquid exfoliation. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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16 pages, 6341 KiB

Open AccessArticle

Evaluation of Calcium Oxide Nanoparticles from Industrial Waste on the Performance of Hardened Cement Pastes: Physicochemical Study

by Youssef Abdelatif, Abdel-Aal M. Gaber, Abd El-Aziz S. Fouda and Tarek Alsoukarry

Processes 2020, 8(4), 401; https://doi.org/10.3390/pr8040401 - 30 Mar 2020

Cited by 12 | Viewed by 4229

Abstract

Large amounts of carbonated mud waste (CMW) require disposal during sugar manufacturing after the carbonation process. The lightweight of CMW enables its utilization as a partial replacement for the cement to reduce costs and CO₂ emissions. Here, various levels of CMW, namely, [...] Read more.

Large amounts of carbonated mud waste (CMW) require disposal during sugar manufacturing after the carbonation process. The lightweight of CMW enables its utilization as a partial replacement for the cement to reduce costs and CO₂ emissions. Here, various levels of CMW, namely, 0, 5, 10, 15, 20, and 25 wt.% were applied to produce composite cement samples with ordinary Portland cement (OPC) as a regular mix design series. Pure calcium oxide (CaO) nanoparticles were obtained after the calcination of CMW. The techniques of X-ray fluorescence spectrometers (XRF), Transmission electron microscope (TEM), Selected area diffraction (SAED), Scanning electron microscope (SEM), energy dixpersive X-ray (EDX), and dynamic light scattering (DLS) were used to characterize the obtained CaO nanoparticles. According to the compressive strength and bulk density results, 15 wt.% CMW was optimal for the mix design. The specific surface area increased from 27.8 to 134.8 m²/g when the CMW was calcined to 600 °C. The compressive strength of the sample containing 15% CMW was lower than the values of the other pastes containing 5% and 10% CMW at all of the curing times. The porosity factor of the hardened cement pastes released with a curing time of up to 28 days. Excessive CMW of up to 25 wt.% reduced the properties of OPC. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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22 pages, 2509 KiB

Open AccessArticle

Techno-Economic Analysis of CO₂ Capture Technologies in Offshore Natural Gas Field: Implications to Carbon Capture and Storage in Malaysia

by Norhasyima Rahmad Sukor, Abd Halim Shamsuddin, Teuku Meurah Indra Mahlia and Md Faudzi Mat Isa

Processes 2020, 8(3), 350; https://doi.org/10.3390/pr8030350 - 19 Mar 2020

Cited by 33 | Viewed by 9203

Abstract

Growing concern on global warming directly related to CO₂ emissions is steering the implementation of carbon capture and storage (CCS). With Malaysia having an estimated 37 Tscfd (Trillion standard cubic feet) of natural gas remains undeveloped in CO₂ containing natural gas [...] Read more.

Growing concern on global warming directly related to CO₂ emissions is steering the implementation of carbon capture and storage (CCS). With Malaysia having an estimated 37 Tscfd (Trillion standard cubic feet) of natural gas remains undeveloped in CO₂ containing natural gas fields, there is a need to assess the viability of CCS implementation. This study performs a techno-economic analysis for CCS at an offshore natural gas field in Malaysia. The framework includes a gas field model, revenue model, and cost model. A techno-economic spreadsheet consisting of Net Present Value (NPV), Payback Period (PBP), and Internal Rate of Return (IRR) is developed over the gas field’s production life of 15 years for four distinctive CO₂ capture technologies, which are membrane, chemical absorption, physical absorption, and cryogenics. Results predict that physical absorption solvent (Selexol) as CO₂ capture technology is most feasible with IRR of 15% and PBP of 7.94 years. The output from the techno-economic model and associated risks of the CCS project are quantified by employing sensitivity analysis (SA), which indicated that the project NPV is exceptionally sensitive to gas price. On this basis, the economic performance of the project is reliant on revenues from gas sales, which is dictated by gas market price uncertainties. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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22 pages, 7815 KiB

Open AccessArticle

Synthesis and Characterization of New Schiff Base/Thiol-Functionalized Mesoporous Silica: An Efficient Sorbent for the Removal of Pb(II) from Aqueous Solutions

by Moawia O. Ahmed, Ameen Shrpip and Muhammad Mansoor

Processes 2020, 8(2), 246; https://doi.org/10.3390/pr8020246 - 21 Feb 2020

Cited by 12 | Viewed by 4995

Abstract

A new type of silica hybrid material functionalized with Schiff base-propyl-thiol and propyl-thiol groups (adsorbents 1 and 2, respectively) was synthesized using a co-condensation method. The synthesized materials and their starting materials were successfully characterized using a variety of techniques such as [...] Read more.

A new type of silica hybrid material functionalized with Schiff base-propyl-thiol and propyl-thiol groups (adsorbents 1 and 2, respectively) was synthesized using a co-condensation method. The synthesized materials and their starting materials were successfully characterized using a variety of techniques such as Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), nitrogen adsorption–desorption isotherms, the Brunauer–Emmett–Teller (BET) surface area calculation method, the Barrett, Joyner, and Halenda (BJH) pore size calculation method, thermogravimetry analysis (TGA), and 1H and 13C nuclear magnetic resonance (NMR) spectra. The results indicate that the new material (adsorbent 1) has a large surface and possesses different functional groups (-SH, -OH, -C=O and –N=C). The newly synthesized hybrid materials (1 and 2) were investigated as potential adsorbents for removal of toxic heavy metals, such as Pb(II) from aqueous solutions. The adsorption results show that materials 1 and 2 have different sorption properties and were found to be effective adsorbents for Pb(II) removal from aqueous solutions. In addition, compound 1 exhibited a higher adsorption capacity for Pb(II) compared to compound 2. The results showed that the optimum pH for Pb(II) sorption was 6.5. Contact time was observed to occur after 30 min for 25 mg L⁻¹ Pb(II) concentration and adsorbent dose of 0.4 g L⁻¹ at 25 °C. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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33 pages, 4461 KiB

Open AccessFeature PaperArticle

Quantifying the Benefit of a Dynamic Performance Assessment of WWTP

by Silvana Revollar, Montse Meneses, Ramón Vilanova, Pastora Vega and Mario Francisco

Processes 2020, 8(2), 206; https://doi.org/10.3390/pr8020206 - 7 Feb 2020

Cited by 9 | Viewed by 2728

Abstract

In this work a comprehensive analysis of the environmental impact of the operation of a wastewater treatment plant (WWTP) using different control strategies is carried out considering the dynamic evolution of some environmental indicators and average operation costs. The selected strategies are PI [...] Read more.

In this work a comprehensive analysis of the environmental impact of the operation of a wastewater treatment plant (WWTP) using different control strategies is carried out considering the dynamic evolution of some environmental indicators and average operation costs. The selected strategies are PI (proportional integral) control schemes such as dissolved oxygen control in the aerobic zone (DO control), DO control and nitrates control in the anoxic zone (DO + NO control) and regulation of ammonium control at the end of aerobic zone (Cascade S_NHSP) commonly used in WWTPs to maintain the conditions that ensure the desired effluent quality in a variable influent scenario. The main novelty of the work is the integration of potential insights into environmental impact from the analysis of dynamic evolution of environmental indicators at different time scales. The consideration of annual, bimonthly and weekly temporal windows to evaluate performance indicators makes it possible to capture seasonal effects of influent disturbances and control actions on environmental costs of wastewater treatment that are unnoticed in the annual-based performance evaluation. Then, in the case of periodic events, it is possible to find solutions to improve operation by the adjustment of the control variables in specific periods of time along the operation horizon. The analysis of the annual average and dynamic profiles (weekly and bimonthly) of environmental indicators showed that ammonium-based control (Cascade S_NHSP) produce the best compromise solution between environmental and operation costs compared with DO control and DO + NO control. An alternative control strategy, named S_NHSP _var Q_{carb var}, has been defined considering a sequence of changes on ammonium set-point (S_NHSP) and carbon dosage (Q_carb) on different temporal windows. It is compared with DO control considering weekly and bimonthly profiles and annual average values leading to the conclusion that both strategies, Cascade S_NHSP and S_NHSP _var Q_{carb var}, produce an improvement of dynamic and annual average environmental performance and operation costs, but benefits of Cascade S_NHSP strategy are associated with reduction of electricity consumption and emissions to water, while S_NHSP _var Q_{carb var} strategy reduces electricity consumption, use of chemicals (reducing external carbon dosage) and operation costs. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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11 pages, 3408 KiB

Open AccessArticle

Stabilization/Solidification of Strontium Using Magnesium Silicate Hydrate Cement

by Tingting Zhang, Jing Zou, Yimiao Li, Yuan Jia and Christopher R. Cheeseman

Processes 2020, 8(2), 163; https://doi.org/10.3390/pr8020163 - 1 Feb 2020

Cited by 22 | Viewed by 4118

Abstract

Magnesium silicate hydrate (M–S–H) cement, formed by reacting MgO, SiO₂, and H₂O, was used to encapsulate strontium (Sr) radionuclide. Samples were prepared using light-burned magnesium oxide and silica fume, with sodium hexametaphosphate added to the mix water as a [...] Read more.

Magnesium silicate hydrate (M–S–H) cement, formed by reacting MgO, SiO₂, and H₂O, was used to encapsulate strontium (Sr) radionuclide. Samples were prepared using light-burned magnesium oxide and silica fume, with sodium hexametaphosphate added to the mix water as a dispersant. The performance of the materials formed was evaluated by leach testing and the microstructure of the samples was also characterized. The stabilizing/solidifying effect on Sr radionuclide in the MgO–SiO₂–H₂O system with low alkalinity is demonstrated in the study. The leaching rate in a standard 42-day test was 2.53 × 10⁻⁴ cm/d, and the cumulative 42-day leaching fraction was 0.06 cm. This meets the relevant national standard performance for leaching requirements. Sr²⁺ was effectively incorporated into the M–S–H hydration products and new phase formation resulted in low Sr leaching being observed. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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16 pages, 5728 KiB

Open AccessFeature PaperArticle

Thermal Isolation of a Clean Alloy from Waste Slag and Polymeric Residue of Electronic Waste

by Rasoul Khayyam Nekouei, Samane Maroufi, Mohammad Assefi, Farshid Pahlevani and Veena Sahajwalla

Processes 2020, 8(1), 53; https://doi.org/10.3390/pr8010053 - 2 Jan 2020

Cited by 13 | Viewed by 3837

Abstract

Unprecedented advances and innovation in technology and short lifespans of electronic devices have resulted in the generation of a considerable amount of electronic waste (e-waste). Polymeric components present in electronic waste contain a wide range of organic materials encompassing a significant portion of [...] Read more.

Unprecedented advances and innovation in technology and short lifespans of electronic devices have resulted in the generation of a considerable amount of electronic waste (e-waste). Polymeric components present in electronic waste contain a wide range of organic materials encompassing a significant portion of carbon (C). This source of carbon can be employed as a reducing agent in the reduction of oxides from another waste stream, i.e., steelmaking slag, which contains ≈20 wt%–40 wt% iron oxide. This waste slag is produced on a very large scale by the steel industry due to the nature of the process. In this research, the polymeric residue leftover from waste printed circuit boards (PCBs) after a physical-chemical recycling process was used as the source of carbon in the reduction of iron oxide from electric arc furnace (EAF) slag. Prior to the recycling tests, the polymer content of e-waste was characterized in terms of composition, morphology, thermal behavior, molecular structure, hazardous elements such as Br, the volatile portion, and the fixed carbon content. After the optimization of the ratio between the waste slag (Fe source) and the waste polymer (the carbon source), the microstructure of the recycled alloy showed no Br, Cl, S, or other contamination. Hence, two problematic and complex waste streams were successfully converted to a clean alloy with 4 wt% C, 4% Cr, 2% Si, 1% Mn, and 89% Fe. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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12 pages, 1368 KiB

Open AccessArticle

Risk Assessment of Potentially Toxic Elements Pollution from Mineral Processing Steps at Xikuangshan Antimony Plant, Hunan, China

by Saijun Zhou, Renjian Deng and Andrew Hursthouse

Processes 2020, 8(1), 29; https://doi.org/10.3390/pr8010029 - 25 Dec 2019

Cited by 28 | Viewed by 4216

Abstract

We evaluated the direct release to the environment of a number of potentially toxic elements (PTEs) from various processing nodes at Xikuangshan Antimony Mine in Hunan Province, China. Sampling wastewater, processing dust, and solid waste and characterizing PTE content (major elements Sb, As, [...] Read more.

We evaluated the direct release to the environment of a number of potentially toxic elements (PTEs) from various processing nodes at Xikuangshan Antimony Mine in Hunan Province, China. Sampling wastewater, processing dust, and solid waste and characterizing PTE content (major elements Sb, As, Zn, and associated Hg, Pb, and Cd) from processing activities, we extrapolated findings to assess wider environmental significance using the pollution index and the potential ecological risk index. The Sb, As, and Zn in wastewater from the antimony benefication industry and a wider group of PTEs in the fine ore bin were significantly higher than their reference values. The content of Sb, As, and Zn in tailings were relatively high, with the average value being 2674, 1040, and 590 mg·kg⁻¹, respectively. The content of PTEs in the surface soils surrounding the tailings was similar to that in tailings, and much higher than the background values. The results of the pollution index evaluation of the degree of pollution by PTEs showed that while dominated by Sb, some variation in order of significance was seen namely for: (1) The ore processing wastewater Sb > Pb > As > Zn > Hg > Cd, (2) in dust Sb > As > Cd > Pb > Hg > Zn, and (3) surface soil (near tailings) Sb > Hg > Cd > As > Zn > Pb. From the assessment of the potential ecological risk index, the levels were most significant at the three dust generation nodes and in the soil surrounding the tailings reservoir. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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12 pages, 6672 KiB

Open AccessArticle

Porous Aromatic Melamine Schiff Bases as Highly Efficient Media for Carbon Dioxide Storage

by Raghad M. Omer, Emaad T. B. Al-Tikrity, Gamal A. El-Hiti, Mohammed F. Alotibi, Dina S. Ahmed and Emad Yousif

Processes 2020, 8(1), 17; https://doi.org/10.3390/pr8010017 - 20 Dec 2019

Cited by 23 | Viewed by 4247

Abstract

High energy demand has led to excessive fuel consumption and high-concentration CO₂ production. CO₂ release causes serious environmental problems such as the rise in the Earth’s temperature, leading to global warming. Thus, chemical industries are under severe pressure to provide a [...] Read more.

High energy demand has led to excessive fuel consumption and high-concentration CO₂ production. CO₂ release causes serious environmental problems such as the rise in the Earth’s temperature, leading to global warming. Thus, chemical industries are under severe pressure to provide a solution to the problems associated with fuel consumption and to reduce CO₂ emission at the source. To this effect, herein, four highly porous aromatic Schiff bases derived from melamine were investigated as potential media for CO₂ capture. Since these Schiff bases are highly aromatic, porous, and have a high content of heteroatoms (nitrogen and oxygen), they can serve as CO₂ storage media. The surface morphology of the Schiff bases was investigated through field emission scanning electron microscopy, and their physical properties were determined by gas adsorption experiments. The Schiff bases had a pore volume of 0.005–0.036 cm³/g, an average pore diameter of 1.69–3.363 nm, and a small Brunauer–Emmett–Teller surface area (5.2–11.6 m²/g). The Schiff bases showed remarkable CO₂ uptake (up to 2.33 mmol/g; 10.0 wt%) at 323 K and 40 bars. The Schiff base containing the 4-nitrophenyl substituent was the most efficient medium for CO₂ adsorption and, therefore, can be used as a gas sorbent. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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16 pages, 1875 KiB

Open AccessArticle

Vapor Liquid Equilibrium Measurements of Two Promising Tertiary Amines for CO₂ Capture

by Diego D. D. Pinto, Znar Zahraee, Vanja Buvik, Ardi Hartono and Hanna K. Knuutila

Processes 2019, 7(12), 951; https://doi.org/10.3390/pr7120951 - 12 Dec 2019

Cited by 3 | Viewed by 4224

Abstract

Post combustion CO₂ capture is still a rather energy intense, and therefore expensive, process. Much of the current research for reducing the process energy requirements is focused on the regeneration section. A good description of the vapor liquid equilibrium of the solvent [...] Read more.

Post combustion CO₂ capture is still a rather energy intense, and therefore expensive, process. Much of the current research for reducing the process energy requirements is focused on the regeneration section. A good description of the vapor liquid equilibrium of the solvent is necessary for the accurate representation of the process. 3-(Diethylamino)-1,2-propanediol (DEA-12-PD) and 1-(2-hydroxyethyl)piperidine (12-HEPP) have been proposed as potential components in solvent blends for the membrane contactor. However, there are few available experimental data for these two tertiary amines making difficult to accurate simulate such process. In this work, we provide experimental data on the pure component saturation pressure (383 to 443 K) and on VLE of aqueous solutions of these amines (313 to 373 K) in order to fill part of the data gap. The data were used to estimate model parameters used to represent the data. The saturation pressure was modeled using the Antoine equation and the deviation is calculated lower than 2%. The NRTL model was used in this work to calculate the activity coefficients in the aqueous systems. The deviations in pressure for the aqueous systems were lower than 5% in both systems. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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9 pages, 3179 KiB

Open AccessFeature PaperArticle

Copper Adsorption by Magnetized Pine-Needle Biochar

by Eleni Nicolaou, Katerina Philippou, Ioannis Anastopoulos and Ioannis Pashalidis

Processes 2019, 7(12), 903; https://doi.org/10.3390/pr7120903 - 2 Dec 2019

Cited by 25 | Viewed by 4309

Abstract

The Cu(II) adsorption from aqueous solutions by magnetic biochar obtained from pine needles has been studied by means of batch-type experiments. The biochar fibers have been magnetized prior (pncm: carbonized-magnetized pine needles) and after oxidation (pncom: carbonized-oxidized-magnetized pine needles) and have been used [...] Read more.

The Cu(II) adsorption from aqueous solutions by magnetic biochar obtained from pine needles has been studied by means of batch-type experiments. The biochar fibers have been magnetized prior (pncm: carbonized-magnetized pine needles) and after oxidation (pncom: carbonized-oxidized-magnetized pine needles) and have been used as adsorbents to study the presence of carboxylic moieties on the magnetization and following adsorption process. The effect of pH (2–10), initial metal concentration (10⁻⁵–9·10⁻³ mol·L⁻¹) and contact time (0–60 min) has been studied by varying the respective parameter, and the adsorbents have been characterized by Fourier transform infrared (FTIR) and X-ray diffraction (XRD) measurements prior and after Cu(II)-adsorption. FTIR measurements were performed to investigate the formation of surface species and XRD measurements to record possible solid phase formation and characterize formed solids, including the evaluation of their average crystal size. The data obtained from the batch-type studies show that the oxidized magnetic biochar (pncom) presents significantly higher adsorption capacity (1.0 mmol g⁻¹) compared to pncm (0.4 mmol g⁻¹), which is ascribed to the synergistic effect of the carboxylic moieties present on the pncom surface, and the adsorption process follows the pseudo-second order kinetics. On the other hand, the FTIR spectra prove the formation of inner-sphere complexes and XRD diffractograms indicate Cu(II) solid phase formation at pH 6 and increased metal ion concentrations. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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12 pages, 3919 KiB

Open AccessArticle

Filtration Performances of Different Polysaccharides in Microfiltration Process

by Shujuan Meng, Hongju Liu, Qian Zhao, Nan Shen and Minmin Zhang

Processes 2019, 7(12), 897; https://doi.org/10.3390/pr7120897 - 2 Dec 2019

Cited by 15 | Viewed by 3727

Abstract

Membrane technology has been widely applied for water treatment, while membrane fouling still remains a big challenge. The polysaccharides in extracellular polymeric substances (EPS) have been known as a significant type of foulant due to their high fouling propensity. However, polysaccharides have many [...] Read more.

Membrane technology has been widely applied for water treatment, while membrane fouling still remains a big challenge. The polysaccharides in extracellular polymeric substances (EPS) have been known as a significant type of foulant due to their high fouling propensity. However, polysaccharides have many varieties which definitely behave differently in membrane filtration. Therefore, in this study, different polysaccharides alginate sodium and xanthan gum were chosen to study their effects on membrane fouling in a wide concentration range. The results demonstrated that the filtration behaviors of alginate sodium and xanthan gum were completely different, which was due to their different molecular structures. Alginate had a small molecular weight and it was easy for alginate to penetrate membrane pores resulting in pore blocking. A series of concentrations of alginate including 5 mg/L, 10 mg/L, 20 mg/L, 30 mg/L, 40 mg/L, and 50 mg/L were examined and it was found that the permeate flux decline highly depended on the level of alginate in the feed water. While for the filtration of xanthan gum, the same concentration of xanthan gum led to more serious fouling than that observed in alginate, which might be due to its large molecule. In addition, calcium chloride was added in the solutions of both alginate and xanthan gum to examine the influence of a divalent cation on polysaccharide fouling. A “unimodal” peak can be observed in the fouling propensity caused by Ca²⁺ and alginate with increasing the concentration of alginate. Such a phenomenon was not found in the fouling of xanthan gum and Ca²⁺ led to more serious fouling for all concentrations of xanthan gum. In light of this, this study gave new insights into the fouling propensities of different polysaccharides. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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15 pages, 3300 KiB

Open AccessFeature PaperArticle

Numerical Study on Separation Performance of Cyclone Flue Used in Grate Waste Incinerator

by Dong-mei Chen, Jing-yu Ran, Jun-tian Niu, Zhong-qing Yang, Ge Pu and Lin Yang

Processes 2019, 7(12), 866; https://doi.org/10.3390/pr7120866 - 20 Nov 2019

Cited by 4 | Viewed by 3391

Abstract

The traditional treatment of waste incineration flue gas is mostly carried out in low temperatures, but there are some problems such as corrosion of the heating surface at high and low temperatures, re-synthesis of dioxins, and low efficiency. Therefore, it is necessary to [...] Read more.

The traditional treatment of waste incineration flue gas is mostly carried out in low temperatures, but there are some problems such as corrosion of the heating surface at high and low temperatures, re-synthesis of dioxins, and low efficiency. Therefore, it is necessary to remove the pollutants at high temperatures. For the grate waste incinerator, this study proposes an adiabatic cyclone flue arranged at the exit of the first-stage furnace of the grate waste incinerator to pre-remove the fly ash at high temperatures, so as to alleviate the abrasion and corrosion of the tail heating surface. In this paper, computational fluid dynamics (CFD) method is applied to study the performance of a cyclone flue under different structural parameters, and the comprehensive performance of the cyclone flue is evaluated by the technique for order preference by similarity to an ideal solution (TOPSIS) method. The results show that particle separation efficiency increases at first and then decreases with the increase of the vortex finder length, the vortex finder diameter, and the distance between vortex finder and gas outlet tube, while it decreases with the increase of the gas outlet tube diameter. The pressure drop increases with the increase of the vortex finder length, and the vortex finder diameter, while decreases with the increase of the distance between the vortex finder, the gas outlet tube, and the gas outlet tube diameter. In the scope of this study, when h₁/a = 1.1, D₁/A = 0.33, h₂/A = 1.5, and D₂/A = 0.50, the comprehensive performance of the cyclone flue is much better. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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12 pages, 4213 KiB

Open AccessArticle

Insights into the Fouling Propensities of Natural Derived Alginate Blocks during the Microfiltration Process

by Shujuan Meng, Rui Wang, Minmin Zhang, Xianghao Meng, Hongju Liu and Liang Wang

Processes 2019, 7(11), 858; https://doi.org/10.3390/pr7110858 - 17 Nov 2019

Cited by 14 | Viewed by 3338

Abstract

Membrane technology has been one of the most promising techniques to solve the water problem in future. Unfortunately, it suffers from the fouling problem which is ubiquitous in membrane systems. The origin of the bewilderments of the fouling problem lies in the lack [...] Read more.

Membrane technology has been one of the most promising techniques to solve the water problem in future. Unfortunately, it suffers from the fouling problem which is ubiquitous in membrane systems. The origin of the bewilderments of the fouling problem lies in the lack of deep understanding. Recent studies have pointed out that the molecular structure of foulant affects its fouling propensity which has been ignored in the past. In this study, the filtration behaviors of alginate blocks derived from the same source were comprehensively explored. Alginate blocks share the same chemical composition but differ from each other in molecular structure. The alginate was first extracted from natural seaweed using calcium precipitation and ion-exchange methods. Extracted alginate was further fractionized into MG-, MM- and GG-blocks and the characteristics of the three blocks were examined by Fourier transform infrared spectroscopy (FTIR) and field emission scanning electron microscopy (FESEM) observations, and transparent exopolymer particles’ (TEPs) measurements. Results showed that MG-, MM- and GG-blocks had the same functional groups, but they showed different intermolecular interactions. TEP formation from MG-, MM- and GG-blocks revealed that the molecule crosslinking of them decreased in the order of MM-blocks > GG-blocks > MG-blocks. It was further found from microfiltration tests that these alginate blocks had completely different fouling propensities which can be explained by the TEP formation. TEPs would accumulate on membrane surfaces and worked as a pre-filter to avoid serious pore blocking of membrane. That all suggested that the membrane fouling was closely related to the molecular structure of foulant. It is expected that this study can provide useful insights into the fouling propensities of different types of polysaccharides during filtration processes. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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9 pages, 3884 KiB

Open AccessArticle

Modifying Nanoporous Carbon through Hydrogen Peroxide Oxidation for Removal of Metronidazole Antibiotics from Simulated Wastewater

by Teguh Ariyanto, Rut Aprillia Galuh Sarwendah, Yove Maulana Novirdaus Amimmal, William Teja Laksmana and Imam Prasetyo

Processes 2019, 7(11), 835; https://doi.org/10.3390/pr7110835 - 8 Nov 2019

Cited by 17 | Viewed by 3652

Abstract

This study examined change in pore structure and microstructure of nanoporous carbon after surface oxidation and how it affects the adsorption performance of metronidazole antibiotics. The surface oxidation was performed by hydrogen peroxide at 60 °C. The properties of porous carbon were investigated [...] Read more.

This study examined change in pore structure and microstructure of nanoporous carbon after surface oxidation and how it affects the adsorption performance of metronidazole antibiotics. The surface oxidation was performed by hydrogen peroxide at 60 °C. The properties of porous carbon were investigated by N₂-sorption analysis (pore structure), scanning electron microscopy (surface morphology), the Boehm titration method (quantification of surface functional group), and Fourier transform infrared spectroscopy (type of surface functional group). The results showed that the oxidation of porous carbon by hydrogen peroxide has a minor defect in the carbon pore structure. Only a slight decrease in specific surface area (8%) from its original value (973 m²g⁻¹) was seen but more mesoporosity was introduced. The oxidation of porous carbon with hydrogen peroxide modified the amount of oxide groups i.e., phenol, carboxylic acid and lactone. Moreover, in the application the oxidized carbon exhibited a higher the metronidazole uptake capacity of up to three-times manifold with respect to the pristine carbon. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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22 pages, 9925 KiB

Open AccessArticle

Knowledge Mapping of Carbon Footprint Research in a LCA Perspective: A Visual Analysis Using CiteSpace

by Shihu Zhong, Rong Chen, Fei Song and Yanmin Xu

Processes 2019, 7(11), 818; https://doi.org/10.3390/pr7110818 - 5 Nov 2019

Cited by 22 | Viewed by 5626

Abstract

Carbon emissions are inevitably linked to lifestyle and consumption behaviours, and the concept of “carbon footprinting” is now well-recognised beyond academia. Life cycle assessment (LCA) is one of the primary tools for assessing carbon footprints. The aim of this paper is to present [...] Read more.

Carbon emissions are inevitably linked to lifestyle and consumption behaviours, and the concept of “carbon footprinting” is now well-recognised beyond academia. Life cycle assessment (LCA) is one of the primary tools for assessing carbon footprints. The aim of this paper is to present a systematic review of literatures focusing on carbon footprint calculated with life cycle assessment. We used CiteSpace software to draw the knowledge map of related research to identify and trace the knowledge base and frontier terminology. It was found that the LCA application in respects of carbon footprint studies was completed mainly for the following aspect: beef production and dairy industry, seafood and fishery, nutrition, urban structure and energy use. The CiteSpace analysis showed the development path of the above aspects, for example, beef production and dairy industry has been a long-term topic in this kind of research, while the topic of nutrition appeared in recent years. There was also a cluster of literature discussing footprint evaluation tools, such as comparing LCA with input–output analysis. The CiteSpace analysis indicated that earlier methodological literature still plays an important role in recent research. Moreover, through the analysis of burst keywords, it was found that agriculture productions (dairy, meat, fish, crop) as well as global climate issues (greenhouse gases emission, global warming potential) have always been the areas of concern, which matches the result of co-citation analysis. Building materials (low-carbon building, natural buildings, sustainable buildings) and soil issues (soil carbon sequestration, soil organic carbon) are the topics of recent concern, which could arouse the attention of follower-up researchers. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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15 pages, 6964 KiB

Open AccessArticle

Mechanism and Kinetics of Ammonium Sulfate Roasting of Boron-Bearing Iron Tailings for Enhanced Metal Extraction

by Xiaoshu Lv, Fuhui Cui, Zhiqiang Ning, Michael L. Free and Yuchun Zhai

Processes 2019, 7(11), 812; https://doi.org/10.3390/pr7110812 - 4 Nov 2019

Cited by 7 | Viewed by 3179

Abstract

The large amount of boron-bearing iron tailings in China is a resource for metals that needs to be more completely and efficiently utilized. In this evaluation, the ammonium sulfate roasting process was used to make a controllable phase transformation to facilitate the subsequent [...] Read more.

The large amount of boron-bearing iron tailings in China is a resource for metals that needs to be more completely and efficiently utilized. In this evaluation, the ammonium sulfate roasting process was used to make a controllable phase transformation to facilitate the subsequent extraction of valuable metals from boron-bearing iron tailings. The effects of roasting temperature, roasting time, the molar ratio of ammonium sulfate to tailings, and the particle size on the extraction of elements were investigated. The orthogonal experimental design of experiments was used to determine the optimal processing conditions. XRD (X-Ray Diffractomer), scanning electron microscope (SEM), and simultaneous DSC–TG analyzer were used to assist in elucidating the mechanism of ammonium sulfate roasting. The experimental results showed that nearly all Fe, Al, and Mg were extracted under the following conditions: (1) the molar ratio of ammonium sulfate to iron tailings was 3:1; (2) the roasting temperature was 450 °C; (3) the roasting time was 120 min.; and, (4) the particle size was less than 80 μm. The kinetics analysis indicated that the sulfation of metals was controlled by internal diffusion, with the apparent activation energies of 17.10 kJ·mol⁻¹, 17.85 kJ·mol⁻¹, 19.79 kJ·mol⁻¹, and 29.71 kJ·mol⁻¹ for Fe, Al, Mg, and B, respectively. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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22 pages, 2889 KiB

Open AccessArticle

Determination of the Least Impactful Municipal Solid Waste Management Option in Harare, Zimbabwe

by Trust Nhubu and Edison Muzenda

Processes 2019, 7(11), 785; https://doi.org/10.3390/pr7110785 - 1 Nov 2019

Cited by 19 | Viewed by 5007

Abstract

Six municipal solid waste management (MSWM) options (A1–A6) in Harare were developed and analyzed for their global warming, acidification, eutrophication and human health impact potentials using life cycle assessment methodology to determine the least impactful option in Harare. Study findings will aid the [...] Read more.

Six municipal solid waste management (MSWM) options (A1–A6) in Harare were developed and analyzed for their global warming, acidification, eutrophication and human health impact potentials using life cycle assessment methodology to determine the least impactful option in Harare. Study findings will aid the development of future MSWM systems in Harare. A1 and A2 considered the landfilling and incineration, respectively, of indiscriminately collected MSW with energy recovery and byproduct treatment. Source-separated biodegradables were anaerobically treated with the remaining non-biodegradable fraction being incinerated in A3 and landfilled in A4. A5 and A6 had the same processes as in A3 and A4, respectively, except the inclusion of the recovery of 20% of the recoverable materials. The life cycle stages considered were collection and transportation, materials recovery, anaerobic digestion, landfilling and incineration. A5 emerged as the best option. Materials recovery contributed to impact potential reductions across the four impact categories. Sensitivity analysis revealed that doubling materials recovery and increasing it to 28% under A5 resulted in zero eutrophication and acidification, respectively. Increasing material recovery to 24% and 26% under A6 leads to zero acidification and eutrophication, respectively. Zero global warming and human health impacts under A6 are realised at 6% and 9% materials recovery levels, respectively. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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13 pages, 857 KiB

Open AccessFeature PaperArticle

Chromium VI and Fluoride Competitive Adsorption on Different Soils and By-Products

by Ana Quintáns-Fondo, Gustavo Ferreira-Coelho, Manuel Arias-Estévez, Juan Carlos Nóvoa-Muñoz, David Fernández-Calviño, Esperanza Álvarez-Rodríguez, María J. Fernández-Sanjurjo and Avelino Núñez-Delgado

Processes 2019, 7(10), 748; https://doi.org/10.3390/pr7100748 - 15 Oct 2019

Cited by 12 | Viewed by 2906

Abstract

Chromium (as Cr(VI)) and fluoride (F⁻) are frequently found in effluents from different industrial activities. In cases where these effluents reach soil, it can play an important role in retaining those pollutants. Similarly, different byproducts could act as bio-adsorbents to directly [...] Read more.

Chromium (as Cr(VI)) and fluoride (F⁻) are frequently found in effluents from different industrial activities. In cases where these effluents reach soil, it can play an important role in retaining those pollutants. Similarly, different byproducts could act as bio-adsorbents to directly treat polluted waters or to enhance the purging potential of soil. In this work, we used batch-type experiments to study competitive Cr(VI) and F⁻ adsorption in two different soils and several kinds of byproducts. Both soils, as well as mussel shell, oak ash, and hemp waste showed higher adsorption for F⁻, while pyritic material, pine bark, and sawdust had a higher affinity for Cr(VI). Considering the binary competitive system, a clear competition between both elements in anionic form is shown, with decreases in adsorption of up to 90% for Cr(VI), and of up to 30% for F⁻. Adsorption results showed better fitting to Freundlich’s than to Langmuir’s model. None of the individual soils or byproducts were able to adsorbing high percentages of both pollutants simultaneously, but it could be highly improved by adding pine bark to increase Cr(VI) adsorption in soils, thus drastically reducing the risks of pollution and deleterious effects on the environment and on public health. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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35 pages, 2750 KiB

Open AccessFeature PaperReview

Nitrogen Removal from Agricultural Subsurface Drainage by Surface-Flow Wetlands: Variability

by Lipe Renato Dantas Mendes

Processes 2021, 9(1), 156; https://doi.org/10.3390/pr9010156 - 15 Jan 2021

Cited by 8 | Viewed by 2754

Abstract

Agriculture has long been considered a great source of nitrogen (N) to surface waters and a major cause of eutrophication. Thus, management practices at the farm-scale have since attempted to mitigate the N losses, although often limited in tile-drained agricultural catchments, which speed [...] Read more.

Agriculture has long been considered a great source of nitrogen (N) to surface waters and a major cause of eutrophication. Thus, management practices at the farm-scale have since attempted to mitigate the N losses, although often limited in tile-drained agricultural catchments, which speed up the N transport, while minimizing natural removal in the landscape. In this context, surface-flow constructed wetlands (SFWs) have been particularly implemented as an edge-of-field strategy to intercept tile drains and reduce the N loads by re-establishing ecosystems services of previously drained water ponded areas. These systems collect the incoming water volumes in basins sufficiently large to prolong the hydraulic residence time to a degree where biogeochemical processes between the water, soil, sediments, plants, macro and microorganisms can mediate the removal of N. Despite their documented suitability, great intra and inter-variability in N treatment is still observed to date. Therefore, it is essential to thoroughly investigate the driving factors behind performance of SFWs, in order to support their successful implementation according to local catchment characteristics, and ensure compliance with N removal goals. This review contextualizes the aforementioned issue, and critically evaluates the influence of hydrochemistry, hydrology and biogeochemistry in the treatment of N by SFWs. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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24 pages, 380 KiB

Open AccessFeature PaperReview

Effective Heavy Metals Removal from Water Using Nanomaterials: A Review

by Mohamed A. Tahoon, Saifeldin M. Siddeeg, Norah Salem Alsaiari, Wissem Mnif and Faouzi Ben Rebah

Processes 2020, 8(6), 645; https://doi.org/10.3390/pr8060645 - 29 May 2020

Cited by 119 | Viewed by 13087

Abstract

The discharge of toxic heavy metals including zinc (Zn), nickel (Ni), lead (Pb), copper (Cu), chromium (Cr), and cadmium (Cd) in water above the permissible limits causes high threat to the surrounding environment. Because of their toxicity, heavy metals greatly affect the human [...] Read more.

The discharge of toxic heavy metals including zinc (Zn), nickel (Ni), lead (Pb), copper (Cu), chromium (Cr), and cadmium (Cd) in water above the permissible limits causes high threat to the surrounding environment. Because of their toxicity, heavy metals greatly affect the human health and the environment. Recently, better remediation techniques were offered using the nanotechnology and nanomaterials. The attentions were directed toward cost-effective and new fabricated nanomaterials for the application in water/wastewater remediation, such as zeolite, carbonaceous, polymer based, chitosan, ferrite, magnetic, metal oxide, bimetallic, metallic, etc. This review focused on the synthesis and capacity of various nanoadsorbent materials for the elimination of different toxic ions, with discussion of the effect of their functionalization on the adsorption capacity and separation process. Additionally, the effect of various experimental physicochemical factors on heavy metals adsorption, such as ionic strength, initial ion concentration, temperature, contact time, adsorbent dose, and pH was discussed. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

22 pages, 2193 KiB

Open AccessFeature PaperReview

Current Advances in Biofouling Mitigation in Membranes for Water Treatment: An Overview

by Daniela Pichardo-Romero, Zahirid Patricia Garcia-Arce, Alejandra Zavala-Ramírez and Roberto Castro-Muñoz

Processes 2020, 8(2), 182; https://doi.org/10.3390/pr8020182 - 5 Feb 2020

Cited by 127 | Viewed by 7799

Abstract

Membranes, as the primary tool in membrane separation techniques, tend to suffer external deposition of pollutants and microorganisms depending on the nature of the treating solutions. Such issues are well recognized as biofouling and is identified as the major drawback of pressure-driven membrane [...] Read more.

Membranes, as the primary tool in membrane separation techniques, tend to suffer external deposition of pollutants and microorganisms depending on the nature of the treating solutions. Such issues are well recognized as biofouling and is identified as the major drawback of pressure-driven membrane processes due to the influence of the separation performance of such membrane-based technologies. Herein, the aim of this review paper is to elucidate and discuss new insights on the ongoing development works at facing the biofouling phenomenon in membranes. This paper also provides an overview of the main strategies proposed by “membranologists” to improve the fouling resistance in membranes. Special attention has been paid to the fundamentals on membrane fouling as well as the relevant results in the framework of mitigating the issue. By analyzing the literature data and state-of-the-art, the concluding remarks and future trends in the field are given as well. Full article

(This article belongs to the Special Issue Gas, Water and Solid Waste Treatment Technology)

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