Impedance diagnostics is commonly employed in the study of transport phenomena in conducting media of different sizes. A common reason for choosing the more complex method of exciting the conductive medium at finite frequencies (
mode) instead of the relatively simple
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Impedance diagnostics is commonly employed in the study of transport phenomena in conducting media of different sizes. A common reason for choosing the more complex method of exciting the conductive medium at finite frequencies (
mode) instead of the relatively simple method of excitation at zero frequency (
mode) is to eliminate the influence of contact phenomena on the current–volt charateristic (IVC) during
measurements. In this paper, we analyze relaxation phenomena in electrolytes with linear electrohydrodynamics in terms of dopant density
. It is shown that the requirement of linearity on
of the electrohydrodynamics of dilute solutions cannot be satisfied by the Debye–Huckel–Onsager theory of electrolyte conductivity. A linear alternative based on the fundamental principles of the theory of transport in finely dispersed two-phase systems is proposed. This alternative is referred to in the literature as Maxwell’s formalism. It is noted that, in this case, there is a consistent possibility of treating the observed relaxation time,
, as impedance time
. Here,
R is the resistance of the dilute electrolyte part of the cell, and
C is the electrolytic capacitance of the same cell. This capacitance does not coincide with the traditional geometric one,
, and has to be calculated self-consistently. Examples of the successful application of
-consistent
diagnostics are discussed. This refers to the numerous instances in which the effective conductivity of various colloidal media deviates from the predictions of Maxwell’s well-known theory and to the correct interpretation of these anomalies in the RC representation.
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