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Batteries, Volume 4, Issue 3

2018 September - 18 articles

Cover Story: We investigate the olivine-type compounds currently used in positive electrodes in lithium-ion batteries. While intensive research has been devoted to LiFePO4, the other elements of the family have recently succeeded in significantly improving their electrochemical performance, so that some of them may now be applied in the battery industry. They constitute the current state-of-the-art and the progress that has been made recently on all the elements of the family and their solid solutions. View this paper.
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Articles (18)

  • Article
  • Open Access
57 Citations
14,168 Views
18 Pages

Enhancing the Cycle Life of a Zinc–Air Battery by Means of Electrolyte Additives and Zinc Surface Protection

  • Aroa R. Mainar,
  • Luis C. Colmenares,
  • Hans-Jürgen Grande and
  • J. Alberto Blázquez

13 September 2018

The commercialization of rechargeable alkaline zinc–air batteries (ZAB) requires advanced approaches to improve secondary zinc anode performance, which is hindered by the high corrosion and dissolution rate of zinc in this medium. Modified (wit...

  • Review
  • Open Access
51 Citations
16,504 Views
62 Pages

13 September 2018

Flow batteries (also: redox batteries or redox flow batteries RFB) are briefly introduced as systems for conversion and storage of electrical energy into chemical energy and back. Their place in the wide range of systems and processes for energy conv...

  • Article
  • Open Access
12 Citations
7,419 Views
8 Pages

12 September 2018

Over the past few years, the use of 18650 form factor lithium-ion (Li-ion) cells have transitioned from primarily commercial applications to consumer/residential use. An evaluation of eight commercially available, circuit protected, 18650 form factor...

  • Article
  • Open Access
16 Citations
9,311 Views
10 Pages

Investigating the Impact of Particle Size on the Performance and Internal Resistance of Aqueous Zinc Ion Batteries with a Manganese Sesquioxide Cathode

  • Christian Bischoff,
  • Oliver Fitz,
  • Christian Schiller,
  • Harald Gentischer,
  • Daniel Biro and
  • Hans-Martin Henning

11 September 2018

Aqueous zinc ion batteries are considered to be one of the most promising battery types for stationary energy storage applications. Due to their aqueous electrolyte, they are inherently safe concerning flammability and environmentally friendly. In th...

  • Article
  • Open Access
75 Citations
23,165 Views
22 Pages

10 September 2018

Currently, Li-ion cells are the preferred candidates as energy sources for existing portable applications and for those being developed. Thus, a proper characterization of Li-ion cells is required to optimize their use and their manufacturing process...

  • Article
  • Open Access
29 Citations
18,628 Views
11 Pages

3 September 2018

A novel chemical process has been developed to formulate injectable nickel ink for conductive film. This chemical method has the ability to remove the oxidation on nickel nano-particle surfaces during ink fabrication; the nickel ions, which are produ...

  • Article
  • Open Access
22 Citations
10,552 Views
14 Pages

The Effect of Sulfuric Acid Concentration on the Physical and Electrochemical Properties of Vanadyl Solutions

  • Jamie S. Lawton,
  • Sophia M. Tiano,
  • Daniel J. Donnelly,
  • Sean P. Flanagan and
  • Thomas M. Arruda

1 September 2018

The effects of sulfuric acid concentration in VO2+ solutions were investigated via electrochemical methods and electron paramagnetic resonance. The viscosity of solutions containing 0.01 M VOSO4 in 0.1–7.0 M H2SO4 was measured. Diffusion coeffi...

  • Article
  • Open Access
9 Citations
7,437 Views
23 Pages

A New Glass-Forming Electrolyte Based on Lithium Glycerolate

  • Gioele Pagot,
  • Sara Tonello,
  • Keti Vezzù and
  • Vito Di Noto

1 September 2018

The detailed study of the interplay between the physicochemical properties and the long-range charge migration mechanism of polymer electrolytes able to carry lithium ions is crucial in the development of next-generation lithium batteries. Glycerol e...

  • Review
  • Open Access
59 Citations
24,534 Views
32 Pages

Among the compounds of the olivine family, LiMPO4 with M = Fe, Mn, Ni, or Co, only LiFePO4 is currently used as the active element of positive electrodes in lithium-ion batteries. However, intensive research devoted to other elements of the family ha...

  • Article
  • Open Access
13 Citations
10,648 Views
14 Pages

An Experimental Setup with Alternating Current Capability for Evaluating Large Lithium-Ion Battery Cells

  • Rudi Soares,
  • Alexander Bessman,
  • Oskar Wallmark,
  • Göran Lindbergh and
  • Pontus Svens

In the majority of applications using lithium-ion batteries, batteries are exposed to some harmonic content apart from the main charging/discharging current. The understanding of the effects that alternating currents have on batteries requires specif...

  • Article
  • Open Access
25 Citations
14,900 Views
16 Pages

Processing of Advanced Battery Materials—Laser Cutting of Pure Lithium Metal Foils

  • Tobias Jansen,
  • David Blass,
  • Sven Hartwig and
  • Klaus Dilger

Due to the increasing demand for high-performance cells for mobile applications, the standards of the performance of active materials and the efficiency of cell production strategies are rising. One promising cell technology to fulfill the increasing...

  • Article
  • Open Access
48 Citations
12,466 Views
13 Pages

Frequency-dependent capacitance C(ω) is a rapid and reliable method for the determination of the state-of-charge (SoC) of electrochemical storage devices. The state-of-the-art of SoC monitoring using impedance spectroscopy is reviewed, and comp...

  • Article
  • Open Access
91 Citations
24,408 Views
19 Pages

Binding Energy Referencing for XPS in Alkali Metal-Based Battery Materials Research (II): Application to Complex Composite Electrodes

  • Steffen Oswald,
  • Franziska Thoss,
  • Martin Zier,
  • Martin Hoffmann,
  • Tony Jaumann,
  • Markus Herklotz,
  • Kristian Nikolowski,
  • Frieder Scheiba,
  • Michael Kohl and
  • Helmut Ehrenberg
  • + 2 authors

X-ray photoelectron spectroscopy (XPS) is a key method for studying (electro-)chemical changes in metal-ion battery electrode materials. In a recent publication, we pointed out a conflict in binding energy (BE) scale referencing at alkali metal sampl...

  • Article
  • Open Access
76 Citations
13,612 Views
18 Pages

Microbial fuel cells (MFCs) and microbial electrolysis cells (MECs) are promising bioelectrochemical systems (BESs) for simultaneous wastewater treatment and energy/resource recovery. Unlike conventional fuel cells that are based on stable chemical r...

  • Article
  • Open Access
19 Citations
9,355 Views
9 Pages

Because of an increasing interest in NaSICON materials as electrolyte materials in all-solid state sodium batteries, their thermal expansion was investigated in this study. The thermal expansion coefficient (CTE) of the Al and Y-substituted NaSICON c...

  • Article
  • Open Access
8 Citations
7,724 Views
12 Pages

Effect of La3+ Modification on the Electrochemical Performance of Na3V2(PO4)2F3

  • Nina V. Kosova,
  • Daria O. Rezepova and
  • Nicolas Montroussier

La3+ modification of Na3V2(PO4)2F3 was performed by the direct mechanochemically assisted solid-state synthesis of the Na3V2−xLax(PO4)2F3 compositions, and by the LaPO4 coating of the as-prepared Na3V2(PO4)2F3 via the precipitation method. It h...

  • Article
  • Open Access
5 Citations
6,931 Views
12 Pages

Comparison of Battery Architecture Dependability

  • Christophe Savard,
  • Pascal Venet,
  • Éric Niel,
  • Laurent Piétrac and
  • Ali Sari

This paper presents various solutions for organizing an accumulator battery. It examines three different architectures: series-parallel, parallel-series and C3C architecture, which spread the cell output current flux to three other cells. Alternative...

  • Article
  • Open Access
41 Citations
28,071 Views
25 Pages

Modularity-in-design of battery packs for electric vehicles (EVs) is crucial to offset their high manufacturing cost. However, inconsistencies in performance of EV battery packs can be introduced by various sources. Sources of variation affect their...

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Batteries - ISSN 2313-0105