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Magnetochemistry, Volume 9, Issue 6

2023 June - 23 articles

Cover Story: Co-based amorphous metal nanocomposites (MANCs) are a material of interest for future use in power electronics applications. Faulting and Mn partitioning behavior has been observed in these materials. To understand these behaviors, we performed first principle calculations to gain insights into the faulting and magnetic behaviors of these types of materials. We found that the faulting and magnetic behaviors are both susceptible to variation depending on the partitioning and percentage of Mn within a volume of Co, such that we can tailor these behaviors as necessary via controlling the Mn doping within these MANCs. View this paper
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Articles (23)

  • Article
  • Open Access
1 Citations
1,702 Views
14 Pages

Nonlinear Electromagnetic Properties of Thinfilm Nanocomposites (CoFeZr)x(MgF2)100−x

  • Evelina P. Domashevskaya,
  • Sergey A. Ivkov,
  • Pavel V. Seredin,
  • Dmitry L. Goloshchapov,
  • Konstantin A. Barkov,
  • Stanislav V. Ryabtsev,
  • Yrii G. Segal,
  • Alexander V. Sitnikov and
  • Elena A. Ganshina

The aim of this work is a comprehensive study of the effect of variable atomic composition and structural-phase state of (CoFeZr)x(MgF2)100−x nanocomposites (NCs) on their nonlinear electronic and magnetic/magneto-optical properties. Micrometer...

  • Article
  • Open Access
6 Citations
1,905 Views
12 Pages

The Organic Ammonium Counterion Effect on Slow Magnetic Relaxation of the [Er(hfac)4] Complexes

  • Tatiana G. Prokhorova,
  • Denis V. Korchagin,
  • Gennady V. Shilov,
  • Alexei I. Dmitriev,
  • Mikhail V. Zhidkov and
  • Eduard B. Yagubskii

The first mononuclear anionic erbium complex [Er(hfac)4] (hfac = hexafluoroacetylacetone) with an organic ammonium cation [(CH3)4N+] as the counterion was synthesized and structurally and magnetically characterized. The coordination geometries...

  • Feature Paper
  • Article
  • Open Access
6 Citations
3,265 Views
19 Pages

We present a micromagnetic investigation of the spin dynamics at remanence (zero applied field) in a periodic square artificial spin ice (ASI) prepared four different microstates (i.e., with zero, two or four magnetic charges at the vertex). The ASI...

  • Feature Paper
  • Article
  • Open Access
15 Citations
3,820 Views
14 Pages

Reduction of Oxidizable Pollutants in Waste Water from the Wadi El Bey River Basin Using Magnetic Nanoparticles as Removal Agents

  • Hajer Tlili,
  • Anis Elaoud,
  • Nedra Asses,
  • Karima Horchani-Naifer,
  • Mounir Ferhi,
  • Gerardo F. Goya and
  • Jesús Antonio Fuentes-García

Many of the current strategies for removing pollutants from water are based on nanomaterials and nanotechnology. Lower values of Biological Oxygen Demand (BOD5) and Chemical Oxygen Demand (COD) in water results in reduction in the amount of oxidizabl...

  • Review
  • Open Access
43 Citations
11,025 Views
39 Pages

Ferrites have excellent magnetic, electric, and optical properties that make them an indispensable choice of material for a plethora of applications, such as in various biomedical fields, magneto–optical displays, rechargeable lithium batteries...

  • Article
  • Open Access
4 Citations
2,955 Views
16 Pages

Spin Frustrated Pyrazolato Triangular CuII Complex: Structure and Magnetic Properties, an Overview

  • Walter Cañón-Mancisidor,
  • Patricio Hermosilla-Ibáñez,
  • Evgenia Spodine,
  • Verónica Paredes-García,
  • Carlos J. Gómez-García and
  • Diego Venegas-Yazigi

The synthesis and structural characterization of a new triangular Cu3–μ3OH pyrazolato complex of formula, [Cu33−OH)(pz)3(Hpz)3][BF4]2 (1−Cu3), Hpz = pyrazole, is presented. The triangular unit forms a quasi-isosceles triangl...

  • Article
  • Open Access
3 Citations
2,749 Views
17 Pages

A selection of dimeric Cu(II) complexes with bidentate N,N′ ligands with the general formula [Cu(L)(X)(μ-OH)]2·nH2O and [Cu(L)(μ-OH)]2X2·nH2O were magneto-structurally analyzed using the Density Functional Theory (DFT). A Br...

  • Feature Paper
  • Article
  • Open Access
6 Citations
3,810 Views
18 Pages

Band Structure Evolution during Reversible Interconversion between Dirac and Standard Fermions in Organic Charge-Transfer Salts

  • Ryuhei Oka,
  • Keishi Ohara,
  • Kensuke Konishi,
  • Ichiro Yamane,
  • Toshihiro Shimada and
  • Toshio Naito

Materials containing Dirac fermions (DFs) have been actively researched because they often alter electrical and magnetic properties in an unprecedented manner. Although many studies have suggested the transformation between standard fermions (SFs) an...

  • Article
  • Open Access
5 Citations
2,358 Views
9 Pages

Some Magnetic Properties and Magnetocaloric Effects in the High-Temperature Antiferromagnet YbCoC2

  • Denis Alexandrovich Salamatin,
  • Vladimir Nikolaevich Krasnorussky,
  • Mariya Viktorovna Magnitskaya,
  • Alexei Valeryevich Semeno,
  • Alexander Vladimirovich Bokov,
  • Atanas Velichkov,
  • Zbigniew Surowiec and
  • Anatoly Vasilyevich Tsvyashchenko

The YbCoC2 compound, which crystallizes in a base-centered orthorhombic unit cell in the Amm2 space group CeNiC2 structure, is unique among Yb-based compounds due to the highest magnetic ordering temperature of TN=27 K....

  • Article
  • Open Access
2,147 Views
11 Pages

The Adsorption Performance of Porous Activated Carbons Prepared from Iron (II) Precursors Precipitated on the Porous Carbon Matrix Thermolysis

  • Alexander Kalenskii,
  • Aleksey Ivanov,
  • Dmitriy Sevostyanov,
  • Alexander Zvekov and
  • Alexander Krechetov

The creation of new compounds featuring high adsorption and catalytic performance with magnetic properties of the material is one of the important fields of magnetochemistry. The typical synthetic schemes of magnetic carbonaceous adsorbents are rathe...

  • Article
  • Open Access
1,610 Views
7 Pages

Chemically altering molecules can have dramatic effects on the physical properties of a series of very similar molecular compounds. A good example of this is within the quasi-1D spin-Peierls system potassium TCNQ (TCNQ = 7,7,8,8-tetracyanoqunidimetha...

  • Feature Paper
  • Article
  • Open Access
4 Citations
3,521 Views
14 Pages

From Micro to Nano: Grinding Natural Magnetite Ore for Microalgae Harvesting

  • Michael Schobesberger,
  • Simone Helmhagen,
  • Stefan Mende,
  • Sonja Berensmeier and
  • Paula Fraga-García

Microalgae represent a promising feedstock for sustainable biomass and energy. The low cell concentration after cultivation, however, limits the current application fields. Magnetic microalgae harvesting is a recent approach to overcome the economic...

  • Review
  • Open Access
4 Citations
3,859 Views
16 Pages

Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields

  • Włodzimierz Makulski,
  • Mateusz A. Słowiński and
  • Piotr Garbacz

Nuclear magnetic resonance (NMR) is a branch of spectroscopy commonly used for identifying the chemical structure of various materials. One of the areas in which NMR provides accurate data is the determination of nuclear magnetic moments. This work r...

  • Feature Paper
  • Article
  • Open Access
4 Citations
2,149 Views
13 Pages

Substitution Effects in Spin-Polarized (Cr4-xFex)0.5AC (A = Ge, Si, Al) MAX Phases

  • Natalja A. Fedorova,
  • Alena V. Kovaleva,
  • Julia S. Olshevskaya,
  • Daria A. Ivanova,
  • Victoria V. Kozak,
  • Alexander A. Shubin,
  • Anton S. Tarasov,
  • Sergey N. Varnakov,
  • Sergei G. Ovchinnikov and
  • Felix N. Tomilin
  • + 3 authors

The use of spintronic devices with a tunable magnetic order on small scales is highly important for novel applications. The MAX phases containing transition metals and/or magnetic ion-substituted lattices attract a lot of attention. In this study, th...

  • Article
  • Open Access
3 Citations
2,359 Views
12 Pages

MnZn ferrite precursor powders were prepared by the nano in situ composite method. Three surfactants, which include polyethylene glycol 400 (PEG-400), cetyltrimethyl ammonium bromide (CTAB), and sodium dodecyl sulfate (SDS), were usedM and the impact...

  • Article
  • Open Access
2 Citations
3,116 Views
12 Pages

Soft magnetic composites (SMCs) are composed of alloy materials with the core and insulating layers as the shell. These composites exhibit high saturation magnetic sensitivity and low hysteresis loss, making them a promising material for various appl...

  • Article
  • Open Access
8 Citations
2,365 Views
12 Pages

Magnetism and Exchange Bias Properties in Ba2ScRuO6

  • Prachi Mohanty,
  • Sourav Marik and
  • Ravi Prakash Singh

This paper presents structural, detailed magnetic, and exchange bias studies in polycrystalline Ba2ScRuO6 synthesized at ambient pressure. In contrast to its strontium analogue, this material crystallizes in a 6L hexagonal structure with space group...

  • Article
  • Open Access
4 Citations
2,391 Views
17 Pages

Study of Dynamic Viscoelasticity of a Mineral Oil-Based Magnetic Fluid

  • Zhanxian Li,
  • Yifei Guo,
  • Hujun Wang,
  • Chengyao Deng,
  • Jiahao Dong,
  • Zhongru Song and
  • Zhenkun Li

Magnetic fluid is a field-responsive intelligent fluid, which has the flow characteristics of liquid and the elastic properties of solid. Because of its unique properties, it has a strong application prospect in the fields of magnetic soft robot, int...

  • Article
  • Open Access
4 Citations
2,058 Views
13 Pages

Magnetoelectric Coupling Effects in Tb-Doped BiFeO3 Nanoparticles

  • Iliana Apostolova,
  • Angel Apostolov and
  • Julia Wesselinowa

The magnetic, electric, and optical properties in Tb-doped BiFeO3 nanoparticles as functions of size and doping concentrations were investigated using a microscopic model, taking into account both linear and quadratic magnetoelectric (ME) coupling. W...

  • Article
  • Open Access
2,069 Views
17 Pages

Thermal Conductivity for p–(Bi, Sb)2Te3 Films of Topological Insulators

  • Lidia N. Lukyanova,
  • Yuri A. Boikov,
  • Oleg A. Usov,
  • Viacheslav A. Danilov,
  • Igor V. Makarenko and
  • Vasilii N. Petrov

In this study, we investigated the temperature dependencies of the total, crystal lattice, and electronic thermal conductivities in films of topological insulators p–Bi0.5Sb1.5Te3 and p–Bi2Te3 formed by discrete and thermal evaporation me...

  • Feature Paper
  • Article
  • Open Access
1 Citations
1,903 Views
13 Pages

Controlling the Magnetic Properties of La0.9A0.1Mn0.9Cr0.1O3 (A: Li, K, Na) Powders and Ceramics by Alkali Ions Doping

  • Paweł Głuchowski,
  • Ruslan Nikonkov,
  • Daniela Kujawa,
  • Wiesław Stręk,
  • Tomas Murauskas,
  • Andrius Pakalniškis,
  • Aivaras Kareiva,
  • Andrii Yaremkevych,
  • Olena Fesenko and
  • Dmitry Karpinsky
  • + 1 author

Nanocrystalline La0.9A0.1Mn0.9Cr0.1O3 (A: Li, K, Na) powders have been synthesized by combustion method. The powders were used to prepare ceramics by high-pressure low-temperature sintering technique. For all samples the structure, elemental composit...

  • Article
  • Open Access
5 Citations
3,351 Views
11 Pages

Hydrothermal Synthesis and Magnetic Properties of Zn/Mn Oxides Nano Particles

  • Izabela Kuryliszyn-Kudelska,
  • Witold Dobrowolski,
  • Monika Arciszewska,
  • Branka Hadžić,
  • Nebojsa Romčević,
  • Maja Romčević,
  • Daniel Sibera and
  • Urszula Narkiewicz

The aim of this study was to investigate the magnetic properties of mixed nanocrystalline Zn/manganese oxide compounds synthesized by a hydrothermal method. These compounds are designed as (ZnO)1−n(MnO)n, where index n ranges from 0.05 to 0.60....

  • Feature Paper
  • Article
  • Open Access
1 Citations
1,918 Views
19 Pages

Influence of Mn Doping on Local Spin Moments and Stacking Fault Energies in Co(Mn) Alloys

  • Kayla Cole-Piepke,
  • Prabandha Nakarmi,
  • Alicia Koenig,
  • Gregory B. Thompson,
  • Tim Mewes,
  • Claudia Mewes,
  • Ronald Noebe and
  • Alex Leary

We report on the results of first principles calculations investigating the influences of Mn doping on the local moments and stacking fault energies (SFEs) in the Co95.8Mn4.2 and Co91.6Mn8.4 systems as compared to pure face-centered cubic Co. A super...

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Magnetochemistry - ISSN 2312-7481