Table of Contents
Magnetochemistry, Volume 6, Issue 2 (June 2020) – 12 articles
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Cover Story (view full-size image) The single-molecule magnet (SMM) performances of phenanthroline dione (L)-based mononuclear [...] Read more. The single-molecule magnet (SMM) performances of phenanthroline dione (L)-based mononuclear complexes can be modulated by changing the β-diketonate ancillary ligand associated with the dysprosium center. Surprisingly, both experimental measurements and wavefunction theory calculations highlighted better SMM behavior for the [Dy(hfac)3(L)] compound than for [Dy(tta)3(L)], which might be due to the difference in dipolar interactions through σ–π interactions. View this paper