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ChemEngineering, Volume 6, Issue 4

2022 August - 20 articles

Cover Story: In this work, it was demonstrated that the application of the scCO2 to the recovery of oil from Japonica Luna rice bran not only eliminates the use of organic solvents in the process but achieves yields similar to that reported by n-hexane extraction. Two design of experiments (DoE) methods were successfully applied to optimize the scCO2 extraction process. In addition, three mathematical models based on differential mass balances were applied to simulate the experimental cumulative extraction yield curves obtained. View this paper
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Articles (20)

  • Feature Paper
  • Article
  • Open Access
10 Citations
2,961 Views
18 Pages

Preparation of Ca2Al1–mFem(OH)6Cl·2H2O-Doped Hydrocalumites and Application of Their Derived Mixed Oxides in the Photodegradation of Ibuprofen

  • Alejandro Jiménez,
  • Marta Valverde,
  • Alexander Misol,
  • Raquel Trujillano,
  • Antonio Gil and
  • Miguel Angel Vicente

Aluminum from saline slags generated during the recycling of this metal, extracted under reflux conditions with aqueous NaOH, was used in the synthesis of hydrocalumite-type solids with the formula Ca2Al1–mFem(OH)6Cl·2H2O. The characteri...

  • Feature Paper
  • Article
  • Open Access
7 Citations
3,038 Views
16 Pages

This study presents an optimization strategy for recovery of oil from Japonica Luna rice bran using supercritical carbon dioxide (scCO2), based on design of experiments (DoE). Initially, a 24−1 two level fractional factorial design (FFD) was us...

  • Article
  • Open Access
2 Citations
2,182 Views
12 Pages

Modeling of 1,2-Dibromoethane Biodegradation in Constant Electric Field

  • Petya Popova-Krumova,
  • Venko Beschkov,
  • Evgenia Vasileva and
  • Tsvetomila Parvanova-Mancheva

This study proposes a mathematical modeling approach for evaluating the effect of applying a permanent electric field on the biodegradation of 1,2-dibromoethane by bacterial cells of Bradyrhizobium japonicum 273. Two models for inhibited microbial gr...

  • Article
  • Open Access
3 Citations
3,181 Views
11 Pages

After subjecting Zamora building stones to accelerated ageing tests, colour changes were studied, namely: (a) freezing/thawing and thermal shock (gelifraction and thermoclasty), and (b) combination of freezing/thawing plus thermal shock and salt crys...

  • Feature Paper
  • Article
  • Open Access
10 Citations
4,198 Views
16 Pages

Hydrotalcite is the name of a mineral discovered in Sweden in 1842 whose formula is Mg6Al2(OH)16CO3·4H2O and presents a layered crystal structure that consists of positively charged hydroxide layers neutralized by interlayer anions as carbonat...

  • Article
  • Open Access
28 Citations
4,285 Views
13 Pages

Solubility of Rosmarinic Acid in Supercritical Carbon Dioxide Extraction from Orthosiphon stamineus Leaves

  • Ahmad Hazim Abdul Aziz,
  • Nor Faadila Mohd Idrus,
  • Nicky Rahmana Putra,
  • Mohd Azrie Awang,
  • Zuhaili Idham,
  • Hasmadi Mamat and
  • Mohd Azizi Che Yunus

Rosmarinic acid (RA) is present in a broad variety of plants, including those in the Lamiaceae family, and has a wide range of pharmacological effects, particularly antioxidant activity. To extract RA from Orthosiphon stamineus (OS) leaves, a Lamiace...

  • Review
  • Open Access
81 Citations
8,506 Views
33 Pages

Current Trends in the Utilization of Photolysis and Photocatalysis Treatment Processes for the Remediation of Dye Wastewater: A Short Review

  • S M Anisuzzaman,
  • Collin G. Joseph,
  • Chuan Kian Pang,
  • Nur Ammarah Affandi,
  • Sitti Nurazida Maruja and
  • Veena Vijayan

Development in the textile industry leads to an increased demand for the use of various dyes. Moreover, there is the use of some dyes in the food industry as well as medical diagnostics. Thereby, increased demand for dyes in various fields has result...

  • Article
  • Open Access
5 Citations
2,807 Views
13 Pages

Acid-Modified Clays for the Catalytic Obtention of 5-Hydroxymethylfurfural from Glucose

  • Vladimir Sánchez,
  • María Dolores González,
  • Pilar Salagre and
  • Yolanda Cesteros

5-hydroxymethylfurfural (5-HMF) is an important platform molecule for the synthesis of high-added value products. Several synthesized clay materials, such as mesoporous hectorite and fluorohectorite, in addition to commercial montmorillonite K-10, ha...

  • Article
  • Open Access
2 Citations
4,940 Views
13 Pages

A Hill Equation for Solid Specific Heat Capacity Calculation

  • Scott C. Rowe,
  • Boris A. Chubukov and
  • John C. Telotte

The Hill Equation and Hill Coefficient have been used extensively in biochemistry for the description of noncovalent binding. Previously, the Hill Coefficient was correlated with the Gibbs free energy, which suggests that the Hill Equation might be e...

  • Article
  • Open Access
4 Citations
3,429 Views
22 Pages

Photodegradation of Fipronil by Zn-AlPO4 Materials Synthesized by Non-Hydrolytic Sol–Gel Method

  • Omar José de Lima,
  • Denis Talarico de Araújo,
  • Liziane Marçal,
  • Antonio Eduardo Miller Crotti,
  • Guilherme Sippel Machado,
  • Shirley Nakagaki,
  • Emerson Henrique de Faria and
  • Katia Jorge Ciuffi

In recent decades, the increasing use of pesticides to improve food productivity has led to the release of effluents that contaminate the environment. To prepare a material that may help to treat effluents generated during agricultural practice, we u...

  • Article
  • Open Access
4 Citations
3,042 Views
11 Pages

Nanoparticle Black Ceramic Pigment Obtained by Hydrotalcite-like Compound Microwave Treatment

  • María Oset,
  • Alejandro Moya,
  • Guillermo Paulo-Redondo and
  • Isaac Nebot-Díaz

Development of ceramic pigments with controlled particle sizes below 1 µm is essential for the preparation of ceramic inks used in inkjet digital decoration that is currently being applied in the ceramics sector. A black ceramic pigment based o...

  • Article
  • Open Access
4 Citations
5,564 Views
19 Pages

Amines with two carbon atoms in the organic chain [ethylamine (EA), diethylamine (DEA), triethylamine (TEA)] have been used as precipitant agents to obtain a hydrotalcite-like compound with Zn (II) and Al (III) as layered cations and with nitrate ani...

  • Article
  • Open Access
8 Citations
5,306 Views
11 Pages

The developing significance of adsorption has brought about a steadily expanding quantity of logical and innovative writing on different adsorbents. This paper intends to propose experimental and computational methods for measuring the strength of ad...

  • Review
  • Open Access
20 Citations
5,419 Views
25 Pages

An Overview on the Recent Advances in Alternative Solvents as Stabilizers of Proteins and Enzymes

  • Jéssica S. Almeida,
  • Emanuel V. Capela,
  • Ana M. Loureiro,
  • Ana P. M. Tavares and
  • Mara G. Freire

Currently, the use of alternative solvents is increasing, namely ionic liquids (ILs) and deep eutectic solvents (DESs) in diverse fields of knowledge, such as biochemistry, chemistry, chemical engineering, biotechnology and biomedicine. Particularly,...

  • Review
  • Open Access
14 Citations
6,915 Views
18 Pages

Review of the Application of Hydrotalcite as CO2 Sinks for Climate Change Mitigation

  • David Suescum-Morales,
  • José Ramón Jiménez and
  • José María Fernández-Rodríguez

In recent decades, the environmental impact caused by greenhouse gases, especially CO2, has driven many countries to reduce the concentration of these gases. The study and development of new designs that maximise the efficiency of CO2 capture continu...

  • Article
  • Open Access
3 Citations
3,559 Views
11 Pages

Graphene-Wine Waste Derived Carbon Composites for Advanced Supercapacitors

  • Violeta Ureña-Torres,
  • Gelines Moreno-Fernández,
  • Juan Luis Gómez-Urbano,
  • Miguel Granados-Moreno and
  • Daniel Carriazo

In this work, we investigate the potential of a novel carbon composite as an electrode for high-voltage electrochemical double-layer capacitors. The carbon composite was prepared following a sustainable synthetic approach that first involved the pyro...

  • Article
  • Open Access
1 Citations
2,595 Views
16 Pages

Experimental Study and Numerical Simulation of Hydrodynamic Parameters of Tangential Swirlers

  • Nikolai A. Voinov,
  • Alexander S. Frolov,
  • Anastasiya V. Bogatkova and
  • Denis A. Zemtsov

This paper presents and patents new profiled- and annular-channel tangential swirlers with 1.8–3 times less hydraulic drag coefficient compared to swirlers with straight channel walls at the same flow rate, respectively. The results of numerica...

  • Article
  • Open Access
11 Citations
4,478 Views
20 Pages

Hydrogen and CNT Production by Methane Cracking Using Ni–Cu and Co–Cu Catalysts Supported on Argan-Derived Carbon

  • Fernando Cazaña,
  • Zainab Afailal,
  • Miguel González-Martín,
  • José Luis Sánchez,
  • Nieves Latorre,
  • Eva Romeo,
  • Jesús Arauzo and
  • Antonio Monzón

The 21st century arrived with global growth of energy demand caused by population and standard of living increases. In this context, a suitable alternative to produce COx-free H2 is the catalytic decomposition of methane (CDM), which also allows for...

  • Article
  • Open Access
1 Citations
2,515 Views
12 Pages

Combustible carbon-based energy is still prevailing as the world’s leading energy due to its high energy density. However, the oxidation of these hydrocarbons disturbs the natural carbon cycle greatly by increasing greenhouse gases. As emission...

  • Review
  • Open Access
17 Citations
5,608 Views
44 Pages

The synthesis and applications of composites based on layered double hydroxides (LDHs) and nanocarbons have recently seen great development. On the one hand, LDHs are versatile 2D compounds that present a plethora of applications, from medicine to en...

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ChemEngineering - ISSN 2305-7084