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Inorganics, Volume 13, Issue 6

June 2025 - 33 articles

Cover Story: Pterin-fused phenanthroline (PteN˄N) ligands are notoriously insoluble, limiting their use in coordination chemistry. In this study, a mechanochemical approach enabled the selective synthesis of heteroleptic [Cu(PteN˄N)(P˄P)][BF4] complexes with bisphosphine co-ligands. Unlike traditional solution methods, solid-state grinding overcame solubility barriers and delivered stable, well-defined complexes. Remarkably, the transformation into copper complexes greatly enhanced solubility, enabling comprehensive spectroscopic and spectrometric characterization. While photophysical performance was modest, this work demonstrates the power of mechanochemistry to access challenging ligand frameworks and sets the stage for future development of photoactive materials. View this paper
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Articles (33)

  • Article
  • Open Access
1 Citations
704 Views
9 Pages

Reversible Sodium Storage of CoTe2 Anode via Lanthanum Doping

  • Haonan Xie,
  • Xiaolin Xie,
  • Taijiao Guo and
  • Ting Deng

Cobalt telluride (CoTe2) is considered an advanced anode material for sodium-ion batteries (SIBs) because of its high theoretical capacity and high conductivity. Nevertheless, the ionic radius of the Co2+ ion (0.74 Å) is smaller than that of th...

  • Article
  • Open Access
862 Views
19 Pages

Exploring the Impact of Bi Content in Nanostructured Pd-Bi Catalysts Used for Selective Oxidation of Glucose: Synthesis, Characterization and Catalytic Properties

  • Mariya P. Shcherbakova-Sandu,
  • Semyon A. Gulevich,
  • Eugene P. Meshcheryakov,
  • Kseniya I. Kazantseva,
  • Aleksandr V. Chernyavskii,
  • Alexey N. Pestryakov,
  • Ajay K. Kushwaha,
  • Ritunesh Kumar,
  • Akshay K. Sonwane and
  • Sonali Samal
  • + 1 author

This work is devoted to the study of the effect of small Bi additives on the functional properties of Pdx:Bi/Al2O3 catalysts in the selective oxidation of glucose to gluconic acid. The catalysts obtained by the joint impregnation method were characte...

  • Article
  • Open Access
719 Views
9 Pages

The polycondensation of silica from soluble silicic acid is at the basis of several chemical processes. The usual industrial route requires harsh pH conditions and high concentrations of the precursor molecules, not to mention a thermal treatment for...

  • Article
  • Open Access
1 Citations
642 Views
17 Pages

In Vitro Evaluation of Silver-NHC Complexes Against a Clinical Isolate of Acanthamoeba castellanii: Time- and Dose-Dependent Effects

  • Zübeyda Akın-Polat,
  • Neslihan Şahin,
  • Shaima Hkiri,
  • Bui Minh Thu Ly,
  • İsmail Özdemir and
  • David Sémeril

The synthesis of a series of six chloro[N-alkyl-N-cinnamyl-benzimidazol-2-yliden]silver(I) complexes was successfully achieved, wherein allyl (3a), methoxymethyl (3b), benzyl (3c), 3-fluorobenzyl (3d), 4-fluorobenzyl (3e) and 4-methyl-benzyl (3f) sub...

  • Article
  • Open Access
1 Citations
951 Views
18 Pages

Exploring Layered Ruddlesden-Popper Structures for High-Performance Energy Devices

  • Ahmad Hussain,
  • Sumaira Zafar,
  • Nawishta Jabeen,
  • Muhammad Usman Khan,
  • Imtiaz Ahmad Khan and
  • Mahmoud M. Hessien

This study presents comprehensive DFT calculations to determine the structural, electronic, mechanical, and optical properties of the Ruddlesden–Popper Phase family member, La2XO4, which has an orthorhombic crystal structure with a Cmce space g...

  • Communication
  • Open Access
576 Views
15 Pages

Polarized Small-Angle Neutron Scattering is a versatile low-energy neutron scattering technique that allows for the access of magnetic information on nanosize objects of size 2–100 nm, from individual properties like the magnetization distribut...

  • Article
  • Open Access
1,113 Views
13 Pages

Titanium nitride (TiN) is a typical inorganic compound capable of achieving resistance modulation by adjusting the element ratio. In this work, to deeply investigate the resistance-tunable characteristics and electron emission properties of TiN, we p...

  • Article
  • Open Access
1,497 Views
14 Pages

Synergistic Enhancement of Near-Infrared Electrochromic Performance in W18O49 Nanowire Thin Films via Copper Doping and Langmuir–Blodgett Assembly

  • Yueyang Wu,
  • Honglong Ning,
  • Ruiqi Luo,
  • Muyun Li,
  • Zijian Zhang,
  • Rouqian Huang,
  • Junjie Wang,
  • Mingyue Peng,
  • Runjie Zhuo and
  • Rihui Yao
  • + 1 author

The development of high-performance electrochromic materials demands innovative approaches to simultaneously control the nanoscale architecture and the electronic structure. We present a dual-modification strategy that synergistically combines copper...

  • Article
  • Open Access
905 Views
13 Pages

It is found that Mo doping can enhance the supercapacitor performance of VS2 microflowers. The X-ray diffraction combined with energy dispersive X-ray, X-ray photoelectron spectroscopy, and Raman spectra results verify the successful doping of Mo ato...

  • Article
  • Open Access
1 Citations
1,397 Views
24 Pages

DNA Binding with Dipyrromethene Ruthenium(II) Complexes

  • Maria Isabel Murillo,
  • Carlos Felipe Mejia,
  • Andrés Restrepo-Acevedo,
  • Benjamin Barraud,
  • Adrian L. Orjuela,
  • Marcos Flores-Alamo,
  • Rubén A. Toscano,
  • Jorge Alí-Torres,
  • Alexander D. Ryabov and
  • Ronan Le Lagadec

Four new arene–ruthenium(II) complexes [(η6-p-cymene)RuCl(dpm)], where dpm are hexa-(L3–L5) and meso-substituted (L6) dipyrromethene ligands, were synthesized. These ligands and the corresponding complexes were thoroughly characterize...

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Inorganics - ISSN 2304-6740