Ammonium nitrate (NH
4NO
3) is a major constituent of fine particulate matter (PM
2.5), playing a critical role in air quality and atmospheric chemistry. However, the dual regulatory role of ammonia (NH
3) in both the formation and
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Ammonium nitrate (NH
4NO
3) is a major constituent of fine particulate matter (PM
2.5), playing a critical role in air quality and atmospheric chemistry. However, the dual regulatory role of ammonia (NH
3) in both the formation and volatilization of NH
4NO
3 under ambient atmospheric conditions remains inadequately understood. To address this gap, we conducted high-resolution field measurements at a clean tropical coastal site in China using an integrated system of Aerosol Ion Monitor-Ion Chromatography, a Scanning Mobility Particle Sizer, and online OC/EC analyzers. These observations were complemented by thermodynamic modeling (E-AIM) and source apportionment via a Positive Matrix Factorization (PMF) model. The E-AIM simulations revealed persistent thermodynamic disequilibrium, with particulate NO
3− tending to volatilize even under NH
3gas-rich conditions during the northeast monsoon. This suggests that NH
4NO
3 in PM
2.5 forms rapidly within fresh combustion plumes and/or those modified by non-precipitation clouds and then undergoes substantial evaporation as it disperses through the atmosphere. Under the southeast monsoon conditions, reactions constrained by sea salt aerosols became dominant, promoting the formation of particulate NO
3− while suppressing NH
4NO
3 formation despite ongoing plume influence. In scenarios of regional accumulation, elevated NH
3 concentrations suppressed NH
4NO
3 volatilization, thereby enhancing the stability of particulate NO
3− in PM
2.5. PMF analysis identified five source factors, with NO
3− in PM
2.5 primarily associated with emissions from local power plants and the large-scale regional background, showing marked seasonal variability. These findings highlight the complex and dynamic interplay between the formation and evaporation of NH
4NO
3 in NH
3gas-rich coastal atmospheres.
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