Process Modeling and Risk Assessment of Ammonia and Hydrogen Storage and Transport Systems

A Special Issue of Processes (ISSN 2227-9717) belonging to the section "Process Control, Modeling and Optimization".

Deadline for manuscript submissions: 25 October 2026 | Viewed by 792

Editors


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Guest Editor
College of Chemical Engineering, Fuzhou University, Fuzhou 350108, China
Interests: ammonia–hydrogen storage and transportation technology and equipment; safe pipeline transportation technology for liquid ammonia; multiphase pipeline flow technology for oil, gas and water

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Guest Editor
College of Energy Storage Technology, Shandong University of Science and Technology, Qingdao 266590, China
Interests: liquid hydrogen storage and transportation; SOFC system hydrogen electric power supply process; offshore FLNG; low-temperature liquefaction energy storage

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Guest Editor
College of Storage & Transportation and Architectural Engineering, China University of Petroleum (Huadong), Dongying 257099, China
Interests: basic theory and engineering application of structural safety for oil and gas pipelines and new energy pipelines

Special Issue Information

Dear Colleagues,

Ammonia and hydrogen are seen as important energy carriers for a low-carbon future. They offer promising ways to store renewable energy for a long time and transport it over long distances. However, for them to be widely used, we need storage and transport systems that are safe, efficient, and affordable. Hydrogen has a low energy density by volume, so it usually requires high-pressure compression (350–700 bar) or cooling down to very low temperatures (−253 °C). Ammonia is easier to turn into a liquid, but it is toxic, corrosive, and flammable. Process modeling is a practical and cost-effective way to simulate how these systems behave—looking at things like flow, heat transfer, phase changes, and how the system responds to normal or unexpected conditions. At the same time, standard risk assessment methods—such as quantitative risk analysis (QRA), consequence modeling, and hazard reviews like HAZOP and LOPA—help us understand what could go wrong, including leaks, dispersion, fires, explosions, and domino effects. By combining process modeling with risk assessment, engineers can better design systems, set up safety measures, decide on safe distances, and plan emergency responses. This helps speed up the deployment of ammonia and hydrogen infrastructure.

This Special Issue on “Process Modeling and Risk Assessment of Ammonia and Hydrogen Storage and Transport Systems” seeks high quality works focusing on the development and application of modeling and risk-based approaches to address safety, reliability, and performance challenges across the entire value chain. Topics include, but are not limited to:

  • Dynamic simulation of ammonia and hydrogen storage and transportation systems;
  • CFD modeling of accidental releases, dispersion, jet fires, vapor cloud explosions, and toxic dispersion of ammonia and hydrogen;
  • Hydrogen embrittlement and material compatibility in storage and transport components;
  • Process safety of liquid ammonia and liquid hydrogen storage and transportation system;
  • Process design and optimization of ammonia decomposition hydrogen production and storage system;
  • Quantitative risk assessment (QRA) and consequence analysis for storage facilities, refueling stations, pipelines, and transport vehicles;
  • Safety zoning, mitigation strategies, and emergency response planning based on probabilistic risk metrics.

Thank you and we look forward to your contributions.

Dr. Pengbo Yin
Dr. Chongzheng Sun
Dr. Ying Zhen
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-anonymized peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Processes is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • ammonia storage and transportation
  • hydrogen storage and transportation
  • process modeling
  • risk assessment
  • cryogenic storage
  • CFD simulation
  • hydrogen embrittlement
  • quantitative risk assessment (QRA)
  • process safety
  • ammonia decomposition

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Published Papers (1 paper)

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Research

23 pages, 6843 KB  
Article
Simulation of Purging and Injection in Long-Distance Liquid Ammonia Pipeline Commissioning Process
by Pengbo Yin, Bo Wang, Peiyan Zeng, Wen Yang, Junwen Chen, Zhenchao Li, Weidong Li, Jiaqing Li, Lin Teng and Lilong Jiang
Processes 2026, 14(12), 2008; https://doi.org/10.3390/pr14122008 - 20 Jun 2026
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Abstract
With the expansion of ammonia energy applications, long-distance liquid ammonia pipelines are expected to support large-scale cross-regional ammonia transport. In the liquid ammonia pipeline commissioning process, gaseous ammonia purging involves ammonia–nitrogen mixing and possible liquefaction, while liquid ammonia injection may induce flashing and [...] Read more.
With the expansion of ammonia energy applications, long-distance liquid ammonia pipelines are expected to support large-scale cross-regional ammonia transport. In the liquid ammonia pipeline commissioning process, gaseous ammonia purging involves ammonia–nitrogen mixing and possible liquefaction, while liquid ammonia injection may induce flashing and severe local cooling, all of which can affect commissioning safety. To characterize these thermodynamic phenomena, a transient gas–liquid two-phase flow model was established and validated using OLGA 2022.1.0 software for simulating the long-distance liquid ammonia pipeline commissioning. The model adopts the cross-sectionally averaged one-dimensional approach. A volume-corrected Soave–Redlich–Kwong (SRK) equation of state for ammonia was adapted, validated, and used to generate OLGA-compatible thermodynamic property tables. The results show that, during gaseous ammonia purging, a higher flowrate shortens the displacement time by accelerating nitrogen removal, and this effect is more pronounced at higher ambient temperatures due to enhanced molecular diffusion. Along the pipeline, pressure gradually decreases from frictional resistance, with a steeper drop near the outlet caused by gas acceleration, and temperature gradually approaches ambient through heat exchange with the pipe wall and surrounding soil. A high gaseous ammonia flowrate can cause partial liquefaction, regasification, and temperature fluctuations. During liquid ammonia injection, local condensation and slight liquid accumulation occur before the liquid front arrives, and the low-temperature region moves with the liquid front. The liquid ammonia mass flowrate has the strongest influence on the injection process, as it reduces the completion time but increases the outlet temperature, outlet pressure, and the low-temperature risk downstream of the valve. Therefore, it should be controlled within an appropriate range to balance efficiency and low-temperature safety risks. This work provides a rapid and efficient prediction model for key thermo-hydraulic parameters during liquid ammonia pipeline commissioning, and the overall analyses offer insights for on-site process design and safety control. Full article
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