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Magnetochemistry, Volume 6, Issue 1

2020 March - 16 articles

Cover Story: A possibility of the intramolecular ferromagnetic interaction in pyrazole-bridged dinuclear metal complexes was examined through DFT calculations. The antiferromagnetic interaction becomes very weak when acetate-bridging ligand is used. In the acetate-bridged complexes, an energy split of the frontier orbitals suggests the orbital counter-complementarity effect between the dxy orbital pair, which contributes to the ferromagnetic interaction; however, a significant overlap of other d-orbital pairs avoids the ferromagnetic interaction. In conclusion, the orbital counter-complementarity effect by the acetate-bridging ligand competes with the overlap of other d-orbital pairs. View this paper.
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Articles (16)

  • Article
  • Open Access
5 Citations
5,625 Views
13 Pages

Structural Characterization of the S-glycosylated Bacteriocin ASM1 from Lactobacillus plantarum

  • Alexander K. Goroncy,
  • Trevor S. Loo,
  • Adrian M. Koolaard,
  • Mark L. Patchett and
  • Gillian E. Norris

In order to protect their environmental niche, most bacteria secret antimicrobial substances designed to target specific bacterial strains that are often closely related to the producer strain. Bacteriocins, small, ribosomally synthesised antimicrobi...

  • Review
  • Open Access
89 Citations
9,947 Views
22 Pages

Nano-Structured Dilute Magnetic Semiconductors for Efficient Spintronics at Room Temperature

  • Akanksha Gupta,
  • Rui Zhang,
  • Pramod Kumar,
  • Vinod Kumar and
  • Anup Kumar

In recent years, many efforts have been made to develop advanced metal oxide semiconductor nanomaterials with exotic magnetic properties for modern applications w.r.t traditional analogues. Dilute magnetic semiconductor oxides (DMSOs) are promising c...

  • Article
  • Open Access
35 Citations
5,449 Views
9 Pages

Effect of Terbium Ion Substitution in Inverse Spinel Nickel Ferrite: Structural and Magnetic Study

  • Deepa Guragain,
  • Binod Kumar Rai,
  • Sunghyun Yoon,
  • Tej Prasad Poudel,
  • Subash Chandra Bhandari and
  • Sanjay R Mishra

Doping rare-earth ions into spinel ferrites can alter their electrical and magnetic properties. The present study delineates the structure–property relationship of the effect of rare-earth terbium doping in NiFe2O4 ferrite. X-ray diffraction an...

  • Review
  • Open Access
21 Citations
5,610 Views
10 Pages

Drug formulations and suitable methods for their detection play a very crucial role in the development of therapeutics towards degenerative neurological diseases. For diseases such as Alzheimer’s disease, magnetic resonance imaging (MRI) is a n...

  • Article
  • Open Access
4 Citations
3,844 Views
8 Pages

The incorporation of the natural amino acid L-proline in the synthesis to vanadium-chromium Prussian blue derivatives results in materials exhibiting magnetic ordering including chiral magnetic centers. Although the amorphous nature of these material...

  • Review
  • Open Access
67 Citations
7,430 Views
12 Pages

Relaxivity r2 and thus the contrast efficacy of superparamagnetic nanoparticles (NPs) can be enhanced via either NP’s magnetic properties or coating optimization. Numerous reports can be found about the investigation of the optimal iron oxide n...

  • Article
  • Open Access
4 Citations
3,636 Views
9 Pages

A possibility of the intramolecular ferromagnetic (FM) interaction in pyrazole-bridged dinuclear Mn(II), Fe(II), Co(II), and Ni(II) complexes is examined by density functional theory (DFT) calculations. When azide is used for additional bridging liga...

  • Article
  • Open Access
5 Citations
3,362 Views
12 Pages

The effects of substitution of Zr and Ga on the structural and magnetic properties of Dy2Fe17 intermetallic compound were investigated in this study. The Rietveld analysis confirmed that the crystalline system was a Th2Ni17 structure. Lattice paramet...

  • Article
  • Open Access
9 Citations
4,582 Views
20 Pages

Design, Characterization and Molecular Modeling of New Fluorinated Paramagnetic Contrast Agents for Dual 1H/19F MRI

  • Emilie Hequet,
  • Céline Henoumont,
  • Vera Djouana Kenfack,
  • Vincent Lemaur,
  • Roberto Lazzaroni,
  • Sébastien Boutry,
  • Luce Vander Elst,
  • Robert N. Muller and
  • Sophie Laurent

One major goal in medical imaging is the elaboration of more efficient contrast agents (CAs). Those agents need to be optimized for the detection of affected tissues such as cancers or tumors while decreasing the injected quantity of agents. The para...

  • Perspective
  • Open Access
22 Citations
6,293 Views
12 Pages

The 1884 suggestion of Pierre Curie (1859–1906) that the type of dissymmetry shown by collinear electric and magnetic fields may induce an enantiomeric excess, in a chemical reaction that would otherwise produce a racemic mixture, is explored i...

  • Review
  • Open Access
37 Citations
7,455 Views
27 Pages

Hybrid Nanostructured Magnetite Nanoparticles: From Bio-Detection and Theragnostics to Regenerative Medicine

  • Yolanda Piñeiro,
  • Manuel González Gómez,
  • Lisandra de Castro Alves,
  • Angela Arnosa Prieto,
  • Pelayo García Acevedo,
  • Román Seco Gudiña,
  • Julieta Puig,
  • Carmen Teijeiro,
  • Susana Yáñez Vilar and
  • José Rivas

Nanotechnology offers the possibility of operating on the same scale length at which biological processes occur, allowing to interfere, manipulate or study cellular events in disease or healthy conditions. The development of hybrid nanostructured mat...

  • Feature Paper
  • Review
  • Open Access
99 Citations
13,422 Views
36 Pages

Magnetic Nanoparticle Systems for Nanomedicine—A Materials Science Perspective

  • Vlad Socoliuc,
  • Davide Peddis,
  • Viktor I. Petrenko,
  • Mikhail V. Avdeev,
  • Daniela Susan-Resiga,
  • Tamas Szabó,
  • Rodica Turcu,
  • Etelka Tombácz and
  • Ladislau Vékás

Iron oxide nanoparticles are the basic components of the most promising magneto-responsive systems for nanomedicine, ranging from drug delivery and imaging to hyperthermia cancer treatment, as well as to rapid point-of-care diagnostic systems with ma...

  • Article
  • Open Access
9 Citations
4,578 Views
7 Pages

Magnetoelectrochemistry and Asymmetric Electrochemical Reactions

  • Suryakant Mishra,
  • Marzia di Marzio,
  • Roberto Giovanardi and
  • Francesco Tassinari

Magnetoelectrochemistry is a branch of electrochemistry where magnetic fields play a vital role in the oxidation and reduction process of the molecules. When it comes to spin-dependent electrochemistry (SDE), becomes a new paradigm. This work present...

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Magnetochemistry - ISSN 2312-7481