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Magnetochemistry, Volume 6, Issue 1

March 2020 - 16 articles

Cover Story: A possibility of the intramolecular ferromagnetic interaction in pyrazole-bridged dinuclear metal complexes was examined through DFT calculations. The antiferromagnetic interaction becomes very weak when acetate-bridging ligand is used. In the acetate-bridged complexes, an energy split of the frontier orbitals suggests the orbital counter-complementarity effect between the dxy orbital pair, which contributes to the ferromagnetic interaction; however, a significant overlap of other d-orbital pairs avoids the ferromagnetic interaction. In conclusion, the orbital counter-complementarity effect by the acetate-bridging ligand competes with the overlap of other d-orbital pairs. View this paper.
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Articles (16)

  • Article
  • Open Access
5 Citations
5,506 Views
13 Pages

Structural Characterization of the S-glycosylated Bacteriocin ASM1 from Lactobacillus plantarum

  • Alexander K. Goroncy,
  • Trevor S. Loo,
  • Adrian M. Koolaard,
  • Mark L. Patchett and
  • Gillian E. Norris

In order to protect their environmental niche, most bacteria secret antimicrobial substances designed to target specific bacterial strains that are often closely related to the producer strain. Bacteriocins, small, ribosomally synthesised antimicrobi...

  • Review
  • Open Access
88 Citations
9,635 Views
22 Pages

Nano-Structured Dilute Magnetic Semiconductors for Efficient Spintronics at Room Temperature

  • Akanksha Gupta,
  • Rui Zhang,
  • Pramod Kumar,
  • Vinod Kumar and
  • Anup Kumar

In recent years, many efforts have been made to develop advanced metal oxide semiconductor nanomaterials with exotic magnetic properties for modern applications w.r.t traditional analogues. Dilute magnetic semiconductor oxides (DMSOs) are promising c...

  • Article
  • Open Access
35 Citations
5,246 Views
9 Pages

Effect of Terbium Ion Substitution in Inverse Spinel Nickel Ferrite: Structural and Magnetic Study

  • Deepa Guragain,
  • Binod Kumar Rai,
  • Sunghyun Yoon,
  • Tej Prasad Poudel,
  • Subash Chandra Bhandari and
  • Sanjay R Mishra

Doping rare-earth ions into spinel ferrites can alter their electrical and magnetic properties. The present study delineates the structure–property relationship of the effect of rare-earth terbium doping in NiFe2O4 ferrite. X-ray diffraction an...

  • Review
  • Open Access
20 Citations
5,379 Views
10 Pages

Drug formulations and suitable methods for their detection play a very crucial role in the development of therapeutics towards degenerative neurological diseases. For diseases such as Alzheimer’s disease, magnetic resonance imaging (MRI) is a n...

  • Article
  • Open Access
4 Citations
3,754 Views
8 Pages

The incorporation of the natural amino acid L-proline in the synthesis to vanadium-chromium Prussian blue derivatives results in materials exhibiting magnetic ordering including chiral magnetic centers. Although the amorphous nature of these material...

  • Review
  • Open Access
66 Citations
7,086 Views
12 Pages

Relaxivity r2 and thus the contrast efficacy of superparamagnetic nanoparticles (NPs) can be enhanced via either NP’s magnetic properties or coating optimization. Numerous reports can be found about the investigation of the optimal iron oxide n...

  • Article
  • Open Access
4 Citations
3,580 Views
9 Pages

A possibility of the intramolecular ferromagnetic (FM) interaction in pyrazole-bridged dinuclear Mn(II), Fe(II), Co(II), and Ni(II) complexes is examined by density functional theory (DFT) calculations. When azide is used for additional bridging liga...

  • Article
  • Open Access
5 Citations
3,291 Views
12 Pages

The effects of substitution of Zr and Ga on the structural and magnetic properties of Dy2Fe17 intermetallic compound were investigated in this study. The Rietveld analysis confirmed that the crystalline system was a Th2Ni17 structure. Lattice paramet...

  • Article
  • Open Access
9 Citations
4,497 Views
20 Pages

Design, Characterization and Molecular Modeling of New Fluorinated Paramagnetic Contrast Agents for Dual 1H/19F MRI

  • Emilie Hequet,
  • Céline Henoumont,
  • Vera Djouana Kenfack,
  • Vincent Lemaur,
  • Roberto Lazzaroni,
  • Sébastien Boutry,
  • Luce Vander Elst,
  • Robert N. Muller and
  • Sophie Laurent

One major goal in medical imaging is the elaboration of more efficient contrast agents (CAs). Those agents need to be optimized for the detection of affected tissues such as cancers or tumors while decreasing the injected quantity of agents. The para...

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Magnetochemistry - ISSN 2312-7481